United Kingdom
Economic Performance Evaluation of Flexible Centralised and Decentralised Blue Hydrogen Production Systems Design Under Uncertainty
Sep 2023
Publication
Blue hydrogen is viewed as an important energy vector in a decarbonised global economy but its large-scale and capital-intensive production displays economic performance vulnerabities in the face of increased market and regulatory uncertainty. This study analyses flexible (modular) blue hydrogen production plant designs and evaluates their effectiveness to enhance economic performance under uncertainty. The novelty of this work lies in the development of a comprehensive techno-economic evaluation framework that considers flexible centralised and decentralised blue hydrogen plant design alternatives in the presence of irreducible uncertainty whilst explicitly considering the time value of money economies of scale and learning effects. A case study of centralised and decentralised blue hydrogen production for the transport sector in the San Francisco area is developed to highlight the underlying value of flexibility. The proposed methodological framework considers various blue hydrogen plant designs (fixed phased and flexible) and compares them using relevant economic indicators (net present value (NPV) capex value-at-risk/gain etc.) through a detailed Monte Carlo simulation framework. Results indicate that flexible centralised hydrogen production yields greater economic value than alternative designs despite the associated cost-premium of modularity. It is also shown that the value of flexibility increases under greater uncertainty higher learning rates and weaker economies of scale. Moreover sensitivity analysis reveals that flexible design remains the preferred investment option over a wide range of market and regulatory conditions except for high initial hydrogen demand. Finally this study demonstrates that major regulatory and market uncertainties surrounding blue hydrogen production can be effectively managed through the application of flexible engineering system design that protects the investment from major downside risks whilst allowing access to favourable upside opportunities.
Towards a Unified Theory of Domestic Hydrogen Acceptance: An Integrative, Comparative Review
Dec 2023
Publication
Hydrogen energy technologies are envisioned to play a critical supporting role in global decarbonisation. While low-carbon hydrogen is primarily targeted for reducing industrial emissions alongside decarbonising parts of the transport sector environmental benefits could also be achieved in the residential context. Presently gasdependent countries such as Japan and the United Kingdom are assessing the feasibility of deploying hydrogen home appliances as part of their national energy strategies. However prospects for the transition will hinge on consumer acceptance alongside an array of other socio-technical factors. To support potential ambitions for large-scale and sustained technology diffusion this study advances a Unified Theory of Domestic Hydrogen Acceptance. Through an integrative comparative literature review targeting hydrogen and domestic energy studies the paper proposes a novel Domestic Hydrogen Acceptance Model (DHAM) which accounts for the cognitive and emotional dimensions of human perceptions. Through this dual interplay the proposed framework can increase the predictive power of hydrogen acceptance models.
Numerical Modelling of a Heavy-duty Diesel-hydrogen Dual-fuel Engine with Late High Pressure Hydrogen Direct Injection and Diesel Pilot
Sep 2023
Publication
Direct gaseous fuel injection in internal combustion engines is a potential strategy for improving in-cylinder combustion processes and performance while reducing emissions and increasing hydrogen energy share (HES). Through use of numerical modelling the current study explores combustion in a compression ignition engine utilising a late compression/early power stroke direct gaseous hydrogen injection ignited by a diesel pilot at up to 99% HES. The combustion process of hydrogen in this type of engine is mapped out and compared to that of the same engine using methane direct injection. Four distinct phases of combustion are found which differ from that of pure diesel operation. Interaction of the injected gas jet with the chamber walls is found to have a considerable impact on performance and emission characteristics and is a factor which needs to be explored in greater detail in future studies. Considerable performance increase and carbon-based emission reductions are identified at up to 99% HES at high load but low load performance greatly deteriorated when 95% HES was exceeded due to a much reduced diesel pilot struggling to ignite the main hydrogen injection.
Integration of Underground Green Hydrogen Storage in Hybrid Energy Generation
May 2024
Publication
One of the major challenges in harnessing energy from renewable sources like wind and solar is their intermittent nature. Energy production from these sources can vary based on weather conditions and time of day making it essential to store surplus energy for later use when there is a shortfall. Energy storage systems play a crucial role in addressing this intermittency issue and ensuring a stable and reliable energy supply. Green hydrogen sourced from renewables emerges as a promising solution to meet the rising demand for sustainable energy addressing the depletion of fossil fuels and environmental crises. In the present study underground hydrogen storage in various geological formations (aquifers depleted hydrocarbon reservoirs salt caverns) is examined emphasizing the need for a detailed geological analysis and addressing potential hazards. The paper discusses challenges associated with underground hydrogen storage including the requirement for extensive studies to understand hydrogen interactions with microorganisms. It underscores the importance of the issue with a focus on reviewing the the various past and present hydrogen storage projects and sites as well as reviewing the modeling studies in this field. The paper also emphasizes the importance of incorporating hybrid energy systems into hydrogen storage to overcome limitations associated with standalone hydrogen storage systems. It further explores the past and future integrations of underground storage of green hydrogen within this dynamic energy landscape.
Synergy of Carbon Capture, Waste Heat Recovery and Hydrogen Production for Industrial Decarbonisation
May 2024
Publication
Industry is the biggest sector of energy consumption and greenhouse gas emissions whose decarbonisation is essential to achieve the Sustainable Development Goals. Carbon capture energy efficiency improvement and hydrogen are among the main strategies for industrial decarbonization. However novel approaches are needed to address the key requirements and differences between sectors to ensure they can work together to well integrate industrial decarbonisation with heat CO2 and hydrogen. The emerging Calcium Looping (CaL) is attracting interest in designing CO2-involved chemical processes for heat capture and storage. The reversibility relatively high-temperature (600 to 900 ◦C) and high energy capacity output as well as carbon capture function make CaL well-fit for CO2 capture and utilisation and waste heat recovery from industrial flue gases. Meanwhile methane dry reforming (MDR) is a promising technology to produce blue hydrogen via the consumption of two major greenhouse gases i.e. CO2 and CH4. It has great potential to combine the two technologies to achieve insitu CO2 utilization with multiple benefits. In this paper progresses on the reaction conditions and performance of CaL for CO2 capture and industrial waste heat recovery as well as MDR were screened. Secondly recent approaches to CaL-MDR synergy have been reviewed to identify the advantages. The major challenges in such a synergistic process include MDR catalyst deactivation CaL sorbents sintering and system integration. Thirdly the paper outlooks future work to explore a rational design of a multi-function system for the proposed synergistic process.
Caveats of Green Hydrogen for Decarbonisation of Heating in Buildings
Oct 2023
Publication
Hydrogen (H2) has rapidly become a topic of great attention when discussing routes to net-zero carbon emissions. About 14% of CO2 emissions globally are directly associated with domestic heating in buildings. Replacing natural gas (NG) with H2 for heating has been highlighted as a rapid alternative for mitigating these emissions. To realise this not only the production challenges but also potential obstacles in the transmission/distribution and combustion of H2 must be technically identified and discussed. This review in addition to delineating the challenges of H2 in NG grid pipelines and H2 combustion also collates the results of the state-of-the-art technologies in H2-based heating systems. We conclude that the sustainability of water and renewable electricity resources strongly depends on sizing siting service life of electrolysis plants and post-electrolysis water disposal plans. 100% H2 in pipelines requires major infrastructure upgrades including production transmission pressurereduction stations distribution and boiler rooms. H2 leakage instigates more environmental risks than economic ones. With optimised boilers burning H2 could reduce GHG emissions and obtain an appropriate heating efficiency; more data from boiler manufacturers must be provided. Overall green H2 is not the only solution to decarbonise heating in buildings and it should be pursued abreast of other heating technologies.
Modelling Underground Hydrogen Storage: A State-of-the-art Review of Fundamental Approaches and Findings
Dec 2023
Publication
This review presents a state-of-the-art of geochemical geomechanical and hydrodynamic modelling studies in the Underground Hydrogen Storage (UHS) domain. Geochemical modelling assessed the reactivity of hydrogen and res pective fluctuations in hydrogen losses using kinetic reaction rates rock mineralogy brine salinity and the integration of hydrogen redox reactions. Existing geomechanics studies offer an array of coupled hydromechanical models suggesting a decline in rock failure during the withdrawal phase in aquifers compared to injection phase. Hydrodynamic modelling evaluations indicate the critical importance of relative permeability hysteresis in determining the UHS performance. Solubility and diffusion of hydrogen gas appear to have minimal impact on UHS. Injection and production rates cushion gas deployment and reservoir heterogeneity however significantly affect the UHS performance stressing the need for thorough modelling and experimental studies. Most of the current UHS modelling efforts focus on assessing the hydrodynamic aspects which are crucial for understanding the viability and safety of UHS. In contrast the lesser-explored geochemical and geomechanical considerations point to potential research gaps. A variety of modelling software tools such as CMG Eclipse COMSOL and PHREEQC evaluated those UHS underlying effects along with a few recent applications of datadriven-based Machine Learning (ML) techniques for enhanced accuracy. This review identified several unresolved challenges in UHS modelling: pronounced lack of expansive datasets leading to a gap between model predictions and their practical reliability; need robust methodologies capable of capturing natural subsurface heterogeneity while upscaling from precise laboratory data to field-scale conditions; demanding intensive computational resources and novel strategies to enhance simulation efficiency; and a gap in addressing geological uncertainties in subsurface environments suggesting that methodologies from oil reservoir simulations could be adapted for UHS. This comprehensive review offers a critical synthesis of the prevailing approaches challenges and research gaps in the domain of UHS thus providing a valuable reference document for further modelling efforts facilitating the informed advancements in this critical domain towards the realization of sustainable energy solutions.
Price Promises, Trust Deficits and Energy Justice: Public Perceptions of Hydrogen Homes
Oct 2023
Publication
In an era characterised by political instability economic uncertainty and mounting environmental pressures hydrogen fuel is being positioned as a critical piece of the global energy security and clean energy agenda. The policy push is noteworthy in the United Kingdom where the government is targeting industrial decarbonisation via hydrogen while exploring a potential role for hydrogen-fuelled home appliances. Despite the imperative to secure social acceptance for accelerating the diffusion of low-carbon energy technologies public perceptions of hydrogen homes remain largely underexplored by the researcher community. In response this analysis draws on extensive focus group data to understand the multi-dimensional nature of social acceptance in the context of the domestic hydrogen transition. Through an integrated mixed-methods multigroup analysis the study demonstrates that socio-political and market acceptance are strongly interlinked owing to a trust deficit in the government and energy industry coupled to underlying dissatisfaction with energy markets. At the community level hydrogen homes are perceived as a potentially positive mechanism for industrial regeneration and local economic development. Households consider short-term disruptive impacts to be tolerable provided temporary disconnection from the gas grid does not exceed three days. However to strengthen social acceptance clearer communication is needed regarding the spatial dynamics and equity implications of the transition. The analysis concludes that existing trust deficits will need to be overcome which entails fulfilling not only a ‘price promise’ on the cost of hydrogen appliances but also enacting a ‘price pledge’ on energy bills. These deliverables are fundamental to securing social acceptance for hydrogen homes.
Techno-economic Study of a 100-MW-class Multi-energy Vehicle Charging/Refueling Station: Using 100% Renewable, Liquid Hydrogen, and Superconductor Technologies
Dec 2022
Publication
Renewable energies such as the wind energy and solar energy generate low-carbon electricity which can directly charge battery electric vehicles (BEVs). Meanwhile the surplus electricity can be used to produce the “green hydrogen” which provides zero-emission hydrogen fuels to those fuel cell electric vehicles (FCEVs). In order to charge/refuel multi-energy vehicles we propose a novel scheme of hybrid hydrogen/electricity supply using cryogenic and superconducting technologies. In this scheme the green hydrogen is further liquefied into the high-density and low-pressure liquid hydrogen (LH2) for bulk energy storage and transmission. Taking the advantage of the cryogenic environment of LH2 (20 K) it can also be used as the cryogen to cool down super conducting cables to realize the virtually zero-loss power transmission from 100 % renewable sources to vehicle charging stations. This hybrid LH2/electricity energy pipeline can realize long-distance large-capacity and high efficiency clean energy transmission to fulfil the hybrid energy supply demand for BEVs and FCEVs. For the case of a 100 MW-class hybrid hydrogen/electricity supply station the system principle and energy management strategy are analyzed through 9 different operating sub-modes. The corresponding static and dynamic economic modeling are performed and the economic feasibility of the hybrid hydrogen/electricity supply is verified using life-cycle analysis. Taking an example of wind power capacity 1898 MWh and solar power capacity 1619 MWh per day the dynamic payback period is 15.06 years the profitability index is 1.17 the internal rate of return is 7.956 % and the accumulative NPV is 187.92 M$. The system design and techno-economic analysis can potentially offer a technically/economically superior solution for future multi-energy vehicle charging/refueling systems.
Techno-economic Analysis to Identify the Optimal Conditions for Green Hydrogen Production
Jun 2023
Publication
The intermittency of renewable energy sources necessitates energy storage to meet the full demand and balancing requirements of the grid. Green hydrogen (H2) is a chemical energy carrier that can be used in a flexible manner and store large amounts of energy for long periods of time. This techno-economic analysis investigates H2 production from wind using commercially available desalination and electrolysis units. Proton exchange membrane and alkaline electrolyser units are utilised and compared. The intermittency of wind is examined with comparison against grid-bought electricity. A model is developed to determine the selling price required to ensure profitability over a 10-year period. Firstly where H2 is produced using energy from the grid with electricity purchased when below a specified price point or between specified hours. In the second scenario a wind turbine is owned by the user and the electricity price is not considered while the turbine capital expenditure is. The price of H2 production from wind is found to be comparable with natural gas derived H2 at a larger scale with a minimum selling price calculated to be 4.85 £/kg at a setpoint of 500 kg of H2/hr. At a setpoint of 50 kg of H2/hr this is significantly higher at 12.10 £/kg. In both cases the alkaline electrolyser produced cheaper H2. This study demonstrates an economy of scale with H2 prices decreasing with increased scale. H2 prices are also closely linked to the capital expenditure with the equipment size space and safety identified as limiting factors.
Life-Cycle and Applicational Analysis of Hydrogen Production and Powered Inland Marine Vessels
Aug 2023
Publication
Green energy is at the forefront of current policy research and engineering but some of the potential fuels require either a lot of deeper research or a lot of infrastructure before they can be implemented. In the case of hydrogen both are true. This report aims to analyse the potential of hydrogen as a future fuel source by performing a life-cycle assessment. Through this the well-to-tank phase of fuel production and the usage phase of the system have been analysed. Models have also been created for traditional fuel systems to best compare results. The results show that hydrogen has great potential to convert marine transport to operating off green fuels when powered through low-carbon energy sources which could reduce a huge percentage of the international community’s greenhouse gas emissions. Hydrogen produced through wind powered alkaline electrolysis produced emission data 5.25 g of CO2 equivalent per MJ compared to the 210 g per MJ produced by a medium efficiency diesel equivalent system a result 40 times larger. However with current infrastructure in most countries not utilising a great amount of green energy production the effects of hydrogen usage could be more dangerous than current fuel sources owing to the incredible energy requirements of hydrogen production with even grid (UK) powered electrolysis producing an emission level of 284 g per MJ which is an increase against standard diesel systems. From this the research concludes that without global infrastructure change hydrogen will remain as a potential fuel rather than a common one.
Precise Dynamic Modelling of Real-World Hybrid Solar-Hydrogen Energy Systems for Grid-Connected Buildings
Jul 2023
Publication
Hybrid renewable hydrogen energy systems could play a key role in delivering sustainable solutions for enabling the Net Zero ambition; however the lack of exact computational modelling tools for sizing the integrated system components and simulating their real-world dynamic behaviour remains a key technical challenge against their widespread adoption. This paper addresses this challenge by developing a precise dynamic model that allows sizing the rated capacity of the hybrid system components and accurately simulating their real-world dynamic behaviour while considering effective energy management between the grid-integrated system components to ensure that the maximum possible proportion of energy demand is supplied from clean sources rather than the grid. The proposed hybrid system components involve a solar PV system electrolyser pressurised hydrogen storage tank and fuel cell. The developed hybrid system model incorporates a set of mathematical models for the individual system components. The developed precise dynamic model allows identifying the electrolyser’s real-world hydrogen production levels in response to the input intermittent solar energy production while also simulating the electrochemical behaviour of the fuel cell and precisely quantifying its real-world output power and hydrogen consumption in response to load demand variations. Using a university campus case study building in Scotland the effectiveness of the developed model has been assessed by benchmarking comparison between its results versus those obtained from a generic model in which the electrochemical characteristics of the electrolyser and fuel cell systems were not taken into consideration. Results from this comparison have demonstrated the potential of the developed model in simulating the real-world dynamic operation of hybrid solar hydrogen energy systems for grid-connected buildings while sizing the exact capacity of system components avoiding oversizing associated with underutilisation costs and inaccurate simulation.
Energy Storage Strategy - Phase 2
Feb 2023
Publication
This document is phase 2 of the energy storage strategy study and it covers the storage challenges of the energy transition. We start in section 3 by covering historical and current natural gas imports into the UK and what these could look like in the future. In section 4 we explore what demand for hydrogen could look like – this has a high level of uncertainty and future policy decisions will have significant impacts on hydrogen volumes and annual variations. We generated two hydrogen storage scenarios based on National Grid’s Future Energy Scenarios and the Climate Change Committee’s Sixth Carbon Budget to assess the future need for hydrogen storage in the UK. We also looked at an extreme weather scenario resulting from an area of high-pressure settled over the British Isles resulting in very low ambient temperatures an unusually high demand for heating and almost no wind generation. In section 5 we investigate options for hydrogen storage and build on work previously carried out by SGN. We discuss the differences between the properties of hydrogen and natural gas and how this affects line pack and depletion of line pack. We discuss flexibility on the supply and demand side and how this can impact on hydrogen storage. We provide a summary table which compares the various options for storage. In section 5 we explore hydrogen trade and options for import and export. Using information from other innovation projects we also discuss production of hydrogen from nuclear power and the impact of hybrid appliances on gas demand for domestic heat. In section 7 we discuss the outputs from a stakeholder workshop with about 40 stakeholders across industry academia and government. The workshop covered UK gas storage strategy to date hydrogen demand and corresponding storage scenarios to 2050 including consideration of seasonal variation and storage options.
Prediction of Transient Hydrogen Flow of Proton Exchange Membrane Electrolyzer Using Artificial Neural Network
Aug 2023
Publication
A proton exchange membrane (PEM) electrolyzer is fed with water and powered by electric power to electrochemically produce hydrogen at low operating temperatures and emits oxygen as a by-product. Due to the complex nature of the performance of PEM electrolyzers the application of an artificial neural network (ANN) is capable of predicting its dynamic characteristics. A handful of studies have examined and explored ANN in the prediction of the transient characteristics of PEM electrolyzers. This research explores the estimation of the transient behavior of a PEM electrolyzer stack under various operational conditions. Input variables in this study include stack current oxygen pressure hydrogen pressure and stack temperature. ANN models using three differing learning algorithms and time delay structures estimated the hydrogen mass flow rate which had transient behavior from 0 to 1 kg/h and forecasted better with a higher count (>5) of hidden layer neurons. A coefficient of determination of 0.84 and a mean squared error of less than 0.005 were recorded. The best-fitting model to predict the dynamic behavior of the hydrogen mass flow rate was an ANN model using the Levenberg–Marquardt algorithm with 40 neurons that had a coefficient of determination of 0.90 and a mean squared error of 0.00337. In conclusion optimally fit models of hydrogen flow from PEM electrolyzers utilizing artificial neural networks were developed. Such models are useful in establishing an agile flow control system for the electrolyzer system to help decrease power consumption and increase efficiency in hydrogen generation.
An Integrated Framework for Optimal Infrastructure Planning for Decarbonising Heating
Apr 2023
Publication
This paper presents the HEGIT (Heat Electricity and Gas Infrastructure and Technology) model for optimal infrastructure planning for decarbonising heating in buildings. HEGIT is an optimisation model based on Mixed Integer Linear Programming. The model co-optimises the integrated operation and capacity expansion planning of electricity and gas grids as well as heating technologies on the consumer side while maintaining the security of supply and subject to different environmental operational and system-wide constraints. The three main features of the HEGIT model are: • It incorporates an integrated unit commitment and capacity expansion problem for coordinated operation and long-term investment planning of the electricity and gas grids. • It incorporates the flexible operation of heating technologies in buildings and demand response in operation and long-term investment planning of gas and electricity grids. • It incorporates a multi-scale techno-economic representation of heating technologies design features into the whole energy system modelling and capacity planning. These features enable the model to quantify the impacts of different policies regarding decarbonising heating in buildings on the operation and long-term planning of electricity and gas grids identify the cost-optimal use of available resources and technologies and identify strategies for maximising synergies between system planning goals and minimising trade-offs. Moreover the multi-scale feature of the model allows for multi-scale system engineering analysis of decarbonising heating including system-informed heating technology design identifying optimal operational setups at the consumer end and assessing trade-offs between consumer investment in heating technologies and infrastructure requirements in different heat decarbonisation pathways.
Advancements in Hydrogen Production, Storage, Distribution and Refuelling for a Sustainable Transport Sector: Hydrogen Fuel Cell Vehicles
Jul 2023
Publication
Hydrogen is considered as a promising fuel in the 21st century due to zero tailpipe CO2 emissions from hydrogen-powered vehicles. The use of hydrogen as fuel in vehicles can play an important role in decarbonising the transport sector and achieving net-zero emissions targets. However there exist several issues related to hydrogen production efficient hydrogen storage system and transport and refuelling infrastructure where the current research is focussing on. This study critically reviews and analyses the recent technological advancements of hydrogen production storage and distribution technologies along with their cost and associated greenhouse gas emissions. This paper also comprehensively discusses the hydrogen refuelling methods identifies issues associated with fast refuelling and explores the control strategies. Additionally it explains various standard protocols in relation to safe and efficient refuelling analyses economic aspects and presents the recent technological advancements related to refuelling infrastructure. This study suggests that the production cost of hydrogen significantly varies from one technology to others. The current hydrogen production cost from fossil sources using the most established technologies were estimated at about $0.8–$3.5/kg H2 depending on the country of production. The underground storage technology exhibited the lowest storage cost followed by compressed hydrogen and liquid hydrogen storage. The levelised cost of the refuelling station was reported to be about $1.5–$8/kg H2 depending on the station's capacity and country. Using portable refuelling stations were identified as a promising option in many countries for small fleet size low-to-medium duty vehicles. Following the current research progresses this paper in the end identifies knowledge gaps and thereby presents future research directions.
Future of Hydrogen in Industry: Initial Industrial Site Surveys
Jul 2023
Publication
This is a summary report of a study which aimed to understand the safety feasibility cost and impacts for 7 industrial sites to switch from natural gas to 100% hydrogen for heating. The volunteer industrial sites:<br/>♦ are located away from industrial clusters<br/>♦ use natural gas to meet most of their energy demand<br/>♦ will likely be most impacted by decisions on the future of the natural gas grid<br/>We have published the report in order to share its findings with other industrial sites and wider industry in particular those considering hydrogen as an option for decarbonisation.<br/>Note that:<br/>♦ some work was carried out on a non-hydrogen alternative energy source but to a lesser level of detail and not to determine the optimal decarbonisation solution<br/>♦ the findings do not apply to other end user environments because of differences between these environments and the consumption of gas<br/>The study was commissioned in 2022 by the former Department for Business and Energy and undertaken by AECOM and their safety sub-contractor ESR.<br/>The evidence will inform strategic decisions in 2026 on the role of low carbon hydrogen as a replacement for natural gas heating.
Review and Meta-analysis of Recent Life Cycle Assessments of Hydrogen Production
Apr 2023
Publication
The world is facing an urgent global climate challenge and hydrogen (H2) is increasingly valued as a carbon-free energy carrier that can play a prominent role in decarbonising economies. However the environmental impact of the different methods for hydrogen production are sometimes overlooked. This work provides a comprehensive overview of the environmental impacts and costs of a diverse range of methods for producing hydrogen. Ninety nine life cycle assessments (LCAs) of hydrogen production published between 2015 and 2022 are categorised by geography production method energy source goal and scope and compared by data sources and methodology. A meta-analysis of methodological choices is used to identify a subset of mutually comparable studies whose results are then compared initially by global warming potential (GWP) then low-GWP scenarios are compared by other indicators. The results show that the lowest GWP is achieved by methods that are currently more expensive (~US $4–9/kg H2) compared to the dominant methods of producing hydrogen from fossil fuels (~US $1–2/kg H2). The research finds that data are currently limited for comparing environmental indicators other than GWP such as terrestrial acidification or freshwater eutrophication. Recommendations are made for future LCAs of hydrogen production.
Policy Design for Diffusing Hydrogen Economy and Its Impact on the Japanese Economy for Carbon Neutrality by 2050: Analysis Using the E3ME-FTT Model
Nov 2023
Publication
To achieve carbon neutrality in Japan by 2050 renewable energy needs to be used as the main energy source. Based on the constraints of various renewable energies the importance of hydrogen cannot be ignored. This study aimed to investigate the diffusion of hydrogen demand technologies in various sectors and used projections and assumptions to investigate the hydrogen supply side. By performing simulations with the E3ME-FTT model and comparing various policy scenarios with the reference scenario the economic and environmental impacts of the policy scenarios for hydrogen diffusion were analyzed. Moreover the impact of realizing carbon neutrality by 2050 on the Japanese economy was evaluated. Our results revealed that large-scale decarbonization via hydrogen diffusion is possible (90% decrease of CO2 emissions in 2050 compared to the reference) without the loss of economic activity. Additionally investments in new hydrogen-based and other low-carbon technologies in the power sector freight road transport and iron and steel industry can improve the gross domestic product (1.6% increase in 2050 compared to the reference) as they invoke economic activity and require additional employment (0.6% increase in 2050 compared to the reference). Most of the employment gains are related to decarbonizing the power sector and scaling up the hydrogen supply sector while a lot of job losses can be expected in the mining and fossil fuel industries.
Resilience-oriented Operation of Microgrids in the Presence of Power-to-hydrogen Systems
Jul 2023
Publication
This study presents a novel framework for improving the resilience of microgrids based on the power-to-hydrogen concept and the ability of microgrids to operate independently (i.e. islanded mode). For this purpose a model is being developed for the resilient operation of microgrids in which the compressed hydrogen produced by power-to-hydrogen systems can either be used to generate electricity through fuel cells or sold to other industries. The model is a bi-objective optimization problem which minimizes the cost of operation and resilience by (i) reducing the active power exchange with the main grid (ii) reducing the ohmic power losses and (iii) increasing the amount of hydrogen stored in the tanks. A solution approach is also developed to deal with the complexity of the bi-objective model combining a goal programming approach and Generalized Benders Decomposition due to the mixed-integer nonlinear nature of the optimization problem. The results indicate that the resilience approach although increasing the operation cost does not lead to load shedding in the event of main grid failures. The study concludes that integrating distributed power-to-hydrogen systems results in significant benefits including emission reductions of up to 20 % and cost savings of up to 30 %. Additionally the integration of the decomposition method improves computational performance by 54 % compared to using commercial solvers within the GAMS software.
Perspectives and Prospects of Underground Hydrogen Storage and Natural Hydrogen
Jun 2022
Publication
Hydrogen is considered the fuel of the future due to its cleaner nature compared to methane and gasoline. Therefore renewable hydrogen production technologies and long-term affordable and safe storage have recently attracted significant research interest. However natural underground hydrogen production and storage have received scant attention in the literature despite its great potential. As such the associated formation mechanisms geological locations and future applications remain relatively under-explored thereby requiring further investigation. In this review the global natural hydrogen formation along with reaction mechanisms (i.e. metamorphic processes pyritization and serpentinization reactions) as well as the suitable geological locations (i.e. ophiolites organic-rich sediments fault zones igneous rocks crystalline basements salt bearing strata and hydrocarbon-bearing basins) are discussed. Moreover the underground hydrogen storage mechanisms are detailed and compared with underground natural gas and CO2 storage. Techno-economic analyses of large-scale underground hydrogen storage are presented along with the current challenges and future directions.
Potential Economic Benefits of Carbon Dioxide (CO2) Reduction Due to Renewable Energy and Electrolytic Hydrogen Fuel Deployment Under Current and Long Term Forecasting of the Social Carbon Cost (SCC)
May 2019
Publication
The 2016 Paris Agreement (UNFCCC Authors 2015) is the latest of initiative to create an international consensus on action to reduce GHG emissions. However the challenge of meeting its targets lies mainly in the intimate relationship between GHG emissions and energy production which in turn links to industry and economic growth. The Middle East and North African region (MENA) particularly those nations rich oil and gas (O&G) resources depend on these as a main income source. Persuading the region to cut down on O&G production or reduce its GHG emissions is hugely challenging as it is so vital to its economic strength. In this paper an alternative option is established by creating an economic link between GHG emissions measured as their CO2 equivalent (CO2e) and the earning of profits through the concept of Social Carbon Cost (SCC). The case study is a small coastal city in Libya where 6% of electricity is assumed to be generated from renewable sources. At times when renewable energy (RE) output exceeds the demand for power the surplus is used for powering the production of hydrogen by electrolysis thus storing the energy and creating an emission-free fuel. Two scenarios are tested based on short and long term SCCs. In the short term scenario the amount of fossil fuel energy saved matches the renewable energy produced which equates to the same amount of curtailed O&G production. The O&G-producing region can earn profits in two ways: (1) by cutting down CO2 emissions as a result of a reduction in O&G production and (2) by replacing an amount of fossil fuel with electrolytically-produced hydrogen which creates no CO2 emissions. In the short term scenario the value of SCC saved is nearly 39% and in the long term scenario this rose to 83%.
Explosion Mitigation Techniques in Tunnels and their Applicability to Scenarios of Hydrogen Tank Rupture in a Fire
Sep 2023
Publication
This paper presents a comprehensive review of existing explosion mitigation techniques for tunnels and evaluates their applicability in scenarios of hydrogen tank rupture in a fire. The study provides an overview of the current state of the art in tunnel explosion mitigation and discusses the challenges associated with hydrogen explosions in the context of fire incidents. The review shows that there are several approaches available to decrease the effects of explosions including wrapping the tunnel with a flexible and compressible barrier and introducing energy-absorbing flexible honeycomb elements. However these methods are limited to the mitigation of the action and do not consider either the mitigation of the structural response or the effects on the occupants. The study highlights how the structural response is affected by the duration of the action and the natural period of the structural elements and how an accurate design of the element stiffness can be used in order to mitigate the structural vulnerability to the explosion. The review also presents various passive and active mitigation techniques aimed at mitigating the explosion effects on the occupants. Such techniques include tunnel branching ventilation openings evacuation lanes right-angled bends drop-down perforated plates or high-performance fibre-reinforced cementitious composite (HPFRCC) panels for blast shielding. While some of these techniques can be introduced during the tunnel's construction phase others require changes to the already working tunnels. To simulate the effect of blast wave propagation and evaluate the effectiveness of these mitigation techniques a CFD-FEM study is proposed for future analysis. The study also highlights the importance of considering these mitigation techniques to ensure the safety of the public and first responders. Finally the study identifies the need for more research to understand blast wave mitigation by existing structural elements in the application for potential accidents associated with hydrogen tank rupture in a tunnel.
Multi-Objective Optimization for Solar-Hydrogen-Battery-Integrated Electric Vehicle Charging Stations with Energy Exchange
Oct 2023
Publication
The importance of electric vehicle charging stations (EVCS) is increasing as electric vehicles (EV) become more widely used. EVCS with multiple low-carbon energy sources can promote sustainable energy development. This paper presents an optimization methodology for direct energy exchange between multi-geographic dispersed EVCSs in London UK. The charging stations (CSs) incorporate solar panels hydrogen battery energy storage systems and grids to support their operations. EVs are used to allow the energy exchange of charging stations. The objective function of the solar-hydrogen-battery storage electric vehicle charging station (SHS-EVCS) includes the minimization of both capital and operation and maintenance (O&M) costs as well as the reduction in greenhouse gas emissions. The system constraints encompass the power output limits of individual components and the need to maintain a power balance between the SHS-EVCSs and the EV charging demand. To evaluate and compare the proposed SHS-EVCSs two multi-objective optimization algorithms namely the Non-dominated Sorting Genetic Algorithm (NSGA-II) and the Multi-objective Evolutionary Algorithm Based on Decomposition (MOEA/D) are employed. The findings indicate that NSGA-II outperforms MOEA/D in terms of achieving higher-quality solutions. During the optimization process various factors are considered including the sizing of solar panels and hydrogen storage tanks the capacity of electric vehicle chargers and the volume of energy exchanged between the two stations. The application of the optimized SHS-EVCSs results in substantial cost savings thereby emphasizing the practical benefits of the proposed approach.
Hydrogen Dispersion Following Blowdown Releases into a Tunnel
Sep 2023
Publication
This paper presents work undertaken by the HSE as part of the Hytunnel-CS project a consortium investigating safety considerations for fuel cell hydrogen (FCH) vehicles in tunnels and similar confined spaces. The test programme investigating hydrogen dispersion in tunnels involved simulating releases analogous to Thermally activated Pressure Relief Devices (TPRDs) typically found on hydrogen vehicles into the HSE Tunnel facility. The releases were scaled and based upon four scenarios: cars buses and two different train designs. The basis for this scaling was the size of the tunnel and the expected initial mass flow rates of the releases scenarios. The results of the 12 tests completed have been analysed in two ways: the initial mass flow rates of the tests were calculated based upon facility measurements and the Able-Noble equations of state for comparison to the intended initial flow rate; and observations of the hydrogen dispersion in the tunnel were made based on 15 hydrogen sensors arrayed along the tunnel. The calculated mass flow rates showed reasonable agreement with the intended initial conditions showing that the scaling methodology can be used to interpret the data based on the full-scale tunnel of interest. Observations of the hydrogen dispersion show an initial turbulent mixing followed by a movement of the mixed hydrogen/air cloud down the tunnel. No vertical stratification of the cloud was observed but this effect could be possible in longer tunnels or tunnels with larger diameters. Higher ventilation rates in the tunnel resulted in a reduction of the residence time of the hydrogen and a slight increase in the dilution.
CFD Dispersion Simulations of Compressed Hydrogen Releases through TPRD Inside Scaled Tunnel
Sep 2023
Publication
To achieve the net zero carbon emissions goals by 2050 the transition to cleaner forms and carriers of energy should be accelerated without though jeopardizing the public safety. Although hydrogen has been deemed to play significant role in the energy transition for years now there are still concerns for its risks that hamper its widespread implementation in several applications like for instance automobile applications. Hydrogen-powered vehicles raise concerns about their safety especially inside confined spaces like tunnels and thus research on that topic has been intensified during the last years. In this context experiments have been conducted by UK HSE within the EU-funded project HyTunnel-CS to examine hydrogen dispersion and deflagration inside a scaled tunnel resulting from fuel cell car bus and train release.<br/>In this work that was also carried out within the HyTunnel-CS we present the Computational Fluid Dynamics (CFD) simulations of the HSE unignited experiments. Blowdown tests related to high-pressure hydrogen releases through Thermal Pressure Relief Device (TPRD) installed in car and in train were modeled using the ADREA-HF code. The scope of these simulations was two-fold: a) contribute to the design of the experiments (e.g. indicate sensor positioning ignition point etc.) and the interpretation of hydrogen behavior and b) validate the CFD code. For the former pre-test simulations preceded the experiments to provide design recommendations. When the experiments were conducted the measurements were used for the code validation. Overall the CFD results are in satisfactory agreement with the experiments. Finally simulations with different ventilation rates and with model vehicles inside the tunnel were conducted to examine their effect on mixture dispersion and tunnel safety.
A Study on the Viability of Fuel Cells as an Alternative to Diesel Fuel Generators on Ships
Jul 2023
Publication
This study investigates methods for reducing air pollution in the shipping sector particularly in port areas. The study examines the use of fuel cells as an alternative to diesel generators. Environmental pollution at ports remains a critical issue so using fuel cells as an alternative to conventional energy systems warrants further research. This study compares commercial fuel cell types that can be used on a case study very large crude carrier (VLCC) vessel specifically although the technology is applicable to other vessels and requirements. Seven different fuel cell types were ranked based on five criteria to accomplish this. The proton-exchange membrane cell type was found to be the most suitable fuel cell type for the case study vessel. Based on the input fuel ammonia-based hydrogen storage has been identified as the most promising option along with using an ammonia reforming unit to produce pure hydrogen. Furthermore this study provides an integrated fuel cell module and highlights the economic environmental and maintenance aspects of implementing the proton-exchange membrane fuel cell module for this case study. It also calculates the required space as a crucial constraint of implementing fuel cell technology at sea.
Comparing Alternative Pathways for the Future Role of the Gas Grid in a Low-carbon Heating System
Aug 2023
Publication
This paper uses a whole-system approach to examine different strategies related to the future role of the gas grid in a low-carbon heat system. A novel model of integrated gas electricity and heat systems HEGIT is used to investigate four key sets of scenarios for the future of the gas grid using the UK as a case study: (a) complete electrification of heating; (b) conversion of the existing gas grid to deliver hydrogen; (c) a hybrid heat pump system; and (d) a greener gas grid. Our results indicate that although the infrastructure requirements the fuel or resource mix and the breakdown of costs vary significantly over the complete electrification to complete conversion of the gas grid to hydrogen spectrum the total system transition cost is relatively similar. This reduces the significance of total system cost as a guiding factor in policy decisions on the future of the gas grid. Furthermore we show that determining the roles of low-carbon gases and electrification for decarbonising heating is better guided by the trade-offs between short- and long-term energy security risks in the system as well as trade-offs between consumer investment in fuel switching and infrastructure requirements for decarbonising heating. Our analysis of these trade-offs indicates that although electrification of heating using heat pumps is not the cheapest option to decarbonise heat it has clear co-benefits as it reduces fuel security risks and dependency on carbon capture and storage infrastructure. Combining different strategies such as grid integration of heat pumps with increased thermal storage capacity and installing hybrid heat pumps with gas boilers on the consumer side are demonstrated to effectively moderate the infrastructure requirements consumer costs and reliability risks of widespread electrification. Further reducing demand on the electricity grid can be accomplished by complementary options at the system level such as partial carbon offsetting using negative emission technologies and partially converting the gas grid to hydrogen.
Additive Manufacturing for Proton Exchange Membrane (PEM) Hydrogen Technologies: Merits, Challenges, and Prospects
Jul 2023
Publication
With the growing demand for green technologies hydrogen energy devices such as Proton Exchange Membrane (PEM) fuel cells and water electrolysers have received accelerated developments. However the materials and manufacturing cost of these technologies are still relatively expensive which impedes their widespread commercialization. Additive Manufacturing (AM) commonly termed 3D Printing (3DP) with its advanced capabilities could be a potential pathway to solve the fabrication challenges of PEM parts. Herein in this paper the research studies on the novel AM fabrication methods of PEM components are thoroughly reviewed and analysed. The key performance properties such as corrosion and hydrogen embrittlement resistance of the additively manufactured materials in the PEM working environment are discussed to emphasise their reliability for the PEM systems. Additionally the major challenges and required future developments of AM technologies to unlock their full potential for PEM fabrication are identified. This paper provides insights from the latest research developments on the significance of advanced manufacturing technologies in developing sustainable energy systems to address the global energy challenges and climate change effects.
Current and Future role of Haber–Bosch Ammonia in a Carbon-free Energy Landscape
Dec 2019
Publication
The future of a carbon-free society relies on the alignment of the intermittent production of renewable energy with our continuous and increasing energy demands. Long-term energy storage in molecules with high energy content and density such as ammonia can act as a buffer versus short-term storage (e.g. batteries). In this paper we demonstrate that the Haber–Bosch ammonia synthesis loop can indeed enable a second ammonia revolution as energy vector by replacing the CO2 intensive methane-fed process with hydrogen produced by water splitting using renewable electricity. These modifications demand a redefinition of the conventional Haber–Bosch process with a new optimisation beyond the current one which was driven by cheap and abundant natural gas and relaxed environmental concerns during the last century. Indeed the switch to electrical energy as fuel and feedstock to replace fossil fuels (e.g. methane) will lead to dramatic energy efficiency improvements through the use of high efficiency electrical motors and complete elimination of direct CO2 emissions. Despite the technical feasibility of the electrically-driven Haber–Bosch ammonia the question still remains whether such revolution will take place. We reveal that its success relies on two factors: increased energy efficiency and the development of small-scale distributed and agile processes that can align to the geographically isolated and intermittent renewable energy sources. The former requires not only higher electrolyser efficiencies for hydrogen production but also a holistic approach to the ammonia synthesis loop with the replacement of the condensation separation step by alternative technologies such as absorption and catalysis development. Such innovations will open the door to moderate pressure systems the development and deployment of novel ammonia synthesis catalysts and even more importantly the opportunity for integration of reaction and separation steps to overcome equilibrium limitations. When realised green ammonia will reshape the current energy landscape by directly replacing fossil fuels in transportation heating electricity etc. and as done in the last century food.
Techno-economic Feasibility of Distributed Waste-to-hydrogen Systems to Support Green Transport in Glasgow
Mar 2022
Publication
Distributed waste-to-hydrogen (WtH) systems are a potential solution to tackle the dual challenges of sustainable waste management and zero emission transport. Here we propose a concept of distributed WtH systems based on gasification and fermentation to support hydrogen fuel cell buses in Glasgow. A variety of WtH scenarios were configured based on biomass waste feedstock hydrogen production reactors and upstream and downstream system components. A cost-benefit analysis (CBA) was conducted to compare the economic feasibility of the different WtH systems with that of the conventional steam methane reforming-based method. This required the curation of a database that included inter alia direct cost data on construction maintenance operations infrastructure and storage along with indirect cost data comprising environmental impacts and externalities cost of pollution carbon taxes and subsidies. The levelized cost of hydrogen (LCoH) was calculated to be 2.22 GB P/kg for municipal solid waste gasification and 2.02 GB P/kg for waste wood gasification. The LCoHs for dark fermentation and combined dark and photo fermentation systems were calculated to be 2.15 GB P/kg and 2.29 GB P/kg. Sensitivity analysis was conducted to identify the most significant influential factors of distributed WtH systems. It was indicated that hydrogen production rates and CAPEX had the largest impact for the biochemical and thermochemical technologies respectively. Limitations including high capital expenditure will require cost reduction through technical advancements and carbon tax on conventional hydrogen production methods to improve the outlook for WtH development.
Navigating Turbulence: Hydrogen's Role in the Decarbonization of the Aviation Sector
Jan 2024
Publication
This paper offers a comprehensive analysis of the historical evolution and the current state of the aviation industry with a particular emphasis on the critical need for this sector to decarbonize. It delves into emerging propulsion technologies such as battery electric and hydrogen-based systems assessing their potential impact on sustainability within the aviation sector. Special attention is devoted to the global regulatory framework notably carbon offsetting and emission reduction scheme for international aviation which encapsulates initiatives such as lower carbon aviation fuels and sustainable aviation fuels. Examining the environmental challenges facing aviation the paper underscores the necessity for a balanced and comprehensive strategy that integrates various approaches to achieve sustainable solutions. By addressing both the historical context and contemporary advances the paper aims to provide a nuanced understanding of the complexities surrounding aviation's decarbonization journey acknowledging the industry's strides while recognizing the ongoing challenges in the pursuit of sustainability.
Inspection of Coated Hydrogen Transportation Pipelines
Sep 2023
Publication
The growing need for hydrogen indicates that there is likely to be a demand for transporting hydrogen. Hydrogen pipelines are an economical option but the issue of hydrogen damage to pipeline steels needs to be studied and investigated. So far limited research has been dedicated to determining how the choice of inspection method for pipeline integrity management changes depending on the presence of a coating. Thus this review aims to evaluate the effectiveness of inspection methods specifically for detecting the defects formed uniquely in coated hydrogen pipelines. The discussion will begin with a background of hydrogen pipelines and the common defects seen in these pipelines. This will also include topics such as blended hydrogen-natural gas pipelines. After which the focus will shift to pipeline integrity management methods and the effectiveness of current inspection methods in the context of standards such as ASME B31.12 and BS 7910. The discussion will conclude with a summary of newly available inspection methods and future research directions.
Numerical Simulation of Liquid Hydrogen Evaporation in the Pressurized Tank During Venting
Sep 2023
Publication
CFD modelling of liquified hydrogen boiling and evaporation during the pressurised tank venting is presented. The model is based on the volume-of-fluid method for tracking liquid and gas phases and Lee’s model for phase change. The simulation results are compared against the liquid hydrogen evaporation experiment performed by Tani et al. (2021) in a large-scale pressurised storage tank using experimental pressure dynamics and temperatures measured in gas and liquid phases. The study focuses on tank pressure decrease and recovery phenomena during the first 15 s of the venting process. The model sensitivity have been studied applying different Lee’s model evaporisation-condensation coefficients. The CFD model provided reasonable agreement with the observed pressure and gas phase temperature dynamics during the liquid hydrogen storage depressurisation using Lee’s model coefficient =0.05 s-1. Experimentalists’ hypothesis about particularly intensive boiling in the proximity of thermocouples was supported by close agreement between simulated and experimental saturation temperatures obtained from pressure dynamics.
Factors Driving the Decarbonisation of Industrial Clusters: A Rapid Evidence Assessment of International Experience
Sep 2023
Publication
Reducing industrial emissions to achieve net-zero targets by the middle of the century will require profound and sustained changes to how energy intensive industries operate. Preliminary activity is now underway with governments of several developed economies starting to implement policy and providing funding to support the deployment of low carbon infrastructure into high emitting industrial clusters. While clusters appear to offer the economies of scale and institutional capacity needed to kick-start the industrial transition to date there has been little systematic assessment of the factors that may influence the success of these initiatives. Drawing from academic and grey literature this paper presents a rapid evidence assessment of the approaches being used to drive the development of low carbon industrial clusters internationally. Many projects are still at the scoping stage but it is apparent that current initiatives focus on the deployment of carbon capture technologies alongside hydrogen as a future secondary revenue stream. This model of decarbonisation funnels investment into large coastal clusters with access to low carbon electricity and tends to obscure questions about the integration of these technologies with other decarbonisation interventions such as material efficiency and electrification. The technology focus also omits the importance that a favourable location and shared history and culture appears to have played in helping progress the most advanced initiatives; factors that cannot be easily replicated elsewhere. If clusters are to kick-start the low-carbon industrial transition then greater attention is needed to the social and political dimensions of this process and to a broader range of decarbonisation interventions and cluster types than represented by current projects.
Necessary and Sufficient Conditions for Deploying Hydrogen Homes: A Consumer-oriented Perspective
May 2024
Publication
As part of its efforts to secure a ‘net-zero society’ the UK government will take a strategic decision on the role of hydrogen in decarbonising homes within the next years. While scholars have recently advanced the social science research agenda on hydrogen technology acceptance studies are yet to engage with the prospective dynamics of adopting ‘hydrogen homes’. In response this study examines the perceived adoption potential of hydrogen heating and cooking technologies as evaluated through the eyes of consumer. Engaging with behavioural and market acceptance this research draws on data from a broadly nationally representative online survey to examine the influence of safety technological economic environmental and emotional factors on the domestic hydrogen transition in the UK context. The analysis follows a multi-stage empirical approach integrating findings from partial least squares structural equation and necessary condition analysis to crystallise insights on this emergent subject. At this juncture perceived adoption potential may hinge primarily on emotional environmental safety and to a lesser extent technological perspectives. However consumers have an expressed preference for hydrogen heating over hydrogen cooking with perceived boiler performance emerging as a necessary condition for enabling adoption potential. At the formative phase of the transition risks associated with energy insecurity and fuel poverty exceed concerns over purchasing and running costs. Nevertheless economic factors remain less critical during the pre-deployment phase of the innovation-decision process. Across the full sample simple slope analysis highlights the moderating effects of gender age and housing tenure. Moreover statistically significant differences from both a sufficiency- and necessity-based perspective are detected between male property owners aged 55+ and female mortgage owners 18–34 years old. By bridging the knowledge gap between social acceptance and adoption intention this contribution reinforces the need for consumer engagement in the hydrogen economy advocating for more fine-grained mixed-methods analyses of technology acceptance dynamics to support decarbonisation strategies.
Conflicts Between Economic and Low-carbon Reorientation Processes: Insights from a Contextual Analysis of Evolving Company Strategies in the United Kingdrom Petrochemical Industry (1970-2021)
Jul 2022
Publication
To situate its low-carbon transition process in longer-term real-world business contexts this article makes a longitudinal analysis of the UK petrochemical industry focusing on changing economic and socio-political environments and company strategies in the last 50 years. Using the Triple Embeddedness Framework the paper identifies two parallel and conflicting reorientation processes in the UK petrochemical industry. The first one which started in the 1970s and is driven by long-standing competitiveness problems led to retrenchment in the 1980s exit of incumbent companies (BP Shell ICI) and the entry of new firms (INEOS SABIC) in the 1990s and 2000s and diversification into upstream fossil fuel production and ethane imports in the 2010s. The second reorientation process which started in the 2010s is driven by climate change considerations and has led petrochemical firms to reluctantly explore low-carbon alternatives. Despite advancing ambitious visions and plans companies are weakly committed to low-carbon reorientation because this is layered on top of and conflicts with the deeper economically-motivated reorientation process. The paper further concludes that the industry's low-carbon plans and visions are partial because they focus more on some innovations (hydrogen-as-fuel CCS) than on other innovations (recycling bio-feedstocks synthetic feedstocks). Despite exploring alternatives firms also use political resistance strategies to hamper and delay deeper low-carbon reorientation
UK HSE Hydrogen for Heating Evidence Review Process
Sep 2023
Publication
As part of the UK Government’s Net Zero targets to tackle Climate Change the Health and Safety Executive (HSE) aims to reach an authoritative view on the safety of using 100% hydrogen for heating across the UK to feed into Government policy decisions by the mid-2020s. This paper describes the background and process of a programme of work led by HSE in support of the Department for Energy Security and Net Zero (formerly BEIS) that will inform strategic policy decisions by 2026. The strategic framework of HSE’s programme of work was defined between BEIS and HSE. HSE’s programme of work follows on from a previous project which engaged with HSE policy regulatory and scientific colleagues working with industry stakeholders identifying knowledge gaps for the safe distribution storage and use of hydrogen gas in domestic industrial and commercial premises. These knowledge gaps were subsequently used in discussions with stakeholders to prioritise research projects and evidence gathering exercises. To review this scientific evidence HSE developed a review framework and convened Evidence Review Groups (ERGs) to cover all evidence areas encompassing topics such as quantified risk assessment material compatibility and operational procedures. These ERGs include representation from relevant divisions across HSE (policy regulation and science). The paper explains the structure of HSE’s input into the hydrogen for heating programme the ERG process and timelines along with the proposed outputs. Additional activities have been undertaken by HSE within the programme to highlight specific issues in support of the review process which will also be discussed.
Explosion Free in Fire Self-venting (TPRD-less) Composite Tanks: Performance Under Fire Intervention Conditions
Sep 2023
Publication
This paper describes the performance of explosion free in fire self-venting (TPRD-less) composite tanks of Type IV in fires of realistic intensity HRR/A=1 MW/m2 in conditions of first responders’ intervention. This breakthrough safety technology does not require the use of thermally activated pressure relief devices (TPRD). It provides microleaks-no-burst (LNB) performance of high-pressure hydrogen storage tanks in a fire. Two fire intervention strategies are investigated one is the removal of a vehicle with LNB tank from the fire and another is the extinction of the fire. The removal from the fire scenario is investigated for one carbon-carbon and one carbon-basalt double-composite wall tank prototype. The fire extinction scenario is studied for four carbon-basalt prototypes. All six prototypes of 7.5 L volume and nominal working pressure of 70 MPa demonstrated safe release of hydrogen through microchannels of the composite wall after melting a liner. The technology allows fire brigades to apply standard intervention strategies and tactics at the fire scene with hydrogen vehicles if LNB tanks are used in the vehicle.
Review of Common Hydrogen Storage Tanks and Current Manufacturing Methods for Aluminium Tank Liners
Aug 2023
Publication
With the growing concern about climate issues and the urgent need to reduce carbon emissions hydrogen has attracted increasing attention as a clean and renewable vehicle energy source. However the storage of flammable hydrogen gas is a major challenge and it restricts the commercialisation of fuel cell electric vehicles (FCEVs). This paper provides a comprehensive review of common on-board hydrogen storage tanks possible failure mechanisms and typical manufacturing methods as well as their future development trends. There are generally five types of hydrogen tanks according to different materials used with only Type III (metallic liner wrapped with composite) and Type IV (polymeric liner wrapped with composite) tanks being used for vehicles. The metallic liner of Type III tank is generally made from aluminium alloys and the associated common manufacturing methods such as roll forming deep drawing and ironing and backward extrusion are reviewed and compared. In particular backward extrusion is a method that can produce near net-shape cylindrical liners without the requirement of welding and its tool designs and the microstructural evolution of aluminium alloys during the process are analysed. With the improvement and innovation on extrusion tool designs the extrusion force which is one of the most demanding issues in the process can be reduced significantly. As a result larger liners can be produced using currently available equipment at a lower cost.
Green Hydrogen and its Unspoken Challenges for Energy Justice
Oct 2024
Publication
Green hydrogen is often promoted as a key facilitator for the clean energy transition but its implementation raises concerns around energy justice. This paper examines the socio-political and techno-economic challenges that green hydrogen projects may pose to the three tenets of energy justice: distributive procedural and recognition justice. From a socio-political perspective the risk of neocolonial resource extraction uneven distribution of benefits exclusion of local communities from decision-making and disregard for indigenous rights and cultures threaten all three justice tenets. Techno-economic factors such as water scarcity land disputes and resource-related conflicts in potential production hotspots further jeopardise distributive and recognition justice. The analysis framed by an adapted PEST model reveals that while green hydrogen holds promise for sustainable development its implementation must proactively address these justice challenges. Failure to do so could perpetuate injustices exploitation and marginalisation of vulnerable communities undermining the sustainability goals it aims to achieve. The paper highlights the need for inclusive and equitable approaches that respect local sovereignty integrate diverse stakeholders and ensure fair access and benefit-sharing. Only by centring justice considerations can the transition to green hydrogen catalyse positive social change and realise its full potential as a driver of sustainable energy systems.
Modelling Flexibility Requirements in Deep Decarbonisation Scenarios: The Role of Conventional Flexibility and Sector Coupling Options in the European 2050 Energy System
Feb 2024
Publication
Russia’s invasion of Ukraine has reaffirmed the importance of scaling up renewable energy to decarbonise Europe’s economy while rapidly reducing its exposure to foreign fossil fuel suppliers. Therefore the question of sources of flexibility to support a fully decarbonised European energy system is becoming even more critical in light of a renewable-dominated energy system. We developed and used a Pan-European energy system model to systematically assess and quantify sources of flexibility to meet deep decarbonisation targets. The electricity supply sector and electricity-based end-use technologies are crucial in achieving deep decarbonisation. Other low-carbon energy sources like biomethane hydrogen synthetic e-fuels and bioenergy with carbon capture and storage will also play a role. To support a fully decarbonised European energy system by 2050 both temporal and spatial flexibility will be needed. Spatial flexibility achieved through investments in national electricity networks and cross-border interconnections is crucial to support the aggressive roll-out of variable renewable energy sources. Cross-border trade in electricity is expected to increase and in deep decarbonisation scenarios the electricity transmission capacity will be larger than that of natural gas. Hydrogen storage and green hydrogen production will play a key role in providing traditional inter-seasonal flexibility and intraday flexibility will be provided by a combination of electrical energy storage hydrogen-based storage solutions (e.g. liquid H2 and pressurised storage) and hybrid heat pumps. Hydrogen networks and storage will become more critical as we move towards the highest decarbonisation scenario. Still the need for natural gas networks and storage will decrease substantially.
Zone Negligible Extent: Example of Specific Detailed Risk Assessment for Low Pressure Equipment in a Hydrogen Refuelling Station
Sep 2023
Publication
The MultHyFuel project aims to develop evidence-based guidelines for the safe implementation of Hydrogen Refueling Stations (HRS) in a multi-fuel context. As a part of the generation of good practice guidelines for HRS Hazardous Area Classification (HAC) methodologies were analyzed and applied to case studies representing example configurations of HRS. It has been anticipated that Negligible Extent (NE) classifications might be applicable for sections of the HRS for instance a hydrogen generator. A NE zone requires that an ignition of a flammable cloud would result in negligible consequences. In addition depending on the pressure of the system IEC 60079-10-1:2020 establishes specific requirements in order to classify the hazardous area as being of NE. One such requirement is that a zone of NE shall not be applied for releases from flammable gas systems at pressures above 2000 kPag (20 barg) unless a specific detailed risk assessment is documented. However there is no definition within the standard as to the requirements of the specific detailed risk assessment. In this work an example for a specific detailed risk assessment for the NE classification is presented:<br/>• Firstly the requirements of cloud volume dilution and background concentration for a zone of NE classification from IEC 60079-10-1:2020 are analyzed for hydrogen releases from equipment placed in a mechanically ventilated enclosure.<br/>• Secondly the consequences arising from the ignition of the localized cloud are estimated and compared to acceptable harm criteria in order to assess if negligible consequences are obtained from the scenario.<br/>• In addition a specific qualitative risk assessment for the ignition of the cloud in the enclosure was considered incorporating the estimated consequences and analyzing the available safeguards in the example system.<br/>Recommendations for the specific detailed risk assessment are proposed for this scenario with the intention to support improved definition of the requirement in future revisions of IEC 60079-10-1.
Review of Next Generation Hydrogen Production from Offshore Wind Using Water Electrolysis
Dec 2023
Publication
Hydrogen produced using renewable energy from offshore wind provides a versatile method of energy storage and power-to-gas concepts. However few dedicated floating offshore electrolyser facilities currently exist and therefore conditions of the offshore environment on hydrogen production cost and efficiency remain uncertain. Therefore this review focuses on the conversion of electrical energy to hydrogen using water electrolysis located in offshore areas. The challenges associated with the remote locations fluctuating power and harsh conditions are highlighted and recommendations for future electrolysis system designs are suggested. The latest research in polymer electrolyte membrane alkaline and membraneless electrolysis are evaluated in order to understand their capital costs efficiency and current research status for achieving scaled manufacturing to the GW scale required in the next three decades. Operating fundamentals that govern the performance of each device are investigated and future recommendations of research specifically for the integration of water electrolysers with offshore wind turbines is presented.
An Experimental Investigation of Hydrogen Production through Biomass Electrolysis
Jan 2024
Publication
This work investigated hydrogen production from biomass feedstocks (i.e. glucose starch lignin and cellulose) using a 100 mL h-type proton exchange membrane electrolysis cell. Biomass electrolysis is a promising process for hydrogen production although low in technology readiness level but with a series of recognised advantages: (i) lower-temperature conditions (compared to thermochemical processes) (ii) minimal energy consumption and low-cost post-production (iii) potential to synthesise high-volume H2 and (iv) smaller carbon footprint compared to thermochemical processes. A Lewis acid (FeCl3 ) was employed as a charge carrier and redox medium to aid in the depolymerisation/oxidation of biomass components. A comprehensive analysis was conducted measuring the H2 and CO2 emission volume and performing electrochemical analysis (i.e. linear sweep voltammetry and chronoamperometry) to better understand the process. For the first time the influence of temperature on current density and H2 evolution was studied at temperatures ranging from ambient temperature (i.e. 19 ◦C) to 80 ◦C. The highest H2 volume was 12.1 mL which was produced by FeCl3 -mediated electrolysis of glucose at ambient temperature which was up to two times higher than starch lignin and cellulose at 1.20 V. Of the substrates examined glucose also showed a maximum power-to-H2 -yield ratio of 30.99 kWh/kg. The results showed that hydrogen can be produced from biomass feedstock at ambient temperature when a Lewis acid (FeCl3 ) is employed and with a higher yield rate and a lower electricity consumption compared to water electrolysis.
Analysis of the Combustion Speed in a Spark Ignition Engine Fuelled with Hydrogen and Gasoline Blends at Different Air Fuel Ratios
Nov 2024
Publication
The use of hydrogen in internal combustion engines is a promising solution for the decarbonisation of the transport sector. The current transition scenario is marked by the unavailability and storage challenges of hydrogen. Dual fuel combustion of hydrogen and gasoline in current spark ignition engines is a feasible solution in the short and medium term as it can improve engine efficiency reduce pollutant emissions and contribute significantly in tank to wheel decarbonisation without major engine modification. However new research is needed to understand how the incorporation of hydrogen affects existing engines to effectively implement gasoline-hydrogen dual fuel option. Understanding the impact of hydrogen on the combustion process (e.g. combustion speed) will guide and optimize the operation of engines under dual fuel combustion conditions. In this work a commercial gasoline direct injection engine has been modified to operate with gasolinehydrogen fuels. The experiments have been carried out at various air–fuel ratios ranging from stoichiometric to lean combustion conditions at constant engine speed and torque. At each one of the 14 experimental points 200-cycle in-cylinder pressure traces were recorded and processed with a quasi-dimensional diagnostic model and a combustion speed analysis was then carried out. It has been understood that hydrogen mainly reduces the duration of the first combustion phase. Hydrogen also enables to increase air excess ratios (lean in fuel combustion) without significantly increasing combustion duration. Furthermore a correlation is proposed to predict combustion speed as a function of the fuel and air mixture properties. This correlation can be incorporated to calculate combustion duration in predictive models of engines operating under different fuel mixtures and different geometries of the combustion chamber with pent-roof cylinder head and flat piston head.
Multi-criteria Site Selection Workflow for Geological Storage of Hydrogen in Depleted Gas Fields: A Case for the UK
Oct 2023
Publication
Underground hydrogen storage (UHS) plays a critical role in ensuring the stability and security of the future clean energy supply. However the efficiency and reliability of UHS technology depend heavily on the careful and criteria-driven selection of suitable storage sites. This study presents a hybrid multi-criteria decision-making framework integrating the Analytical Hierarchy Process (AHP) and Preference Ranking Organisation Method for Enrichment of Evaluations (PROMETHEE) to identify and select the best hydrogen storage sites among depleted gas reservoirs in the UK. To achieve this a new set of site selection criteria is proposed in light of the technical and economic aspects of UHS including location reservoir rock quality and tectonic characteristics maximum achievable hydrogen well deliverability rate working gas capacity cushion gas volume requirement distance to future potential hydrogen clusters and access to intermittent renewable energy sources (RESs). The framework is implemented to rank 71 reservoirs based on their potential and suitability for UHS. Firstly the reservoirs are thoroughly evaluated for each proposed criterion and then the AHP-PROMETHEE technique is employed to prioritise the criteria and rank the storage sites. The study reveals that the total calculated working gas capacity based on single-well plateau withdrawal rates is around 881 TWh across all evaluated reservoirs. The maximum well deliverability rates for hydrogen withdrawal are found to vary considerably among the sites; however 22 % are estimated to have deliverability rates exceeding 100 sm3 /d and 63 % are located within a distance of 100 km from a major hydrogen cluster. Moreover 70 % have access to nearby RESs developments with an estimated cumulative RESs capacity of approximately 181 GW. The results highlight the efficacy of the proposed multicriteria site selection framework. The top five highest-ranked sites for UHS based on the evaluated criteria are the Cygnus Hamilton Saltfleetby Corvette and Hatfield Moors gas fields. The insights provided by this study can contribute to informed decision-making sustainable development and the overall progress of future UHS projects within the UK and globally.
Underground Hydrogen Storage: A UK Perspective
Oct 2023
Publication
Hydrogen is anticipated to play a key role in global decarbonization and within the UK’s pathway to achieving net zero targets. However as the production of hydrogen expands in line with government strategies a key concern is where this hydrogen will be stored for later use. This study assesses the different large-scale storage options in geological structures available to the UK and addresses the surrounding uncertainties moving towards establishing a hydrogen economy. Currently salt caverns look to be the most favourable option considering their proven experience in the storage of hydrogen especially high purity hydrogen natural sealing properties low cushion gas requirement and high charge and discharge rates. However their geographical availability within the UK can act as a major constraint. Additionally a substantial increase in the number of new caverns will be necessary to meet the UK’s storage demand. Salt caverns have greater applicability as a good short-term storage solution however storage in porous media such as depleted hydrocarbon reservoirs and saline aquifers can be seen as a long-term and strategic solution to meet energy demand and achieve energy security. Porous media storage solutions are estimated to have capacities which far exceed projected storage demand. Depleted fields have generally been well explored prior to hydrocarbon extraction. Although many saline aquifers are available offshore UK geological characterizations are still required to identify the right candidates for hydrogen storage. Currently the advantages of depleted gas reservoirs over saline aquifers make them the favoured option after salt caverns.
Deflagrations of Non-uniform Hydrogen/Air Clouds in a Tunnel
Sep 2023
Publication
This paper presents work undertaken by the HSE as part of the Hytunnel-CS project a consortium investigating safety considerations for fuel cell hydrogen (FCH) vehicles in tunnels and similar confined spaces.<br/>Hydrogen vehicles typically have a Thermally activated Pressure Release Device (TPRD) providing protection to the on-board storage of the vehicle. Upon activation the content of the vessel is released in a blowdown. The release of this hydrogen gas poses a significant hazard of ignition. The consequences of such an ignition could also be compounded by confinement or congestion.<br/>HSE undertook a series of experiments investigating the consequences of these events by releasing hydrogen into a tunnel and causing ignitions. A sub-section of these tests involved steel structures providing congestion in the tunnel. The mass of hydrogen released into the tunnel prior to ignition was varied by storage pressure (up to 59 MPa) release diameter and ignition delay. The ignition delays were set based on the expected worst-case predicted by pre-simulation models. To assess the consequences overpressure measurements were made down the tunnel walls and for the tests with congestion at the face and rear of the congestion structures. The flame arrival time was also measured using exposed-tip thermocouples resulting in an estimate for flame speed down the tunnel. The measured overpressure and flame extent results are presented and compared against overpressure levels of concern.
Recent Developments on Carbon Neutrality through Carbon Dioxide Capture and Utilization with Clean Hydrogen for Production of Alternative Fuels for Smart Cities
Jul 2024
Publication
This review comprehensively evaluates the integration of solar-powered electrolytic hydrogen (H2) production and captured carbon dioxide (CO2) management for clean fuel production considering all potential steps from H2 production methods to CO2 capture and separation processes. It is expected that the near future will cover CO2-capturing technologies integrated with solar-based H2 production at a commercially viable level and over 5 billion tons of CO2 are expected to be utilized potentially for clean fuel production worldwide in 2050 to achieve carbon-neutral levels. The H2 production out of hydrocarbon-based processes using fossil fuels emits greenhouse gas emissions of 17-38 kg CO2/kg H2. On the other hand . renewable energy based green hydrogen production emits less than 2 kg CO2/kg H2 which makes it really clean and appealing for implementation. In addition capturing CO2 and using for synthesizing alternative fuels with green hydrogen will help generate clean fuels for smart cities. In this regard the most sustainable and promising CO2 capturing method is post-combustion with an adsorption-separation-desorption processes using monoethanolamine adsorbent with high CO2 removal efficiencies from flue gases. Consequently this review article provides perspectives on the potential of integrating CO2-capturing technologies and renewable energy-based H2 production systems for clean production to create sustainable cities and communities.
Prospects for Long-Distance Cascaded Liquid—Gaseous Hydrogen Delivery: An Economic and Environmental Assessment
Oct 2024
Publication
As an important energy source to achieve carbon neutrality green hydrogen has always faced the problems of high use cost and unsatisfactory environmental benefits due to its remote production areas. Therefore a liquid-gaseous cascade green hydrogen delivery scheme is proposed in this article. In this scheme green hydrogen is liquefied into high-density and low-pressure liquid hydrogen to enable the transport of large quantities of green hydrogen over long distances. After longdistance transport the liquid hydrogen is stored and then gasified at transfer stations and converted into high-pressure hydrogen for distribution to the nearby hydrogen facilities in cities. In addition this study conducted a detailed model evaluation of the scheme around the actual case of hydrogen energy demand in Chengdu City in China and compared it with conventional hydrogen delivery methods. The results show that the unit hydrogen cost of the liquid-gaseous cascade green hydrogen delivery scheme is only 51.58 CNY/kgH2 and the dynamic payback periods of long- and short-distance transportation stages are 13.61 years and 7.02 years respectively. In terms of carbon emissions this scheme only generates indirect carbon emissions of 2.98 kgCO2/kgH2 without using utility electricity. In sum both the economic and carbon emission analyses demonstrate the advantages of the liquidgaseous cascade green hydrogen delivery scheme. With further reductions in electricity prices and liquefication costs this scheme has the potential to provide an economically/environmentally superior solution for future large-scale green hydrogen applications.
Innovations in Hydrogen Storage Materials: Synthesis, Applications, and Prospects
Jul 2024
Publication
Hydrogen globally recognized as the most efficient and clean energy carrier holds the potential to transform future energy systems through its use as a fuel and chemical resource. Although progress has been made in reversible hydrogen adsorption and release challenges in storage continue to impede widespread adoption. This review explores recent advancements in hydrogen storage materials and synthesis methods emphasizing the role of nanotechnology and innovative synthesis techniques in enhancing storage performance and addressing these challenges to drive progress in the field. The review provides a comprehensive overview of various material classes including metal hydrides complex hydrides carbon materials metal-organic frameworks (MOFs) and porous materials. Over 60 % of reviewed studies focused on metal hydrides and alloys for hydrogen storage. Additionally the impact of nanotechnology on storage performance and the importance of optimizing synthesis parameters to tailor material properties for specific applications are summarized. Various synthesis methods are evaluated with a special emphasis on the role of nanotechnology in improving storage performance. Mechanical milling emerges as a commonly used and cost-effective method for fabricating intermetallic hydrides capable of adjusting hydrogen storage properties. The review also explores hydrogen storage tank embrittlement mechanisms particularly subcritical crack growth and examines the advantages and limitations of different materials for various applications supported by case studies showcasing real-world implementations. The challenges underscore current limitations in hydrogen storage materials highlighting the need for improved storage capacity and kinetics. The review also explores prospects for developing materials with enhanced performance and safety providing a roadmap for ongoing advancements in the field. Key findings and directions for future research in hydrogen storage materials emphasize their critical role in shaping future energy systems.
A Systematic Comparison of the Energy and Emissions Intensity of Hydrogen Production Pathways in the United Kingdom
Sep 2024
Publication
Meeting climate targets requires profound transformations in the energy system. Most energy uses should be electrified but where this is not feasible hydrogen can be part of the solution. However 98% of global hydrogen production involves greenhouse gas emissions with an average of 12 kg CO2e/kg H2. Therefore new hydrogen production pathways are needed in order to make hydrogen production compatible with climate targets. In this work we fill this gap by systematically comparing the energy and emissions intensity of 173 hydrogen production pathways suitable for the UK. Scenarios include onshore and offshore pathways and the use of repurposed infrastructure. Unlike fossil-fuel based pathways the results show that electrolytic hydrogen powered by fixed offshore wind could align with proposed emissions standards either onshore or offshore. However the embodied and fugitive emissions are important to consider for electrolytic pathways as they result in 10–50% of the total emissions intensity.
Design of a Hydrogen Aircraft for Zero Persistent Contrails
Jul 2023
Publication
Contrails are responsible for a significant proportion of aviation’s climate impact. This paper uses data from the European Centre for Medium-Range Weather Forecasts to identify the altitudes and latitudes where formed contrails will not persist. This reveals that long-lived contrails may be prevented by flying lower in equatorial regions and higher in non-equatorial regions. Subsequently it is found that the lighter fuel and reduced seating capacity of hydrogen-powered aircraft lead to a reduced aircraft weight which increases the optimal operating altitude by about 2 km. In non-equatorial regions this would lift the aircraft’s cruise point into the region where long-lived contrails do not persist unlocking hydrogen-powered low-contrails operation. The baseline aircraft considered is an A320 retrofitted with in-fuselage hydrogen tanks. The impacts of the higher-altitude cruise on fuel burn and the benefits unlocked by optimizing the wing geometry for this altitude are estimated using a drag model based on theory proposed by Cavcar Lock and Mason and verified against existing aircraft. The weight penalty associated with optimizing wing geometry for this altitude is estimated using Torenbeek’s correlation. It is found that thinner wings with higher aspect ratios are particularly suited to this high-altitude operation and are enabled by the relaxation of the requirement to store fuel in the wings. An example aircraft design for the non-equatorial region is provided which cruises at a 14 km altitude at Mach 0.75 with a less than 1% average probability of generating long-lived contrails when operating at latitudes more than 35◦ from the equator. Compared to the A320 this concept design is estimated to have a 20% greater cruise lift–drag ratio due to the 33% thinner wings with a 50% larger aspect ratio enabling just 5% more energy use per passenger-km despite fitting 40% fewer seats.
Offshore Green Hydrogen Production from Wind Energy: Critical Review and Perspective
Feb 2024
Publication
Hydrogen is envisaged to play a major role in decarbonizing our future energy systems. Hydrogen is ideal for storing renewable energy over longer durations strengthening energy security. It can be used to provide electricity renewable heat power long-haul transport shipping and aviation and in decarbonizing several industrial processes. The cost of green hydrogen produced from renewable via electrolysis is dominated by the cost of electricity used. Operating electrolyzers only during periods of low electricity prices will limit production capacity and underutilize high investment costs in electrolyzer plants. Hydrogen production from deep offshore wind energy is a promising solution to unlock affordable electrolytic hydrogen at scale. Deep offshore locations can result in an increased capacity factor of generated wind power to 60–70% 4–5 times that of onshore locations. Dedicated wind farms for electrolysis can use the majority >80% of the produced energy to generate economical hydrogen. In some scenarios hydrogen can be the optimal carrier to transport the generated energy onshore. This review discusses the opportunities and challenges in offshore hydrogen production using electrolysis from wind energy and seawater. This includes the impact of site selection size of the electrolyzer and direct use of seawater without deionization. The review compares overall electrolysis system efficiency cost and lifetime when operating with direct seawater feed and deionized water feed using reverse osmosis and flash evaporation systems. In the short to medium term it is advised to install a reverse osmosis plant with an ion exchanger to feed the electrolysis instead of using seawater directly.
Green Hydrogen Production and Liquefaction Using Offshore Wind Power, Liquid Air, and LNG Cold Energy
Sep 2023
Publication
Coastal regions have abundant off-shore wind energy resources and surrounding areas have large-scale liquefied natural gas (LNG) receiving stations. From the engineering perspectives there are limitations in unstable off-shore wind energy and fluctuating LNG loads. This article offers a new energy scheme to combine these 2 energy units which uses surplus wind energy to produce hydrogen and use LNG cold energy to liquefy and store hydrogen. In addition in order to improve the efficiency of utilizing LNG cold energy and reduce electricity consumption for liquid hydrogen (LH2) production at coastal regions this article introduces the liquid air energy storage (LAES) technology as the intermediate stage which can stably store the cold energy from LNG gasification. A new scheme for LNG-LAES-LH2 hybrid LH2 production is built. The case study is based on a real LNG receiving station at Hainan province China and this article presents the design of hydrogen production/liquefaction process and carries out the optimizations at key nodes and proves the feasibility using specific energy consumption and exergy analysis. In a 100 MW system the liquid air storage round-trip efficiency is 71.0% and the specific energy consumption is 0.189 kWh/kg and the liquid hydrogen specific energy consumption is 7.87 kWh/kg and the exergy efficiency is 46.44%. Meanwhile the corresponding techno-economic model is built and for a LNGLAES-LH2 system with LH2 daily production 140.4 tons the shortest dynamic payback period is 9.56 years. Overall this novel hybrid energy scheme can produce green hydrogen using a more efficient and economical method and also can make full use of surplus off-shore wind energy and coastal LNG cold energy.
OIES Podcast - Aviation Fuels and the Potential of Hydrogen
Feb 2024
Publication
In the latest OIES podcast from the Hydrogen Programme James Henderson talks to Abdurahman Alsulaiman about his latest paper entitled “Navigating Turbulence: Hydrogen’s Role in the Decarbonisation of the Aviation Sector.” In the podcast we discuss the current balance of fuels in the aviation sector the importance of increasing efficiency of aero-engines and the impact of increasing passenger miles travelled. The podcast then considers different decarbonisation options for the sector focussing on a change of engine technology to allow the use of alternative fuels such as hydrogen or electricity but also looking at the potential for hydrogen to play an important role in the development of Sustainable Aviation Fuels (SAFs) for use with current engine technology. We also look at Low Carbon Aviation Fuels which are essentially existing fuels derived from a significantly decarbonised supply chain and assess whether they have an important role to play as the aviation sector targets a net zero outcome.
The podcast can be found on their website.
The podcast can be found on their website.
‘Greening’ an Oil Exporting Country: A Hydrogen, Wind and Gas Turbine Case Study
Feb 2024
Publication
In the quest for achieving decarbonisation it is essential for different sectors of the economy to collaborate and invest significantly. This study presents an innovative approach that merges technological insights with philosophical considerations at a national scale with the intention of shaping the national policy and practice. The aim of this research is to assist in formulating decarbonisation strategies for intricate economies. Libya a major oil exporter that can diversify its energy revenue sources is used as the case study. However the principles can be applied to develop decarbonisation strategies across the globe. The decarbonisation framework evaluated in this study encompasses wind-based renewable electricity hydrogen and gas turbine combined cycles. A comprehensive set of both official and unofficial national data was assembled integrated and analysed to conduct this study. The developed analytical model considers a variety of factors including consumption in different sectors geographical data weather patterns wind potential and consumption trends amongst others. When gaps and inconsistencies were encountered reasonable assumptions and projections were used to bridge them. This model is seen as a valuable foundation for developing replacement scenarios that can realistically guide production and user engagement towards decarbonisation. The aim of this model is to maintain the advantages of the current energy consumption level assuming a 2% growth rate and to assess changes in energy consumption in a fully green economy. While some level of speculation is present in the results important qualitative and quantitative insights emerge with the key takeaway being the use of hydrogen and the anticipated considerable increase in electricity demand. Two scenarios were evaluated: achieving energy self-sufficiency and replacing current oil exports with hydrogen exports on an energy content basis. This study offers for the first time a quantitative perspective on the wind-based infrastructure needs resulting from the evaluation of the two scenarios. In the first scenario energy requirements were based on replacing fossil fuels with renewable sources. In contrast the second scenario included maintaining energy exports at levels like the past substituting oil with hydrogen. The findings clearly demonstrate that this transition will demand great changes and substantial investments. The primary requirements identified are 20529 or 34199 km2 of land for wind turbine installations (for self-sufficiency and exports) and 44 single-shaft 600 MW combined-cycle hydrogen-fired gas turbines. This foundational analysis represents the commencement of the research investment and political agenda regarding the journey to achieving decarbonisation for a country.
Techno-economic Analysis of Underground Hydrogen Storage in Europe
Dec 2023
Publication
Hydrogen storage is crucial to developing secure renewable energy systems to meet the European Union’s 2050 carbon neutrality objectives. However a knowledge gap exists concerning the site-specific performance and economic viability of utilizing underground gas storage (UGS) sites for hydrogen storage in Europe. We compile information on European UGS sites to assess potential hydrogen storage capacity and evaluate the associated current and future costs. The total hydrogen storage potential in Europe is 349 TWh of working gas energy (WGE) with site-specific capital costs ranging from $10 million to $1 billion. Porous media and salt caverns boasting a minimum storage capacity of 0.5 TWh WGE exhibit levelized costs of $1.5 and $0.8 per kilogram of hydrogen respectively. It is estimated that future levelized costs associated with hydrogen storage can potentially decrease to as low as $0.4 per kilogram after three experience cycles. Leveraging these techno-economic considerations we identify suitable storage sites.
Environmental-economic Sustainability of Hydrogen and Ammonia Fuels for Short Sea Shipping Operations
Jan 2024
Publication
Alternative fuels of low or zero carbon content can decarbonise the shipping operations. This study aims at assessing the lifetime environmental-economic sustainability of ammonia and hydrogen as alternatives to diesel fuel for short sea shipping cargo vessels. A model is employed to calculate key performance indicators representing the lifetime financial sustainability and environmental footprint of the case ship using a realistic operating profile and considering several scenarios with different diesel substitution rates. Scenarios meeting the carbon emissions reduction targets set by the International Maritime Organisation (IMO) for 2030 are identified whereas policy measures for their implementation including the emissions taxation are discussed. The derived results demonstrate that the future implementation of carbon emissions taxation in the ranges of 136–965 €/t for hydrogen and 356–2647 €/t for ammonia can support these fuels financial sustainability in shipping. This study provides insights for adopting zero-carbon fuels and as such impacts the de-risking of shipping decarbonisation.
Hydrogen as a Deep Sea Shipping Fuel: Modelling the Volume Requirements
May 2024
Publication
Recent targets have increased pressure for the maritime sector to accelerate the uptake of clean fuels. A potential future fuel for shipping is hydrogen however there is a common perception that the volume requirements for this fuel are too large for deep sea shipping. This study has developed a range of techniques to accurately simulate the fuel requirements of hydrogen for a case study vessel. Hydrogen can use fuel cells which achieve higher efficiencies than combustion methods but may require a battery hybrid system to meet changes in demand. A series of novel models for different fuel cell types and other technologies have been developed. The models have been used to run dynamic simulations for different energy system setups. Simulations tested against power profiles from real-world shipping data to establish the minimum viable setup capable of meeting all the power demand for the case study vessel to a higher degree of accuracy than previously achieved. Results showed that the minimum viable setup for hydrogen was with liquid storage a 105.6 MW PEM fuel cell stack and 6.9 MWh of batteries resulting in a total system size of 8934 m3 . Volume requirement results could then be compared to other concepts such as systems using ammonia and methanol 8970 m3 and 6033 m3 respectively.
Safety Calculations for Emerging Technologies
Sep 2023
Publication
As part of executing 25 hydrogen-based Power to X (PtX) projects our team of Safety consultants has completed safety and risk assessments for a number of hydrogen production developments. Drawing on this experience we will present the importance of making comparisons between hydrogen specific data sources such as HyRAM and conventional oil and gas data sets and calculation methods to ensure that project design is carried out to the most appropriate data and provides a robust solution to demonstrate risks are managed. This presentation will be based on case studies where Fire and Explosion Risk Assessments (FERA) and Quantitative Risk Assessments (QRA) were conducted. The frequency calculations for these assessments used the release frequencies and ignition probabilities provided in HyRAM. However it is noted that the HyRAM ignition probabilities are derived from a correlation from oil and gas assessments in the 1990s. The oil and gas approach has moved on from this data source and now derives ignition probabilities based on the type of facility and fluid characteristics. To address this evolution a comparison was made between the leak frequencies for equipment in hydrogen service and established oil and gas release frequencies from IOGP. In addition a comparison between the HyRAM recommended ignition probabilities and the correlations used for oil and gas (from OEUK formerly UKOOA) was conducted. By taking this approach it was confirmed that the UKOOA data was more conservative and sensitivity calculations were carried out. It was also noted that as hydrogen technologies are emerging there is a level of uncertainty around the data and comparisons must be regularly made to ensure the most appropriate basis for calculations is used.
Hydrogen Liquefaction: A Review of the Fundamental Physics, Engineering Practice and Future Opportunities
Apr 2022
Publication
Hydrogen is emerging as one of the most promising energy carriers for a decarbonised global energy system. Transportation and storage of hydrogen are critical to its large-scale adoption and to these ends liquid hydrogen is being widely considered. The liquefaction and storage processes must however be both safe and efficient for liquid hydrogen to be viable as an energy carrier. Identifying the most promising liquefaction processes and associated transport and storage technologies is therefore crucial; these need to be considered in terms of a range of interconnected parameters ranging from energy consumption and appropriate materials usage to considerations of unique liquid-hydrogen physics (in the form of ortho–para hydrogen conversion) and boil-off gas handling. This study presents the current state of liquid hydrogen technology across the entire value chain whilst detailing both the relevant underpinning science (e.g. the quantum behaviour of hydrogen at cryogenic temperatures) and current liquefaction process routes including relevant unit operation design and efficiency. Cognisant of the challenges associated with a projected hydrogen liquefaction plant capacity scale-up from the current 32 tonnes per day to greater than 100 tonnes per day to meet projected hydrogen demand this study also reflects on the next-generation of liquid-hydrogen technologies and the scientific research and development priorities needed to enable them.
A Comparative Analysis of Different Hydrogen Production Methods and Their Environmental Impact
Nov 2023
Publication
This study emphasises the growing relevance of hydrogen as a green energy source in meeting the growing need for sustainable energy solutions. It foregrounds the importance of assessing the environmental consequences of hydrogen-generating processes for their long-term viability. The article compares several hydrogen production processes in terms of scalability costeffectiveness and technical improvements. It also investigates the environmental effects of each approach considering crucial elements such as greenhouse gas emissions water use land needs and waste creation. Different industrial techniques have distinct environmental consequences. While steam methane reforming is cost-effective and has a high production capacity it is coupled with large carbon emissions. Electrolysis a technology that uses renewable resources is appealing but requires a lot of energy. Thermochemical and biomass gasification processes show promise for long-term hydrogen generation but further technological advancement is required. The research investigates techniques for improving the environmental friendliness of hydrogen generation through the use of renewable energy sources. Its ultimate purpose is to offer readers a thorough awareness of the environmental effects of various hydrogen generation strategies allowing them to make educated judgements about ecologically friendly ways. It can ease the transition to a cleaner hydrogen-powered economy by considering both technological feasibility and environmental issues enabling a more ecologically conscious and climate-friendly energy landscape.
Literature Review on Life Cycle Assessment of Transportation Alternative Fuels
Aug 2023
Publication
Environmental concerns such as global warming and human health damage are intensifying and the transportation sector significantly contributes to carbon and harmful emissions. This review examines the life cycle assessment (LCA) of alternative fuels (AF) evaluating current research on fuel types LCA framework development life cycle inventory (LCI) and impact selection. The objectives of this paper are: (1) to compare various AF LCA frameworks and develop a comprehensive framework for the transportation sector; (2) to identify emission hotspots of different AFs through simulations and real-world cases; (3) to review AF LCA research; (4) to extract valuable information for potential future research directions. The analysis reveals that all stages except for hydrogen use have an environmental impact. LCA boundaries and LCIs vary considerably depending on the raw materials production processes and products involved leading to different emission hotspots. Due to knowledge or data limitations some stages remain uncalculated in the current study emphasizing the need for further refinement of the AF LCI. Future research should also explore the various impacts of widespread adoption of alternative fuels in transportation encompassing social economic and environmental aspects. Lastly the review provides structured recommendations for future research directions.
The Global Shift to Hydrogen and Lessons from Outside Industry
Sep 2023
Publication
The recognition of hydrogen as a technically viable combustion fuel and as an alternative to more carbon intensive technologies for all forms of industrial applications has resulted in significant global interest leading to both public and private investment. As with most shifts in technology public acceptance and its safe production and handling will be key to its growth as a widespread energy vector. Specific properties of hydrogen that may prompt concern from the public and that need to be considered in terms of its use and safe handling include the following:<br/>• Hydrogen in its natural state is a colourless odourless and tasteless gas that is combustible with very low ignition energy burns nearly invisibly and is explosive at a very wide range of concentrations with an oxidate.<br/>• Hydrogen as any other gas except oxygen is an asphyxiant in a confined space.<br/>• Hydrogen is an extremely small molecule and interacts with many materials which over time can alter the physical properties and can lead to embrittlement and failure. Additionally due to the small molecular size its permeation and diffusion characteristics make it more difficult to contain compared to other gases.<br/>As hydrogen production use and storage increases these properties will come under greater scrutiny and may raise questions surrounding the cost/benefit of the technology. Understanding how the public sees this technology in relation to their safety and daily lives is important in hydrogen’s adoption as a low carbon alternative. A review of deployable experience relevant to the handling of hydrogen in other industries will help us to understand the technology and experience necessary for ensuring the success of the scaling up of a hydrogen economy. The social considerations of the impacts should also be examined to consider acceptance of the technology as it moves into the mainstream.
Innovative Strategies for Combining Solar and Wind Energy with Green Hydrogen Systems
Oct 2024
Publication
The integration of wind and solar energy with green hydrogen technologies represents an innovative approach toward achieving sustainable energy solutions. This review examines state-ofthe-art strategies for synthesizing renewable energy sources aimed at improving the efficiency of hydrogen (H2 ) generation storage and utilization. The complementary characteristics of solar and wind energy where solar power typically peaks during daylight hours while wind energy becomes more accessible at night or during overcast conditions facilitate more reliable and stable hydrogen production. Quantitatively hybrid systems can realize a reduction in the levelized cost of hydrogen (LCOH) ranging from EUR 3.5 to EUR 8.9 per kilogram thereby maximizing the use of renewable resources but also minimizing the overall H2 production and infrastructure costs. Furthermore advancements such as enhanced electrolysis technologies with overall efficiencies rising from 6% in 2008 to over 20% in the near future illustrate significant progress in this domain. The review also addresses operational challenges including intermittency and scalability and introduces system topologies that enhance both efficiency and performance. However it is essential to consider these challenges carefully because they can significantly impact the overall effectiveness of hydrogen production systems. By providing a comprehensive assessment of these hybrid systems (which are gaining traction) this study highlights their potential to address the increasing global energy demands. However it also aims to support the transition toward a carbon-neutral future. This potential is significant because it aligns with both environmental goals and energy requirements. Although challenges remain the promise of these systems is evident.
Overview and Prospects of Low-emissions Hydrogen (H2) Energy Systems: Roadmap for a Sustainable H2 Economy
Jul 2024
Publication
Hydrogen (2 ) has a big role to play in energy transition to achieve net-zero carbon emissions by 2050. For 2 to compete with other fuels in the energy market more research is required to mitigate key issues like greenhouse gas (GHG) emissions safety and end-use costs. For these reasons a software-supported technical overview of 2 production storage transportation and utilisation is introduced. Drawbacks and mitigation approaches for 2 technologies were highlighted. The recommended areas include solar thermal or renewable-powered plasma systems for feedstock preheating and oxy-hydrogen combustion to meet operating temperatures and heat duties due to losses; integration of electrolysis of 2 into hydrocarbon reforming methods to replace air separation unit (ASU); use of renewable power sources for electrical units and the introduction of thermoelectric units to maximise the overall efficiency. Furthermore a battolyser system for small-scale energy storage; new synthetic hydrides with lower absorption and desorption energy; controlled parameters and steam addition to the combustor/cylinder and combustors with fitted heat exchangers to reduce emissions and improve the overall efficiency are also required. This work also provided detailed information on any of these systems implementations based on location factors and established a roadmap for 2 production and utilisation. The proposed 2 production technologies are hybrid pyrolysis-electrolysis and integrated AD-MEC and DR systems using renewable bioelectrochemical and low-carbon energy systems. Production and utilisation of synthetic natural gas (NG) using renewablepowered electrolysis of 2 oxy-fuel and direct air capture (DAC) is another proposed 2 energy system for a sustainable 2 economy. By providing these factors and information researchers can work towards pilot development and further efficiency enhancement.
Pressure Decline and Gas Expansion in Underground Hydrogen Storage: A Pore-scale Percolation Study
Aug 2024
Publication
Using high-resolution micro-CT imaging at 2.98 μm/voxel we compared the percolation of hydrogen in gas injection with gas expansion for a hydrogen-brine system in Bentheimer sandstone at 1 MPa and 20 ◦C representing hydrogen storage in an aquifer. We introduced dimensionless numbers to quantify the contribution of advection and expansion to displacement. We analysed the 3D spatial distribution of gas and its displacement in both cases and demonstrated that in gas injection hydrogen can only advance from a connected cluster in an invasion-percolation type process while in gas expansion hydrogen can access more of the pore space even from disconnected clusters. The average gas saturation in the sample increased from 30% to 50% by gas expansion and we estimated that 10% of the expanded volume is attributed to hydrogen exsolution from the brine. This work emphasises the importance of studying the combined effects of pressure decline and gas withdrawal in hydrogen storage to assess the influence of gas expansion on remobilising trapped gases.
Forecasting the Development of Clean Energy Vehicles in Large Cities: A System Dynamics Perspective
Jan 2024
Publication
Clean energy vehicles (CEVs) e.g. battery electric vehicles (BEVs) and fuel cell electric vehicles (FCEVs) are being adopted gradually to substitute for internal combustion engine vehicles (ICEVs) around the world. The fueling infrastructure is one of the key drivers for the development of the CEV market. When the government develops funding policies to support the fueling infrastructure development for FCEVs and BEVs it has to assess the effectiveness of different policy options and identify the optimal policy combination which is very challenging in transportation research. In this paper we develop a system dynamics model to study the feedback mechanism between the fueling infrastructure funding policies and the medium- to long-term diffusion of FCEVs and BEVs and the competition between FCEVs and BEVs based on relevant policy and market data in Guangzhou China. The results of the modeling analysis are as follows. (1) Funding hydrogen refueling stations and public charging piles has positive implications for achieving the substitution of CEVs for ICEVs. (2) Adjusting the funding ratio of hydrogen refueling stations and public charging piles or increasing the funding budget and extending the funding cycle does not have a significant impact on the overall substitution of CEVs for ICEVs but only impacts the relative competitive advantage between FCEVs and BEVs. (3) An equal share of funding for hydrogen refueling stations and public charging piles would have better strategic value for future net-zero-emissions urban transportation. (4) Making a moderate-level full investment in hydrogen refueling stations coupled with hydrogen refueling subsidies can provide the ideal conditions for FCEV diffusion.
CFD Model of Refuelling through the Entire Equipment of a Hydrogen Refuelling Station
Dec 2023
Publication
This paper aims at the development and validation of a computational fluid dynamic (CFD) model for simulations of the refuelling process through the entire equipment of the hydrogen refuelling station (HRS). The absence of such models hinders the design of inherently safer refuelling protocols for an arbitrary combination of HRS equipment hydrogen storage parameters and environmental conditions. The CFD model is validated against the complete process of refuelling lasting 195s in Test No.1 performed by the National Renewable Energy Laboratory (NREL). The test equipment includes high-pressure tanks of HRS pressure control valve (PCV) valves pipes breakaway hose and nozzle all the way up to three onboard tanks. The model accurately reproduced hydrogen temperature and pressure through the entire line of HRS equipment. A standout feature of the CFD model distinguishing it from simplified models is the capability to predict temperature non-uniformity in onboard tanks a crucial factor with significant safety implications.
Techno-economic Analysis of Direct Air Carbon Capture and Hydrogen Production Integrated with a Small Modular Reactor
Dec 2023
Publication
This study aims to explore the techno-economic potential of harnessing waste heat from a Small Modular Reactor (SMR) to fuel Direct Air Carbon Capture (DACC) and High Temperature Steam Electrolysis (HTSE) technologies. The proposed system’s material flows and energy demands are modelled via the ASPEN Plus v12.1 where results are utilised to provide estimates of the Levelised Cost of DACC (LCOD) and Levelised Cost of Hydrogen (LCOH). The majority of thermal energy and electrical utilities are assumed to be supplied directly by the SMR. A sensitivity analysis is then performed to investigate the effects of core operational parameters of the system. Key results indicate levelised costs of 4.66 $/kgH2 at energy demands of 34.37 kWh/kgH2 and 0.02 kWh/kgH2 thermal for HTSE hydrogen production and 124.15 $/tCO2 at energy demands of 31.67 kWh/tCO2 and 126.33 kWh/tCO2 thermal for carbon capture; parameters with most impact on levelised costs are air intake and steam feed for LCOD and LCOH respectively. Both levelised costs i.e. LCOD and LCOH would decrease with the production scale. The study implies that an integrated system of DACC and HTSE provided the best cost-benefit results however the cost-benefit analysis is heavily subjective to geography politics and grid demand.
Safety of Cryogenic Liquid Hydrogen Bunkering Operations - The Gaps Between Existing Knowhow and Industry Needs
Sep 2023
Publication
Hydrogen plays an important role in the global transition towards Net-Zero emission. While pipelines are a viable option to transport large quantities of compressed hydrogen over long distances it is not always practical in many applications. In such situations a viable option is to transport and deliver large quantities of hydrogen as cryogenic liquid. The liquefaction process cools hydrogen to cryogenic temperatures below its boiling point of -259.2 0C. Such extreme low temperature implies specific hazards and risks which are different from those associated with the relatively well-known compressed gaseous hydrogen. Managing these specific issues brings new challenges for the stakeholders.<br/>Furthermore the transfer of liquid hydrogen (LH2) and its technical handling is relatively well known for industrial gas or space applications. Experience with LH2 in public and populated areas such as truck and aircraft refuelling stations or port bunkering stations for example is limited or non-existent. Safety requirements in these applications which involve or are in proximity of untrained public are different from rocket/aerospace industry.<br/>The manuscript reviews knowhow already gained by the international hydrogen safety community; and on such basis elucidate the gaps which are yet to be filled to meet industry needs to design and operate inherently safe LH2 operations including the implications for regulations codes and standards (RCS). Where relevant the associated gaps in some underpinning sciences will be mentioned; and the need to contextualise the information and safety practices from NASA1/ESA2/JAXA3 to inform risk adoption will be summarised.
Look-ahead Scheduling of Energy-Water Nexus Integrated with Power2X Conversion Technologies under Multiple Uncertainties
Aug 2023
Publication
Co-optimizing energy and water resources in a microgrid can increase efficiency and improve economic performance. Energy-water storage (EWS) devices are crucial components of a high-efficient energy-water microgrid (EWMG). The state of charge (SoC) at the end of the first day of operation is one of the most significant variables in EWS devices since it is used as a parameter to indicate the starting SoC for the second day which influences the operating cost for the second day. Hence this paper examines the benefits and applicability of a lookahead optimization strategy for an EWMG integrated with multi-type energy conversion technologies and multienergy demand response to supply various energy-water demands related to electric/hydrogen vehicles and commercial/residential buildings with the lowest cost for two consecutive days. In addition a hybrid info-gap/robust optimization technique is applied to cover uncertainties in photovoltaic power and electricity prices as a tri-level optimization framework without generating scenarios and using the probability distribution functions. Duality theory is also used to convert the problem into a single-level MILP so that it can be solved by CPLEX. According to the findings the implemented energy-water storage systems and look-ahead strategy accounted for respectively 4.03% and 0.43% reduction in the total cost.
IEA TCP Task 43 - Subtask Safety Distances: State of the Art
Sep 2023
Publication
The large deployment of hydrogen technologies for new applications such as heat power mobility and other emerging industrial utilizations is essential to meet targets for CO2 reduction. This will lead to an increase in the number of hydrogen installations nearby local populations that will handle hydrogen technologies. Local regulations differ and provide different safety and/or separation distances in different geographies. The purpose of this work is to give an insight on different methodologies and recommendations developed for hydrogen (mainly) risk management and consequences assessment of accidental scenarios. The first objective is to review available methodologies and to identify the divergent points on the methodology. For this purpose a survey has been launched to obtain the needed inputs from the subtask participants. The current work presents the outcomes of this survey highlighting the gaps and suggesting the prioritization of the actions to take to bridge these gaps.
A Review on Liquid Hydrogen Fuel Systems in Aircraft Applications for Gas Turbine Engines
Oct 2024
Publication
The transition from traditional aviation fuels to low-emission alternatives such as hydrogen is a crucial step towards a sustainable future for aviation. Conventional jet fuels substantially contribute to greenhouse gas emissions and climate change. Hydrogen fuel especially "green" hydrogen offers great potential for achieving full sustainability in aviation. Hybrid/electric/fuel cell technologies may be used for shorter flights while longrange aircraft are more likely to combust hydrogen in gas turbines. Liquid hydrogen is necessary to minimize storage tank weight but the required fuel systems are at a low technology readiness level and differ significantly from Jet A-1 systems in architecture operation and performance. This paper provides an in-depth review covering the development of liquid hydrogen fuel system design concepts for gas turbines since the 1950s compares insights from key projects such as NASA studies and ENABLEH2 alongside an analysis of recent publications and patent applications and identifies the technological advancements required for achieving zeroemission targets through hydrogen-fuelled propulsion.
National Gas FutureGrid Phase 1 Closure Report
Jul 2024
Publication
This project an essential part of the National Gas HyNTS programme endeavours to align the NTS with GB’s net zero ambitions by demonstrating the operational viability of the system with varying hydrogen blends using decommissioned assets typical of the natural gas network today ultimately aiming for 100% hydrogen conveyance. Several desktop studies were undertaken within the HyNTS programme to confirm the theoretical potential of the NTS to transport hydrogen safely and reliably. Further to these studies practical demonstration was deemed necessary to bridge the knowledge gaps and ensure the system’s transition maintains the utmost safety and reliability standards. A range of tests on decommissioned assets were conducted offline in a controlled environment to ensure robust outcomes that will ultimately start to build the safety case for a hydrogen network. The key deliverables and testing achievements of FutureGrid included: • Operational testing with natural gas and 2% 5% 20% and 100% hydrogen to verify the network’s ability to transport hydrogen and varying blends. • Standalone offline testing modules complementing evidence gathered on the main test facility. These address specific areas of concern including material permeation flange integrity asset leakage and rupture consequence which are essential for risk mitigation and safety assurance. FutureGrid is a global first facility and a critical part of National Gas’ hydrogen programme providing physical evidence of the capability of our network to transport hydrogen. It provides key evidence for hydrogen blending alongside 100% hydrogen pipelines which are planned under Project Union our Hydrogen Backbone across GB. FutureGrid is pivotal in the journey to reaching Net Zero by 2050 and is a fully operational proven technical demonstrator. FutureGrid’s repurposed assets are representative of today’s live high pressure gas network and have been subjected to testing at different blends of natural gas with hydrogen and 100% hydrogen; this was achieved with no major findings in differences in terms of how the assets interact with hydrogen. The overall project completion date was delayed from November 2023 to February 2024 due to technical issues with the newly built hydrogen re‑compressor. There were no changes made to the project costs.
Hopes and Fears for a Sustainable Energy Future: Enter the Hydrogen Acceptance Matrix
Feb 2024
Publication
Hydrogen-fuelled technologies for home heating and cooking may provide a low-carbon solution for decarbonising parts of the global housing stock. For the transition to transpire the attitudes and perceptions of consumers must be factored into policy making efforts. However empirical studies are yet to explore potential levels of consumer heterogeneity regarding domestic hydrogen acceptance. In response this study explores a wide spectrum of consumer responses towards the prospect of hydrogen homes. The proposed spectrum is conceptualised in terms of the ‘domestic hydrogen acceptance matrix’ which is examined through a nationally representative online survey conducted in the United Kingdom. The results draw attention to the importance of interest and engagement in environmental issues knowledge and awareness of renewable energy technologies and early adoption potential as key drivers of domestic hydrogen acceptance. Critically strategic measures should be taken to convert hydrogen scepticism and pessimism into hope and optimism by recognising the multidimensional nature of consumer acceptance. To this end resources should be dedicated towards increasing the observability and trialability of hydrogen homes in proximity to industrial clusters and hubs where the stakes for consumer acceptance are highest. Progress towards realising a net-zero society can be supported by early stakeholder engagement with the domestic hydrogen acceptance matrix.
Potential Cost Savings of Large-scale Blue Hydrogen Production via Sorption-enhanced Steam Reforming Process
Jan 2024
Publication
As countries work towards achieving net-zero emissions the need for cleaner fuels has become increasingly urgent. Hydrogen produced from fossil fuels with carbon capture and storage (blue hydrogen) has the potential to play a significant role in the transition to a low-carbon economy. This study examined the technical and economic potential of blue hydrogen produced at 600 MWth(LHV) and scaled up to 1000 MWth(LHV) by benchmarking sorption-enhanced steam reforming process against steam methane reforming (SMR) autothermal gasheated reforming (ATR-GHR) integrated with carbon capture and storage (CCS) and SMR with CCS. Aspen Plus® was used to develop the process model which was validated using literature data. Cost sensitivity analyses were also performed on two key indicators: levelised cost of hydrogen and CO2 avoidance cost by varying natural gas price electricity price CO2 transport and storage cost and carbon price. Results indicate that at a carbon price of 83 £/tCO2e the LCOH for SE-SR of methane is the lowest at 2.85 £/kgH2 which is 12.58% and 22.55% lower than that of ATR-GHR with CCS and SMR plant with CCS respectively. The LCOH of ATR-GHR with CCS and SMR plant with CCS was estimated to be 3.26 and 3.68 £/kgH2 respectively. The CO2 avoidance cost was also observed to be lowest for SE-SR followed by ATR-GHR with CCS then SMR plant with CCS and was observed to reduce as the plant scaled to 1000 MWth(LHV) for these technologies.
Review on the Thermal Neutrality of Application-orientated Liquid Organic Hydrogen Carrier for Hydrogen Energy Storage and Delivery
Aug 2023
Publication
The depletion and overuse of fossil fuels present formidable challenge to energy supply system and environment. The human society is in great need of clean renewable and sustainable energy which can guarantee the long-term utilization without leading to escalation of greenhouse effect. Hydrogen as an extraordinary secondary energy is capable of realizing the target of environmental protection and transferring the intermittent primary energy to the application terminal while its nature of low volumetric energy density and volatility need suitable storage method and proper carrier. In this context liquid organic hydrogen carrier (LOHC) among a series of storage methods such as compressed and liquefied hydrogen provokes a considerable amount of research interest since it is proven to be a suitable carrier for hydrogen with safety and stability. However the dehydrogenation of hydrogen-rich LOHC materials is an endothermic process and needs large energy consumption which hampers the scale up of the LOHC system. The heat issue is thus essential to be addressed for fulfilling the potential of LOHC. In this work several strategies of heat intensification and management for LOHC system including the microwave irradiation circulation of exhaust heat and direct LOHC fuel cell are summarized and analyzed to provide suggestions and directions for future research.
Optimal Hydrogen Infrastructure Planning for Heat Decarbonisation
Feb 2024
Publication
Energy decarbonisation is essential to achieve Net-Zero emissions goal by 2050. Consequently investments in alternative low-carbon pathways and energy carriers for the heat sector are required. In this study we propose an optimisation framework for the transition of heat sector in Great Britain focusing on hydrogen infrastructure decisions. A spatially-explicit mixed-integer linear programming (MILP) evolution model is developed to minimise the total system’s cost considering investment and operational decisions. The optimisation framework incorporates both long-term planning horizon of 5-year steps from 2035 to 2050 and typical days with hourly resolution. Aiming to alleviate the computational effort of such multiscale model two hierarchical solution approaches are suggested that result in computational time reduction. From the optimisation results it is shown that the installation of gas reforming hydrogen production technologies with CCS and biomass gasification with CCS can provide a cost-effective strategy achieving decarbonisation goal. What-if analysis is conducted to demonstrate further insights for future hydrogen infrastructure investments. Results indicate that as cost is highly dependent on natural gas price Water Electrolysis capacity increases significantly when gas price rises. Moreover the introduction of carbon tax policy can lead to lower CO2 net emissions.
Case Study: Quantitative Risk Assessment of Hydrogen Blended Natural Gas for an Existing Distribution Network and End-use Equipment in Fort Saskatchewan, Alberta
Sep 2023
Publication
In a first-of-its-kind project for Alberta ATCO Gas and Pipelines Ltd. (ATCO) began delivering a 5% blend of hydrogen (H2) in natural gas into a subsection of the existing Fort Saskatchewan natural gas distribution system (approximately 2100 customers). The project was commissioned in October 2022 with the intention of increasing the blend to 20% H₂ in 2023. As part of project due diligence ATCO in partnership with DNV undertook Quantitative Risk Assessments (QRAs) to understand any risks associated with the introduction of blended gas into its existing distribution system and to its customers. This paper describes key findings from the QRAs through the comparison of risks associated with H2 blended natural gas at concentrations of 5% and 20% H₂ and the current natural gas configuration. The impact of operating pressure and hydrogen blend composition formed a sensitivity study completed as part of this work. To provide context and to help interpret the results an individual risk (IR) level of 1 × 10-6 per year was utilised as a reference threshold for the limit of the ‘broadly acceptable’ risk level and juxtaposed against comparable risk scenarios. Although adding hydrogen increases the IR of ignited releases from mains services meters regulators and end user appliances the ignited release IR was always well below the broadly acceptable reference criterion for all operating pressures and blend cases considered as part of the project. The IR associated with carbon monoxide poisoning dominates the overall IR and the results demonstrate that the reduction in carbon monoxide poisoning associated with the introduction of H₂ blended natural gas negates any incremental risk associated with ignited releases due to H₂ blended gas. The paper also explains how the results of the QRA were incorporated into Engineering Assessments as per the requirements of CSA Z662:19 [1] to justify the conversion of existing natural gas infrastructure to H₂ blended gas infrastructure.
Mitigating Risks in Hydrogen-powered Transportation: A Comprehensive Risk Assessment for Hydrogen Refuelling Stations, Vehicles, and Garages
Oct 2024
Publication
Hydrogen is increasingly seen as a viable alternative to fossil fuels in transportation crucial to achieving net-zero energy goals. However the rapid expansion of hydrogen-powered transportation is outpacing safety standards posing significant risks due to limited operational experience involvement of new actors and lack of targeted guidelines. This study addresses the urgent need for a tailored comprehensive risk assessment framework. Using Structured What-If (SWIFT) and bowtie barrier analysis the research evaluates a hypothetical pilot project focusing on hydrogen refuelling stations vehicles and garages. The study identifies critical hazards and assesses the adequacy of current risk mitigation measures. Key findings reveal gaps in safety practices leading to 41 actionable steps and 5 key activities to help new actors manage hydrogen risks effectively. By introducing novel safety guidelines this research contributes to the development of safe hydrogen use and advances the understanding of hydrogen risks ensuring its sustainable integration into transportation systems.
Coupling Green Hydrogen Production to Community Benefits: A Pathway to Social Acceptance?
Feb 2024
Publication
Hydrogen energy technologies are forecasted to play a critical supporting role in global decarbonisation efforts as reflected by the growth of national hydrogen energy strategies in recent years. Notably the UK government published its Hydrogen Strategy in August 2021 to support decarbonisation targets and energy security ambitions. While establishing techno-economic feasibility for hydrogen energy systems is a prerequisite of the prospective transition social acceptability is also needed to support visions for the ‘hydrogen economy’. However to date societal factors are yet to be embedded into policy prescriptions. Securing social acceptance is especially critical in the context of ‘hydrogen homes’ which entails replacing natural gas boilers and hobs with low-carbon hydrogen appliances. Reflecting the nascency of hydrogen heating and cooking technologies the dynamics of social acceptance are yet to be explored in a comprehensive way. Similarly public perceptions of the hydrogen economy and emerging national strategies remain poorly understood. Given the paucity of conceptual and empirical insights this study develops an integrated acceptance framework and tests its predictive power using partial least squares structural equation modelling. Results highlight the importance of risk perceptions trust dynamics and emotions in shaping consumer perceptions. Foremost prospects for deploying hydrogen homes at scale may rest with coupling renewable-based hydrogen production to local environmental and socio-economic benefits. Policy prescriptions should embed societal factors into the technological pursuit of large-scale sustainable energy solutions to support socially acceptable transition pathways.
Nuclear Enabled Hydrogen CO-generation: Safety and Regulatory Insight
Sep 2023
Publication
National Nuclear Laboratory (NNL) is aiming to demonstrate through a research and development programme that nuclear enabled hydrogen can be used to support future clean energy systems. Demonstrating the safe operation of hydrogen facilities co-generating with a nuclear reactor will be key to enabling the deployment and success of nuclear enabled hydrogen technologies in the future. During the deployment continuity of supply will be paramount and possibly requires inter-seasonal storage. Co-generation is a means of using a source of energy in this case a nuclear reactor to efficiently produce power and thermal energy. Since a great deal of the heat energy is lost to the environment in a power plant making use of wasted energy for other useful output like the production of hydrogen and direct heating would be advantageous to plant economics and energy system flexibility. The civil nuclear industry is regulated around the world. This approach ensures that all the activities related to the production of power from nuclear and the hazards associated with ionising radiation are controlled in a manner which protects workers members of the public property and the environment. Nuclear safety assessments follow a rigorous process and are required as part of the Nuclear Site Licence. A fundamental requirement which is cited in the UK legislation is that the risks associated with all activities at the licensed site be reduced to As Low As Reasonably Practicable (ALARP). The principle places a requirement on duty holders to implement measures to reduce risk where doing so is considered reasonable and proportionate. The inclusion of risks for hazardous materials associated with the hydrogen production facilities need to be considered and this requires harmonisation of two different safety and regulatory governance regimes which have not previously interacted in this way. The safety demonstration for nuclear facilities is provided through the Safety Case.
An Overview of Application-orientated Multifunctional Large-scale Stationary Battery and Hydrogen Hybrid Energy Storage System
Dec 2023
Publication
The imperative to address traditional energy crises and environmental concerns has accelerated the need for energy structure transformation. However the variable nature of renewable energy poses challenges in meeting complex practical energy requirements. To address this issue the construction of a multifunctional large-scale stationary energy storage system is considered an effective solution. This paper critically examines the battery and hydrogen hybrid energy storage systems. Both technologies face limitations hindering them from fully meeting future energy storage needs such as large storage capacity in limited space frequent storage with rapid response and continuous storage without loss. Batteries with their rapid response (90%) excel in frequent short-duration energy storage. However limitations such as a selfdischarge rate (>1%) and capacity loss (~20%) restrict their use for long-duration energy storage. Hydrogen as a potential energy carrier is suitable for large-scale long-duration energy storage due to its high energy density steady state and low loss. Nevertheless it is less efficient for frequent energy storage due to its low storage efficiency (~50%). Ongoing research suggests that a battery and hydrogen hybrid energy storage system could combine the strengths of both technologies to meet the growing demand for large-scale long-duration energy storage. To assess their applied potentials this paper provides a detailed analysis of the research status of both energy storage technologies using proposed key performance indices. Additionally application-oriented future directions and challenges of the battery and hydrogen hybrid energy storage system are outlined from multiple perspectives offering guidance for the development of advanced energy storage systems.
Hydrogen Sampling Systems Adapted to Heavy-duty Refuelling Stations' Current and Future Specifications - A Review
Sep 2024
Publication
To meet the new regulation for the deployment of alternative fuels infrastructure which sets targets for electric recharging and hydrogen refuelling infrastructure by 2025 or 2030 a large infrastructure comprising trucksuitable hydrogen refuelling stations will soon be required. However further standardisation is required to support the uptake of hydrogen for heavy-duty transport for Europe’s green energy future. Hydrogen-powered vehicles require pure hydrogen as some contaminants can reduce the performance of the fuel cell even at very low levels. Even if previous projects have paved the way for the development of the European quality infrastructure for hydrogen conformity assessment sampling systems and methods have yet to be developed for heavy-duty hydrogen refuelling stations (HD-HRS). This study reviews different aspects of the sampling of hydrogen at heavy-duty hydrogen refuelling stations for purity assessment with a focus on the current and future specifications and operations at HD-HRS. This study describes the state-of-the art of sampling systems currently under development for use at HD-HRS and highlights a number of aspects which must be taken into consideration to ensure safe and accurate sampling: risk assessment for the whole sampling exercise selection of cylinders methods to prepare cylinders before the sampling filling pressure and venting of the sampling systems.
Gas Storage in Geological Formations: A Comparative Review on Carbon Dioxide and Hydrogen Storage
Feb 2024
Publication
Carbon dioxide and hydrogen storage in geological formations at Gt scale are two promising strategies toward net-zero carbon emissions. To date investigations into underground hydrogen storage (UHS) remain relatively limited in comparison to the more established knowledge body of underground carbon dioxide storage (UCS). Despite their analogous physical processes can be used for accelerating the advancements in UHS technology the existing distinctions possibly may hinder direct applicability. This review therefore contributes to advancing our fundamental understanding on the key differences between UCS and UHS through multi-scale comparisons. These comparisons encompass key factors influencing underground gas storage including storage media trapping mechanisms and respective fluid properties geochemical and biochemical reactions and injection scenarios. They provide guidance for the conversion of our existing knowledge from UCS to UHS emphasizing the necessity of incorporating these factors relevant to their trapping and loss mechanisms. The article also outlines future directions to address the crucial knowledge gaps identified aiming to enhance the utilisation of geological formations for hydrogen and carbon dioxide storage.
Energy Efficiency of Hydrogen for Vehicle Propulsion: On- or Off-board H2 to Electricity Conversion?
Nov 2024
Publication
If hydrogen fuel is available to support the transportation sector decarbonization its usage can be placed either directly onboard in a fuel cell vehicle or indirectly off-board by using a fuel cell power station to produce electricity to charge a battery electric vehicle. Therefore in this work the direct and indirect conversion scenarios of hydrogen to vehicle propulsion were investigated regarding energy efficiency. Thus in the first scenario hydrogen is the fuel for the onboard electricity production to propel a fuel cell vehicle while in the second hydrogen is the electricity source to charge the battery electric vehicle. When simulated for a drive cycle results have shown that the scenario with the onboard fuel cell consumed about 20% less hydrogen demonstrating higher energy efficiency in terms of driving range. However energy efficiency depends on the outside temperature when heat loss utilization is considered. For outside temperatures of − 5 ◦C or higher the system composed of the battery electric vehicle fueled with electricity from the off-board fuel cell was shown to be more energyefficient. For lower temperatures the system composed of the onboard fuel cell again presented higher total (heat + electricity) efficiency. Therefore the results provide valuable insights into how hydrogen fuel can be used for vehicle propulsion supporting the hydrogen economy development.
A Novel LH2/GH2/Battery Multi-energy Vehicle Supply Station using 100% Local Wind Energy, Technical, Economic and Environmental Perspectives
Feb 2023
Publication
With the gradual maturity of wind power technology China’s wind power generation has grown rapidly over the recent years. However due to the on-site inconsumable electricity the phenomenon of large-scale “wind curtailment” occurs in some areas. In this paper a novel hybrid hydrogen/electricity refueling station is built near a wind farm and a part of the surplus wind power is used to charge electric trucks and the other part of the surplus power is used to produce “green hydrogen”. According to real-time load changes different amounts of liquid hydrogen and gas hydrogen can be properly coordinated to provide timely energy supply for hydrogen trucks. For a 400 MW wind farm in the western Inner Mongolia China the feasibility of the proposed system has been carried out based on the sensitivity and reliability analysis the static and dynamic economic modeling with an entire life cycle analysis. Compared to the conventional technology the initial investment of the proposed scheme (700.07 M$) decreases by 13.97% and the dynamic payback period (10.93 years) decreases by 25.87%. During the life cycle of the proposed system the accumulative NPV reaches 184.63 M$ which increases by 3.14 times compared to the case by conventional wind technology.
Cost Modelling-based Route Applicablity Analysis of United Kingdom Pasenger Railway Decarbonization Options
Jun 2024
Publication
The UK government plans to phase out pure diesel trains by 2040 and fully decarbonize railways by 2050. Hydrogen fuel cell (HFC) trains electrified trains using pantographs (Electrified Trains) and battery electric multiple unit (BEMU) trains are considered the main solutions for decarbonizing railways. However the range of these decarbonization options’ line upgrade cost advantages is unclear. This paper analyzes the upgrade costs of three types of trains on different lines by constructing a cost model and using particle swarm optimization (PSO) including operating costs and fixed investment costs. For the case of decarbonization of the London St. Pancras to Leicester line the electrified train option is more cost-effective than the other two options under the condition that the service period is 30 years. Then the traffic density range in which three new energy trains have cost advantages on different line lengths is calculated. For route distances under 100 km and with a traffic density of less than 52 trips/day BEMU trains have the lowest average cost while electrified trains are the most costeffective in other ranges. For route distances over 100 km the average cost of HFC trains is lower than that of electrified trains at traffic densities below about 45 trips/day. In addition if hydrogen prices fall by 26 % the cost advantage range of HFC trains will increase to 70 trips per day. For route distances under 100 km BEMU trains still maintain their advantages in terms of lower traffic density.
Integration of Renewable Energy Sources in Tandem with Electrolysis: A Technology Review for Green Hydrogen Production
Jun 2024
Publication
The global shift toward sustainable energy solutions emphasises the urgent need to harness renewable sources for green hydrogen production presenting a critical opportunity in the transition to a low-carbon economy. Despite its potential integrating renewable energy with electrolysis to produce green hydrogen faces significant technological and economic challenges particularly in achieving high efficiency and cost-effectiveness at scale. This review systematically examines the latest advancements in electrolysis technologies—alkaline proton exchange membrane electrolysis cell (PEMEC) and solid oxide—and explores innovative grid integration and energy storage solutions that enhance the viability of green hydrogen. The study reveals enhanced performance metrics in electrolysis processes and identifies critical factors that influence the operational efficiency and sustainability of green hydrogen production. Key findings demonstrate the potential for substantial reductions in the cost and energy requirements of hydrogen production by optimising electrolyser design and operation. The insights from this research provide a foundational strategy for scaling up green hydrogen as a sustainable energy carrier contributing to global efforts to reduce greenhouse gas emissions and advance toward carbon neutrality. The integration of these technologies could revolutionise energy systems worldwide aligning with policy frameworks and market dynamics to foster broader adoption of green hydrogen.
A Parametric Study on In-situ Hydrogen Production from Hydrocarbon Reservoirs - Effect of Reservoir and Well Properties
Jul 2024
Publication
Energy transition is a key driver to combat climate change and achieve zero carbon future. Sustainable and costeffective hydrogen production will provide valuable addition to the renewable energy mix and help minimize greenhouse gas emissions. This study investigates the performance of in-situ hydrogen production (IHP) process using a full-field compositional model as a precursor to experimental validation The reservoir model was simulated as one geological unit with a single point uniform porosity value of 0.13 and a five-point connection type between cell to minimize computational cost. Twenty-one hydrogen forming reactions were modelled based on the reservoir fluid composition selected for this study. The thermodynamic and kinetic parameters for the reactions were obtained from published experiments due to the absence of experimental data specific to the reservoir. A total of fifty-four simulation runs were conducted using CMG STARS software for 5478 days and cumulative hydrogen produced for each run was recorded. Results generated were then used to build a proxy model using Box-Behnken design of experiment method and Support Vector Machine with RBF kernel. To ascertain accuracy of the proxy models analysis of variance (ANOVA) was conducted on the variables. The average absolute percentage error between the proxy model and numerical simulation was calculated to be 10.82%. Optimization of the proxy model was performed using genetic algorithm to maximize cumulative hydrogen produced. Based on this optimized model the influence of porosity permeability well location injection rate and injection pressure were studied. Key results from this study reveals that lower permeability and porosity reservoirs supports more hydrogen yield injection pressure had a negligible effect on hydrogen yield and increase in oxygen injection rate corelated strongly with hydrogen production until a threshold value beyond which hydrogen yield decreased. The framework developed in the study could be used as tool to assess candidate reservoirs for in-situ hydrogen production.
Assessing the Potential of Decarbonization Options for Industrial Sectors
Jan 2024
Publication
Industry emits around a quarter of global greenhouse gas (GHG) emissions. This paper presents the first comprehensive review to identify the main decarbonization options for this sector and their abatement potentials. First we identify the important GHG emitting processes and establish a global average baseline for their current emissions intensity and energy use. We then quantify the energy and emissions reduction potential of the most significant abatement options as well as their technology readiness level (TRL). We find that energy-intensive industries have a range of decarbonization technologies available with medium to high TRLs and mature options also exist for decarbonizing low-temperature heat across a wide range of industrial sectors. However electrification and novel process change options to reduce emissions from high-temperature and sector-specific processes have much lower TRLs in comparison. We conclude by highlighting important barriers to the deployment of industrial decarbonization options and identifying future research development and demonstration needs.
OIES Podcast - Key Energy Themes for 2024
Jan 2024
Publication
In this latest OIES podcast James Henderson talks to Bill Farren-Price the new Head of the Gas Programme about some of Key Themes identified by OIES research fellows for 2024. After a review of the outcomes from 2023 we look at the oil and gas markets and discuss a common theme around the contrast between the fundamental tightness in both markets compared with the relative softness of prices. We then move onto a number of energy transition issues starting with some of the key actions from COP28 that need to be implemented in 2024 and following with a review of the outlook for carbon markets hydrogen developments and offshore wind. We also consider the impact of emerging competition between regions over green industrial policy. Finally we consider some of the key geopolitical drivers for 2024 with the influence of China being the most critical. However in an election year for so many countries it will be critical to follow the key policy announcements of the main candidates and of most critically the outcome of the US election in November.
The podcast can be found on their website
The podcast can be found on their website
Technoeconomic, Environmental and Multi-criteria Decision Making Investigations for Optimisation of Off-grid Hybrid Renewable Energy System with Green Hydrogen Production
Jan 2024
Publication
The current study presents a comprehensive investigation of different energy system configurations for a remote village community in India with entirely renewable electricity. Excess electricity generated by the systems has been stored using two types of energy storage options: lithium-ion batteries and green hydrogen production through the electrolysers. The hybrid renewable energy system (HRES) configurations have been sized by minimising the levelised cost of energy (LCOE). In order to identify the best-performing HRES configuration economic and environmental performance indicators has been analysed using the multi-criteria decision-making method (MCDM) TOPSIS. Among the evaluated system configurations system-1 with a photovoltaic panel (PV) size of 310.24 kW a wind turbine (WT) size of 690 kW a biogas generator (BG) size of 100 kW a battery (BAT) size of 174 kWh an electrolyser (ELEC) size of 150 kW a hydrogen tank (HT) size of 120 kg and a converter (CONV) size of 106.24 kW has been found to be the best-performing system since it provides the highest relative closeness (RC) value (∼0.817) and also has the lowest fuel consumption rate of 2.31 kg/kWh. However system-6 shows the highest amount of CO2 (143.97 kg/year) among all the studied system configurations. Furthermore a detailed technical economic and environmental analysis has been conducted on the optimal HRES configuration. The minimum net present cost (NPC) LCOE and cost of hydrogen (COH) for system 1 has been estimated to be $1960584 $0.44/kWh and $22.3/kg respectively.
Hydrogen Import and Export: Unlocking the UK's Hydrogen Trade Potential
May 2024
Publication
Hydrogen trade is an emerging area of interest for hydrogen developers end-users traders and governments around the world. It can enhance system flexibility energy security and clean growth enabling decarbonisation at a lower cost and faster pace. Thanks to its competitive advantage in existing ports terminals and interconnectors the UK is well placed to be the European trade hub for hydrogen and its carriers. With its access to world leading offshore wind generation capacity and geological storage the UK will almost certainly be a net exporter of hydrogen in the future delivering economic value and creating jobs. However hydrogen trade will not be a one-way process. In order to best position the UK as a future hydrogen trade hub there could be value in investing in small scale hydrogen imports and exports to ‘wet the pipes’ and stimulate investment in infrastructure. Imports could also enhance our energy security as a part of a diverse energy mix and support demand whilst domestic production gets up to speed. Both imports and exports will be key to build supply chains and skills and enhance clean growth. With major European economies having established their hydrogen trade strategy there is growing uncertainty as to how the United Kingdom will capitalise on its competitive advantage and position itself in the global hydrogen market. This is the first qualitative report released by Hydrogen UK’s Import and Export Taskforce. This report aims to provide a high-level overview of Hydrogen UK’s vision and recommendations with subsequent reports exploring this topic in further detail.
This report can be found on Hydrogen UK's website.
This report can be found on Hydrogen UK's website.
The Cost of Clean Hydrogen from Offshore Wind and Electrolysis
Feb 2024
Publication
The decarbonization of industry heating and transportation is a major challenge for many countries’ energy transition. Hydrogen is a direct low-carbon fuel alternative to natural gas offering a higher flexibility in the range of possible applications yet currently most hydrogen is produced using carbonintensive steam methane reforming due to cost considerations. Therefore this study explores the economics of a prominent low-carbon method of hydrogen production comparing the cost of hydrogen generation from offshore wind farms with and without grid electricity imports to conventional hydrogen production methods. A novel techno-economic model for offshore electrolysis production costs is presented which makes hydrogen production fully dispatchable leveraging geological salt-cavern storage. This model determines the lifetime costs aportioned across the system components as well as the Levelized Cost of Hydrogen (LCOH). Using the United Kingdom as a case study LCOH from offshore wind power is calculated to be €8.68 /kgH2 using alkaline electrolysis (AEL) €10.49 /kgH2 using proton exchange membrane electrolysis (PEMEL) and €10.88 /kgH2 with grid electricity to backup the offshore wind power. A stochastic Monte-Carlo model is used to asses the uncertainty on costs and identify the cost of capital electrolyser and wind farm capital costs and cost of electricity as the most important drivers of LCOH across the different scenarios. Reducing the capital cost to comparative levels observed on today’s wind farms alone could see AEL LCOH fall to €5.32 /kgH2 near competitive with conventional generation methods.
CFD Simulations of Hydrogen Tank Fuelling: Sensitivity to Turbulence Model and Grid Resolution
Dec 2023
Publication
CFD modelling of compressed hydrogen fuelling provides information on the hydrogen and tank structure temperature dynamics required for onboard storage tank design and fuelling protocol development. This study compares five turbulence models to develop a strategy for costeffective CFD simulations of hydrogen fuelling while maintaining a simulation accuracy acceptable for engineering analysis: RANS models k-ε and RSM; hybrid models SAS and DES; and LES model. Simulations were validated against the fuelling experiment of a Type IV 29 L tank available in the literature. For RANS with wall functions and blended models with near-wall treatment the simulated average hydrogen temperatures deviated from the experiment by 1–3% with CFL ≈ 1–3 and dimensionless wall distance y + ≈ 50–500 in the tank. To provide a similar simulation accuracy the LES modelling approach with near-wall treatment requires mesh with wall distance y + ≈ 2–10 and demonstrates the best-resolved flow field with larger velocity and temperature gradients. LES simulation on this mesh however implies a ca. 60 times longer CPU time compared to the RANS modelling approach and 9 times longer compared to the hybrid models due to the time step limit enforced by the CFL ≈ 1.0 criteria. In all cases the simulated pressure histories and inlet mass flow rates have a difference within 1% while the average heat fluxes and maximum hydrogen temperature show a difference within 10%. Compared to LES the k-ε model tends to underestimate and DES tends to overestimate the temperature gradient inside the tank. The results of RSM and SAS are close to those of LES albeit of 8–9 times faster simulations.
Flame Acceleration, Detonation Limit and Heat Loss for Hydrogen-Oxygen Mixture at Cryogenic Temperature of 77 K
Sep 2023
Publication
Experiments are performed in hydrogen-oxygen mixtures at the cryogenic temperature of 77 K with the equivalence ratio of 1.5 and 2.0. The optical fibers pressure sensors and the smoked foils are used to record the flame velocity overpressure evolution curve and detonation cells respectively. The 1st and 2nd shock waves are captured and they finally merge to form a stronger precursor shock wave prior to the onset of detonation. The cryogenic temperature will cause the larger expansion ratio which results in the occurrence of strong flame acceleration. The stuttering mode the galloping mode and the deflagration mode are observed when the initial pressure decreases from 0.50 atm to 0.20 atm with the equivalence ratio of 1.5 and the detonation limit is within 0.25-0.30 atm. The heat loss effect on the detonation limit is analysed. In addition the regularity of detonation cell is investigated and the larger post-shock specific heat ratio !"" and the lower normalized activation energy # at lower initial pressure will cause the more regular detonation cell. Also the detonation cell width is predicted by a model of = ($) ⋅ Δ# and the prediction results are mainly consistent with the experimental results.
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