Ireland
Perspectives and Prospects of Underground Hydrogen Storage and Natural Hydrogen
Jun 2022
Publication
Hydrogen is considered the fuel of the future due to its cleaner nature compared to methane and gasoline. Therefore renewable hydrogen production technologies and long-term affordable and safe storage have recently attracted significant research interest. However natural underground hydrogen production and storage have received scant attention in the literature despite its great potential. As such the associated formation mechanisms geological locations and future applications remain relatively under-explored thereby requiring further investigation. In this review the global natural hydrogen formation along with reaction mechanisms (i.e. metamorphic processes pyritization and serpentinization reactions) as well as the suitable geological locations (i.e. ophiolites organic-rich sediments fault zones igneous rocks crystalline basements salt bearing strata and hydrocarbon-bearing basins) are discussed. Moreover the underground hydrogen storage mechanisms are detailed and compared with underground natural gas and CO2 storage. Techno-economic analyses of large-scale underground hydrogen storage are presented along with the current challenges and future directions.
Tourist Preferences for Fuel Cell Vehicle Rental: Going Green with Hydrogen on the Island of Tenerife
Mar 2023
Publication
Using a discrete choice experiment (DCE) a survey of international tourists on the island of Tenerife is conducted to examine preferences for fuel cell vehicle (FCV) rental while on vacation. Survey respondents were generally supportive of FCVs and willing to hire one as part of their trip but for most individuals this is contingent on an adequate fuel station infrastructure. A latent class model was used to identify three distinct groups; one of which potentially represent early adopters e they have a high willingness-to-pay (WTP) for green hydrogen and are more likely to accept a low number of fuel stations but it could be challenging to convince them to use FCVs if they are not run on green hydrogen.
Green Hydrogen Integration in Aluminium Recycling: Techno-economic Analysis Towards Sustainability Transition in the Expanding Aluminium Market
Feb 2024
Publication
The use of aluminum-based products is widespread and growing particularly in industries such as automotive food packaging and construction. Obtaining aluminum is expensive and energy-intensive making the recycling of existing products essential for economic and environmental viability. This work explores the potential of using green hydrogen as a replacement for natural gas in the smelting and refining furnaces in aluminum recycling facilities. The adoption of green hydrogen has the potential to curtail approximately 4.54 Ktons/year of CO2 emissions rendering it a sustainable and economically advantageous solution. The work evaluates the economic viability of a case study through assessing the Net Present Value (NPV) and the Internal Rate of Return (IRR). Furthermore it is employed single- and multi-parameter sensitivity analyses to obtain insight on the most relevant conditions to achieve economic viability. Results demonstrate that integrating on-site green hydrogen generation yields a favorable NPV of €57370 an IRR of 9.83% and a 19.63-year payback period. The primary factors influencing NPV are the initial electricity consumption stack and the H2 price.
Integration of Underground Green Hydrogen Storage in Hybrid Energy Generation
May 2024
Publication
One of the major challenges in harnessing energy from renewable sources like wind and solar is their intermittent nature. Energy production from these sources can vary based on weather conditions and time of day making it essential to store surplus energy for later use when there is a shortfall. Energy storage systems play a crucial role in addressing this intermittency issue and ensuring a stable and reliable energy supply. Green hydrogen sourced from renewables emerges as a promising solution to meet the rising demand for sustainable energy addressing the depletion of fossil fuels and environmental crises. In the present study underground hydrogen storage in various geological formations (aquifers depleted hydrocarbon reservoirs salt caverns) is examined emphasizing the need for a detailed geological analysis and addressing potential hazards. The paper discusses challenges associated with underground hydrogen storage including the requirement for extensive studies to understand hydrogen interactions with microorganisms. It underscores the importance of the issue with a focus on reviewing the the various past and present hydrogen storage projects and sites as well as reviewing the modeling studies in this field. The paper also emphasizes the importance of incorporating hybrid energy systems into hydrogen storage to overcome limitations associated with standalone hydrogen storage systems. It further explores the past and future integrations of underground storage of green hydrogen within this dynamic energy landscape.
Thermodynamic Modelling and Optimisation of a Green Hydrogen-blended Syngas-fueled Integrated PV-SOFC System
Sep 2023
Publication
Developing an effective energy transition roadmap is crucial in the face of global commitments to achieve net zero emissions. While renewable power generation systems are expanding challenges such as curtailments and grid constraints can lead to energy loss. To address this surplus electricity can be converted into green hydrogen serving as a key component in the energy transition. This research explores the use of renewable solar energy for powering a proton exchange membrane electrolyser to produce green hydrogen while a downdraft gasifier fed by municipal solid waste generates hydrogen-enriched syngas. The blended fuel is then used to feed a Solid Oxide Fuel Cell (SOFC) system. The study investigates the impact of hydrogen content on the performance of the fuel cell-based power plant from thermodynamics and exergoeconomic perspectives. Multiobjective optimisation using a genetic algorithm identifies optimal operating conditions for the system. Results show that blending hydrogen with syngas increases combined heat and power efficiency by up to 3% but also raises remarkably the unit product cost and reduces carbon dioxide emissions. Therefore the optimal values for hydrogen content current density temperatures and other parameters are determined. These findings contribute to the design and operation of an efficient and sustainable energy generation system.
A Flexible Techno-economic Analysis Tool for Regional Hydrogen Hubs - A Case Study for Ireland
Apr 2023
Publication
The increasing urgency with which climate change must be addressed has led to an unprecedented level of interest in hydrogen as a clean energy carrier. Much of the analysis of hydrogen until this point has focused predominantly on hydrogen production. This paper aims to address this by developing a flexible techno-economic analysis (TEA) tool that can be used to evaluate the potential of future scenarios where hydrogen is produced stored and distributed within a region. The tool takes a full year of hourly data for renewables availability and dispatch down (the sum of curtailment and constraint) wholesale electricity market prices and hydrogen demand as well as other user-defined inputs and sizes electrolyser capacity in order to minimise cost. The model is applied to a number of case studies on the island of Ireland which includes Ireland and Northern Ireland. For the scenarios analysed the overall LCOH ranges from V2.75e3.95/kgH2. Higher costs for scenarios without access to geological storage indicate the importance of cost-effective storage to allow flexible hydrogen production to reduce electricity costs whilst consistently meeting a set demand.
A Techno-economic Analysis of Global Renewable Hydrogen Value Chains
Jul 2024
Publication
Many countries especially those with a high energy demand but insufficient renewable resources are currently investigating the role that imported low carbon hydrogen may play in meeting future energy requirements and emission reduction targets. A future hydrogen economy is uncertain and predicated on reduced price of hydrogen delivered to customers. Current hydrogen production steam reforming of natural gas or coal gasification is co-located to its end-use as a chemical feedstock. Large-scale multi-source value chains of hydrogen needed to support its use for energy are still at concept phase. This research investigates the combination of technical and economic factors which will determine the viability and competitiveness of two competing large scale renewable hydrogen value chains via ammonia and liquid hydrogen. Using a techno-economic model an evaluation of whether green hydrogen exports to Germany from countries with low-cost renewable electricity production but high-costs of storage distribution and transport will be economically competitive with domestic renewable hydrogen production is conducted. The model developed in Python calculates costs and energy losses for each step in the value chain. This includes production from an optimised combination of solar and/or wind generation capacity optimised storage requirements conversion to ammonia or liquid hydrogen distribution shipping and reconversion. The model can easily be applied to any scenario by changing the inputs and was used to compare export from Chile Namibia and Morocco with production in Germany using a 1 GW electrolyser and 2030 cost scenario in each case.
An Assessment of Decarbonisation Pathways for Intercontinental Deep-sea Shipping Using Power-to-X Fuels
Aug 2024
Publication
Shipping corridors act as the arteries of the global economy. The maritime shipping sector is also a major source of greenhouse gas emissions accounting for 2.9% of the global total. The international nature of the shipping sector combined with issues surrounding the use of battery technology means that these emissions are considered difficult to eliminate. This work explores the transition to renewable fuels by examining the use of electrofuels (in the form of liquid hydrogen methane methanol ammonia and Fischer-Tropsch fuel) to decarbonise large container ships from a technical economic and environmental perspective. For an equivalent range to current fossil fuel vessels the cargo capacity of vessels powered by electrofuels decreases by between 3% and 16% depending on the fuel of choice due to the lower energy density compared with conventional marine fuels. If vessel operators are willing to sacrifice range cargo space can be preserved by downsizing onboard energy storage which necessitates more frequent refuelling. For a realistic green hydrogen cost of €3.5/kg (10.5 €c/kWh) in 2030 the use of electrofuels in the shipping sector results in an increase in the total cost of ownership of between 124% and 731% with liquid hydrogen in an internal combustion engine being the most expensive and methanol in an internal combustion engine resulting in the lowest cost increase. Despite this we find that the increased transportation costs of some consumer goods to be relatively small adding for example less than €3.27 to the cost of a laptop. In general fuels which do not require cryogenic storage and can be used in internal combustion engines result in the lowest cost increases. For policymakers reducing the environmental impact of the shipping sector is a key priority. The use of liquid hydrogen which results in the largest cost increase offers a 70% reduction in GHG emissions for an electricity carbon intensity of 80 gCO2e/ kWh which is the greatest reduction of all fuels assessed in this work. A minimum carbon price of €400/tCO2 is required to allow these fuels to reach parity with conventional shipping operations. To meet European Union emissions reductions targets electricity with an emissions intensity below 40 gCO2e/kWh is required which suggests that for electrofuels to be truly sustainable direct connection with a source of renewable electricity is required.
Above-ground Hydrogen Storage: A State-of-the-art Review
Nov 2024
Publication
Hydrogen is increasingly recognized as a clean energy alternative offering effective storage solutions for widespread adoption. Advancements in storage electrolysis and fuel cell technologies position hydrogen as a pathway toward cleaner more efficient and resilient energy solutions across various sectors. However challenges like infrastructure development cost-effectiveness and system integration must be addressed. This review comprehensively examines above-ground hydrogen storage technologies and their applications. It highlights the importance of established hydrogen fuel cell infrastructure particularly in gaseous and LH2 systems. The review favors material-based storage for medium- and long-term needs addressing challenges like adverse thermodynamics and kinetics for metal hydrides. It explores hydrogen storage applications in mobile and stationary sectors including fuel-cell electric vehicles aviation maritime power generation systems off-grid stations power backups and combined renewable energy systems. The paper underscores hydrogen’s potential to revolutionize stationary applications and co-generation systems highlighting its significant role in future energy landscapes.
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