United Kingdom
Assessment of the Effects of Inert Gas and Hydrocarbon Fuel Dilution on Hydrogen Flames
Sep 2009
Publication
To advance hydrogen into the energy market it is necessary to consider risk assessment for scenarios that are complicated by accidental hydrogen release mixing with other combustible hydrocarbon fuels. The paper is aimed at examining the effect of mixing the hydrocarbon and inert gas into the hydrogen flame on the kinetic mechanisms the laminar burning velocity and the flame stability. The influences of hydrogen concentration on the flame burning velocity were determined for the hydrogen/propane (H2-C3H8) hydrogen/ethane (H2-C2H6) hydrogen/methane (H2-CH4) and hydrogen/carbon dioxide (H2-CO2) mixtures. Experimental tests were carried out to determine the lift-off blow-out and blowoff stability limits of H2 H2-C3H8 H2-C2H6 H2-CH4 and H2-CO2 jet flames in a 2 mm diameter burner. The kinetic mechanisms of hydrogen interacting with C3 C2 and C1 fuels is analysed using the kinetic mechanisms for hydrocarbon combustion.
Hydrogen Production from Biomass and Organic Waste Using Dark Fermentation: An Analysis of Literature Data on the Effect of Operating Parameters on Process Performance
Jan 2022
Publication
In the context of hydrogen production from biomass or organic waste with dark fermentation this study analysed 55 studies (339 experiments) in the literature looking for the effect of operating parameters on the process performance of dark fermentation. The effect of substrate concentration pH temperature and residence time on hydrogen yield productivity and content in the biogas was analysed. In addition a linear regression model was developed to also account for the effect of nature and pretreatment of the substrate inhibition of methanogenesis and continuous or batch operating mode. The analysis showed that the hydrogen yield was mainly affected by pH and residence time with the highest yields obtained for low pH and short residence time. High hydrogen productivity was favoured by high feed concentration short residence time and low pH. More modest was the effect on the hydrogen content. The mean values of hydrogen yield productivity and content were respectively 6.49% COD COD−1 135 mg L−1 d −1 51% v/v while 10% of the considered experiments obtained yield productivity and content of or higher than 15.55% COD COD−1 305.16 mg L−1 d −1 64% v/v. Overall this study provides insight into how to select the optimum operating conditions to obtain the desired hydrogen production.
Numerical Study of Hydrogen Explosions in a Vehicle Refill Environment
Sep 2009
Publication
Numerical simulations have been carried out for pressurised hydrogen release through a nozzle in a simulated vehicle refilling environment of an experiment carried out in a joint industry project by Shell bp Exxon and the UK HSE Shirvill[1]. The computational domain mimics the experimental set up for a vertical downwards release in a vehicle refuelling environment. Due to lack of detailed data on pressure decay in the storage cylinder following the release a simple analytical model has also been developed to provide the transient pressure conditions at nozzle exit. The modelling is carried out using the traditional Computational fluid dynamics (CFD) approach based on Reynolds averaged Navier Stokes equations. The Pseudo diameter approach is used to bypass the shock-laden flow structure in the immediate vicinity of the nozzle. For combustion the Turbulent Flame Closure (TFC) model is used while the shear stress transport (SST) model is used for turbulence
Numerical Study of Spontaneous Ignition in Pressurized Hydrogen Release Through a Length of Tube with Local Contraction
Sep 2011
Publication
Numerical investigations have been conducted on the effect of the internal geometry of a local contraction on the spontaneous ignition of pressurized hydrogen release through a length of tube using a 5th-order WENO scheme. A mixture-averaged multi-component approach was used for accurate calculation of molecular transport. The auto-ignition and combustion chemistry were accounted for using a 21-step kinetic scheme. It is found that a local contraction can significantly facilitate the occurrence of spontaneous ignition by producing elevated flammable mixture and enhancing turbulent mixing from shock formation reflection and interaction. The first ignition kernel is observed upstream the contraction. It then quickly propagates along the contact interface and transits to a partially premixed flame due to the enhanced turbulent mixing. The partially premixed flames are highly distorted and overlapped with each other. Flame thickening is observed which is due to the merge of thin flames. The numerical predictions suggested that sustained flames could develop for release pressure as low as 25 bar. For the release pressure of 18 bar spontaneous ignition was predicted but the flame was soon quenched. To some extent this finding is consistent with Dryer et al.'s experimental observation in that the minimum release pressure required to induce a spontaneous ignition for the release through a tube with internal geometries is only 20.4 bar.
Numerical Study on Spontaneous Ignition of Pressurized Hydrogen Release Through a Length of Tube
Sep 2009
Publication
The issue of spontaneous ignition of highly pressurized hydrogen release is of important safety concern e.g. in the assessment of risk and design of safety measures. This paper reports on recent numerical investigation of this phenomenon through releases via a length of tube. This mimics a potential accidental scenario involving release through instrument line. The implicit large eddy simulation (ILES) approach was used with the 5th-order weighted essentially non-oscillatory (WENO) scheme. A mixture-averaged multi-component approach was used for accurate calculation of molecular transport. The thin flame was resolved with fine grid resolution and the autoignition and combustion chemistry were accounted for using a 21-step kinetic scheme.<br/>The numerical study revealed that the finite rupture process of the initial pressure boundary plays an important role in the spontaneous ignition. The rupture process induces significant turbulent mixing at the contact region via shock reflections and interactions. The predicted leading shock velocity inside the tube increases during the early stages of the release and then stabilizes at a nearly constant value which is higher than that predicted by one-dimensional analysis. The air behind the leading shock is shock-heated and mixes with the released hydrogen in the contact region. Ignition is firstly initiated inside the tube and then a partially premixed flame is developed. Significant amount of shock-heated air and well developed partially premixed flames are two major factors providing potential energy to overcome the strong under-expansion and flow divergence following spouting from the tube.<br/>Parametric studies were also conducted to investigate the effect of rupture time release pressure tube length and diameter on the likelihood of spontaneous ignition. It was found that a slower rupture time and a lower release pressure will lead to increases in ignition delay time and hence reduces the likelihood of spontaneous ignition. If the tube length is smaller than a certain value even though ignition could take place inside the tube the flame is unlikely to be sufficiently strong to overcome under-expansion and flow divergence after spouting from the tube and hence is likely to be quenched.
The Fifth Carbon Budget: The Next Step Towards a Low-carbon Economy
Nov 2015
Publication
This report sets out our advice on the fifth carbon budget covering the period 2028-2032 as required under Section 4 of the Climate Change Act; the Government will propose draft legislation for the fifth budget in summer 2016.
An Independent Assessment of the UK’s Clean Growth Strategy: From Ambition to Action
Nov 2018
Publication
This report provides the Committee on Climate Change’s response to the UK Government’s Clean Growth Strategy.
The report finds that:
The report finds that:
- The Government has made a strong commitment to achieving the UK’s climate change targets.
- Policies and proposals set out in the Clean Growth Strategy will need to be firmed up.
- Gaps to meeting the fourth and fifth carbon budgets remain. These gaps must be closed.
- Risks of under-delivery must be addressed and carbon budgets met on time.
Hydrogen in a Low-carbon Economy
Nov 2018
Publication
This report by the Committee on Climate Change (CCC) assesses the potential role of hydrogen in the UK’s low-carbon economy.
It finds that hydrogen:
It finds that hydrogen:
- is a credible option to help decarbonise the UK energy system but its role depends on early Government commitment and improved support to develop the UK’s industrial capability
- can make an important contribution to long-term decarbonisation if combined with greater energy efficiency cheap low-carbon power generation electrified transport and new ‘hybrid’ heat pump systems which have been successfully trialled in the UK
- could replace natural gas in parts of the energy system where electrification is not feasible or is prohibitively expensive for example in providing heat on colder winter days industrial heat processes and back-up power generation
- is not a ‘silver bullet’ solution; the report explores some commonly-held misconceptions highlighting the need for careful planning
- Government must commit to developing a low-carbon heat strategy within the next three years
- Significant volumes of low-carbon hydrogen should be produced in a carbon capture and storage (CCS) ‘cluster’ by 2030 to help the industry grow
- Government must support the early demonstration of the everyday uses of hydrogen in order to establish the practicality of switching from natural gas to hydrogen
- There is low awareness amongst the general public of reasons to move away from natural gas heating to low-carbon alternatives
- A strategy should be developed for low-carbon heavy goods vehicles (HGVs) which encourages a move away from fossil fuels and biofuels to zero-emission solutions by 2050
Public Acceptability of the Use of Hydrogen for Heating and Cooking in the Home: Results from Qualitative and Quantitative Research in UK<br/>Executive Summary
Nov 2018
Publication
This report for the CCC by Madano and Element Energy assesses the public acceptability of two alternative low-carbon technologies for heating the home: hydrogen heating and heat pumps.
These technologies could potentially replace natural gas in many UK households as part of the government’s efforts to decrease carbon emissions in the UK.
The report’s key findings are:
These technologies could potentially replace natural gas in many UK households as part of the government’s efforts to decrease carbon emissions in the UK.
The report’s key findings are:
- carbon emissions reduction is viewed as an important issue but there is limited awareness of the need to decarbonise household heating or the implications of switching over to low-carbon heating technologies
- acceptability of both heating technologies is limited by a lack of perceived tangible consumer benefit which has the potential to drive scepticism towards the switch over more generally
- heating technology preferences are not fixed at this stage although heat pumps appear to be the favoured option in this research studythree overarching factors were identified as influencing preferences for heating technologies.
- perceptions of the negative installation burden
- familiarity with the lived experience of using the technologies for heating
- perceptions of how well the technologies would meet modern heating needs both hydrogen heating and heat pumps face significant challenges to secure public acceptability
Meeting Carbon Budgets – Ensuring a Low-carbon Recovery
Jun 2010
Publication
As part of its statutory role the Committee provides annual reports to Parliament on the progress that Government is making in meeting carbon budgets and in reducing emissions of greenhouse gases.<br/>Meeting Carbon Budgets – ensuring a low-carbon recovery is the Committee’s 2nd progress report. Within this report we assess the latest emissions data and determine whether emissions reductions have occurred as a result of the recession or as a result of other external factors. We assess Government’s progress towards achieving emissions reductions in 4 key areas of: Power Buildings and Industry Transport and Agriculture.
Reducing Emissions in Scotland – 2018 Progress Report
Sep 2019
Publication
This is the Committee’s seventh report on Scotland’s progress towards meetings emissions targets as requested by Scottish Ministers under the Climate Change (Scotland) Act 2009.
Overall Scotland continues to outperform the rest of the UK in reducing its greenhouse gas emissions but successful strategies for energy and waste mask a lack of progress in other parts of the Scottish economy.
The report shows that Scotland’s total emissions fell by 10% in 2016 compared to 2015. The lion’s share of this latest drop in emissions came from electricity generation.
The key findings are:
Overall Scotland continues to outperform the rest of the UK in reducing its greenhouse gas emissions but successful strategies for energy and waste mask a lack of progress in other parts of the Scottish economy.
The report shows that Scotland’s total emissions fell by 10% in 2016 compared to 2015. The lion’s share of this latest drop in emissions came from electricity generation.
The key findings are:
- Overall Scotland met its annual emissions targets in 2016.
- Scotland’s progress in reducing emissions from the power sector masks a lack of action in other areas particularly transport agriculture forestry and land use.
- Low-carbon heat transport agriculture and forestry sector policies need to improve in order to hit 2032 emissions targets.
- The Scottish Government’s Climate Change Plan – published in February 2018 – now has sensible expectations across each sector to reduce emissions.
Experimental Releases of Liquid Hydrogen
Sep 2011
Publication
If the hydrogen economy is to progress more hydrogen refuelling stations are required. In the short term in the absence of a hydrogen distribution network the most likely means of supplying the refuelling stations will be by liquid hydrogen road tanker. This development will clearly increase the number of tanker offloading operations significantly and these may need to be performed in more challenging environments with close proximity to the general public. The work described in this paper was commissioned in order to determine the hazards associated with liquid hydrogen spills onto the ground at rates typical for a tanker hose failure during offloading.
Experiments have been performed to investigate spills of liquid hydrogen at a rate of 60 litres per minute. Measurements were made on both unignited and ignited releases.
These include:
Experiments have been performed to investigate spills of liquid hydrogen at a rate of 60 litres per minute. Measurements were made on both unignited and ignited releases.
These include:
- Concentration of hydrogen in air thermal gradient in the concrete substrate liquid pool formation and temperatures within the pool
- Flame velocity within the cloud thermal radiation IR and visible spectrum video records.
- Sound pressure measurements
- An estimation of the extent of the flammable cloud was made from visual observation video IR camera footage and use of a variable position ignition source.
Modelling of Lean Uniform and Non-Uniform Hydrogen-Air Mixture Explosions in a Closed Vessel
Sep 2009
Publication
Simulation of hydrogen-air mixture explosions in a closed large-scale vessel with uniform and nonuniform mixture compositions was performed by the group of partners within the EC funded project “Hydrogen Safety as an Energy Carrier” (HySafe). Several experiments were conducted previously by Whitehouse et al. in a 10.7 m3 vertically oriented (5.7-m high) cylindrical facility with different hydrogen-air mixture compositions. Two particular experiments were selected for simulation and comparison as a Standard Benchmark Exercise (SBEP) problem: combustion of uniform 12.8% (vol.) hydrogen-air mixture and combustion of non-uniform hydrogen-air mixture with average 12.6% (vol.) hydrogen concentration across the vessel (vertical stratification 27% vol. hydrogen at the top of the vessel 2.5% vol. hydrogen at the bottom of the vessel); both mixtures were ignited at the top of the vessel. The paper presents modelling approaches used by the partners comparison of simulation results against the experiment data and conclusions regarding the non-uniform mixture combustion modelling in real-life applications.
Heat Networks 2020
Dec 2020
Publication
This publication by the Department for Business Energy and Industrial Strategy (BEIS) brings together heat networks investment opportunities in England and Wales. The opportunities present a wide range of projects supported through the development stages by the Heat Networks Delivery Unit (HNDU) and projects seeking capital support from the Heat Networks Investment Project (HNIP).
The publication includes a list of one-page summaries for each of the heat network projects supported by BEIS which set out details of HNDU and HNIP projects where projects have provided enough detail in time for publication.
For HNIP this represents projects which have submitted at least a pre-application to the Delivery Partner Triple Point Heat Networks Investment Management since the scheme opened in February 2019. As a number of the projects are at different stages of development some of the costs aren’t currently available or will be subject to project consent and change as they progress through the project lifecycle.
Related Document: Heat Network Detailed Project Development Resource: Guidance on Strategic and Commercial Case
The publication includes a list of one-page summaries for each of the heat network projects supported by BEIS which set out details of HNDU and HNIP projects where projects have provided enough detail in time for publication.
For HNIP this represents projects which have submitted at least a pre-application to the Delivery Partner Triple Point Heat Networks Investment Management since the scheme opened in February 2019. As a number of the projects are at different stages of development some of the costs aren’t currently available or will be subject to project consent and change as they progress through the project lifecycle.
Related Document: Heat Network Detailed Project Development Resource: Guidance on Strategic and Commercial Case
Predicting the Probability of Failure of Gas Pipelines Including Inspection and Repair Procedures
Sep 2007
Publication
This paper is concerned with predicting the impact on the probability of failure of adding hydrogen to the natural gas distribution network. Hydrogen has been demonstrated to change the behaviour of crack like defects which may affect the safety of pipeline or make it more expensive to operate. A tool has been developed based on a stochastic approach to assess the failure probability of the gas pipeline due to the existence of crack-lie defects including the operational aspects of the pipeline such as inspection and repair procedures. With various parameters such as crack sizes material properties internal pressure modelled as uncertainties a reliability analysis based on failure assessment diagram is performed through direct Monte Carlo simulation. Inspection and repair procedures are included in the simulation to enable realistic pipeline maintenance scenarios to be simulated. In the data preparation process the accuracy of the probabilistic definition of the uncertainties is crucial as the results are very sensitive to certain variables such as the crack depth length and crack growth rate. The failure probabilities of each defect and the whole pipeline system can be obtained during simulation. Different inspection and repair criteria are available in the Monte Carlo simulation whereby an optimal maintenance strategy can be obtained by comparing different combinations of inspection and repair procedures. The simulation provides not only data on the probability of failure but also the predicted number of repairs required over the pipeline life thus providing data suitable for economic models of the pipeline management. This tool can be also used to satisfy certain target reliability requirement. An example is presented comparing a natural gas pipeline with a pipeline containing hydrogen.
Hydrogen Impact on Gas Engine CHP - Cadent Ltd
Feb 2019
Publication
The key project objectives include:
The output from this project will also inform the HyDeploy NIC project in relation to potential hydrogen content limits. The project will be presented at the IGEM Gas Quality Working Group (IGEM GQWG).
This report and any attachment is freely available on the ENA Smarter Networks Portal here. IGEM Members can download the report and any attachment directly by clicking on the pdf icon above.
- Understand the range size type mode of operation and control system of installed gas engines in the UK. This will include equipment for CHP and for stand-by power operation.
- Produce data sets on the impact of hydrogen on gas engine operational performance.
- Develop knowledge on the impact of hydrogen content on the operation of the gas engine including overall efficiency changes to emissions profiles overall system operability.
- Providing outline guidance on a potential hydrogen limit that should be considered regarding use of natural gas/hydrogen mixed fuels in gas engines.
- Outlining a high-level view on the reliability and impact on maintenance and replacement regimes if gas engines operate on natural gas/hydrogen mixed fuels for extended time periods.
- Highlight any existing barriers to use of natural gas and hydrogen blends in gas engine and through contact with OEMs develop an understanding of future technology developments that may be needed to enable the use of “high” hydrogen blends.
The output from this project will also inform the HyDeploy NIC project in relation to potential hydrogen content limits. The project will be presented at the IGEM Gas Quality Working Group (IGEM GQWG).
This report and any attachment is freely available on the ENA Smarter Networks Portal here. IGEM Members can download the report and any attachment directly by clicking on the pdf icon above.
World Energy Issues Monitor 2019 Managing the Grand Energy Transition
Oct 2019
Publication
This is the tenth consecutive year of the World Energy Council’s (the Council) annual survey of key challenges and opportunities facing energy leaders in managing and shaping Energy Transitions. This year’s Issues Monitor report provides seven global maps six regional maps and fifty national maps.
These maps have been developed by analysing the responses of nearly 2300 energy leaders drawn from across the Council’s diverse and truly global energy community.
The Council’s Issues Monitor identifies the strategic energy landscape of specific countries and regions in the world through an analysis of 42 energy issues and 4 digitalisation-specific issues affecting the energy system. It provides a unique reality check and horizon scanning of persistent and emerging concerns involved in whole energy systems transition. This year’s report welcomes a significant increase in both the participation of global leaders (up over 75% from 1300 to nearly 2300) as well as the participation of 86 countries.
Each Issue Map provides a visual snapshot of the uncertainties and action priorities that energy policymakers CEOs and leading experts strive to address to shape and manage successful Energy
Transitions. Maps can be used in the following ways:
These maps have been developed by analysing the responses of nearly 2300 energy leaders drawn from across the Council’s diverse and truly global energy community.
The Council’s Issues Monitor identifies the strategic energy landscape of specific countries and regions in the world through an analysis of 42 energy issues and 4 digitalisation-specific issues affecting the energy system. It provides a unique reality check and horizon scanning of persistent and emerging concerns involved in whole energy systems transition. This year’s report welcomes a significant increase in both the participation of global leaders (up over 75% from 1300 to nearly 2300) as well as the participation of 86 countries.
Each Issue Map provides a visual snapshot of the uncertainties and action priorities that energy policymakers CEOs and leading experts strive to address to shape and manage successful Energy
Transitions. Maps can be used in the following ways:
- To promote a shared understanding of successful Energy Transitions
- To appreciate and contrast regional variations to better understand differing priorities and areas of concern
- To follow the evolution of specific technology trends related to the energy sector
Initial Assessment of the Impact of Jet Flame Hazard from Hydrogen Cars in Road Tunnels and the Implication on Hydrogen Car Design
Sep 2007
Publication
Underground or partial underground tunnels form a very important part of modern road transportation systems. As the development of hydrogen cars advancing into the markets it is unavoidable in the near future that hydrogen cars would become the users of ordinary road tunnels. This paper discusses potential fire scenarios and fire hazards of hydrogen cars in road tunnels and implications on the fire safety measures and ventilation systems in existing tunnels. The information needed for carry out risk assessment of hydrogen cars in road tunnels are discussed. hydrogen has a low ignition energy and wide flammable range suggesting that leaks have a high probability of ignition and result hydrogen flame. CFD simulations of hydrogen fires in a full scale 5m by 5m square cross-section tunnel were carried out. The effect of the ventilation on controlling the back-layering and the downstream flame are discussed.
Allowable Hydrogen Permeation Rate From Road Vehicle Compressed Gaseous Storage Systems In Garages- Part 1- Introduction, Scenarios, and Estimation of an Allowable Permeation Rate
Sep 2009
Publication
The paper presents an overview of the main results of the EC NOE HySafe activity to estimate an allowable hydrogen permeation rate for automotive legal requirements and standards. The work was undertaken as part of the HySafe internal project InsHyde.<br/>A slow long term hydrogen release such as that due to permeation from a vehicle into an inadequately ventilated enclosed structure is a potential risk associated with the use of hydrogen in automotive applications. Due to its small molecular size hydrogen permeates through the containment materials found in compressed gaseous hydrogen storage systems and is an issue that requires consideration for containers with non-metallic (polymer) liners. Permeation from compressed gaseous hydrogen storage systems is a current hydrogen safety topic relevant to regulatory and standardisation activities at both global and regional levels.<br/>Various rates have been proposed in different draft legal requirements and standards based on different scenarios and the assumption that hydrogen dispenses homogeneously. This paper focuses on the development of a methodology by HySafe Partners (CEA NCSRD. University of Ulster and Volvo Technology) to estimate an allowable upper limit for hydrogen permeation in automotive applications by investigating the behaviour of hydrogen when released at small rates with a focus on European scenario. The background to the activity is explained. reasonable scenarios are identified a methodology proposed and a maximum hydrogen permeation rate from road vehicles into enclosed structures is estimated The work is based on conclusions from the experimental and numerical investigations described by CEA NCSRD and the University of Ulster in related papers.
SGN Aberdeen Vision Project: Final Report
May 2020
Publication
The Aberdeen Vision Project could deliver CO2 savings of 1.5MtCO2/y compared with natural gas. A dedicated pipeline from St Fergus to Aberdeen would enable the phased transfer of the Aberdeen regional gas distribution system to 20% then 100% hydrogen.
The study has demonstrated that 2% hydrogen can be injected into the National Transmission System (NTS) at St Fergus and its distribution through the system into the gas distribution network. Due to unique regional attributes the Aberdeen region could lead the UK in the conversion to largescale clean hydrogen. A 200MW hydrogen generation plant is planned to suit 2% blend into the NTS followed by a build out to supply the Aberdeen gas networks and to enable low cost hydrogen transport applications.
This report and any attachment is freely available on the ENA Smarter Networks Portal here. IGEM Members can download the report and any attachment directly by clicking on the pdf icon above.
The study has demonstrated that 2% hydrogen can be injected into the National Transmission System (NTS) at St Fergus and its distribution through the system into the gas distribution network. Due to unique regional attributes the Aberdeen region could lead the UK in the conversion to largescale clean hydrogen. A 200MW hydrogen generation plant is planned to suit 2% blend into the NTS followed by a build out to supply the Aberdeen gas networks and to enable low cost hydrogen transport applications.
This report and any attachment is freely available on the ENA Smarter Networks Portal here. IGEM Members can download the report and any attachment directly by clicking on the pdf icon above.
No more items...