Australia
Comprehensive Review of Development and Applications of Hydrogen Energy Technologies in China for Carbon Neutrality: Technology Advances and Challenges
Jul 2024
Publication
Concerning the transition from a carbon-based energy economy to a renewable energy economy hydrogen is considered an essential energy carrier for efficient and broad energy systems in China in the near future. China aims to gradually replace fossil fuel-based power generation with renewable energy technologies to achieve carbon neutrality by 2060. This ambitious undertaking will involve building an industrial production chain spanning the production storage transportation and utilisation of hydrogen energy by 2030 (when China’s carbon peak will be reached). This review analyses the current status of technological R&D in China’s hydrogen energy industry. Based on published data in the open literature we compared the costs and carbon emissions for grey blue and green hydrogen production. The primary challenges concerning hydrogen transportation and storage are highlighted in this study. Given that primary carbon emissions in China are a result of power generation using fossil fuels we provide an overview of the advances in hydrogen-to-power industry technology R&D including hydrogen-related power generation technology hydrogen fuel cells hydrogen internal combustion engines hydrogen gas turbines and catalytic hydrogen combustion using liquid hydrogen carriers (e.g. ammonia methanol and ethanol).
Economics of Renewable Hydrogen Production Using Wind and Solar Energy: A Case Study for Queensland, Australia
Dec 2023
Publication
This study presents a technoeconomic analysis of renewables-based hydrogen production in Queensland Australia under Optimistic Reference and Pessimistic scenarios to address uncertainty in cost predictions. The goal of the work was to ascertain if the target fam-gate cost of AUD 3/kg (approx. USD 2/kg) could be reached. Economies of scale and the learning rate concept were factored into the economic model to account for the effect of scale-up and cost reductions as electrolyser manufacturing capacity grows. The model assumes that small-scale to large-scale wind turbine (WT)-based and photovoltaic (PV)-based power generation plants are directly coupled with an electrolyser array and utilises hourly generation data for the Gladstone hydrogen-hub region. Employing first a commonly used simplified approach the electrolyser array was sized based on the maximum hourly power available for hydrogen production. The initial results indicated that scale-up is very beneficial: the levelised cost of green hydrogen (LCOH) could decrease by 49% from $6.1/kg to $3.1/kg when scaling PV-based plant from 10 MW to 1 GW and for WT-based plant by 36% from $5.8/kg to $3.7/kg. Then impacts on the LCOH of incorporating curtailment of ineffective peak power and electrolyser overload capacity were investigated and shown to be significant. Also significant was the beneficial effect of recognising that electrolyser efficiency depends on input power. The latter two factors have mostly been overlooked in the literature. Incorporating in the model the influence on the LCOH of real-world electrolyser operational characteristics overcomes a shortcoming of the simplified sizing method namely that a large portion of electrolyser capacity is under-utilised leading to unnecessarily high values of the LCOH. It was found that AUD 3/kg is achievable if the electrolyser array is properly sized which should help to incentivise large-scale renewable hydrogen projects in Australia and elsewhere.
Decarbonizing Combustion with Hydrogen Blended Fuels: An Exploratory Study of Impact of Hydrogen on Hydrocarbon Autoignition
Jan 2024
Publication
Blending hydrogen to existing fuel mix represents a major opportunity for decarbonisation. One important consideration for this application is the chemical interaction between hydrogen and hydrocarbon fuels arising from their different combustion chemistries and varying considerably with combustion processes. This paper conducted an exploratory study of hydrogen’s impact on autoignition in several combustion processes where hydrogen is used as a blending component or the main fuel. Case studies are presented for spark ignition engines (H2/natural gas) compression ignition engines (H2/diesel) moderate or intense low-oxygen dilution (MILD) combustors (H2/natural gas) and rotational detonation engines (H2/natural gas). Autoignition reactivity as a function of the hydrogen blending level is investigated numerically using the ignition delay iso-contours and state-of-the-art kinetic models at time scales representative of each application. The results revealed drastically different impact of hydrogen blending on autoignition due to different reaction temperature pressure and time scale involved in these applications leaving hydrocarbon interacting with hydrogen at different ignition branches where the negative pressure/temperature dependency of oxidation kinetics could take place. The resulted non-linear and at times non-monotonic behaviours indicate a rich topic for combustion chemistry and also demonstrates ignition delay iso-contour as a useful tool to scope autoignition reactivity for a wide range of applications.
Upcycling of Plastic Wastes for Hydrogen Production: Advances and Perspectives
Feb 2024
Publication
The abundant plastic wastes become an imperative global issue and how to handle these organic wastes gains growing scientific and industrial interest. Recently converting plastic wastes into hydrogen fuel has been investigated and the “waste-to-value” practice accelerates the circular economy. To accelerate the development of plastic-to-hydrogen conversion in this review recent advances in plastic-to-hydrogen conversion via thermochemical photocatalytic and electrocatalytic routes are analyzed. All of the thermo- photo- and electrochemical processes can transform different plastic wastes into hydrogen and the hydrogen production efficiency depends heavily on the selected techniques operating parameters and applied catalysts. The application of rational-designed catalysts can promote the selective production of hydrogen from plastic feedstocks. Further studies on process optimization cost-effective catalyst design and mechanism investigation are needed.
Advancing a Hydrogen Economy in Australia: Public Perceptions and Aspirations
Nov 2023
Publication
Supporters of hydrogen energy urge scaling up technology and reducing costs for competitiveness. This paper explores how hydrogen energy technologies (HET) are perceived by Australia’s general population and considers the way members of the public imagine their role in the implementation of hydrogen energy now and into the future. The study combines a nationally representative survey (n = 403) and semi-structured interviews (n = 30). Results show age and gender relationships with self-reported hydrogen knowledge. Half of the participants obtained hydrogen information from televised media. Strong support was observed for renewable hydrogen while coal (26%) and natural gas (41%) versions had less backing. Participants sought more safety-related information (41% expressed concern). Most felt uncertain about influencing hydrogen decisions and did not necessarily recognise they had agency beyond their front fence. Exploring the link between political identity and agency in energy decision-making is needed with energy democracy a potentially productive direction.
Opportunities and Challenges of Hydrogen Ports: An Empirical Study in Australia and Japan
Jul 2024
Publication
This paper investigated the opportunities and challenges of integrating ports into hydrogen (H2 ) supply chains in the context of Australia and Japan because they are leading countries in the field and are potential leaders in the upcoming large-scale H2 trade. Qualitative interviews were conducted in the two countries to identify opportunities for H2 ports necessary infrastructure and facilities key factors for operations and challenges associated with the ports’ development followed by an online survey investigating the readiness levels of H2 export and import ports. The findings reveal that there are significant opportunities for both countries’ H2 ports and their respective regions which encompass business transition processes and decarbonisation. However the ports face challenges in areas including infrastructure training standards and social licence and the sufficiency and readiness levels of port infrastructure and other critical factors are low. Recommendations were proposed to address the challenges and barriers encountered by H2 ports. To optimise logistics operations within H2 ports and facilitate effective integration of H2 applications this paper developed a user-oriented working process framework to provide guidance to ports seeking to engage in the H2 economy. Its findings and recommendations contribute to filling the existing knowledge gap pertaining to H2 ports.
Fuelling the Future: An In-depth Review of Recent Trends, Challenges and Opportunities of Hydrogen Fuel Cell for a Sustainable Hydrogen Economy
Sep 2023
Publication
Hydrogen has gained tremendous momentum worldwide as an energy carrier to transit to a net zero emission energy sector. It has been widely adopted as a promising large-scale renewable energy (RE) storage solution to overcome RE resources’ variability and intermittency nature. The fuel cell (FC) technology became in focus within the hydrogen energy landscape as a cost-effective pathway to utilize hydrogen for power generation. Therefore FC technologies’ research and development (R&D) expanded into many pathways such as cost reduction efficiency improvement fixed and mobile applications lifetime safety and regulations etc. Many publications and industrial reports about FC technologies and applications are available. This raised the necessity for a holistic review study to summarize the state-of-the-art range of FC stacks such as manufacturing the balance of plant types technologies applications and R&D opportunities. At the beginning the principal technologies to compare the well known types followed by the FC operating parameters are presented. Then the FC balance of the plant i.e. building components and materials with its functionality and purpose types and applications are critically reviewed with their limitations and improvement opportunities. Subsequently the electrical properties of FCs with their key features including advantages and disadvantages were investigated. Applications of FCs in different sectors are elaborated with their key characteristics current status and future R&D opportunities. Economic attributes of fuel cells with a pathway towards low cost are also presented. Finally this study identifies the research gaps and future avenues to guide researchers and the hydrogen industry.
Renewable Hydrogen for the Energy Transition in Australia - Current Trends, Challenges and Future Directions
Sep 2024
Publication
Hydrogen is viewed as a potential energy solution for the 21st century with capabilities to tackle issues relating to environmental emissions sustainability energy shortages and security. Even though there are potential benefits of renewable hydrogen towards transitioning to net-zero emissions there is a limited study on the current use ongoing development and future directions of renewable hydrogen in Australia. Thus this study conducts a systematic review of studies for exploring Australia’s renewable hydrogen energy transition current trends strategies developments and future directions. By using the Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) guidelines earlier studies from 2005 to 2024 from two major databases such as ProQuest and Web of Science are gathered and analyzed. The study highlights significant issues relating to hydrogen energy technologies and opportunities/challenges in production storage distribution utilization and environmental impacts. The study found that Australia’s ambition for a strong hydrogen economy is made apparent with its clear strategic actions to develop a clean technology-based hydrogen production storage and distribution system. This study provides several practical insights on Australia’s hydrogen energy transition hydrogen energy technologies investments and innovation as well as strategies/recommendations for achieving a more environment friendly secure affordable and sustainable energy future.
The Impact of Water Injection and Hydrogen Fuel on Performance and Emissions in a Hydrogen/Diesel Dual-Fuel Engine
Nov 2024
Publication
As the need for alternative energy sources and reduced emissions grows proven technologies are often sidelined in favour of emerging solutions that lack the infrastructure for mass adoption. This study explores a transitional approach by modifying existing compression ignition engines to run on a hydrogen/diesel mixture for performance improvement utilising water injection to mitigate the drawbacks associated with hydrogen combustion. This approach can yield favourable results with current technology. In this modelling study ten hydrogen energy ratios (0–90%) and nine water injection rates (0–700 mg/cycle) were tested in a turbocharged Cummins ISBe 220 31 six-cylinder diesel engine. An engine experiment was conducted to validate the model. Key performance indicators such as power mechanical efficiency thermal efficiency indicated mean effective pressure (IMEP) and brake-specific fuel consumption (BSFC) were measured. Both water injection and hydrogen injection led to slight improvements in all performance metrics except BSFC due to hydrogen’s lower energy density. In terms of emissions CO and CO2 levels significantly decreased as hydrogen content increased with reductions of 94% and 96% respectively at 90% hydrogen compared to the baseline diesel. Water injection at peak rates further reduced CO emissions by approximately 40% though it had minimal effect on CO2 . As expected NOx (which is a typical challenge with hydrogen combustion and also with diesel engines in general) increased with hydrogen fuelling resulting in an approximately 70% increase in total NOx emissions over the range of 0–90% hydrogen energy. Similar increases were observed in NO and NO2 e.g. 90% and 57% increases with 90% hydrogen respectively. However water injection reduced NO and NO2 levels by up to 16% and 83% respectively resulting in a net decrease in NOX emissions in many combined cases not only with hydrogen injection but also when compared to baseline diesel.
Optimizing an Integrated Hybrid Energy System with Hydrogen-based Storage to Develop an Off-grid Green Community for Sustainable Development in Bangladesh
Dec 2024
Publication
An integrated renewable system that utilizes solid waste-based biogas is important steps towards the sustainable energy solutions to rural off-grid communities in Bangladesh. In this study a hybrid energy system consisting of photovoltaic modules wind turbines biogas generators fuel cells and electrolyzer-hydrogen tank-based energy storage is optimized using non-dominated sorting genetic algorithm (NSGA-II). The hybrid system is optimized based on the cost of energy and human health damage as objective functions and a fuzzy decision-making technique is employed to determine the optimal solution to the multi-objective approach. Additionally several economic ecological and social indicators are also investigated while meeting a certain load reliability. An energy management strategy has been developed in the MATALB environment to satisfy the community load and the battery-driven electric vehicle load. Results from this comprehensive analysis suggest that the optimal configuration of PV/WT/FC/BG has an energy cost of 0.1634 $/kWh and an ecosystem damage of 0.00098 species.year. The human health damage and the human development index of the optimized system are 0.1732 DALYs and 0.696 DALYs respectively. Additionally the proposed system has a lifecycle emission of 123730 kg CO2-eq/year carbon emission penalties of $1856/year a job creation potential of 30 jobs/MW over the 25 years of project lifetime. The hybrid system oversees solid waste management solutions and provides the community with sustainable energy and vehicle recharge.
The Hydrogen-water Collision: Assessing Water and Cooling Demands for Large-scale Green Hydrogen Production in a Warming Climate
Dec 2024
Publication
Hydrogen is expected to play a critical role in future energy systems projected to have an annual demand of 401–660 Mt by 2050. With large-scale green hydrogen projects advancing in water-scarce regions like Australia Chile and the Middle East and North Africa understanding water requirements for large-scale green hydrogen production is crucial. Meeting this future hydrogen demand will necessitate 4010 to 6600 GL of demineralised water annually for electrolyser feedwater if dry cooling is employed or an additional 6015 to 19800 GL for cooling water per year if evaporative cooling is employed. Using International Panel of Climate Change 2050 climate projections this work evaluated the techno-economic implications of dry vs. evaporative cooling for large-scale electrolyser facilities under anticipated higher ambient temperatures. The study quantifies water demands costs and potential operational constraints showing that evaporative cooling is up to 8 times cheaper to implement than dry cooling meaning that evaporative cooling can be oversized to accommodate increased cooling demand of high temperature events at a lower cost. Furthermore of the nations analysed herein Chile emerged as having the lowest cost of hydrogen owing to the lower projected ambient temperatures and frequency of high temperature events.
A Study on Hydrogen Embrittlement of a High-strength Pipeline Steel Weldment after Microstructure Manipulation by Targeted Heat Treatments
Dec 2024
Publication
Hydrogen embrittlement (HE) is a major concern when steel pipelines are used for hydrogen transportation and storage. The weldments of steel pipelines are of particular concern because they are reported to have higher HE susceptibility compare to the base metal. In this work targeted heat treatments were used to manipulate the microstructure in a pipeline steel weldment to examine the effects of different microstructural features on HE susceptibility. Complementary analyses of the microstructure mechanical testing and fracture surface identified inclusions and ferrite morphology as the most dominant microstructural features that affect the susceptibility to HE. Specimens with different microstructures but sharing similar Ti-rich inclusions exhibited significant re ductions in elongation to failure after hydrogen charging and showed brittle fracture surfaces decorated with multiple ‘fish-eye’ features. In addition co-existence of bainitic microstructure with Ti-rich inclusions resulted in the highest susceptibility to HE.
A Risk-based Multi-criteria Decision-making Framework for Offshore Green Hydrogen System Developments: Pathways for Utilizing Existing and New Infrastructure
Mar 2024
Publication
Unlocking the potential of offshore renewables for green hydrogen (GH2) production can be a game-changer empowering economies with their visionary clean energy policies amplifying energy security and promoting economic growth. However their novelty entails uncertainty and risk necessitating a robust framework for facility deployment and infrastructure planning. To optimize offshore GH2 infrastructure placement this work proposes a novel and robust GIS-based multi-criteria decision-making (MCDM) framework. Encompassing thirtytwo techno-socio-economic-safety factors and ocean environmental impact analysis this methodology facilitates informed decision-making for sustainable and safe GH2 development. Utilizing the synergies between offshore wind and solar resources this study investigates the potential of hybrid ocean technologies to enhance space utilization and optimize efficiency. To illustrate the practical application of the proposed framework a case study examining a GH2 system in Australia's marine region and its potential nexus with nearby offshore industries has been conducted. The performed life cycle assessment (LCA) explored various configurations of GH2 production storage and transportation technologies. A Bayesian objective weight integrating technique has been introduced and contrasted statistically with the hybrid CRITIC Entropy MEREC and MARCOS-based MCDM approaches. Various locations are ranked based on the net present value of life cycle cost GH2 production capacity risk availability and environment sustainability factors illustrating their compatibility. A sensitivity analysis is conducted to confirm that a Bayesian approach improves the decision-making outcomes through identifying optimal criteria weights and alternative ranks more effectively. Empowering strategic GH2 decisions globally the proposed approach optimizes system performances cost sustainability and safety excelling in harsh environments.
Towards Safer Hydrogen Refuelling Stations: Insights from Computational Fluid Dynamics LH2 Leakage
May 2024
Publication
The transition to a sustainable future with hydrogen as a key energy carrier necessitates a comprehensive understanding of the safety aspects of hydrogen including liquid hydrogen (LH₂). Hence this study presents a detailed computational fluid mechanics analysis to explore accidental LH₂ leakage and dispersion in a hydrogen refuelling station under varied conditions which is essential to prevent fire and explosion. The correlated impact of influential parameters including wind direction wind velocity leak direction and leak rate were analysed. The study shows that hydrogen dispersion is significantly impacted by the combined effect of wind direction and surrounding structures. Additionally the leak rate and leak direction have a significant effect on the development of the flammable cloud volume (FCV) which is critical for estimating the explosion hazards. Increasing wind velocity from 2 to 4 m/s at a constant leak rate of 0.06 kg/s results in an 82% reduction in FCV. The minimum FCV occurs when leak and wind directions oppose at 4 m/s. The most critical situation concerning FCV arises when the leak and wind directions are perpendicular with a leak rate of 0.06 kg/s and a wind velocity of 2 m/s. These findings can aid in the development of optimised sensing and monitoring systems and operational strategies to reduce the risk of catastrophic fire and explosion consequences.
Challenges and Opportunities for Hydrogen Production from Microalgae
Nov 2015
Publication
The global population is predicted to increase from ~7.3 billion to over 9 billion people by 2050.Together with rising economic growth this is forecast to result in a 50% increase in fueldemand which will have to be met while reducing carbon dioxide (CO 2 ) emissions by 50–80%to maintain social political energy and climate security. This tension between rising fuel demandand the requirement for rapid global decarbonization highlights the need to fast-track thecoordinated development and deployment of efficient cost-effective renewable technologies forthe production of CO 2 neutral energy. Currently only 20% of global energy is provided aselectricity while 80% is provided as fuel. Hydrogen (H 2) is the most advanced CO 2 -free fuel andprovides a ‘common’ energy currency as it can be produced via a range of renewabletechnologies including photovoltaic (PV) wind wave and biological systems such as microalgaeto power the next generation of H 2 fuel cells. Microalgae production systems for carbon-basedfuel (oil and ethanol) are now at the demonstration scale. This review focuses on evaluating thepotential of microalgal technologies for the commercial production of solar-driven H2 fromwater. It summarizes key global technology drivers the potential and theoretical limits ofmicroalgal H2 production systems emerging strategies to engineer next-generation systems andhow these fit into an evolving H 2 economy.
A High-performance Capillary-fed Electrolysis Cell Promises More Cost-competitive Renewable Hydrogen
Mar 2022
Publication
Renewable or green hydrogen will play a critical role in the decarbonisation of hard-to-abate sectors and will therefore be important in limiting global warming. However renewable hydrogen is not cost-competitive with fossil fuels due to the moderate energy efficiency and high capital costs of traditional water electrolysers. Here a unique concept of water electrolysis is introduced wherein water is supplied to hydrogen- and oxygen-evolving electrodes via capillary-induced transport along a porous inter-electrode separator leading to inherently bubble-free operation at the electrodes. An alkaline capillary-fed electrolysis cell of this type demonstrates water electrolysis performance exceeding commercial electrolysis cells with a cell voltage at 0.5 A cm−2 and 85 °C of only 1.51 V equating to 98% energy efficiency with an energy consumption of 40.4 kWh/kg hydrogen (vs. ~47.5 kWh/kg in commercial electrolysis cells). High energy efficiency combined with the promise of a simplified balance-ofplant brings cost-competitive renewable hydrogen closer to reality.
Numerical Modelling of Hydrogen Release and Dispersion in Under-deck Compressed Hydrogen Storage of Marine Ships
Feb 2024
Publication
There is growing interest in using hydrogen (H2) as a marine fuel. Fire and explosion risks depend on hydrogen release and dispersion characteristics. Based on a validated Computational Fluid Dynamics (CFD) model this study performed hydrogen release and dispersion analysis on an under-deck compressed H2 storage system for a Live-Fish Carrier. A realistic under-deck H2 storage room was modelled based on the ship’s main dimensions and operational profile. Det Norske Veritas (DNV) Rules and Regulations for natural gas storage as a marine fuel were employed as base design guidelines. Case studies were developed to study the effect of two ceiling types (flat and slanted) in terms of flammable cloud formation and dissipation. During the leak’s duration it was found that the recommended ventilation rate was insufficient to dilute the average H2 concentration below 25% of the flammable range as required by DNV (1.2% required against 1.3% slanted and 1.4% flat). However after 35 s of gas extraction the H2 concentration was reduced to 0.5% and 0.6% in the slanted and flat cases respectively. The proposed methodology remains valid to improve the ventilation system and assess mitigation alternatives or other leakage scenarios in confined or semi-confined spaces containing compressed hydrogen gas.
Comparative Study of LNG, Liquid Hydrogen ,and Liquid Ammonia Post-release Evaporation and Dispersion During Bunkering
Apr 2024
Publication
The use of alternative fuels is a primary means for decarbonising the maritime industry. Liquefied natural gas (LNG) liquid hydrogen (LH2) and liquid ammonia (LNH3) are liquified gases among the alternative fuels. The safety risks associated with these fuels differ from traditional fuels. In addition to their low-temperature hazards the flammability of LNG and LH2 and the high toxicity of LNH3 present challenges in fuel handlings due to their high likelihood of fuel release during bunkering. This study aims at drawing extensive comparisons of the evaporation and vapour dispersion behaviours for the three fuels after release accidents during bunkering and discuss their safety issues. The study involved the release event of the three fuels on the main deck area of a reference bulk carrier with a deadweight of 208000 tonnes. Two release scenarios were considered: Scenario 1 involved a release of 0.3 m3 of fuel and Scenario 2 involved a release of 100 kg of fuel. An empirical equation was used to calculate the fuel evaporation process and the Computational Fluid Dynamic (CFD) code FDS was employed to simulate the dispersion of vapour clouds. The obtained results reveal that LH2 has the highest evaporation rate followed by LNG and LNH3. The vapour clouds of LNG and LNH3 spread along the main deck surface while the LH2 vapour cloud exhibits upward dispersion. The flammable vapour clouds of LNG and LH2 remain within the main deck area whereas the toxic gas cloud of LNH3 disperses towards the shore and spreads near the ground on the shore side. Based on the dispersion behaviours the hazards of LNG and LH2 are com parable while LNH3 poses significantly higher hazards. In terms of hazard mitigations effective water curtain systems can suppress the vapour dispersion.
Evaluation and Outlook for Australian Renewable Energy Export via Circular Liquid Hydrogen Carriers
Oct 2023
Publication
To combat global temperature rise we need affordable clean and renewable energy that does not add carbon to the atmosphere. Hydrogen is a promising option because it can be used as a carbon-free energy source. However storing and transporting pure hydrogen in liquid or gaseous forms is challenging. To overcome the limitations associated with conventional compressed and liquefied hydrogen or physio-chemical adsorbents for bulk storage and transport hydrogen can be attached to other molecules known as hydrogen carriers. Circular carriers which involve the production of CO2 or nitrogen during the hydrogen recovery process include substances such as methanol ammonia or synthetic natural gas. These carriers possess higher gravimetric and volumetric hydrogen densities (i.e. 12.5 wt% and 11.88 MJ/L for methanol) than cyclic carriers (i.e. 6.1 wt% and 5.66 MJ/L for methylcyclohexane (MCH)) which produce cyclic organic chemicals during dehydrogenation. This makes circular carriers particularly appealing for the Australian energy export market. Furthermore the production-decomposition cycle of circular carriers can be made carbon-neutral if they are derived from renewable H2 sources and combined with atmospheric or biomass-based CO2 or nitrogen. The key parameters are investigated in this study focusing on circular hydrogen carriers relevant to Australia. The parameters are ranked from 0 (worst) to 10 (best) depending on the bandwidth of the parameter in this review. Methanol shows great potential as a cost-effective solution for long-distance transport of renewable energy being a liquid at standard conditions with a boiling point of 64.7 °C. Methane is also an important hydrogen carrier due to the availability of natural gas infrastructure and its role as a significant export product for Australia.
Life Cycle Assessment of Renewable Hydrogen Transport by Ammonia
Nov 2024
Publication
Ammonia is a promising hydrogen carrier for enabling the efficient transport of hydrogen as observed by the many hydrogen transport projects using ammonia. For the clean energy future understanding environmental impacts of the transport system is important. This study conducts life cycle assessment (LCA) for the marine transport of renewable hydrogen using ammonia as the hydrogen carrier. The LCA considered renewable hydrogen produced from four systems; wind-powered electrolysis gasification of forest residue anaerobic digestion of food waste and landfill gas reforming; followed by Haber-Bosch ammonia synthesis using the renewable hydrogen and nitrogen produced from air separation. The ammonia was then transported 11000 km by sea to a destination facility where it was decomposed using either Ru or Ni catalysts to obtain hydrogen. Among the four hydrogen transport systems operated with renewable energy electrolysis-hydrogen system presented the highest global warming impact of 3.31 kg CO2 eq/kg H2 due to electricity use for the electrolysis whereas simpler processes based on a landfill gas system led to the lowest impact of 2.27 kg CO2 eq/kg H2. Process energy consumption was the major contributor to global warming impact with 27%–49.2% of contri bution. The consumption of metals and energy during wind turbine construction resulted in the most significant impact in six out of 12 midpoint impact categories for the electrolysis-hydrogen system which also led to the highest endpoint impacts. The endpoint impacts of the four systems were in the order of electrolysis > food waste > forest residue > landfill gas (from high to low) for both endpoint human health and ecosystems impacts. Ammonia decomposition using Ru catalysts exhibited slightly lower global warming impact than Ni catalysts while final purification of hydrogen by vanadium membrane presented 4.8% lower impacts than the purification by pressure swing adsorption. Large-scale hydrogen supply chains can be achieved by technological improve ment and support of policies and financial schemes.
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