Switzerland
The Long Term Price Elastic Demand of Hydrogen - A Multi-model Analysis for Germany
May 2024
Publication
Hydrogen and its derivatives are important components to achieve climate policy goals especially in terms of greenhouse gas neutrality. There is an ongoing controversial debate about the applications in which hydrogen and its derivatives should be used and to what extent. Typically the estimation of hydrogen demand relies on scenario-based analyses with varying underlying assumptions and targets. This study establishes a new framework consisting of existing energy system simulation and optimisation models in order to assess the long-term price-elastic demand of hydrogen. The aim of this work is to shift towards an analysis of the hydrogen demand that is primarily driven by its price. This is done for the case of Germany because of the expected high hydrogen demand for the years 2025–2045. 15 wholesale price pathways were established with final prices in 2045 between 56 €/MWh and 182 €/MWh. The results suggest that – if climate targets are to be achieved - even with high hydrogen prices (252 €/MWh in 2030 and 182 €/MWh in 2045) a significant hydrogen demand in the industry sector and the energy conversion sector is expected to emerge (318 TWh). Furthermore the energy conversion sector has a large share of price sensitive hydrogen demand and therefore its demand strongly increases with lower prices. The road transportation sector will only play a small role in terms of hydrogen demand if prices are low. In the decentralised heating for buildings no relevant demand will be seen over the considered price ranges whereas the centralised supply of heat via heat grids increases as prices fall.
Investigations on Pressure Dependence of Coriolis Mass Flow Meters Used at Hydrogen Refueling Stations
Sep 2020
Publication
In the framework of the ongoing EMPIR JRP 16ENG01 ‘‘Metrology for Hydrogen Vehicles’’ a main task is to investigate the influence of pressure on the measurement accuracy of Coriolis Mass Flow Meters (CFM) used at Hydrogen Refueling Stations (HRS). At a HRS hydrogen is transferred at very high and changing pressures with simultaneously varying flow rates and temperatures. It is clearly very difficult for CFMs to achieve the current legal requirements with respect to mass flow measurement accuracy at these measurement conditions. As a result of the very dynamic filling process it was observed that the accuracy of mass flow measurement at different pressure ranges is not sufficient. At higher pressures it was found that particularly short refueling times cause significant measurement deviations. On this background it may be concluded that pressure has a great impact on the accuracy of mass flow measurement. To gain a deeper understanding of this matter RISE has built a unique high-pressure test facility. With the aid of this newly developed test rig it is possible to calibrate CFMs over a wide pressure and flow range with water or base oils as test medium. The test rig allows calibration measurements under the conditions prevailing at a 70 MPa HRS regarding mass flows (up to 3.6 kg min−1) and pressures (up to 87.5 MPa).
Global Land and Water Limits to Electrolytic Hydrogen Production Using Wind and Solar Resources
Sep 2023
Publication
Proposals for achieving net-zero emissions by 2050 include scaling-up electrolytic hydrogen production however this poses technical economic and environmental challenges. One such challenge is for policymakers to ensure a sustainable future for the environment including freshwater and land resources while facilitating low-carbon hydrogen production using renewable wind and solar energy. We establish a country-by-country reference scenario for hydrogen demand in 2050 and compare it with land and water availability. Our analysis highlights countries that will be constrained by domestic natural resources to achieve electrolytic hydrogen self-sufficiency in a net-zero target. Depending on land allocation for the installation of solar panels or wind turbines less than 50% of hydrogen demand in 2050 could be met through a local production without land or water scarcity. Our findings identify potential importers and exporters of hydrogen or conversely exporters or importers of industries that would rely on electrolytic hydrogen. The abundance of land and water resources in Southern and Central-East Africa West Africa South America Canada and Australia make these countries potential leaders in hydrogen export.
Lab-Scale Investigation of the Integrated Backup/Storage System for Wind Turbines Using Alkaline Electrolyzer
Apr 2023
Publication
The depletion of fossil fuel sources has encouraged the authorities to use renewable resources such as wind energy to generate electricity. A backup/storage system can improve the performance of wind turbines due to fluctuations in power demand. The novelty of this study is to utilize a hybrid system for a wind farm using the excess electricity generated by the wind turbines to produce hydrogen in an alkaline electrolyzer (AEL). The hydrogen storage tank stores the produced hydrogen and provides hydrogen to the proton-exchange membrane fuel cell (PEMFC) to generate electricity once the power demand is higher than the electricity generated by the wind turbines. The goal of this study is to use the wind profile of a region in Iran namely the Cohen region to analyze the performance of the suggested integrated system on a micro scale. The output results of this study can be used as a case study for construction in the future based on the exact specification of NTK300 wind turbines. The results indicate that with the minimum power supply of 30 kW from the wind turbines on a lab scale the generated power by the PEMFC will be 1008 W while the maximum generated hydrogen will be 304 mL/h.
Understanding Degradation Effects of Elevated Temperature Operating Conditions in Polymer Electrolyte Water Electrolyzers
Apr 2021
Publication
The cost of polymer electrolyte water electrolysis (PEWE) is dominated by the price of electricity used to power the water splitting reaction. We present a liquid water fed polymer electrolyte water electrolyzer cell operated at a cell temperature of 100 °C in comparison to a cell operated at state-of-the-art operation temperature of 60 °C over a 300 h constant current period. The hydrogen conversion efficiency increases by up to 5% at elevated temperature and makes green hydrogen cheaper. However temperature is a stress factor that accelerates degradation causes in the cell. The PEWE cell operated at a cell temperature of 100 °C shows a 5 times increased cell voltage loss rate compared to the PEWE cell at 60 °C. The initial performance gain was found to be consumed after a projected operation time of 3500 h. Elevated temperature operation is only viable if a voltage loss rate of less than 5.8 μV h−1 can be attained. The major degradation phenomena that impact performance loss at 100 °C are ohmic (49%) and anode kinetic losses (45%). Damage to components was identified by post-test electron-microscopic analysis of the catalyst coated membrane and measurement of cation content in the drag water. The chemical decomposition of the ionomer increases by a factor of 10 at 100 °C vs 60 °C. Failure by short circuit formation was estimated to be a failure mode after a projected lifetime 3700 h. At elevated temperature and differential pressure operation hydrogen gas cross-over is limiting since a content of 4% hydrogen in oxygen represents the lower explosion limit.
Design of Gravimetric Primary Standards for Field-testing of Hydrogen Refuelling Stations
Apr 2020
Publication
The Federal Institute of Metrology METAS developed a Hydrogen Field Test Standard (HFTS) that can be used for field verification and calibration of hydrogen refuelling stations. The testing method is based on the gravimetric principle. The experimental design of the HFTS as well as the description of the method are presented here.
Decarbonisation of Geographical Islands and the Feasibility of Green Hydrogen Production Using Excess Electricity
May 2023
Publication
Islands face limitations in producing and transporting energy due to their geographical constraints. To address this issue the ROBINSON project funded by the EU aims to create a flexible self-sufficient and environmentally friendly energy system that can be used on isolated islands. The feasibility of renewable electrification and heating system decarbonization of Eigerøy in Norway is described in this article. A mixed-integer linear programming framework was used for modelling. The optimization method is designed to be versatile and adaptable to suit individual scenarios with a flexible and modular formulation that can accommodate boundary conditions specific to each case. Onshore and offshore wind farms and utility-scale photovoltaic (PV) were considered to generate renewable electricity. Each option was found to be feasible under certain conditions. The heating system composed of a biomass gasifier a combined heat and power system with a gas boiler as backup unit was also analyzed. Parameters were identified in which the combination of all three thermal units represented the best system option. In addition the possibility of green hydrogen production based on the excess electricity from each scenario was evaluated.
Near-term Infrastructure Rollout and Investment Strategies for Net-zero Hydrogen Supply Chains
Feb 2024
Publication
Low-carbon hydrogen plays a key role in European industrial decarbonization strategies. This work investigates the cost-optimal planning of European low-carbon hydrogen supply chains in the near term (2025–2035) comparing several hydrogen production technologies and considering multiple spatial scales. We focus on mature hydrogen production technologies: steam methane reforming of natural gas biomethane reforming biomass gasification and water electrolysis. The analysis includes carbon capture and storage for natural gas and biomass-derived hydrogen. We formulate and solve a linear optimization model that determines the costoptimal type size and location of hydrogen production and transport technologies in compliance with selected carbon emission targets including the EU fit for 55 target and an ambitious net-zero emissions target for 2035. Existing steam methane reforming capacities are considered and optimal carbon and biomass networks are designed. Findings identify biomass-based hydrogen production as the most cost-efficient hydrogen technology. Carbon capture and storage is installed to achieve net-zero carbon emissions while electrolysis remains costdisadvantageous and is deployed on a limited scale across all considered sensitivity scenarios. Our analysis highlights the importance of spatial resolution revealing that national perspectives underestimate costs by neglecting domestic transport needs and regional resource constraints emphasizing the necessity for highly decarbonized infrastructure designs aligned with renewable resource availabilities.
The Role of Hydrogen Storage in an Electricity System with Large Hydropower Resources
Feb 2024
Publication
Hydrogen is considered one of the key pillars of an effective decarbonization strategy of the energy sector; however the potential of hydrogen as an electricity storage medium is debated. This paper investigates the role of hydrogen as an electricity storage medium in an electricity system with large hydropower resources focusing on the Swiss electricity sector. Several techno-economic and climate scenarios are considered. Findings suggest that hydrogen storage plays no major role under most conditions because of the large hydropower resources. More specifically no hydrogen storage is installed in Switzerland if today’s values of net-transfer capacities and low load-shedding costs are assumed. This applies even to hydrogen-favorable climate scenarios (dry years with low precipitation and dam inflows) and economic assumptions (high learning rates for hydrogen technologies). In contrast hydrogen storage is installed when net-transfer capacities between countries are reduced below 30% of current values and load-shedding costs are above 1000 EUR/MWh. When installed hydrogen is deployed in a few large-scale installations near the national borders.
European Hydrogen Train the Trainer Framework for Responders: Outcomes of the Hyresponder Project
Sep 2023
Publication
Síle Brennan,
Didier Bouix,
Christian Brauner,
Dominic Davis,
Natalie DeBacker,
Alexander Dyck,
André Vagner Gaathaug,
César García Hernández,
Laurence Grand-Clement,
Etienne Havret,
Deborah Houssin-Agbomson,
Petr Kupka,
Laurent Lecomte,
Eric Maranne,
Vladimir V. Molkov,
Pippa Steele,
Adolfo Pinilla,
Paola Russo and
Gerhard Schoepf
HyResponder is a European Hydrogen Train the Trainer programme for responders. This paper describes the key outputs of the project and the steps taken to develop and implement a long-term sustainable train the trainer programme in hydrogen safety for responders across Europe and beyond. This FCH2 JU (now Clean Hydrogen Joint Undertaking) funded project has built on the successful outcomes of the previous HyResponse project. HyResponder has developed further and updated educational operational and virtual reality training for trainers of responders to reflect the state-of-the-art in hydrogen safety including liquid hydrogen and expand the programme across Europe and specifically within the 10 countries represented directly within the project consortium: Austria Belgium the Czech Republic France Germany Italy Norway Spain Switzerland and the United Kingdom. For the first time four levels of educational materials from fire fighter through to specialist have been developed. The digital training resources are available on the e-Platform (https://hyresponder.eu/e-platform/). The revised European Emergency Response Guide is now available to all stakeholders. The resources are intended to be used to support national training programs. They are available in 8 languages: Czech Dutch English French German Italian Norwegian and Spanish. Through the HyResponder activities trainers from across Europe have undertaken joint actions which are in turn being used to inform the delivery of regional and national training both within and beyond the project. The established pan-European network of trainers is shaping the future in the important for inherently safer deployment of hydrogen systems and infrastructure across Europe and enhancing the reach and impact of the programme.
Grid-neutral Hydrogen Mobility: Dynamic Modelling and Techno-economic Assessment of a Renewable-powered Hydrogen Plant
Jun 2024
Publication
The seasonally varying potential to produce electricity from renewable sources such as wind PV and hydropower is a challenge for the continuous supply of hydrogen for transport and mobility. Seasonal storage of energy allows to avoid the use of grid electricity when it is scarce; storage systems can thus increase the resilience of the energy system. For grid-neutral and renewable hydrogen production an electrolyser is considered together with a Power-to-Gas seasonal storage system which consists of a methanation the gas grid as intermediate storage and a steam reformer. As feed stream electricity from an own photovoltaic (PV) system is considered and for some cases additional electricity from the grid or from a wind turbine. The dynamic operation of the plant during a year is simulated. It is possible to safely supply fuel cell vehicles with hydrogen from the grid-neutral plant without using electricity when it is scarce and expensive. To supply 135 kgH2/day unit sizes of 1 MW–2.9 MW for the PV system and 0.9 MW–2.6 MW for the electrolysis are required depending on the amount of available grid-electricity. The usage of grid-electricity increases the capacity factor of the electrolysis which results in decreased unit sizes and in a better economic performance. Seasonal storage of energy is required which results in an increased hydrogen production in summer of approximately 50% more than directly needed by the fuel cell vehicles. The overall efficiency from electricity to hydrogen is decreased due to the storage path by 10%-points to 56% based on the higher heating value. Assuming a cost-equivalent hydrogen price per driven kilometre in comparison to the actual diesel price and electricity costs of 10 Ct/kWhel from the grid the revenues of the system are higher than the operating costs.
Hydrogen Refuelling Station Calibration with a Traceable Gravimetric Standard
Apr 2020
Publication
Of all the alternatives to hydrocarbon fuels hydrogen offers the greatest long-term potential to radically reduce the many problems inherent in fuel used for transportation. Hydrogen vehicles have zero tailpipe emissions and are very efficient. If the hydrogen is made from renewable sources such as nuclear power or fossil sources with carbon emissions captured and sequestered hydrogen use on a global scale would produce almost zero greenhouse gas emissions and greatly reduce air pollutant emissions. The aim of this work is to realise a traceability chain for hydrogen flow metering in the range typical for fuelling applications in a wide pressure range with pressures up to 875 bar (for Hydrogen Refuelling Station - HRS with Nominal Working Pressure of 700 bar) and temperature changes from −40 °C (pre-cooling) to 85 °C (maximum allowed vehicle tank temperature) in accordance with the worldwide accepted standard SAE J2601. Several HRS have been tested in Europe (France Netherlands and Germany) and the results show a good repeatability for all tests. This demonstrates that the testing equipment works well in real conditions. Depending on the installation configuration some systematic errors have been detected and explained. Errors observed for Configuration 1 stations can be explained by pressure differences at the beginning and end of fueling in the piping between the Coriolis Flow Meter (CFM) and the dispenser: the longer the distance the bigger the errors. For Configuration 2 where this distance is very short the error is negligible.
Hydrogen in Natural Gas Grids: Prospects and Recommendations About Gas Flow Meters
Aug 2024
Publication
To inject green hydrogen (H2) into the existing natural gas (NG) infrastructure is one way to decarbonize the European energy system. However asset readiness is necessary to be successful. Preliminary analysis and experimental results about the compatibility of hydrogen and natural gas mixtures (H2NG) with the actual gas grids make the scientific community confident about the feasibility. Nevertheless specific technical questions need more research. A significant topic of debate is the impact of H2NG mixtures on the performance of state-ofthe-art fiscal measuring devices which are essential for accurate billing. Identifying and addressing any potential degradation in their metrological performance due to H2NG is critical for decision-making. However the literature lacks data about the gas meters’ technologies currently installed in the NG grids such as a comprehensive overview of their readiness at different concentrations while data are fragmented among different sources. This paper addresses these gaps by analyzing the main characteristics and categorizing more than 20000 gas meters installed in THOTH2 project partners’ grids and by summarizing the performance of traditional technologies with H2NG mixtures and pure H2 based on literature review operators experience and manufacturers knowledge. Based on these insights recommendations are given to stakeholders on overcoming the identified barriers to facilitate a smooth transition.
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