Austria
Sustainable Hydrogen Society - Vision, Findings and Development of a Hydrogen Economy Using the Example of Austria
Oct 2021
Publication
Based on technical environmental economic and social facts and recent findings the feasibility of the transition from our current fossil age to the new green age is analyzed in detail at both global and local level. To avert the threats of health problems environmental pollution and climate change to our quality and standard of life a twofold radical paradigm shift is outlined: Green Energy Revolution means the complete change from fossil-based to green prim Read More
Addressing H-Material Interaction in Fast Diffusion Materials—A Feasibility Study on a Complex Phase Steel
Oct 2020
Publication
Hydrogen embrittlement (HE) is one of the main limitations in the use of advanced high-strength steels in the automotive industry. To have a better understanding of the interaction between hydrogen (H) and a complex phase steel an in-situ method with plasma charging was applied in order to provide continuous H supply during mechanical testing in order to avoid H outgassing. For such fast-H diffusion materials only direct observation during in- Read More
Accelerated Degradation for Solid Oxide Electrolysers: Analysis and Prediction of Performance for Varying Operating Environments
Jan 2022
Publication
Solid oxide electrolysis cells (SOECs) are an efficient technology for the production of green hydrogen that has great potential to contribute to the energy transition and decarbonization of industry. To date however time- and resource-intensive experimental campaigns slow down the development and market penetration of the technology. In order to speed-up the evaluation of SOEC performance and durability accelerated testing protocols are required. Read More
Hydrogen Uptake and Embrittlement of Carbon Steels in Various Environments
Aug 2020
Publication
To avoid failures due to hydrogen embrittlement it is important to know the amount of hydrogen absorbed by certain steel grades under service conditions. When a critical hydrogen content is reached the material properties begin to deteriorate. The hydrogen uptake and embrittlement of three different carbon steels (API 5CT L80 Type 1 P110 and 42CrMo4) was investigated in autoclave tests with hydrogen gas (H2) at elevated pressure and in ambient pr Read More
Safety Demands for Automotive Hydrogen Storage Systems
Sep 2005
Publication
Fuel storage systems for vehicles require a fail-safe design strategy. In case of system failures or accidents the control electronics have to switch the system into a safe operation mode. Failure Mode and Effect Analysis (FMEA) or Failure Tree Analysis (FTA) are performed already in the early design phase in order to minimize the risk of design failures in the fuel storage system. Currently the specifications of requirements for pressurized and liquid hydrogen fue Read More
High-pressure Hydrogen Production with Inherent Sequestration of a Pure Carbon Dioxide Stream Via Fixed Bed Chemical Looping
Feb 2019
Publication
The proof of concept for the production of pure pressurized hydrogen from hydrocarbons in combination with the sequestration of a pure stream of carbon dioxide with the reformer steam iron cycle is presented. The iron oxide based oxygen carrier (95% Fe2O3 5% Al2O3) is reduced with syngas and oxidized with steam at 1023 K. The carbon dioxide separation is achieved via partial reduction of the oxygen carrier from Fe2O3 to Fe3O4 yielding thermodyna Read More
Recent Advancements in Chemical Looping Water Splitting for the Production of Hydrogen
Oct 2016
Publication
Chemical looping water splitting or chemical looping hydrogen is a very promising technology for the production of hydrogen. In recent years extensive research has enabled remarkable leaps towards a successful integration of the chemical looping technology into a future hydrogen infrastructure. Progress has been reported with iron based oxygen carriers for stable hydrogen production capacity over consecutive cycles without significant signs of de Read More
Critical Review of Models for H2-permeation Through Polymers with Focus on the Differential Pressure Method
May 2021
Publication
To reduce loss of hydrogen in storage vessels with high energy-to-weight-ratio new materials especially polymers have to be developed as barrier materials. Very established methods for characterization of barrier materials with permeation measurements are the time-lag and flow rate method along with the differential pressure method which resembles the nature of hydrogen vessel systems very well. Long measurement durations are necessary to gai Read More
Prospects of Enhancing the Understanding of Material-hydrogen Interaction by Novel In-situ and In-operando Methods
Jan 2022
Publication
A main scientific and technical challenge facing the implementation of new and sustainable energy sources is the development and improvement of materials and components. In order to provide commercial viability of these applications an intensive research in material-hydrogen (H) interaction is required. This work provides an overview of recently developed in-situ and in-operando H-charging methods and their applicability to investigate Read More
Decarbonization of Australia’s Energy System: Integrated Modelling of the Transformation of Electricity, Transportation, and Industrial Sectors
Jul 2020
Publication
To achieve the Paris Agreement’s long-term temperature goal current energy systems must be transformed. Australia represents an interesting case for energy system transformation modelling: with a power system dominated by fossil fuels and specifically with a heavy coal component there is at the same time a vast potential for expansion and use of renewables. We used the multi-sectoral Australian Energy Modelling System (AUSeMOSYS) to perfor Read More
Asymmetric Solvation of the Zinc Dimer Cation Revealed by Infrared Multiple Photon Dissociation Spectroscopy of Zn2+(H2O)n (n = 1–20)
Jun 2021
Publication
Investigating metal-ion solvation—in particular the fundamental binding interactions—enhances the understanding of many processes including hydrogen production via catalysis at metal centers and metal corrosion. Infrared spectra of the hydrated zinc dimer (Zn2+(H2O)n; n = 1–20) were measured in the O–H stretching region using infrared multiple photon dissociation (IRMPD) spectroscopy. These spectra were then compared with those calculated by Read More
Porosity and Thickness Effect of Pd–Cu–Si Metallic Glasses on Electrocatalytic Hydrogen Production and Storage
Aug 2021
Publication
This contribution places emphasis on tuning pore architecture and film thickness of mesoporous Pd–Cu–Si thin films sputtered on Si/SiO2 substrates for enhanced electrocatalytic and hydrogen sorption/desorption activity and their comparison with the state-of-the-art thin film electrocatalysts. Small Tafel slope of 43 mV dec–1 for 1250 nm thick coatings with 2 µm diameter pores with 4.2 µm interspacing (H2) electrocatalyst with comparable hydrogen ov Read More
Constrained Extended Kalman Filter Design and Application for On-line State Estimation of High-order Polymer Electrolyte Membrane Fuel Cell Systems
Jun 2021
Publication
In this paper an alternative approach to extended Kalman filtering (EKF) for polymer electrolyte membrane fuel cell (FC) systems is proposed. The goal is to obtain robust real-time capable state estimations of a high-order FC model for observer applications mixed with control or fault detection. The introduced formulation resolves dependencies on operating conditions by successive linearization and constraints allowing to run the nonlinear FC model at si Read More
Energy Management of Heavy-duty Fuel Cell Vehicles in Real-world Driving Scenarios: Robust Design of Strategies to Maximize the Hydrogen Economy and System Lifetime
Feb 2021
Publication
Energy management is a critical issue for the advancement of fuel cell vehicles because it significantly influences their hydrogen economy and lifetime. This paper offers a comprehensive investigation of the energy management of heavy-duty fuel cell vehicles for road freight transportation. An important and unique contribution of this study is the development of an extensive and realistic representation of the vehicle operation which includes 1750 hour Read More
Scenarios to Decarbonize Austria’s Energy Consumption and the Role of Underground Hydrogen Storage
May 2022
Publication
The European Union is aiming at reaching greenhouse gas (GHG) emission neutrality in 2050. Austria’s current greenhouse gas emissions are 80 million t/year. Renewable Energy (REN) contributes 32% to Austria’s total energy consumption. To decarbonize energy consumption a substantial increase in energy generation from renewable energy is required. This increase will add to the seasonality of energy supply and amplifies the seasonality in energy d Read More
Validation of Selected Optical Methods for Assessing Polyethylene (PE) Liners Used in High Pressure Vessels for Hydrogen Storage
Jun 2021
Publication
A polyethylene (PE) liner is the basic element in high-pressure type 4 composite vessels designed for hydrogen or compressed natural gas (CNG) storage systems. Liner defects may result in the elimination of the whole vessel from use which is very expensive both at the manufacturing and exploitation stage. The goal is therefore the development of efficient non-destructive testing (NDT) methods to test a liner immediately after its manufacturing befor Read More
Hydrogen Trapping in bcc Iron
May 2020
Publication
Fundamental understanding of H localization in steel is an important step towards theoretical descriptions of hydrogen embrittlement mechanisms at the atomic level. In this paper we investigate the interaction between atomic H and defects in ferromagnetic body-centered cubic (bcc) iron using density functional theory (DFT) calculations. Hydrogen trapping profiles in the bulk lattice at vacancies dislocations and grain boundaries (GBs) are calcula Read More
Critical Assessment of the Effect of Atmospheric Corrosion Induced Hydrogen on Mechanical Properties of Advanced High Strength Steel
Dec 2020
Publication
Hydrogen absorption into steel during atmospheric corrosion has been of a strong concern during last decades. It is technically important to investigate if hydrogen absorbed under atmospheric exposure conditions can significantly affect mechanical properties of steels. The present work studies changes of mechanical properties of dual phase (DP) advanced high strength steel specimens with sodium chloride deposits during corrosion in humid air usin Read More
Advanced Optimal Planning for Microgrid Technologies Including Hydrogen and Mobility at a Real Microgrid Testbed
Apr 2021
Publication
This paper investigates the optimal planning of microgrids including the hydrogen energy system through mixed-integer linear programming model. A real case study is analyzed by extending the only microgrid lab facility in Austria. The case study considers the hydrogen production via electrolysis seasonal storage and fuelling station for meeting the hydrogen fuel demand of fuel cell vehicles busses and trucks. The optimization is performed relative t Read More
Using the Jet Stream for Sustainable Airship and Balloon Transportation of Cargo and Hydrogen
Jul 2019
Publication
The maritime shipping sector is a major contributor to CO2 emissions and this figure is expected to rise in coming decades. With the intent of reducing emissions from this sector this research proposes the utilization of the jet stream to transport a combination of cargo and hydrogen using airships or balloons at altitudes of 10–20 km. The jet streams flow in the mid-latitudes predominantly in a west–east direction reaching an average wind speed of 165 Read More
Characterization of Materials in Pressurized Hydrogen Under Cyclic Loading at Service Conditions in Hydrogen Powered Engines
Sep 2005
Publication
A new testing device for cyclic loading of specimens with a novel shape design is presented. The device was applied for investigations of fatigue of metallic specimens under pressurized hydrogen up to 300 bar at temperatures up to 200 °C. Main advantage of the specimen design is the very small amount of medium here hydrogen used for testing. This allows experiments with hazardous substances at lower safety level. Additionally no gasket for the lo Read More
Expectations as a Key to Understanding Actor Strategies in the Field of Fuel Cell and Hydrogen Vehicles
Feb 2012
Publication
Due to its environmental impact the mobility system is increasingly under pressure. The challenges to cope with climate change air quality depleting fossil resources imply the need for a transition of the current mobility system towards a more sustainable one. Expectations and visions have been identified as crucial in the guidance of such transitions and more specifically of actor strategies. Still it remained unclear why the actors involved in transition a Read More
Exergy as Criteria for Efficient energy Systems - Maximising Energy Efficiency from Resource to Energy Service, an Austrian Case Study
Sep 2021
Publication
The EU aims for complete decarbonisation. Therefore renewable generation must be massively expanded and the energy and exergy efficiency of the entire system must be significantly increased. To increase exergy efficiency a holistic consideration of the energy system is necessary. This work analyses the optimal technology mix to maximise exergy efficiency in a fully decarbonised energy system. An exergy-based optimisation model is presented an Read More
Hydrogen-assisted Cracking of GMA Welded 960 & A Grade High-strength Steels
Jan 2020
Publication
High-strength steels with yield strength of 960 MPa are susceptible to hydrogen-assisted cracking (HAC) during welding processing. In the present paper the implant test is used to study HAC in a quenched and tempered steel S960QL and a high-strength steel produced by thermo-mechanical controlled process S960MC. Welding is performed using the gas-metal arc welding process. Furthermore diffusible hydrogen concentration (HD) in arc weld metal is d Read More
Achieving Carbon-neutral Iron and Steelmaking in Europe Through the Deployment of Bioenergy with Carbon Capture and Storage
Jan 2019
Publication
The 30 integrated steel plants operating in the European Union (EU) are among the largest single-point CO2 emitters in the region. The deployment of bioenergy with carbon capture and storage (bio-CCS) could significantly reduce their emission intensities. In detail the results demonstrate that CO2 emission reduction targets of up to 20% can be met entirely by biomass deployment. A slow CCS technology introduction on top of biomass deployment is e Read More
The Future Potential Hydrogen Demand in Energy-intensive Industries - A Site-specific Approach Applied to Germany
Dec 2021
Publication
Hydrogen when based on renewable electricity can play a key role in the transition towards CO2-neutral industrial production since its use as an energy carrier as well as a feedstock in various industrial process routes is promising. At the same time a large-scale roll-out of hydrogen for industrial use would entail substantial impacts on the energy system which can only be assessed if the regional distribution of future hydrogen demand is considered. Read More
Magnesium Gasar as a Potential Monolithic Hydrogen Absorbent
Feb 2021
Publication
The study focuses on the aspect of using the structure of gasars i.e. materials with directed open porosity as a potential hydrogen storage. The structure of the tested gasar is composed of a large number of thin open tubular pores running through the entire longitudinal section of the sample. This allows hydrogen to easily penetrate into the entire sample volume. The analysis of pore distribution showed that the longest diffusion path needed for full Read More
Hydrocarbon Production by Continuous Hydrodeoxygenation of Liquid Phase Pyrolysis Oil with Biogenous Hydrogen Rich Synthesis Gas
Feb 2019
Publication
This paper presents a beneficial combination of biomass gasification and pyrolysis oil hydrodeoxygenation for advanced biofuel production. Hydrogen for hydrodeoxygenation (HDO) of liquid phase pyrolysis oil (LPP oil) was generated by gasification of softwood. The process merges dual fluidized bed (DFB) steam gasification which produces a hydrogen rich product gas and the HDO of LPP oil. Synthesis gas was used directly without further cleaning a Read More
Data-driven Parameterization of Polymer Electrolyte Membrane fuel Cell Models Via Simultaneous Local Linear Structured State Space Identification
Feb 2021
Publication
In order to mitigate the degradation and prolong the lifetime of polymer electrolyte membrane fuel cells advanced model-based control strategies are becoming indispensable. Thereby the availability of accurate yet computationally efficient fuel cell models is of crucial importance. Associated with this is the need to efficiently parameterize a given model to a concise and cost-effective experimental data set. A challenging task due to the large number Read More
Methodology for Efficient Parametrisation of Electrochemical PEMFC Model for Virtual Observers: Model Based Optimal Design of Experiments Supported by Parameter Sensitivity Analysis
Nov 2020
Publication
Determination of the optimal design of experiments that enables efficient parametrisation of fuel cell (FC) model with a minimum parametrisation data-set is one of the key prerequisites for minimizing costs and effort of the parametrisation procedure. To efficiently tackle this challenge the paper present an innovative methodology based on the electrochemical FC model parameter sensitivity analysis and application of D-optimal design plan. Relying o Read More
Hydrogen Storage Performance of the Multi-principal-component CoFeMnTiVZr Alloy in Electrochemical and Gas–solid Reactions
Jun 2020
Publication
The single-phase multi-principal-component CoFeMnTiVZr alloy was obtained by rapid solidification and examined by a combination of electrochemical methods and gas–solid reactions. X-ray diffraction and high-resolution transmission electron microscopy analyses reveal a hexagonal Laves-phase structure (type C14). Cyclic voltammetry and electrochemical impedance spectroscopy investigations in the hydrogen absorption/desorption region give insi Read More
Hydrogen in Grid Balancing: The European Market Potential for Pressurized Alkaline Electrolyzers
Jan 2022
Publication
To limit the global temperature change to no more than 2 ◦C by reducing global emissions the European Union (EU) set up a goal of a 20% improvement on energy efficiency a 20% cut of greenhouse gas emissions and a 20% share of energy from renewable sources by 2020 (10% share of renewable energy (RE) specifically in the transport sector). By 2030 the goal is a 27% improvement in energy efficiency a 40% cut of greenhouse gas emissions and a 27 Read More
Macroeconomic Implications of Switching to process-emission-free Iron and Steel Production in Europe
Nov 2018
Publication
Climate change is one of the most serious threats to the human habitat. The required structural change to limit anthropogenic forcing is expected to fundamentally change daily social and economic life. The production of iron and steel is a special case of economic activities since it is not only associated with combustion but particularly with process emissions of greenhouse gases which have to be dealt with likewise. Traditional mitigation options of Read More
Characterization of the Inducible and Slow-Releasing Hydrogen Sulfide and Persulfide Donor P*: Insights into Hydrogen Sulfide Signaling
Jun 2021
Publication
Hydrogen sulfide (H2S) is an important mediator of inflammatory processes. However controversial findings also exist and its underlying molecular mechanisms are largely unknown. Recently the byproducts of H2S per-/polysulfides emerged as biological mediators themselves highlighting the complex chemistry of H2S. In this study we characterized the biological effects of P* a slow-releasing H2S and persulfide donor. To differentiate between H2 Read More
Beyond Traditional Energy Sector Coupling: Conserving and Efficient Use of Local Resources
Jun 2022
Publication
Decentralisation and sector coupling are becoming increasingly crucial for the decarbonisation of the energy system. Resources such as waste and water have high energy recovery potential and are required as inputs for various conversion technologies; however waste and water have not yet been considered in sector coupling approaches but only in separate examinations. In this work an open-source sector coupling optimisation model considering all o Read More
State-of-the-art Expansion Planning of Integrated Power, Natural Gas, and Hydrogen Systems
Apr 2022
Publication
Renewable hydrogen is considered key in the transition towards a carbon-neutral future. This is due to its spatio-temporal storage and sector coupling potential which has seen it referred to as energy vector. However many unresolved issues remain regarding hydrogen's large-scale deployment e.g. least-cost production optimal facility siting and overall implications on power and energy systems. Expansion planning provides an option to study these Read More
Role of Grain Boundaries in Hydrogen Embrittlement of Alloy 725: Single and Bi-crystal Microcantilever Bending Study
Jan 2022
Publication
In situ electrochemical microcantilever bending tests were conducted in this study to investigate the role of grain boundaries (GBs) in hydrogen embrittlement (HE) of Alloy 725. Specimens were prepared under three different heat treatment conditions and denoted as solution-annealed (SA) aged (AG) and over-aged (OA) samples. For single-crystal beams in an H-containing environment all three heat-treated samples exhibited crack formation an Read More
Interlinking the Renewable Electricity and Gas Sectors: A Techno-Economic Case Study for Austria
Oct 2021
Publication
Achieving climate neutrality requires a massive transformation of current energy systems. Fossil energy sources must be replaced with renewable ones. Renewable energy sources with reasonable potential such as photovoltaics or wind power provide electricity. However since chemical energy carriers are essential for various sectors and applications the need for renewable gases comes more and more into focus. This paper determines the Austrian Read More
Role of Hydrogen-based Energy Carriers as an Alternative Option to Reduce Residual Emissions Associated with Mid-century Decarbonization Goals
Mar 2022
Publication
Hydrogen-based energy carriers including hydrogen ammonia and synthetic hydrocarbons are expected to help reduce residual carbon dioxide emissions in the context of the Paris Agreement goals although their potential has not yet been fully clarified in light of their competitiveness and complementarity with other mitigation options such as electricity biofuels and carbon capture and storage (CCS). This study aimed to explore the role of hydrogen in the Read More
Simulation-Assisted Determination of the Start-Up Time of a Polymer Electrolyte Fuel Cell
Nov 2021
Publication
Fuel starvation is a major cause of anode corrosion in low temperature polymer electrolyte fuel cells. The fuel cell start-up is a critical step as hydrogen may not yet be evenly distributed in the active area leading to local starvation. The present work investigates the hydrogen distribution and risk for starvation during start-up and after nitrogen purge by extending an existing computational fluid dynamic model to capture transient behavior. The results of Read More
Natural Iron Ores for Large-scale Thermochemical Hydrogen and Energy Storage
Jun 2022
Publication
A stable energy supply will require balancing the fluctuations of renewable energy generation due to the transition to renewable energy sources. Intraday and seasonal storage systems are often limited to local geographical or infrastructural circumstances. This study experimentally verifies the application of inexpensive and abundant natural iron ores for energy storage with combined hydrogen and heat release. The incorporated iron oxides are reduc Read More
Investigation of Pre-cooling Strategies for Heavy-duty Hydrogen Refuelling
Mar 2024
Publication
Green hydrogen presents a promising solution for transitioning from fossil fuels to a clean energy future particularly with the application of fuel cell electric vehicles (FCEVs). However the hydrogen refuelling process for FCEVs requires extensive pre-cooling to achieve fast filling times. This study presents experiments and simulations of a hydrogen refuelling station equipped with an adaptable cold-fill unit aiming to maximize fuelling efficiencies. For Read More
The Economics and the Environmental Benignity of Different Colors of Hydrogen
Feb 2022
Publication
Due to the increasing greenhouse gas emissions as well as due to the rapidly increasing use of renewable energy sources in the electricity generation over the last years interest in hydrogen is rising again. Hydrogen can be used as a storage for renewable energy balancing the whole energy systems and contributing to the decarbonization of the energy system especially of the industry and the transport sector. The major objective of this paper is to Read More
Hydrogen Deep Ocean Link: A Global Sustainable Interconnected Energy Grid
Mar 2022
Publication
The world is undergoing a substantial energy transition with an increasing share of intermittent sources of energy on the grid which is increasing the challenges to operate the power grid reliably. An option that has been receiving much focus after the COVID pandemic is the development of a hydrogen economy. Challenges for a hydrogen economy are the high investment costs involved in compression storage and long-distance transportation. Th Read More
Assessment and Recommendations for a Fossil Free Future for Track Work Machinery
Oct 2021
Publication
Current railway track work machinery is mainly operated with diesel fuel. As a result track maintenance of Austrian Federal Railways (OeBB) amounts to nearly 9000 t CO2 equivalent per year according to calculations from Graz University of Technology. OeBB’s total length of railway lines only accounts for 0.56% of the world’s length of lines. This indicates huge potential for mitigating greenhouse gas emissions considering the need for track mainten Read More
Prospects and Impediments for Hydrogen Fuel Cell Buses
Jun 2021
Publication
The number of demonstration projects with fuel cell buses has been increasing worldwide. The goal of this paper is to analyse prospects and barriers for fuel cell buses focusing on their economic- technical- and environmental performance. Our results show that the prices of fuel cell buses although decreasing over time are still about 40% higher than those of diesel buses. With the looming ban of diesel vehicles and current limitations of battery electric v Read More
Green Hydrogen-Based Direct Reduction for Low-Carbon Steelmaking
May 2020
Publication
The European steel industry aims at a CO2 reduction of 80–95% by 2050 ensuring that Europe will meet the requirements of the Paris Agreement. As the reduction potentials of the current steelmaking routes are low the transfer toward breakthrough-technologies is essential to reach these goals. Hydrogen-based steelmaking is one approach to realize CO2-lean steelmaking. Therefore the natural gas (NG)-based direct reduction (DR) acts as a basis fo Read More
Economic and Environmental Assessment of Different Hydrogen Production and Transportation Modes
Apr 2024
Publication
Hydrogen is widely considered as the energy carrier of the future but the rather high energy losses for its production are often neglected. The major current hydrogen production technology is steam methane reforming of fossil gas but there is a growing interest in producing hydrogen sustainably from water using electrolysis. This article examines four main hydrogen production chains and two transportation options (pipeline and ship) from North Africa to Eu Read More
Linking Geological and Infrastructural Requirements for Large-scale Underground Hydrogen Storage in Germany
Jun 2023
Publication
Hydrogen storage might be key to the success of the hydrogen economy and hence the energy transition in Germany. One option for cost-effective storage of large quantities of hydrogen is the geological subsurface. However previous experience with underground hydrogen storage is restricted to salt caverns which are limited in size and space. In contrast pore storage facilities in aquifers -and/or depleted hydrocarbon reservoirs- could play a vital role in Read More
On the Future Relevance of Green Hydrogen in Europe
Jan 2024
Publication
Hydrogen is among the energy carriers which are most often considered for bringing about a sustainable energy system. Yet so far hydrogen has not delivered as an energy carrier. The core objective of this paper is to provide a comprehensive analysis of the state-of-the-art and the future prospects of green hydrogen in the European energy system from economic energetic and CO2 emissions point-of-view. The analysis shows that there are som Read More
European Hydrogen Train the Trainer Framework for Responders: Outcomes of the Hyresponder Project
Sep 2023
Publication
Síle Brennan,
Didier Bouix,
Christian Brauner,
Dominic Davis,
Natalie DeBacker,
Alexander Dyck,
André Vagner Gaathaug,
César García Hernández,
Laurence Grand-Clement,
Etienne Havret,
Deborah Houssin-Agbomson,
Petr Kupka,
Laurent Lecomte,
Eric Maranne,
Vladimir V. Molkov,
Pippa Steele,
Adolfo Pinilla,
Paola Russo and
Gerhard Schoepf
HyResponder is a European Hydrogen Train the Trainer programme for responders. This paper describes the key outputs of the project and the steps taken to develop and implement a long-term sustainable train the trainer programme in hydrogen safety for responders across Europe and beyond. This FCH2 JU (now Clean Hydrogen Joint Undertaking) funded project has built on the successful outcomes of the previous HyResponse project. HyResponder ha Read More
Hydrogen Embrittlement Characteristics in Cold-drawn High-strength Stainless Steel Wires
Mar 2023
Publication
Hydrogen uptake and embrittlement characteristics of a cold-drawn austenitic stainless steel wire were investigated. Slow strain rate testing and fracture surface analysis were applied to determine the hydrogen embrittlement resistance providing an apparent decrease in resistance to hydrogen embrittlement for a 50% degree of cold deformation. The hydrogen content was assessed by thermal desorption and laser-induced breakdown spectroscopy est Read More
Methane Pyrolysis in a Liquid Metal Bubble Column Reactor for CO2-Free Production of Hydrogen
Oct 2023
Publication
In light of the growing interest in hydrogen as an energy carrier and reducing agent various industries including the iron and steel sector are considering the increased adoption of hydrogen. To meet the rising demand in energy-intensive industries the production of hydrogen must be significantly expanded and further developed. However current hydrogen production heavily relies on fossil-fuel-based methods resulting in a considerable environmental bur Read More
Refuelling Tests of a Hydrogen Tank for Heavy-duty Applications
Sep 2023
Publication
A transition towards zero-emission fuels is required in the mobility sector in order to reach the climate goals. Here (green) renewable hydrogen for use in fuel cells will play an important role especially for heavy duty applications such as trucks. However there are still challenges to overcome regarding efficient storage infrastructure integration and optimization of the refuelling process. A key aspect is to reduce the refuelling duration as much as possible Read More
A Review on Metal Hydride Materials for Hydrogen Storage
Jul 2023
Publication
To achieve the shift to renewable energies efficient energy storage is of the upmost importance. Hydrogen as a chemical energy storage represents a promising technology due to its high gravimetric energy density. However the most efficient form of hydrogen storage still remains an open question. Absorption-based storage of hydrogen in metal hydrides offers high volumetric energy densities as well as safety advantages. In this work technic Read More
Greenhouse Gas Emissions Performance of Electric, Hydrogen and Fossil-Fuelled Freight Trucks with Uncertainty Estimates Using a Probabilistic Life-Cycle Assessment (pLCA)
Jan 2024
Publication
This research conducted a probabilistic life-cycle assessment (pLCA) into the greenhouse gas (GHG) emissions performance of nine combinations of truck size and powertrain technology for a recent past and a future (largely decarbonised) situation in Australia. This study finds that the relative and absolute life-cycle GHG emissions performance strongly depends on the vehicle class powertrain and year of assessment. Life-cycle emission factor distributio Read More
Repurposing Fischer-Tropsch and Natural Gas as Bridging Technologies for the Energy Revolution
Jun 2022
Publication
Immediate and widespread changes in energy generation and use are critical to safeguard our future on this planet. However while the necessity of renewable electricity generation is clear the aviation transport and mobility chemical and material sectors are challenging to fully electrify. The age-old Fischer-Tropsch process and natural gas industry could be the bridging solution needed to accelerate the energy revolution in these sectors – temp Read More
Economic Evaluation of Renewable Hydrogen Integration into Steelworks for the Production of Methanol and Methane
Jun 2022
Publication
This work investigates the cost-efficient integration of renewable hydrogen into steelworks for the production of methane and methanol as an efficient way to decarbonize the steel industry. Three case studies that utilize a mixture of steelworks off-gases (blast furnace gas coke oven gas and basic oxygen furnace gas) which differ on the amount of used off-gases as well as on the end product (methane and/or methanol) are analyzed and evaluated in terms Read More
The Influence of Hydrogen Sulfide Contaminations on Hydrogen Production in Chemical Looping Processes
Aug 2021
Publication
Chemical looping with iron-based oxygen carriers enables the production of hydrogen from various fossil and biogenic primary energy sources. In applications with real producer gases such as biogas or gasified biomass hydrogen sulfide represents one of the most challenging contaminants. The impact of H2S on the reactivity of a Fe2O3/Al2O3 oxygen carrier material in chemical looping hydrogen production was investigated in the present work. Read More
Air Mass Flow and Pressure Optimisation of a PEM Fuel Cell Range Extender System
Aug 2022
Publication
In order to eliminate the local CO2 emissions from vehicles and to combat the associated climate change the classic internal combustion engine can be replaced by an electric motor. The two most advantageous variants for the necessary electrical energy storage in the vehicle are currently the purely electrochemical storage in batteries and the chemical storage in hydrogen with subsequent conversion into electrical energy by means of a fuel c Read More
A Bird’s-Eye View on Polymer-Based Hydrogen Carriers for Mobile Applications
Oct 2022
Publication
Globally reducing CO2 emissions is an urgent priority. The hydrogen economy is a system that offers long-term solutions for a secure energy future and the CO2 crisis. From hydrogen production to consumption storing systems are the foundation of a viable hydrogen economy. Each step has been the topic of intense research for decades; however the development of a viable safe and efficient strategy for the storage of hydrogen remains the most chall Read More
Combination of b-Fuels and e-Fuels—A Technological Feasibility Study
Aug 2021
Publication
The energy supply in Austria is significantly based on fossil natural gas. Due to the necessary decarbonization of the heat and energy sector a switch to a green substitute is necessary to limit CO2 emissions. Especially innovative concepts such as power-to-gas establish the connection between the storage of volatile renewable energy and its conversion into green gases. In this paper different methanation strategies are applied on syngas from biomass Read More
Underground Hydrogen Storage: Application of Geochemical Modelling in a Case Study in the Molasse Basin, Upper Austria
Feb 2019
Publication
Hydrogen storage in depleted gas fields is a promising option for the large-scale storage of excess renewable energy. In the framework of the hydrogen storage assessment for the “Underground Sun Storage” project we conduct a multi-step geochemical modelling approach to study fluid–rock interactions by means of equilibrium and kinetic batch simulations. With the equilibrium approach we estimate the long-term consequences of hydrogen storage Read More
Modelling Hydrogen Storage and Filling Systems: A Dynamic and Customizable Toolkit
Aug 2023
Publication
Hydrogen plays a vital role in decarbonizing the mobility sector. With the number of hydrogen vehicles expected to drastically increase a network of refuelling stations needs to be built to keep up with the hydrogen demand. However further research and development on hydrogen refuelling infrastructure storage and standardization is required to overcome technical and economic barriers. Simulation tools can reduce time and costs during the design phase Read More
Hybrid Model Predictive Control of Renewable Microgrids and Seasonal Hydrogen Storage
Jun 2023
Publication
Optimal energy management of microgrids enables efficient integration of renewable energies by considering all system flexibilities. For systems with significant seasonal imbalance between energy production and demand it may be necessary to integrate seasonal storage in order to achieve fully decarbonized operation. This paper develops a novel model predictive control strategy for a renewable microgrid with seasonal hydrogen storage. Read More
Hydrogen Role in the Valorization of Integrated Steelworks Process Off-gases through Methane and Methanol Syntheses
Jun 2021
Publication
The valorization of integrated steelworks process off-gases as feedstock for synthesizing methane and methanol is in line with European Green Deal challenges. However this target can be generally achieved only through process off-gases enrichment with hydrogen and use of cutting-edge syntheses reactors coupled to advanced control systems. These aspects are addressed in the RFCS project i3 upgrade and the central role of hydrogen was Read More
Establishment of Austria’s First Regional Green Hydrogen Economy: WIVA P&G HyWest
Apr 2023
Publication
The regional parliament of Tyrol in Austria adopted the climate energy and resources strategy “Tyrol 2050 energy autonomous” in 2014 with the aim to become climate neutral and energy autonomous. “Use of own resources before others do or have to do” is the main principle within this long-term strategic approach in which the “power on demand” process is a main building block and the “power-to-hydrogen” process covers the intrinsic lack of a lon Read More
Large-scale Underground Hydrogen Storage: Integrated Modeling of a Reservoir-wellbore System
Jan 2023
Publication
Underground Hydrogen Storage (UHS) has received significant attention over the past few years as hydrogen seems well-suited for adjusting seasonal energy gaps. We present an integrated reservoir-well model for “Viking A00 the depleted gas field in the North Sea as a potential site for UHS. Our findings show that utilizing the integrated model results in more reasonable predictions as the gas composition changes over time. Sensitivity analyses show that the Read More
Reduction of Iron Oxides with Hydrogen - A Review
Aug 2019
Publication
This review focuses on the reduction of iron oxides using hydrogen as a reducing agent. Due to increasing requirements from environmental issues a change of process concepts in the iron and steel industry is necessary within the next few years. Currently crude steel production is mainly based on fossil fuels and emitting of the climate-relevant gas carbon dioxide is integral. One opportunity to avoid or reduce greenhouse gas emissions is substituting hydro Read More
Decarbonization of the Steel Industry: A Techno-economic Analysis
Jan 2022
Publication
A substantial CO2-emmissions abatement from the steel sector seems to be a challenging task without support of so-called “breakthrough technologies” such as the hydrogen-based direct reduction process. The scope of this work is to evaluate both the potential for the implementation of green hydrogen generated via electrolysis in the direct reduction process as well as the constraints. The results for this process route are compared with both the well-establi Read More
The Sector Coupling Concept: A Critical Review
Jun 2020
Publication
Pursued climate goals require reduced greenhouse gas emissions by substituting fossil fuels with energy from renewable sources in all energy-consuming processes. On a large-scale this can mainly be achieved through electricity from wind and sun which are subject to intermittency. To efficiently integrate this variable energy a coupling of the power sector to the residential transport industry and commercial/trade sector is often promoted called sector c Read More
Refurbishment of Natural Gas Pipelines towards 100% Hydrogen—A Thermodynamic-Based Analysis
Dec 2022
Publication
Hydrogen is a key enabler of a sustainable society. Refurbishment of the existing natural gas infrastructure for up to 100% H2 is considered one of the most energy- and resource-efficient energy transportation methods. The question remains whether the transportation of 100% H2 with reasonable adaptions of the infrastructure and comparable energy amounts to natural gas is possible. The well-known critical components for refurbishment such as incre Read More
Hydrogen Production by Methane Pyrolysis in Molten Binary Copper Alloys
Sep 2023
Publication
The utilization of hydrogen as an energy carrier and reduction agent in important industrial sectors is considered a key parameter on the way to a sustainable future. Steam reforming of methane is currently the most industrially used process to produce hydrogen. One major drawback of this method is the simultaneous generation of carbon dioxide. Methane pyrolysis represents a viable alternative as the basic reaction produces no CO2 but solid carb Read More
Evaluation of Process Simulation and Reactor Technologies of an Integrated Power-to-liquid Plant at a Cement Factory
Mar 2023
Publication
A novel carbon capture and utilization (CCU) process is described in which process-related carbon dioxide is captured from cement plant exhaust gas (10000 tons/year) and converted with green hydrogen in a Fischer Tropsch synthesis to liquid mainly paraffinic hydrocarbons (syncrude approx. 3000 tons/year) which is finally processed to polyolefins. This CCU process chain is simulated with the software package ASPEN Plus V12.1®. In a first step the influ Read More
Risk Assessment of the Low-carbon Transition of Austria’s Steel and Electricity Sectors
Dec 2018
Publication
To limit global temperature increase below +2°C societies need to reduce greenhouse gas emissions radically within the next few decades. Amongst other mitigation measures this requires transforming process-emission intensive industries towards emission neutrality. One way to this end is the renewables-based electrification of industries. We present results of a recent coproduction process which brought together stakeholders from industry policy a Read More
Hydrogen Deep Ocean Link: A Global Sustainable Interconnected Energy Grid<br/><br/><br/>
Mar 2022
Publication
The world is undergoing a substantial energy transition with an increasing share of intermittent sources of energy on the grid which is increasing the challenges to operate the power grid reliably. An option that has been receiving much focus after the COVID pandemic is the development of a hydrogen economy. Challenges for a hydrogen economy are the high investment costs involved in compression storage and long-distance transportation. Th Read More
Solid Air Hydrogen Liquefaction, the Missing Link of the Hydrogen Economy
Mar 2023
Publication
The most challenging aspect of developing a green hydrogen economy is long-distance oceanic transportation. Hydrogen liquefaction is a transportation alternative. However the cost and energy consumption for liquefaction is currently prohibitively high creating a major barrier to hydrogen supply chains. This paper proposes using solid nitrogen or oxygen as a medium for recycling cold energy across the hydrogen liquefaction supply chain. When a liquid Read More
Just Energy Transition: Learning from the Past for a More Just and Sustainable Hydrogen Transition in West Africa
Dec 2022
Publication
The rising demand for energy and the aim of moving away from fossil fuels and to low-carbon power have led many countries to move to alternative sources including solar energy wind geothermal energy biomass and hydrogen. Hydrogen is often considered a “missing link” in guaranteeing the energy transition providing storage and covering the volatility and intermittency of renewable energy generation. However due to potential injustice with regard to t Read More
Renewable Marine Fuel Production for Decarbonised Maritime Shipping: Pathways, Policy Measures and Transition Dynamics
Jun 2023
Publication
This article investigates the potential of renewable and low-carbon fuel production for the maritime shipping sector using Sweden as a case in focus. Techno-economic modelling and socio-technical transition studies are combined to explore the conditions opportunities and barriers to decarbonising the maritime shipping industry. A set of scenarios have been developed considering demand assumptions and potential instruments such as carbon price energ Read More
Hydrogen as Short-Term Flexibility and Seasonal Storage in a Sector-Coupled Electricity Market
Jul 2023
Publication
The rapid expansion of renewable energies has the potential to decarbonize the electricity supply. This is more challenging in difficult-to-electrify sectors. The use of hydrogen provides a massive potential for this issue. However expanding hydrogen production increases electricity demand while providing additional flexibility to the electricity market. This paper mainly aims to analyze the economic effects of this sector coupling between the European electricity Read More
Hydrogen Quality in Used Natual Gas Pipelines: An Experimental Investigation of Contaminants According to ISO 14687:2019 Standard
Sep 2023
Publication
The transport of hydrogen in used natural gas pipelines is a strategic key element of a pan-European hydrogen infrastructure. At the same time accurate knowledge of the hydrogen quality is essential in order to be able to address a wide application range. Therefore an experimental investigation was carried out to find out which contaminants enter into the hydrogen from the used natural gas pipelines. Pipeline elements from the high pressure gas grid Read More
Renewable Hydrogen: Modular Concepts from Production over Storage to the Consumer
Jan 2021
Publication
A simulation tool called HYDRA to optimize individual hydrogen infrastructure layouts is presented. The different electrolyzer technologies namely proton exchange membrane electrolysis anion exchange membrane electrolysis alkaline electrolysis and solid oxide electrolysis as well as hydrogen storage possibilities are described in more detail and evaluated. To illustrate the application opportunities of HYDRA three project examples are discussed. Read More
Transitioning to a Renewable Hydrogen System: Optimal Infrastructure for Self-sufficient Hydrogen Supply in Austria by 2030
Aug 2024
Publication
In this study we employ an optimization model to optimally design a self-sufficient independent of any imports and exports hydrogen infrastructure for Austria by 2030. Our approach integrates key hydrogen technologies within a detailed spatial investment and operation model – coupled with a European scale electricity market model. We focus on optimizing diverse infrastructure componentsincluding trailers pipelines electrolyzers and storages to meet Read More
Thermal Design of a System for Mobile Powersupply
Sep 2023
Publication
Ever more stringent emission regulations for vehicles encourage increasing numbers of battery electric vehicles on the roads. A drawback of storing electric energy in a battery is the comparable low energy density low driving range and the higher propensity to deplete the energy storage before reaching the destination especially at low ambient temperatures. When the battery is depleted stranded vehicles can either be towed or recharged with a mobi Read More
Mid-century Net-zero Emissions Pathways for Japan: Potential Roles of Global Mitigation Scenarios in Informing National Decarbonisation Strategies
Jan 2024
Publication
Japan has formulated a net-zero emissions target by 2050. Existing scenarios consistent with this target generally depend on carbon dioxide removal (CDR). In addition to domestic mitigation actions the import of low-carbon energy carriers such as hydrogen and synfuels and negative emissions credits are alternative options for achieving net-zero emissions in Japan. Although the potential and costs of these actions depend on global energy system tr Read More
The Race Between Hydrogen and Heat Pumps for Space and Water Heating: A Model-based Scenario Analysis
Nov 2023
Publication
This paper analyses different levels and means of the electrification of space and hot water heating using an explorative modelling approach. The analysis provides guidance to the ongoing discussion on favourable pathways for heating buildings and the role of secondary energy carriers such as hydrogen or synthetic fuels. In total 12 different scenarios were modelled with decarbonisation pathways until 2050 which cover all 27 member states of the Eu Read More
Advanced Testing Methods for Proton Exchange Membrane Electrolysis Stacks
Jun 2024
Publication
Research on proton exchange membrane water electrolysis for renewable hydrogen production is rapidly advancing worldwide driven by the imperative to reduce costs and enhance efficiency through development of novel materials. However to effectively evaluate and validate these advancements standardized testing methods are essential extending beyond single-cell analysis to encompass stack-level characterization. This paper proposes c Read More
Recent Advances in Sustainable Hydrogen Production from Microalgae: Mechanisms, Challenges, and Future Perspectives
Jan 2024
Publication
The depletion of fossil fuel reserves has resulted from their application in the industrial and energy sectors. As a result substantial efforts have been dedicated to fostering the shift from fossil fuels to renewable energy sources via technological advancements in industrial processes. Microalgae can be used to produce biofuels such as biodiesel hydrogen and bioethanol. Microalgae are particularly suitable for hydrogen production due to their rapid gro Read More
Hydrogen Intensified Synthesis Processes to Valorise Process Off-gases in Integrated Steelworks
Jul 2023
Publication
Ismael Matino,
Stefano Dettori,
Amaia Sasiain Conde,
Valentina Colla,
Alice Petrucciani,
Antonella Zaccara,
Vincenzo Iannino,
Claudio Mocci,
Alexander Hauser,
Sebastian Kolb,
Jürgen Karl,
Philipp Wolf-Zoellner,
Stephane Haag,
Michael Bampaou,
Kyriakos Panopoulos,
Eleni Heracleousa,
Nina Kieberger,
Katharina Rechberger,
Leokadia Rog and
Przemyslaw Rompalski
Integrated steelworks off-gases are generally exploited to produce heat and electricity. However further valorization can be achieved by using them as feedstock for the synthesis of valuable products such as methane and methanol with the addition of renewable hydrogen. This was the aim of the recently concluded project entitled “Intelligent and integrated upgrade of carbon sources in steel industries through hydrogen intensified synthesis process Read More
Experimental Investigation of Hydrogen Enriched Natural Gas Combustion with a Focus on Nitrogen Oxide Formation on a Semi-industrial Scale
Mar 2024
Publication
Combustion of hydrogen-enriched natural gas is a valuable short-term strategy for reducing CO2 emissions from high temperature industrial heating. This paper presents several experiments on combustion characteristics and the formation of nitrogen oxides. The experiments included hydrogen contents up to 100% and fuel heat inputs up to 75 kW. Water-cooled lances were used to influence the furnace temperature. The analysis includes the distributio Read More
Exhaust Gas Aftertreatment to Minimize Nox Emissions from Hydrogen-fueled Internal Combustion Engines
Oct 2023
Publication
Hydrogen-fueled internal combustion engines are a promising CO2-free and zero-impact emission alternative to battery or fuel cell electric powertrains. Advantages include long service life robustness against fuel impurities and a strong infrastructural base with existing production lines and workshop stations. In order to make hydrogen engines harmless in terms of pollutant emissions as well NOX emissions at the tailpipe must be reduced as low as the z Read More
Techno-economic Assessment of Hydrogen Supply Solutions for Industrial Site
Sep 2024
Publication
In Austria one of the highest priorities of hydrogen usage lies in the industrial sector particularly as a feedstock and for high-temperature applications. Connecting hydrogen producers with consumers is challenging and requires comprehensive research to outline the advantages and challenges associated with various hydrogen supply options. This study focuses on techno-economic assessment of different supply solutions for industrial sites mainly d Read More
Hydrogen Balloon Transportation: A Cheap and Efficiency Mode to Transport Hydrogen
Nov 2023
Publication
The chances of a global hydrogen economy becoming a reality have increased significantly since the COVID pandemic and the war in Ukraine and for net zero carbon emissions. However intercontinental hydrogen transport is still a major issue. This study suggests transporting hydrogen as a gas at atmospheric pressure in balloons using the natural flow of wind to carry the balloon to its destination. We investigate the average wind speeds atmospheric pre Read More
Off-grid Hydrogen Production: Analysing Hydrogen Producton and Supply Costs Considering Country-specifics and Transport to Europe
Jul 2024
Publication
Hydrogen plays a pivotal role in transitioning to CO2-free energy systems yet challenges regarding costs and sourcing persist in supplying Europe with renewable hydrogen. Our paper proposes a simulation-based approach to determine cost-optimal combinations of electrolyser power and renewable peak power for off-grid hydrogen production considering location and energy source dependencies. Key findings include easy estimation of Levelized C Read More
Wind–Photovoltaic–Electrolyzer-Underground Hydrogen Storage System for Cost-Effective Seasonal Energy Storage
Nov 2024
Publication
Photovoltaic (PV) and wind energy generation result in low greenhouse gas footprints and can supply electricity to the grid or generate hydrogen for various applications including seasonal energy storage. Designing integrated wind–PV–electrolyzer underground hydrogen storage (UHS) projects is complex due to the interactions between components. Additionally the capacities of PV and wind relative to the electrolyzer capacity and fluctuating electricity pri Read More
Hydrogen Storage with Gravel and Pipes in Lakes and Reservoirs
Sep 2024
Publication
Climate change is projected to have substantial economic social and environmental impacts worldwide. Currently the leading solutions for hydrogen storage are in salt caverns and depleted natural gas reservoirs. However the required geological formations are limited to certain regions. To increase alternatives for hydrogen storage this paper proposes storing hydrogen in pipes filled with gravel in lakes hydropower and pumped hydro storage reservoirs. Hydr Read More
Towards a Multi-color Hydrogen Production Network? Competing Imaginaries of Development in Northern Patagonia, Argentina
Feb 2024
Publication
Green hydrogen has recently gained importance as a key element in the transition to a low-carbon energy future sparking a boom in possible production regions. This article aims at situating incipient hydrogen production in the Argentine province of Río Negro within a global production network (GPN). The early configuration of the hydrogen-GPN includes several stakeholders and is contested in many ways. To explore the possible materialization of th Read More
Sensitivity Analysis of the Methanation Process in Underground Hydrogen Storage: A Case Study in Upper Austria
Jan 2025
Publication
Underground hydrogen storage (UHS) has attracted increasing attention as a promising technology for the largescale storage of renewable energy resources and the decarbonization of energy systems. This study aimed to identify critical parameters influencing UHS performance particularly the role of hydrogen conversion via in situ methanation and hydrogen recovery during production cycles. The main focus is the Lehen field in Upper Austria where a pil Read More
European Hydrogen Train the Trainer Programme for Responders: The Impact of HyResponder on Training Across Europe
Jan 2025
Publication
Síle Brennan,
Christian Brauner,
Dennis Davis,
Natalie DeBacker,
Alexander Dyck,
César García Hernández,
André Vagner Gaathaug,
Petr Kupka,
Laurence Grand-Clement,
Etienne Havret,
Deborah Houssin-Agbomson,
Laurent Lecomte,
Eric Maranne,
Pippa Steele,
Paola Russo,
Adolfo Pinilla,
Gerhard Schoepf,
Tom Van Esbroeck and
Vladimir V. Molkov
The impact of the HyResponder project on the training of responders in 10 European countries is described. An overview is presented of training activities undertaken within the project in Austria Belgium Czech Republic France Germany Italy Norway Spain Switzerland and the United Kingdom. National leads with training expertise are given and the longer-term plans in each region are mentioned. Responders from each region took part in a specially tailored Read More
Integration of UN Sustainable Development Goals in National Hydrogen Strategies: A Text Analysis Approach
Jan 2025
Publication
Despite the growing recognition of hydrogen’s potential role in sustainable development there is limited un derstanding of how national hydrogen strategies align with the United Nations Sustainable Development Goals (SDGs). This study addresses this knowledge gap by examining the integration of the SDGs into national hydrogen strategies through text analysis. Among 66 reviewed strategic documents only 15 explicitly reference specific SDGs though SDG Read More
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