Finland
The Role of Lock-in Mechanisms in Transition Processes: The Case of Energy for Road Transport
Jul 2015
Publication
This paper revisits the theoretical concepts of lock-in mechanisms to analyse transition processes in energy production and road transportation in the Nordic countries focussing on three technology platforms: advanced biofuels e-mobility and hydrogen and fuel cell electrical vehicles. The paper is based on a comparative analysis of case studies.The main lock-in mechanisms analysed are learning effects economies of scale economies of scope network Read More
Techno-economic Feasibility of Road Transport of Hydrogen Using Liquid Organic Hydrogen Carriers
Sep 2020
Publication
The cost of storing and transporting hydrogen have been one of the main challenges for the realization of the hydrogen economy. Liquid organic hydrogen carriers (LOHC) are a promising novel solution to tackle these challenges. In this paper we compare the LOHC concept to compressed gas truck delivery and on-site production of hydrogen via water electrolysis. As a case study we consider transportation of by-product hydrogen from chlor-alkali and chl Read More
Carbons Formed in Methane Thermal and Thermocatalytic Decomposition Processes: Properties and Applications
Jun 2021
Publication
The hydrogen economy will play a key role in future energy systems. Several thermal and catalytic methods for hydrogen production have been presented. In this review methane thermocatalytic and thermal decomposition into hydrogen gas and solid carbon are considered. These processes known as the thermal decomposition of methane (TDM) and thermocatalytic decomposition (TCD) of methane respectively appear to have the greatest potentia Read More
Experimental Study on Tri-fuel Combustion Using Premixed Methane-hydrogen Mixtures Ignited by a Diesel Pilot
Apr 2021
Publication
A comprehensive investigation on diesel pilot spray ignited methane-hydrogen (CH4–H2) combustion tri-fuel combustion (TF) is performed in a single-cylinder compression ignition (CI) engine. The experiments provide a detailed analysis of the effect of H2 concentration (based on mole fraction MH2) and charge-air temperature (Tair) on the ignition behavior combustion stability cycle-to-cycle (CCV) and engine performance. The results indicate that adding H2 Read More
Determination of Critical Hydrogen Concentration and Its Effect on Mechanical Performance of 2200 MPa and 600 HBW Martensitic Ultra-High-Strength Steel
Jun 2021
Publication
The influence of hydrogen on the mechanical performance of a hot-rolled martensitic steel was studied by means of constant extension rate test (CERT) and constant load test (CLT) followed with thermal desorption spectroscopy measurements. The steel shows a reduction in tensile strength up to 25% of ultimate tensile strength (UTS) at critical hydrogen concentrations determined to be about 1.1 wt.ppm and 50% of UTS at hydrogen concentrations of 2 wt. Read More
National Hydrogen Roadmap for Finland
Nov 2020
Publication
Hydrogen has been used as an industrial chemical for more than 100 years. Today hydrogen is used to manufacture ammonia and hence fertilizers as well as methanol and hydrogen peroxide both vital feedstocks for a wide variety of different chemical products. Furthermore in oil refineries hydrogen is used for the processing of intermediate products as well as to increase the hydrogen contents of the final products that are used propel the vehicles. However Read More
Material Testing and Design Recommendations for Components Exposed to Hydrogen Enhanced Fatigue – the Mathryce Project
Sep 2013
Publication
The three years European MATHRYCE project dedicated to material testing and design recommendations for components exposed to hydrogen enhanced fatigue started in October 2012. Its main goal is to provide an “easy” to implement methodology based on lab-scale experimental tests under hydrogen gas to assess the service life of a real scale component taking into account fatigue loading under hydrogen gas. Dedicated experimental tests will be d Read More
Dynamic Energy and Mass Balance Model for an Industrial Alkaline Water Electrolyzer Plant Process
Nov 2021
Publication
This paper proposes a parameter adjustable dynamic mass and energy balance simulation model for an industrial alkaline water electrolyzer plant that enables cost and energy efficiency optimization by means of system dimensioning and control. Thus the simulation model is based on mathematical models and white box coding and it uses a practicable number of fixed parameters. Zero-dimensional energy and mass balances of each unit operation o Read More
Evaluation of Steels Susceptibility to Hydrogen Embrittlement: A Thermal Desorption Spectroscopy-Based Approach Coupled with Artificial Neural Network
Dec 2020
Publication
A novel approach has been developed for quantitative evaluation of the susceptibility of steels and alloys to hydrogen embrittlement. The approach uses a combination of hydrogen thermal desorption spectroscopy (TDS) analysis with recent advances in machine learning technology to develop a regression artificial neural network (ANN) model predicting hydrogen-induced degradation of mechanical properties of steels. We describe the thermal desor Read More
Replacing Fossil Fuels with Bioenergy in District Heating – Comparison of Technology Options
May 2021
Publication
We combine previously separate models of Northern European power markets local district heating and cooling (DHC2) systems and biomass supply in a single modelling framework to study local and system level impacts of bioenergy technologies in phasing out fossil fuels from a DHC system of the Finnish capital. We model multiple future scenarios and assess the impacts on energy security flexibility provision economic performance and emissions. I Read More
Achieving Carbon-neutral Iron and Steelmaking in Europe Through the Deployment of Bioenergy with Carbon Capture and Storage
Jan 2019
Publication
The 30 integrated steel plants operating in the European Union (EU) are among the largest single-point CO2 emitters in the region. The deployment of bioenergy with carbon capture and storage (bio-CCS) could significantly reduce their emission intensities. In detail the results demonstrate that CO2 emission reduction targets of up to 20% can be met entirely by biomass deployment. A slow CCS technology introduction on top of biomass deployment is e Read More
Baseload Electricity and Hydrogen Supply Based on Hybrid PV-wind Power Plants
Sep 2019
Publication
The reliable supplies of electricity and hydrogen required for 100% renewable energy systems have been found to be achievable by utilisation of a mix of different resources and storage technologies. In this paper more demanding parameter conditions than hitherto considered are used in measurement of the reliability of variable renewable energy resources. The defined conditions require that supply of baseload electricity (BLEL) and baseload hydrogen Read More
Large-scale Compressed Hydrogen Storage as Part of Renewable Electricity Storage Systems
Mar 2021
Publication
Storing energy in the form of hydrogen is a promising green alternative. Thus there is a high interest to analyze the status quo of the different storage options. This paper focuses on the large-scale compressed hydrogen storage options with respect to three categories: storage vessels geological storage and other underground storage alternatives. In this study we investigated a wide variety of compressed hydrogen storage technologies discussing in fa Read More
A Direct Synthesis of Platinum/Nickel Co-catalysts on Titanium Dioxide Nanotube Surface from Hydrometallurgical-type Process Streams
Aug 2018
Publication
Solutions that simulate hydrometallurgical base metal process streams with high nickel (Ni) and minor platinum (Pt) concentrations were used to create Pt/Ni nanoparticles on TiO2 nanotube surfaces. For this electrochemical deposition – redox replacement (EDRR) was used that also allowed to control the nanoparticle size density and Pt/Ni content of the deposited nanoparticles. The Pt/Ni nanoparticle decorated titanium dioxide nanotubes (TiO2 nan Read More
A Numerical Performance Study of a Fixed-bed Reactor for Methanol Synthesis by CO2 Hydrogenation
Mar 2021
Publication
Synthetic fuels are needed to replace their fossil counterparts for clean transport. Presently their production is still inefficient and costly. To enhance the process of methanol production from CO2 and H2 and reduce its cost a particle-resolved numerical simulation tool is presented. A global surface reaction model based on the Langmuir-Hinshelwood-Hougen-Watson kinetics is utilized. The approach is first validated against standard benchmark proble Read More
The BioSCWG Project: Understanding the Trade-Offs in the Process and Thermal Design of Hydrogen and Synthetic Natural Gas Production
Oct 2016
Publication
This article presents a summary of the main findings from a collaborative research project between Aalto University in Finland and partner universities. A comparative process synthesis modelling and thermal assessment was conducted for the production of Bio-synthetic natural gas (SNG) and hydrogen from supercritical water refining of a lipid extracted algae feedstock integrated with onsite heat and power generation. The developed reactor models f Read More
Large-eddy Simulation of Tri-fuel Combustion: Diesel Spray Assisted Ignition of Methanol-hydrogen Blends
May 2021
Publication
Development of marine engines could largely benefit from the broader usage of methanol and hydrogen which are both potential energy carriers. Here numerical results are presented on tri-fuel (TF) ignition using large-eddy simulation (LES) and finite-rate chemistry. Zero-dimensional (0D) and three-dimensional (3D) simulations for n-dodecane spray ignition of methanol/hydrogen blends are performed. 0D results reveal the beneficial role of hy Read More
Modelling and Cost Estimation for Conversion of Green Methanol to Renewable Liquid Transport Fuels via Olefin Oligomerisation
Jun 2021
Publication
The ambitious CO2 emission reduction targets for the transport sector set in the Paris Climate Agreement require low-carbon energy solutions that can be commissioned rapidly. The production of gasoline kerosene and diesel from renewable methanol using methanol-to-olefins (MTO) and Mobil’s Olefins to Gasoline and Distillate (MOGD) syntheses was investigated in this study via process simulation and economic analysis. The current work presents a Read More
From Renewable Energy to Sustainable Protein Sources: Advancement, Challenges, and Future Roadmaps
Jan 2022
Publication
The concerns over food security and protein scarcity driven by population increase and higher standards of living have pushed scientists toward finding new protein sources. A considerable proportion of resources and agricultural lands are currently dedicated to proteinaceous feed production to raise livestock and poultry for human consumption. The 1st generation of microbial protein (MP) came into the market as land-independent proteinaceous feed for liv Read More
Green Hydrogen Production for Oil Refining - Finnish Case
Jan 2023
Publication
This study investigates the production of green hydrogen for use in oil refining as specified in the draft of European union delegated act published in May 2022. The European union plans to set strict requirements of additionality and reporting regarding the criteria of renewable electricity used in hydrogen production. Alkaline electrolyzer proton exchange membrane electrolyzer and solid oxide electrolyzer are evaluated in various scenarios supplied Read More
Cost Benefits of Optimizing Hydrogen Storage and Methanation Capacities for Power-to-Gas Plants in Dynamic Operation
Oct 2019
Publication
Power-to-Gas technologies offer a promising approach for converting renewable electricity into a molecular form (fuel) to serve the energy demands of non-electric energy applications in all end-use sectors. The technologies have been broadly developed and are at the edge of a mass roll-out. The barriers that Power-to-Gas faces are no longer technical but are foremost regulatory and economic. This study focuses on a Power-to-Gas pathway where elect Read More
Simulation Methodology for an Off-grid Solar–battery–water Electrolyzer Plant: Simultaneous Optimization of Component Capacities and System Control
Oct 2021
Publication
The capacity of each component in an off-grid water electrolyzer hydrogen production plant integrated with solar photovoltaics and a battery energy storage system represents a significant factor affecting the viability and reliability of the system. This paper describes a novel method that optimizes simultaneously the component capacities and finite-state machine based control of the system to minimize the cost of green hydrogen production. The compone Read More
A General Vision for Reduction of Energy Consumption and CO2 Emissions from the Steel Industry
Aug 2020
Publication
The 2018 IPCC (The Intergovernmental Panel on Climate Change’s) report defined the goal to limit global warming to 1.5 ◦C by 2050. This will require “rapid and far-reaching transitions in land energy industry buildings transport and cities”. The challenge falls on all sectors especially energy production and industry. In this regard the recent progress and future challenges of greenhouse gas emissions and energy supply are first briefly introduced. Then the curr Read More
Impact of Climate and Geological Storage Potential on Feasibility of Hydrogen Fuels
Apr 2023
Publication
Electrofuels including hydrogen methane and ammonia have been suggested as one pathway in achieving net-zero greenhouse gas energy systems. They can play a role in providing an energy storage and fuel or feedstock to hard-to-abate sectors. In future energy systems their role is often studied in case studies adhering to specific region. In this study we study their role by defining multiple archetypal energy systems which represent approximation Read More
Towards Electrochemical Hydrogen Storage in Liquid Organic Hydrogen Carriers via Proton-coupled Electron Transfers
Jun 2022
Publication
Green hydrogen is identified as one of the prime clean energy carriers due to its high energy density and a zero emission of CO2. A possible solution for the transport of H2 in a safe and low-cost way is in the form of liquid organic hydrogen carriers (LOHCs). As an alternative to loading LOHC with H2 via a two-step procedure involving preliminary electrolytic production of H2 and subsequent chemical hydrogenation of the LOHC we explore here the possibility Read More
Impact of Hydrogen on Natural Gas Compositions to Meet Engine Gas Quality Requirements
Oct 2022
Publication
To meet the target of reducing greenhouse gas emissions hydrogen as a carbon-free fuel is expected to play a major role in future energy supplies. A challenge with hydrogen is its low density and volumetric energy value meaning that large tanks are needed to store and transport it. By injecting hydrogen into the natural gas network the transportation issue could be solved if the hydrogen–natural gas mixture satisfies the grid gas quality requiremen Read More
Hydrogen Technology for Supply Chain Sustainability: The Mexican Transportation Impacts on Society
Mar 2022
Publication
This study sheds light on the Hydrogen technology in transportation for reaching the sustainability goals of societies illustrated by the case of Mexico. In terms of the affected supply chains the study explores how the packaging and distribution of a fuel-saving tool that allows the adoption of hydrogen as complementary energy for maritime transportation to improve economic and environmental performance in Mexico. This exploratory study perfo Read More
True Cost of Solar Hydrogen
Sep 2021
Publication
Green hydrogen will be an essential part of the future 100% sustainable energy and industry system. Up to one-third of the required solar and wind electricity would eventually be used for water electrolysis to produce hydrogen increasing the cumulative electrolyzer capacity to about 17 TWel by 2050. The key method applied in this research is a learning curve approach for the key technologies i.e. solar photovoltaics (PV) and water electrolyzers and leve Read More
Flexible Power and Biomass-To-Methanol Plants With Different Gasification Technologies
Jan 2022
Publication
The competitiveness of biofuels may be increased by integrating biomass gasification plants with electrolysis units which generate hydrogen to be combined with carbon-rich syngas. This option allows increasing the yield of the final product by retaining a higher amount of biogenic carbon and improving the resilience of the energy sector by favoring electric grid services and sector coupling. This article illustrates a techno-economic comparative analys Read More
Operation of Power-to-X-Related Processes Based on Advanced Data-Driven Methods: A Comprehensive Review
Oct 2022
Publication
This study is a systematic analysis of selected research articles about power-to-X (P2X)- related processes. The relevance of this resides in the fact that most of the world’s energy is produced using fossil fuels which has led to a huge amount of greenhouse gas emissions that are the source of global warming. One of the most supported actions against such a phenomenon is to employ renewable energy resources some of which are intermittent such as solar Read More
Challenges and Outlines of Steelmaking toward the Year 2030 and Beyond—Indian Perspective
Oct 2021
Publication
In FY-20 India’s steel production was 109 MT and it is the second-largest steel producer on the planet after China. India’s per capita consumption of steel was around 75 kg which has risen from 59 kg in FY-14. Despite the increase in consumption it is much lower than the average global consumption of 230 kg. The per capita consumption of steel is one of the strongest indicators of economic development across the nation. Thus India has an ambitious plan of Read More
Global Potential of Green Ammonia Based on Hybrid PV-wind Power Plants
Apr 2021
Publication
Ammonia is one of the most commonly used feedstock chemicals globally. Therefore decarbonisation of ammonia production is of high relevance towards achieving a carbon neutral energy system. This study investigates the global potential of green ammonia production from semi-flexible ammonia plants utilising a cost-optimised configuration of hybrid PV-wind power plants as well as conversion and balancing technologies. The global weather data Read More
Two-Dimensional Photocatalysts for Energy and Environmental Applications
Jun 2022
Publication
The depletion of fossil fuels and onset of global warming dictate the achievement of efficient technologies for clean and renewable energy sources. The conversion of solar energy into chemical energy plays a vital role both in energy production and environmental protection. A photocatalytic approach for H2 production and CO2 reduction has been identified as a promising alternative for clean energy production and CO2 conversion. In this process the Read More
Sizing Hydrogen Energy Storage in Consideration of Demand Response in Highly Renewable Generation Power Systems
May 2018
Publication
From an environment perspective the increased penetration of wind and solar generation in power systems is remarkable. However as the intermittent renewable generation briskly grows electrical grids are experiencing significant discrepancies between supply and demand as a result of limited system flexibility. This paper investigates the optimal sizing and control of the hydrogen energy storage system for increased utilization of renewable gene Read More
Prospectivity Analysis for Underground Hydrogen Storage, Taranaki Basin, Aotearoa New Zealand: A Multi-criteria Decision-making Approach
May 2024
Publication
Seasonal underground hydrogen storage (UHS) in porous media provides an as yet untested method for storing surplus renewable energy and balancing our energy demands. This study investigates the technical suitability for UHS in depleted hydrocarbon fields and one deep aquifer site in Taranaki Basin Aotearoa New Zealand. Prospective sites are assessed using a decision tree approach providing a “fast-track” method for identifying potential sites and a d Read More
The Role of Electricity-based Hydrogen in the Emerging Power-to-X Economy
Aug 2023
Publication
As energy system research into high shares of renewables has developed so have the perspectives of the fundamental nature of a highly renewable economy. Early energy system transition research suggested that current fossil fuel energy systems would transition to a ‘Hydrogen Economy’ whereas more recent insights suggest that a ‘Power-to-X Economy’ may be a more appropriate term as renewable electricity will become both the most importa Read More
A Multicriteria Modeling Approach for Evaluating Power Generation Scenarios Under Uncertainty: The Case of Green Hydrogen in Greece
Oct 2023
Publication
Clean energy technological innovations are widely acknowledged as a prerequisite to achieving ambitious longterm energy and climate targets. However the optimal speed of their adoption has been parsimoniously studied in the literature. This study seeks to identify the optimal intensity of moving to a green hydrogen electricity sector in Greece using the OSeMOSYS energy modeling framework. Green hydrogen policies are evaluated first on the basis Read More
Use of Existing Gas Infrastructure in European Hydrogen Economy
Apr 2023
Publication
The rapidly increasing production volume of clean hydrogen creates challenges for transport infrastructure. This study improves understanding of hydrogen transport options in Europe and provides more detailed analysis on the prospects for hydrogen transport in Finland. Previous studies and ongoing pipeline projects were reviewed to identify potential and barriers to hydrogen transport. A fatigue life assessment tool was built because material challeng Read More
Towards Defossilised Steel: Supply Chain Options for a Green European Steel Industry
Mar 2023
Publication
As the European Union intensifies its response to the climate emergency increased focus has been placed on the hard-to-abate energy-intensive industries. Primary among these is the steel industry a cornerstone of the European economy and industry. With the emergence of new hydrogen-based steelmaking options particularly through hydrogen direct reduction the structure of global steel production and supply chains will transition from being based o Read More
Seasonal Hydrogen Storage for Residential On- and Off-grid Solar Photovoltaics Prosumer Applications: Revolutionary Solution or Niche Market for the Energy Transition until 2050?
Apr 2023
Publication
Appropriate climate change mitigation requires solutions for all actors of the energy system. The residential sector is a major part of the energy system and solutions for the implementation of a seasonal hydrogen storage system in residential houses has been increasingly discussed. A global analysis of prosumer systems including seasonal hydrogen storage with water electrolyser hydrogen compressor storage tank and a fuel cell studying the role of such a Read More
Reduction in Greenhouse Gas and Other Emissions from Ship Engines: Current Trends and Future Options
Nov 2022
Publication
The impact of ship emission reductions can be maximised by considering climate health and environmental effects simultaneously and using solutions fitting into existing marine engines and infrastructure. Several options available enable selecting optimum solutions for different ships routes and regions. Carbon-neutral fuels including low-carbon and carbon-negative fuels from biogenic or non-biogenic origin (biomass waste renewable hydrogen) could rese Read More
Power Balance Control and Dimensioning of a Hybrid Off-grid Energy system for a Nordic Climate Townhouse
Mar 2023
Publication
This paper investigates conversion of a Nordic oil-heated townhouse into carbon-neutral by different energy efficiency (EE) improvements and an off-grid system including solar photovoltaics (PV) wind power and battery and hydrogen energy storage systems (BESS and HESS). A heat-pump-based heating system including waste heat recovery (WHR) from the HESS and an off-grid electrical system are dimensioned for the building by applying models Read More
Trends in the Global Steel Industry: Evolutionary Projections and Defossilisation Pathways through Power-to-steel
Sep 2022
Publication
Steel production is a carbon and energy intensive activity releasing 1.9 tons of CO2 and requiring 5.17 MWh of primary energy per ton produced on average globally resulting in 9% of all anthropogenic CO2 emissions. To achieve the goals of the Paris Agreement of limiting global temperature increase to below 1.5 °C compared to pre-industrial levels the structure of the global steel production must change fundamentally. There are several technological path Read More
Green Hydrogen Supply Chain Risk Analysis: A European Hard-to-abate Sectors Perspective
May 2023
Publication
Green hydrogen is a tentative solution for the decarbonisation of hard-to-abate sectors such as steel chemical cement and refinery industries. Green hydrogen is a form of hydrogen gas that is produced using renewable energy sources such as wind or solar power through a process called electrolysis. The green hydrogen supply chain includes several interconnected entities such as renewable energy providers electrolysers distribution facilities and c Read More
Global Demand Analysis for Carbon Dioxide as Raw Material from Key Industrial Sources and Direct Air Capture to Produce Renewable Electricity-based Fuels and Chemicals
Sep 2022
Publication
Defossilisation of the current fossil fuels dominated global energy system is one of the key goals in the upcoming decades to mitigate climate change. Sharp reduction in the costs of solar photovoltaics wind power and battery technologies enables a rapid transition of the power and some segments of the transport sectors to sustainable energy resources. However renewable electricity-based fuels and chemicals are required for the defossilisation of hard-to-a Read More
Deep Decarbonisation Pathways of the Energy System in Times of Unprecedented Uncertainty in the Energy Sector
May 2023
Publication
Unprecedented investments in clean energy technology are required for a net-zero carbon energy system before temperatures breach the Paris Agreement goals. By performing a Monte-Carlo Analysis with the detailed ETSAPTIAM Integrated Assessment Model and by generating 4000 scenarios of the world’s energy system climate and economy we find that the uncertainty surrounding technology costs resource potentials climate sensitivity and the leve Read More
Numerical Study on Hydrogen–Gasoline Dual-Fuel Spark Ignition Engine
Nov 2022
Publication
Hydrogen as a suitable and clean energy carrier has been long considered a primary fuel or in combination with other conventional fuels such as gasoline and diesel. Since the density of hydrogen is very low in port fuel-injection configuration the engine’s volumetric efficiency reduces due to the replacement of hydrogen by intake air. Therefore hydrogen direct in-cylinder injection (injection after the intake valve closes) can be a suitable solution for hydrog Read More
A Review on the Kinetics of Iron Ore Reduction by Hydrogen
Dec 2021
Publication
A clean energy revolution is occurring across the world. As iron and steelmaking have a tremendous impact on the amount of CO2 emissions there is an increasing attraction towards improving the green footprint of iron and steel production. Among reducing agents hydrogen has shown a great potential to be replaced with fossil fuels and to decarbonize the steelmaking processes. Although hydrogen is in great supply on earth extracting pure H2 from its Read More
Numerical Study on Tri-fuel Combustion: Ignition Properties of Hydrogen-enriched Methane-diesel and Methanol-diesel Mixtures
Jan 2020
Publication
Simultaneous and interactive combustion of three fuels with differing reactivities is investigated by numerical simulations. In the present study conventional dual-fuel (DF) ignition phenomena relevant to DF compression ignition (CI) engines are extended and explored in tri-fuel (TF) context. In the present TF setup a low reactivity fuel (LRF) methane or methanol is perfectly mixed with hydrogen and air to form the primary fuel blend at the lean equivalence ra Read More
Impact of International Transportation Chains on Cost of Green E-hydrogen: Global Cost of Hydrogen and Consequences for Germany and Finland
Jun 2023
Publication
Widely available and low-cost solar photovoltaics and wind power can enable production of renewable electricity-based hydrogen at many locations throughout the world. Hydrogen is expected to emerge as an important energy carrier constituting some of the final energy demand; however its most important role will be as feedstock for further processing to e-fuels e-chemicals and e-steel. Apart from meeting their own hydrogen demand cou Read More
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