Applications & Pathways

Hydrogen is an emerging technology changing the context of heating with cleaner combustion than traditional fossil fuels. Studies indicate the potential to repurpose the existing natural gas infrastructure offering consumers a sustainable economically viable option in the future. The integration of hydrogen in combined heat and power systems could provide residential energy demand and reduce environmental emissions. However the widespread adoption of hydrogen will face several challenges such as carbon dioxide emissions from the current production methods and the need for infrastructure modification for transport and safety. Researchers indicated the viability of hydrogen in decarbonizing heat while some studies also challenged its long-term role in the future of heating. In this paper a comprehensive literature review is carried out by identifying the following key aspects which could impact the conclusion on the overall role of hydrogen in heat decarbonization: (i) a holistic view of the energy system considering factors such as renewable integration and system balancing; (ii) consumer-oriented approaches often overlook the broader benefits of hydrogen in emission reduction and grid stability; (iii) carbon capture and storage scalability is a key factor for large-scale production of low-emission blue hydrogen; (iv) technological improvements could increase the cost-effectiveness of hydrogen; (v) the role of hydrogen in enhancing resilience especially during extreme weather conditions raises the potential of hydrogen as a flexible asset in the energy infrastructure for future energy supply; and finally when considering the UK as a basis case (vi) incorporating factors such as the extensive gas network and unique climate conditions necessitates specific strategies.

Green steel produced using renewable energy and hydrogen presents a promising avenue to decarbonize steel manufacturing and expand the hydrogen industry. Australia endowed with abundant renewable resources and iron ore deposits is ideally placed to support this global effort. This paper's two-step analytical approach offers the first comprehensive assessment of Australia's potential to develop green steel as a value-added export commodity. The Economic Fairways modelling reveals a strong alignment between prospective hydrogen hubs and current and future iron ore operations enabling shared infrastructure development and first-mover advantages. By employing a site-based system optimization that integrates both wind and solar power sources the cost of producing green steel could decrease significantly to around AU$900 per tonne by 2030 and AU$750 per tonne by 2050. Moreover replacing 1% of global steel production would require 35 GW of well-optimized wind and solar photovoltaics 11 GW of hydrogen electrolysers and 1000 square kilometres of land. Sensitivity analysis further indicates that iron ore prices would exert a long-term influence on green steel prices. Overall this study highlights the opportunities and challenges facing the Australian iron ore industry in contributing to the decarbonization of the global steel sector underscoring the crucial role of government support in driving the growth and development of the green steel industry.

The presented work concerns experimental research of a spark-ignition engine with variable compression ratio (VCR) adapted to dual-fuel operation in which co-combustion of ammonia with hydrogen was conducted and the energy share of hydrogen varied from 0% to 70%. The research was aimed at assessing the impact of the energy share of hydrogen co-combusted with ammonia on the performance stability and emissions of an engine operating at a compression ratio of 8 (CR 8) and 10 (CR 10). The operation of the engine powered by ammonia alone for both CR 8 and CR 10 is associated with either a complete lack of ignition in a significant number of cycles or with significantly delayed ignition and the related low value of the maximum pressure pmax. Increasing the energy share of hydrogen in the fuel to 12% allows to completely eliminate the instability of the ignition process in the combustible mixture which is confirmed by a decrease in the IMEP uniqueness and a much lower pmax dispersion. For 12% of the energy share of hydrogen co-combusted with ammonia the most favorable course of the combustion process was obtained the highest engine efficiency and the highest IMEP value were recorded. The conducted research shows that increasing the H2 share causes an increase in NO emissions for both analyzed compression ratios

Hydrogen has recently been proposed as a versatile energy carrier to contribute to archiving universal access to clean cooking. In hard-to-reach rural settings decentralized produced hydrogen may be utilized (i) as a clean fuel via direct combustion in pure gaseous form or blended with Liquid Petroleum Gas (LPG) or (ii) via power-to-hydrogen-to-power (P2H2P) to serve electric cooking (e-cooking) appliances. Here we present the first techno-economic evaluation of hydrogen-based cooking solutions. We apply mathematical optimization via energy system modeling to assess the minimal cost configuration of each respective energy system on technical and economic measures under present and future parameters. We further compare the potential costs of cooking for the end user with the costs of cooking with traditional fuels. Today P2H2P-based e-cooking and production of hydrogen for utilization via combustion integrated into the electricity supply system have almost equal energy system costs to simultaneously satisfy the cooking and electricity needs of the isolated rural Kenyan village studied. P2H2P-based e-cooking might become advantageous in the near future when improving the energy efficiency of e-cooking appliances. The economic efficiency of producing hydrogen for utilization by end users via combustion benefits from integrating the water electrolysis into the electricity supply system. More efficient and cheaper hydrogen technologies expected by 2050 may improve the economic performance of integrated hydrogen production and utilization via combustion to be competitive with P2H2P-based e-cooking. The monthly costs of cooking per household may be lower than the traditional use of firewood and charcoal even today when applying the current life-line tariff for the electricity consumed or utilizing hydrogen via combustion. Driven by likely future technological improvements and the expected increase in traditional and fossil fuel prices any hydrogen-based cooking pathway may be cheaper for end users than using charcoal and firewood by 2030 and LPG by 2040. The results suggest that providing clean cooking in rural villages could economically and environmentally benefit from utilizing hydrogen. However facing the complexity of clean cooking projects we emphasize the importance of embedding the results of our techno-economic analysis in holistic energy delivery models. We propose useful starting points for future aspects to be investigated in the discussion section including business and financing models.

Hydrogen-based multi-microgrid systems (HBMMSs) are beneficial for energy saving and emission reductions. However the optimal sizing of HBMMSs lacks a practical configuration optimization model and a reasonable solution method. To address these problems we designed a novel structure of HBMMSs that combines conventional energy renewable energy and a hydrogen energy subsystem. Then we established a bi-level multi-objective capacity optimization model while considering electricity market trading and different hydrogen production strategies. The objective of the inner model which is the minimum annual operation cost and the three objectives of the outer model which are the minimum total annual cost (TAC); the annual carbon emission (ACE); and the maximum self-sufficiency rate (SSR) are researched simultaneously. To solve the above optimization model a two-stage solution method which considers the conflicts between objectives and the objectivity of objective weights is proposed. Finally a case study is performed. The results show that when green hydrogen production strategies are adopted the three objectives of the best configuration optimization scheme are USD 404.987 million 1.106 million tons and 0.486 respectively.

Hydrogen as a carbon-free energy carrier has emerged as a crucial component in the decarbonization of the energy system serving as both an energy storage option and fuel for dispatchable power generation to mitigate the intermittent nature of renewable energy sources. However the unique physical and combustion characteristics of hydrogen which differ from conventional gaseous fuels such as biogas and natural gas present new challenges that must be addressed. To fully integrate hydrogen as an energy carrier in the energy system the development of low-emission and highly reliable technologies capable of handling hydrogen combustion is imperative. This study presents a ground-breaking achievement - the first successful test of a micro gas turbine running on 100% hydrogen with NOx emissions below the standard limits. Furthermore the combustor of the micro gas turbine demonstrates exceptional fuel flexibility allowing for the use of various blends of hydrogen biogas and natural gas covering a wide range of heating values. In addition to a comprehensive presentation of the test rig and its instrumentation this paper illuminates the challenges of hydrogen combustion and offers real-world operational data from engine operation with 100% hydrogen and its blends with methane.

With the massive use of traditional fossil fuels greenhouse gas emissions are increasing and environmental pollution is becoming an increasingly serious problem which led to an imminent energy transition. Therefore the development and application of renewable energy are particularly important. This paper reviews a wide range of issues associated with hybrid renewable energy systems (HRESs). The issues concerning system configurations energy storage options simulation and optimization with artificial intelligence are discussed in detail. Storage technology options are introduced for stand-alone (off-grid) and grid-connected (on-grid) HRESs. Different optimization methodologies including classical techniques intelligent techniques hybrid techniques and software tools for sizing system components are presented. Besides the artificial intelligence methods for optimizing the solar/wind HRESs are discussed in detail.

Improving the energy efficiency of existing technologies such as the on-board power supply of trucks ships and aircraft is an important endeavor for reducing primary energy consumption. The approach consists of using fuel cell technology in conjunction with hydrogen production from liquid fuels. However the energy transition with the goal of complete climate-neutrality requires technological changes in the use of hydrogen produced from renewable energy via electrolysis. Synthetic fuels are an important building block for drive systems that will continue to require liquid energy carriers in the future due to their range. This study addresses the question of whether technical devices that were developed for the generation of hydrogen from liquid fuels for fuel cells to generate electricity are now suitable for the reverse process chain or can play an important role in it. The new process chain produces hydrogen from sustainable electricity combining it with carbon dioxide to create a synthetic liquid fuel.

Fuel cell electric vehicles are a promising solution for reducing the environmental impacts of the automotive sector; however there are still some key points to address in finding the most efficient and less impactful implementation of this technology. In this work three electrical architectures of fuel cell electric vehicles were modeled and compared in terms of the environmental impacts of their manufacturing and use phases. The three architectures differ in terms of the number and position of the DC/DC converters connecting the battery and the fuel cell to the electric motor. The life cycle assessment methodology was employed to compute and compare the impacts of the three vehicles. A model of the production of the main components of vehicles and fuel cell stacks as well as of the production of hydrogen fuel was constructed and the impacts were calculated using the program SimaPro. Eleven impact categories were considered when adopting the ReCiPe 2016 midpoint method and the EF (adapted) method was exploited for a final comparison. The results highlighted the importance of the converters and their influence on fuel consumption which was identified as the main factor in the comparison of the environmental impacts of the vehicle.

This report of the High Level Group for Hydrogen and Fuel Cell Technologies sets out a vision for these technologies in future sustainable energy systems - improving energy security of supply and air quality whilst mitigating climate change. The report recommends actions for developing world-class European hydrogen technologies and fostering their commercial exploitation.

This paper describes a renewable energy system incorporating a hydrogen production unit to address the imbalance between energy supply and demand. The system utilizes renewable energy and hydrogen production energy to release energy to fill the power gap during peak demand power supply for demand peaking and valley filling. The system is optimized by analyzing marine predator behavioral logic and optimizing the system for maximum operational efficiency and best economic value. The results of the study show that after the optimized scheduling of the hydrogen production coupled renewable energy integrated energy system using the improved marine predator optimization algorithm the energy distribution of the whole energy system is good with the primary energy saving rate maintained at 24.75% the CO2 emission reduction rate maintained at 42.32% and the cost saving rate maintained at 0.78%. In addition this paper uses the Adaboost-BP prediction model to predictively analyze the system. The results show that as the price of natural gas increases the advantages of the combined hydrogen production renewable integrated energy system proposed in this paper become more obvious and the cumulative cost over three years is better than other related systems. These research results provide an important reference for the application and development of the system.

This study presents a novel web-based decision support system (DSS) that optimizes the locations of hydrogen refueling stations (HRSs) and hydrogen supply chains (HSCs). The system is developed with a design science approach that identifies key design requirements and features through interviews and literature reviews. Based on the findings a system architecture and data model were designed incorporating scenario management optimization model visualization and data management components. The DSS provides a two-stage solution model that links demand to HRSs and production facilities to HRSs. A prototype is demonstrated with a plan for 2025 and 2030 in the Republic of Korea where 450 to 660 stations were deployed nationwide and linked to production facilities. User evaluation confirmed the effectiveness of the DSS in solving optimization problems and its potential to assist the government and municipalities in planning hydrogen infrastructure.

Fuel cell electric buses (FCBs) have proven to be a technically viable solution for transportation owing to various advantages such as reliability simplicity better energy efficiency and quietness of operation. However largescale adoption of FCBs is hindered by the lack of extensive and structured infrastructure and the high cost of clean hydrogen. Many studies agree that one of the significant contributors to the lack of competitiveness of green hydrogen is the cost of electricity for its production followed by transportation costs. On the one hand to reduce the investment cost of the electrolyzer high operating hours should be achieved; on the other as the number of operating hours decreases the impact of the electricity costs declines. This paper presents an innovative algorithm for a scalable hydrogen refuelling station (HRS) capable of successfully matching and identifying the most cost-efficient levelized cost of hydrogen (LCOH) produced via electrolysis and connected to the grid based on the HRS components’ cost curves and the hourly average electricity price profile. The objective is to identify the least-cost range of LCOH by considering both the electric energy and the investment costs associated with a hydrogen demand given by different FCB sizes and electrolyzer rated powers. In addition sensitivity analyses have been conducted to quantify the technology cost margins and a cost comparison between the refuelling of an FCB fleet and the recharging infrastructure required for an equivalent fleet of Battery Electric Buse (BEB) has been performed. An LCOH of around 10.5 €/kg varying from 12 €/kg (2 FCB) to 10.2 €/kg (30 FCB) has been found for the best-optimized configurations. The final major conclusion of this paper is that FCB technology is currently not economically competitive. Still a cost contraction of the electric energy price and the electrolyzer capital investment would lead to a 50% decrease in the LCOH. Furthermore increasing renewable energies into the grid may shift the electricity cost curve resulting in higher prices when the BEB recharging demand is more significant. This impact in addition to the peak power load and longer recharging times might contribute to bridging the gap with FCBs.

The supply storage and (international) transport of green hydrogen (H2) are essential for the decarbonization of the energy sector. The goal of this study was to assess the final cost-price and carbon footprint of imported green H2 in the market via maritime shipping of liquid organic hydrogen carriers (LOHCs) including dibenzyl toluene-perhydro-dibenzyltoluene (DBTPDBT) and toluene-methylcyclohexane (TOL-MCH) systems. The study focused on logistic steps in intra-European supply chains in different scenarios of future production in Portugal and demand in the Netherlands and carbon tariffs between 2030 and 2050. The case study is based on a formally accepted agreement between Portugal and the Netherlands within the Strategic Forum on Important Projects of Common European Interest (IPCEI). Under the following assumptions the results show that LOHCs are a viable technical-economic solution with logistics costs from 2030 to 2050 varying between 0.30-0.37 €/kg-H2 for DBT-PDBT and 0.28-0.34 €/kg-H2 for TOL-MCH. The associated CO2 emissions of these international H2 supply chains are between 0.46 and 2.46 kg-CO2/GJ (LHV) and 0.55-2.95 kg-CO2/GJ (LHV) for DBT-PDBT and TOL-MCH respectively.

Sustainability is one of the main challenges the aviation industry is currently facing. In a global context of energy transition towards cleaner and renewable sources the sector is developing technologies to fly more efficiently and mitigate its environmental impact. Innovative propulsion alternatives such as biofuels electric aircraft and hydrogen engines are already a reality or are close to becoming so. To assess their feasibility a study is conducted on specific routes and aircraft across different flight ranges. The analysis focuses on the Canary Islands an outermost region of the EU with high mobility and no comparable alternative means of transport. For three routes flight profiles are analyzed obtaining the fuel consumption and emissions generated by the conventional propulsion and later applying the sustainable alternatives. The results indicate optimistic perspectives with reductions in environmental impact ranging between 40% and 75% compared to the present.

This study presents a novel framework for improving the resilience of microgrids based on the power-to-hydrogen concept and the ability of microgrids to operate independently (i.e. islanded mode). For this purpose a model is being developed for the resilient operation of microgrids in which the compressed hydrogen produced by power-to-hydrogen systems can either be used to generate electricity through fuel cells or sold to other industries. The model is a bi-objective optimization problem which minimizes the cost of operation and resilience by (i) reducing the active power exchange with the main grid (ii) reducing the ohmic power losses and (iii) increasing the amount of hydrogen stored in the tanks. A solution approach is also developed to deal with the complexity of the bi-objective model combining a goal programming approach and Generalized Benders Decomposition due to the mixed-integer nonlinear nature of the optimization problem. The results indicate that the resilience approach although increasing the operation cost does not lead to load shedding in the event of main grid failures. The study concludes that integrating distributed power-to-hydrogen systems results in significant benefits including emission reductions of up to 20 % and cost savings of up to 30 %. Additionally the integration of the decomposition method improves computational performance by 54 % compared to using commercial solvers within the GAMS software.

The glass industry is part of the energy-intensive industry with most of the energy needed to melt the raw materials. To produce glass temperatures between 1000 and 1600 °C are necessary. Presently mostly fossil natural gas is the dominant energy source. As direct electrification is not always possible in this paper a Life Cycle Assessment (LCA) for specialty glass production is conducted where the conventional fossil-based reference process is compared to a hydrogen-fired furnace. This hydrogen can be produced on-site in an water electrolyzer using not only the hydrogen for the combustion but also the produced oxygen. Hydrogen can be produced alternatively off-site in a large scale electrolyzer to facilitate economy of scale. For the transport and distribution of this hydrogen different options are available. A rather new option are liquid organic hydrogen carriers (LOHC) which bind the hydrogen in a chemical substance. However temperatures around 300 °C are necessary to separate the hydrogen from the LOHC after transport. At the glass trough waste heat is available at the required temperature level to facilitate the dehydrogenation. The comparison is completed by the production of off-site hydrogen transported to the glass trough as conventional liquefied hydrogen in cooling tanks by truck or in hydrogen pipelines. In this assessment to power the electrolyzers the national grid mix of Germany is used. A time frame from 2020 till 2050 and its changing energy system towards defossilisation is analyzed. Regarding climate change on-site hydrogen production causes the least impact for specialty glass production in 2050. However negative trade-offs for other environmental impact categories e.g. Metal depletion are recorded.

The UK government’s plans to decarbonise residential heating will mean major changes to the energy system whatever the specific technology pathway chosen driving a range of impacts on users and suppliers. We use an energy system model (UK TIMES) to identify the potential energy system impacts of alternative pathways to low or zero carbon heating. We find that the speed of transitioning can affect the network investment requirements the overall energy use and emissions generated while the primary heating fuel shift will determine which sectors and networks require most investment. Crucially we identify that retail price differences between heating fuels in the UK particularly gas and electricity could erode or eliminate bill savings from switching to more efficient heating systems.

The use of alternative fuels remains an important factor in solving the problem of reducing harmful substances caused by vehicles and decarbonising transport. It is also important to ensure the energy efficiency of vehicle power plants when using different fuels at a sufficient level. The article presents the results of theoretical and experimental studies of the conversion of diesel engine to alternative fuels with hydrogen admixtures. Methanol is considered as an alternative fuel which is a cheaper alternative to commercial diesel fuel. The chemical essence of improving the calorific value of alternative methanol fuel was investigated. Studies showed that the energy effect of burning an alternative mixture with hydrogen additives exceeds the effect of burning the same amount of methanol fuel. The increase in combustion energy and engine power is achieved as a result of heat from efficient use of the engine exhaust gases and chemical conversion of methanol. An experimental installation was created to study the work of a converted diesel engine on hydrogen–methanol mixtures and thermochemical regeneration processes. Experimental studies of the energy and environmental parameters of diesel engine converted to work on an alternative fuel with hydrogen admixtures have shown that engine power increases by 10–14% and emissions of harmful substances decrease.

With the development of hydrogen energy containerized hydrogen fuel cell systems are being used in distributed energy-supply systems. Hydrogen pipelines and electronic equipment of fuel cell containers can trigger hydrogen-explosion accidents. In the present study Computational Fluid Dynamics (CFD) software was used to calculate the affected areas of hydrogen fuel cell container-explosion accidents with and without protective walls. The protective effects were studied for protective walls at various distances and heights. The results show that strategically placing protective walls can effectively block the propagation of shock waves and flames. However the protective wall has a limited effect on the reduction of overpressure and temperature behind the wall when the protective wall is insufficiently high. Reflected explosion shock waves and flames will cause damage to the area inside the wall when the protective wall is too close to the container. In this study a protective wall that is 5 m away from the container and 3 m high can effectively protect the area behind the wall and prevent damage to the container due to the reflection of shock waves and flame. This paper presents a suitable protective wall setting scheme for hydrogen fuel cell containers.

Bangladesh focuses on green energy sources to be a lesser dependent on imported fossil fuels and to reduce the GHG emission to decarbonize the energy sector. The integration of renewable energy technologies for green hydrogen production is promising for Bangladesh. Hybrid renewable plants at the coastline along the Bay of Bengal Kuakata Sandwip St. Martin Cox’sbazer and Chattogram for green hydrogen production is very promising to solve the power demand scarcity of Bangladesh. Hydrogen gas turbine and hydrogen fuel cell configured power plant performances are studied to observe the feasibility/prospect to the green energy transition. The Plant’s performances investigated based on specification of the plant’s units and verified by MATLAB SIMULINK software. Fuels blending (different percent of hydrogen with fossil fuel/NG) technique makes the hydrogen more feasible as turbine fuel. The net efficiency of the fuel cell-based combined cycle configuration (74%) is higher than that of the hydrogen gas turbine-based configuration (51.9%). Moreover analyses show that the increment of combined cycle gas turbine efficiency (+18.5%) is more than the combined cycle PEMFC configuration (+14%). Long-term storage of renewable energy in the salt cavern as green hydrogen can be a source of energy for emergency. A significant share of power can be generated by a numbers of green power plants at specified places in Bangladesh.

Facing global warming and recent bans on the use of diesel in vehicles there is a growing need to develop vehicles powered by renewable energy sources to mitigate greenhouse gas and pollutant emissions. Among the various forms of non-fossil energy for vehicles hydrogen fuel is emerging as a promising way to combat global warming. To date most studies on vehicle carbon emissions have focused on diesel and electric vehicles (EVs). Emission assessment methodologies are usually developed for fast-moving consumer goods (FMCG) which are non-durable household goods such as packaged foods beverages and toiletries instead of vehicle products. There is an increase in the number of articles addressing the product carbon footprint (PCF) of hydrogen fuel cell vehicles in the recent years while relatively little research focuses on both vehicle PCF and fuel cycle. Zero-emission vehicles initiative has also brought the importance of investigating the emission throughout the fuel cycle of hydrogen fuel cell and its environmental impact. To address these gaps this study uses the life-cycle assessment (LCA) process of GREET (greenhouse gases regulated emissions and energy use in transportation) to compare the PCF of an EV (Tesla Model 3) and a hydrogen fuel cell car (Toyota MIRAI). According to the GREET results the fuel cycle contributes significantly to the PCF of both vehicles. The findings also reveal the need for greater transparency in the disclosure of relevant information on the PCF methodology adopted by vehicle manufacturers to enable comparison of their vehicles’ emissions. Future work will include examining the best practices of PCF reporting for vehicles powered by renewable energy sources as well as examining the carbon footprints of hydrogen production technologies based on different methodologies.

The paper provides an economic model for the assessment of hydrogen production at the site of an existing thermal power plant which is then integrated into the existing gas grid. The model uses projections of electricity prices natural gas prices and CO2 prices as well as estimates of the cost of building a power-to-gas system for a 25-year period. The objective of this research is to calculate the yellow hydrogen production price for each lifetime year of the Power-to-gas system to evaluate yellow hydrogen competitiveness compared to the fossil alternatives. We test if an incentive scheme is needed to make this technology economically viable. The research also provides several sensitivity scenarios of electricity natural gas and CO2 price changes. Our research results clearly prove that yellow hydrogen is not yet competitive with fossil alternatives and needs incentive mechanisms for the time being. At given natural gas and CO2 prices the incentive for hydrogen production needs to be 52.90 EUR/MWh in 2025 and 36.18 EUR/MWh in 2050. However the role of hydrogen in the green transition could be very important as it provides ancillary services and balances energy sources in the power system.

Hydrogen is considered a promising alternative to fossil fuels in an integrated energy system (IES). In order to reduce the cost of hydrogen energy utilization and the carbon emissions of the IES this paper proposes a low-carbon dispatching strategy for a coordinated integrated energy system using green hydrogen and blue hydrogen. The strategy takes into account the economic and low-carbon complementarity between hydrogen production by water electrolysis and hydrogen production from natural gas. It introduces the green hydrogen production–storage–use module (GH-PSUM) and the blue hydrogen production–storage–use module (BH-PSUM) to facilitate the refined utilization of different types of hydrogen energy. Additionally the flexibility in hydrogen load supply is analyzed and the dynamic response mechanism of the hydrogen load supply structure (DRM-HLSS) is proposed to further reduce operating costs and carbon emissions. Furthermore a carbon trading mechanism (CTM) is introduced to constrain the carbon emissions of the integrated energy system. By comprehensively considering the constraints of each equipment the proposed model aims to minimize the total economic cost which includes wind power operation and curtailment penalty costs energy purchase costs blue hydrogen purification costs and carbon transaction costs. The rationality of the established scheduling model is verified through a comparative analysis of the scheduling results across multiple operating scenarios.

The escalating global demand for goods transport via shipping has heightened energy consumption impacting worldwide health and the environment. To mitigate this international organizations aim to achieve complete fuel desulphurization and decarbonization by 50% by 2050. Investigating eco-friendly fuels is crucial particularly those with a reduced carbon and zero sulfur content. Methanol derived mainly from renewable sources and produced by carbon dioxide’s hydrogenation method stands out as an effective solution for GHG reduction. Leveraging its favorable properties global scalability and compatibility with the existing infrastructure especially LNGs methanol proves to be a cost-efficient and minimally disruptive alternative. This review explores methanol’s role as a hybrid maritime fuel emphasizing its ecological production methods advantages and challenges in the shipping industry’s green transition. It discusses the environmental impacts of methanol use and analyzes economic factors positioning methanol not only as an ecofriendly option but also as a financially prudent choice for global shipping. Methanol is efficient and cost-effective and excels over MGO especially in new ships. It is economically advantageous with decreasing investment costs compared to LNG while providing flexibility without specialized pressure tanks. Global marine fuel trends prioritize fuel traits accessibility and environmental considerations incorporating factors like policies emissions bunkering and engine adaptability during transitions.

Aviation contributes to anthropogenic climate change by emitting both carbon dioxide (CO2) and non-CO2 emissions through the combustion of fossil fuels. One approach to reduce the climate impact of aviation is the use of hydrogen as an alternative fuel. Two distinct technological options are presently under consideration for the implementation of hydrogen in aviation: hydrogen fuel cell architectures and the direct combustion of hydrogen. In this study a hydrogen demand model is developed that considers anticipated advancements in liquid hydrogen aircraft technologies forecasted aviation demand and aircraft startup and retirement cycles. The analysis indicates that global demand for liquid hydrogen in aviation could potentially reach 17 million tons by 2050 leading to a 9% reduction in CO2 emissions from global aviation. Thus the total potential of hydrogen in aviation extends beyond this considering that the total market share of hydrogen aircraft on suitable routes in the model is projected to be only 27% in 2050 due to aircraft retirement cycles. Additionally it is shown that achieving the potential demand for hydrogen in aviation depends on specific market prices. With anticipated declines in current production costs hydrogen fuel costs would need to reach about 70 EUR/MWh by 2050 to fulfill full demand in aviation assuming biofuels provide the cheapest option for decarbonization alongside hydrogen. If e-fuels are the sole option for decarbonization alongside hydrogen which is the more probable scenario the entire hydrogen demand potential in aviation would be satisfied according to this study’s estimates at significantly higher hydrogen prices approximately 180 EUR/MWh.

In Southern Italy near the Mediterranean Sea mobility services like cars bicycles scooters and materialhandling forklifts are frequently required in addition to multimodal local transportation services such as trains ferry boats and airplanes. This research proposes an innovative concept of hydrogen valley virtually simulated in Matlab/Simulink environment located in Calabria. As a novelty hydrogen is produced centrally and delivered via fuel cell hybrid trains to seven hydrogen refueling stations serving various mobility hubs. The centralized production facility operates with a nominal capacity of about 4 tons/day producing hydrogen via PEM electrolysis and storing hydrogen at 200 bar with a hydrogen compressor. As the size of vehicle fleets and the cost of acquiring renewable energy through power purchase agreements vary the hydrogen valley is examined from both a technical and an economic perspective analyzing: the values of the levelized cost of hydrogen the energy consumption and the energy efficiency of the energy systems. Specifically the levelized cost of hydrogen reached competitive values close to 5 €/kg of hydrogen under the most optimistic scenarios with fleet conversions of more than 60 % and a power purchase agreement price lower than 150 €/MWh. Then the benefits of hydrogen rail transport in terms of emissions reduction and health from an economic standpoint are compared to conventional diesel trains and fully electric trains saving respectively 3.2 ktons/year and 0.4 ktons/year of carbon dioxide equivalent emissions and corresponding economic benefits of respectively 51 and 0.548 million euros.

The hydrogen combustion engine (H2 ICE) is known to be able to burn H2 producing no CO2 emissions and extremely low engine-out NOeo emissions. In this work the potential to reduce the NOeo emissions through the implementation of electric hybridization of an H2 ICE-equipped passenger car (H2 -HEV) combined with a dedicated energy management system (EMS) is discussed. Achieving a low H2 consumption and low NOeo emissions are conflicting objectives the trade-off of which depends on the EMS and can be represented as a Pareto front. The dynamic programming algorithm is used to calculate the Pareto-optimal EMS calibrations for various driving missions. Through the utilization of a dedicated energy management calibration H2 -HEVs exhibit the potential to decrease the NOeo x emissions by more than 90% while decreasing the H2 consumption by over 16% compared to a comparable non-hybridized H2 -vehicle. The present paper represents the initial potential analysis suggesting that H2 -HEVs are a viable option towards a CO2 -free mobility with extremely low NOeo emissions.

A promising method of energy storage is the combination of hydrogen and compressed-air energy storage (CAES) systems. CAES systems are divided into diabatic adiabatic and isothermal cycles. In the diabatic cycle thermal energy after air compression is discharged into the environment and the scheme implies the use of organic fuel. Taking into account the prospects of the decarbonization of the energy industry it is advisable to replace natural gas in the diabatic CAES scheme with hydrogen obtained by electrolysis using power-to-gas technology. In this article the SENECA-1A project is considered as a high-power hybrid unit using hydrogen instead of natural gas. The results show that while keeping the 214 MW turbines powered the transition to hydrogen reduces carbon dioxide emissions from 8.8 to 0.0 kg/s while the formation of water vapor will increase from 17.6 to 27.4 kg/s. It is shown that the adiabatic CAES SENECA-1A mode compared to the diabatic has 0.0 carbon dioxide and water vapor emission with relatively higher efficiency (71.5 vs. 62.1%). At the same time the main advantage of the diabatic CAES is the possibility to produce more power in the turbine block (214 vs. 131.6 MW) having fewer capital costs. Thus choosing the technology is a subject of complex technical economic and ecological study.

High fluctuations in the combustion process from one cycle to another referred to as cycle-by-cycle variations can have adverse effects on internal combustion engine performances particularly in spark ignition (SI) engines. These effects encompass incomplete combustion the potential for misfires and adverse impacts on fuel economy. Furthermore the cycle-by-cycle variations can also affect a vehicle’s drivability and overall comfort especially when operating under lean-burn conditions. Although many cycle-by-cycle analyses have been investigated extensively in the past there is limited in-depth knowledge available regarding the causes of cycle-by-cycle (CbC) variations in hydrogen lean-burn SI engines. Trying to contribute to this topic the current study presents a comprehensive analysis of the CbC variations based on the cylinder pressure data. The study was carried out employing a hydrogen single-cylinder research SI engine. The experiments were performed by varying more than fifty operating conditions including the variations in lambda spark advance boost pressure and exhaust gas recirculation however the load and speed were kept constant throughout the experimental campaign. The results indicate that pressure exhibits significant variations during the combustion process and minor variations during non-combustion processes. In the period from the inlet valve close till the start of combustion pressure exhibits the least variations. The coefficient of variation of pressure (COVP) curve depicts three important points in H2-ICE as well: global minima global maxima and second local minima. The magnitude of the COVP curve changes across all the operating conditions however the shape of the COVP curve remains unchanged across all the operating conditions indicating its independence from the operating condition in an H2-ICE. This study presents an alternative approach for a quick combustion analysis of hydrogen engines. Without the need for more complex methodologies like heat release rate analysis the presented cylinder pressure cycle-by-cycle analysis enables a quick and precise identification of primary combustion features (start of combustion center of combustion end of combustion and operation condition stability). Additionally the engine control unit could implement these procedures to automatically adjust cycle-by-cycle variations therefore increasing engine efficiency.

Alternative fuels such as hydrogen compressed natural gas and liquefied natural gas are considered as feasible energy carriers. Selected positive factors from the EU climate and energy policy on achieving climate neutrality by 2050 highlighted the need for the gradual expansion of the infrastructure for alternative fuel. In this research continuity equations and the first and second laws of thermodynamics were used to develop a theoretical model to explore the impact of hydrogen and natural gas on both the filling process and the ultimate in-cylinder conditions of a type IV composite cylinder (20 MPa for CNG 35 MPa and 70 MPa for hydrogen). A composite tank was considered an adiabatic system. Within this study based on the GERG-2008 equation of state a thermodynamic model was developed to compare and determine the influence of (i) hydrogen and (ii) natural gas on the selected thermodynamic parameters during the fast-filling process. The obtained results show that the cylinder-filling time depending on the cylinder capacity is approximately 36–37% shorter for pure hydrogen compared to pure methane and the maximum energy stored in the storage tank for pure hydrogen is approximately 28% lower compared to methane whereas the total entropy generation for pure hydrogen is approximately 52% higher compared to pure methane.

The imperative to address traditional energy crises and environmental concerns has accelerated the need for energy structure transformation. However the variable nature of renewable energy poses challenges in meeting complex practical energy requirements. To address this issue the construction of a multifunctional large-scale stationary energy storage system is considered an effective solution. This paper critically examines the battery and hydrogen hybrid energy storage systems. Both technologies face limitations hindering them from fully meeting future energy storage needs such as large storage capacity in limited space frequent storage with rapid response and continuous storage without loss. Batteries with their rapid response (90%) excel in frequent short-duration energy storage. However limitations such as a selfdischarge rate (>1%) and capacity loss (~20%) restrict their use for long-duration energy storage. Hydrogen as a potential energy carrier is suitable for large-scale long-duration energy storage due to its high energy density steady state and low loss. Nevertheless it is less efficient for frequent energy storage due to its low storage efficiency (~50%). Ongoing research suggests that a battery and hydrogen hybrid energy storage system could combine the strengths of both technologies to meet the growing demand for large-scale long-duration energy storage. To assess their applied potentials this paper provides a detailed analysis of the research status of both energy storage technologies using proposed key performance indices. Additionally application-oriented future directions and challenges of the battery and hydrogen hybrid energy storage system are outlined from multiple perspectives offering guidance for the development of advanced energy storage systems.

This study identifies supply options for sustainable urban energy systems which are robust to external system changes. A multi-criteria optimization model is used to minimize greenhouse gas (GHG) emissions and financial costs of a reference system. Sensitivity analyses examine the impact of changing boundary conditions related to GHG emissions energy prices energy demands and population density. Options that align with both financial and emission reduction and are robust to system changes are called “no-regret” options. Options sensitive to system changes are labeled as “potential-risk” options.<br/>There is a conflict between minimizing GHG emissions and financial costs. In the reference case the emission-optimized scenario enables a reduction of GHG emissions (-93%) but involves higher costs (+160%) compared to the financially-optimized scenario.<br/>No-regret options include photovoltaic systems decentralized heat pumps thermal storages electricity exchange between sub-systems and with higher-level systems and reducing energy demands through building insulation behavioral changes or the decrease of living space per inhabitant. Potential-risk options include solar thermal systems natural gas technologies high-capacity battery storages and hydrogen for buildiing energy supply.<br/>When energy prices rise financially-optimized systems approach the least-emission system design. The maximum profitability of natural gas technologies was already reached before the 2022 European energy crisis.

The agro-livestock sector produces about one third of global greenhouse gas (GHG) emissions. Since more energy is needed to meet the growing demand for food and the industrial revolution in agriculture renewable energy sources could improve access to energy resources and energy security reduce dependence on fossil fuels and reduce GHG emissions. Hydrogen production is a promising energy technology but its deployment in the global energy system is lagging. Here we analyzed the theoretical and practical application of green hydrogen generated by electrolysis of water powered by renewable energy sources in the agro-livestock sector. Green hydrogen is at an early stage of development in most applications and barriers to its large-scale deployment remain. Appropriate policies and financial incentives could make it a profitable technology for the future.

Co-optimizing energy and water resources in a microgrid can increase efficiency and improve economic performance. Energy-water storage (EWS) devices are crucial components of a high-efficient energy-water microgrid (EWMG). The state of charge (SoC) at the end of the first day of operation is one of the most significant variables in EWS devices since it is used as a parameter to indicate the starting SoC for the second day which influences the operating cost for the second day. Hence this paper examines the benefits and applicability of a lookahead optimization strategy for an EWMG integrated with multi-type energy conversion technologies and multienergy demand response to supply various energy-water demands related to electric/hydrogen vehicles and commercial/residential buildings with the lowest cost for two consecutive days. In addition a hybrid info-gap/robust optimization technique is applied to cover uncertainties in photovoltaic power and electricity prices as a tri-level optimization framework without generating scenarios and using the probability distribution functions. Duality theory is also used to convert the problem into a single-level MILP so that it can be solved by CPLEX. According to the findings the implemented energy-water storage systems and look-ahead strategy accounted for respectively 4.03% and 0.43% reduction in the total cost.

This study proposes a country-based life-cycle assessment (LCA) of several conversion pathways related 10 to both on grid-connected Power-to-X (PtX) fuels and advanced biofuel production for maritime transport 11 in Europe. We estimate the biomass resource availability (both agricultural and forest residues and 12 second-generation energy crops from abandoned cropland) electricity mix and a future-oriented 13 prospective LCA to assess how future climate change mitigation policies influence the results. Our results 14 indicate that the potential of PtX fuels to achieve well-to-wake greenhouse gas intensities lower than 15 those of fossil fuels is limited to countries with a carbon intensity of the electricity mix below 100 gCO2eq kWh-1 16 . The more ambitious FuelEU Maritime goal could be achieved with PtX only if connected to electricity sources below ca. 17 gCO2eq kWh-1 17 which can become possible for most of the national 18 electricity mix in Europe by 2050 if renewable energy sources will become deployed at large scales. For 19 drop-in and hydrogen-based biofuels biomass residues have a higher potential to reduce emissions than 20 dedicated energy crops. In Europe the potentials of energy supply from all renewable and low-carbon 21 fuels (RLFs) range from 32-149% of the current annual fuel consumption in European maritime transport. 22 The full deployment of RLFs with carbon capture and storage technologies could mitigate up to 184% of 23 the current well-to-wake shipping emissions in Europe. Overall our study highlights how the strategic use 24 of both hydrogen-based biofuels and PtX fuels can contribute to the climate mitigation targetsfor present 25 and future scenarios of European maritime transport.

Hydrogen (H2) has rapidly become a topic of great attention when discussing routes to net-zero carbon emissions. About 14% of CO2 emissions globally are directly associated with domestic heating in buildings. Replacing natural gas (NG) with H2 for heating has been highlighted as a rapid alternative for mitigating these emissions. To realise this not only the production challenges but also potential obstacles in the transmission/distribution and combustion of H2 must be technically identified and discussed. This review in addition to delineating the challenges of H2 in NG grid pipelines and H2 combustion also collates the results of the state-of-the-art technologies in H2-based heating systems. We conclude that the sustainability of water and renewable electricity resources strongly depends on sizing siting service life of electrolysis plants and post-electrolysis water disposal plans. 100% H2 in pipelines requires major infrastructure upgrades including production transmission pressurereduction stations distribution and boiler rooms. H2 leakage instigates more environmental risks than economic ones. With optimised boilers burning H2 could reduce GHG emissions and obtain an appropriate heating efficiency; more data from boiler manufacturers must be provided. Overall green H2 is not the only solution to decarbonise heating in buildings and it should be pursued abreast of other heating technologies.

This paper offers a set of comprehensive guidelines aimed at facilitating the widespread adoption of hydrogen in the industrial hard-to-abate sectors. The authors begin by conducting a detailed analysis of these sectors providing an overview of their unique characteristics and challenges. This paper delves into specific elements related to hydrogen technologies shedding light on their potential applications and discussing feasible implementation strategies. By exploring the strengths and limitations of each technology this paper offers valuable insights into its suitability for specific applications. Finally through a specific analysis focused on the steel sector the authors provide in-depth information on the potential benefits and challenges associated with hydrogen adoption in this context. By emphasizing the steel sector as a focal point the authors contribute to a more nuanced understanding of hydrogen’s role in decarbonizing industrial processes and inspire further exploration of its applications in other challenging sectors.

Climate change is obvious in many ways. The weather changes rapidly from day to day reaching high temperatures such as 28 ◦C one day and heavy rain the next with temperatures below 18 ◦C. There are also very strong storms caused by this phenomenon. The way the environment acts is different than the current epoch would predict indicating a long-term shift in weather and temperature patterns. The mean temperature of earth is rising due to the greenhouse effect that is caused by human activity and mostly by the burning of fossil fuel emitting CO2 and other pollutant gasses. Nowadays every country is trying to lower CO2 emissions from everyday human activities a movement called “decarbonization”. Since the 18th century there has been a great deal of research carried out on possible alternatives to fossil fuels. Some of the work was just to discover ways to power heaters or automotive vehicle but there is a great deal of work remaining to complete regarding this issue after discovering the greenhouse effect and its impact on the planet’s climate in order to eliminate it by using fuel whose combustion emissions are more environmentally friendly. In the present work many discoveries will be presented that use hydrogen (H2 ) or hydroxy (H-OH) as fuel. The main reason for this is the emission of pure water after combustion but the most interesting part is the approach every scientist uses to create the fuel gas from water.

The production of solid waste in human societies and the related environmental and global warming concerns are increasing. Extensive use of existing conventional diesel and dual-fuel engines also causes the production of high levels of greenhouse gases and aggravating the aforementioned concerns. Therefore the aim of this study is to reduce the greenhouse emissions in existing natural gas/diesel dual-fuel heavy-duty diesel engine. For this purpose changing the type of combustion to reactivity-controlled compression-ignition combustion and using landfill gas instead of natural gas in a dual-fuel engine were simultaneously implemented. Moreover a traditional method was used to evaluate the effect of variations in three important parameters on the engine's performance in order to determine the appropriate engine operating ranges. The simulation results indicate that although the consumption of 102000 cubic meters per year of natural gas in each cylinder is reduced only by replacing landfill gas the level of engine greenhouse gas emissions is too high compared to the relevant levels of emissions standards. Hence by keeping the total energy content of the fuels constant landfill gas enrichment with hydrogen was considered to reduce the engine emissions. The simulation results show that by increasing the hydrogen energy share up to 37% the engine load has the potential to be improved up to 7% without any exposure to diesel knock. However the downfall is the reduction in the gross indicated efficiency up to 3%. Meanwhile not only the fifth level of the European emission standard for nitrogen oxides and the sixth level of this standard for carbon monoxide can be achieved but it is also possible to overcome the high level of unburned methane as a drastic greenhouse gas and formaldehyde as a related carcinogenic species.

Sustainable aviation fuel (SAF) production is one of the strategies to guarantee an environmental-friendly development of the aviation sector. This work evaluates the technical economic and environmental feasibility of obtaining SAFs by hydrogenation of vegetable oils thanks to in-situ hydrogen production via aqueous phase reforming (APR) of glycerol by-product. The novel implementation of APR would avoid the environmental burden of conventional fossil-derived hydrogen production as well as intermittency and storage issues related to the use of RES-based (renewable energy sources) electrolysers. The conceptual design of a conventional and advanced (APR-aided) biorefinery was performed considering a standard plant capacity equal to 180 ktonne/y of palm oil. For the advanced scenario the feed underwent hydrolysis into glycerol and fatty acids; hence the former was subjected to APR to provide hydrogen which was further used in the hydrotreatment reactor where the fatty acids were deoxygenated. The techno-economic results showed that APR implementation led to a slight increase of the fixed capital investment by 6.6% compared to the conventional one while direct manufacturing costs decreased by 22%. In order to get a 10% internal rate of return the minimum fuel selling price was found equal to 1.84 $/kg which is 17% lower than the one derived from conventional configurations (2.20 $/kg). The life-cycle GHG emission assessment showed that the carbon footprint of the advanced scenario was equal to ca. 12 g CO2/MJSAF i.e. 54% lower than the conventional one (considering an energy-based allocation). The sensitivity analysis pointed out that the cost of the feedstock SAF yield and the chosen plant size are keys parameters for the marketability of this biorefinery while the energy price has a negligible impact; moreover the source of hydrogen has significant consequences on the environmental footprint of the plant. Finally possible uncertainties for both scenarios were undertaken via Monte Carlo simulations.

CO2 emissions have been identified as the main driver for climate change with devastating consequences for the global natural environment. The steel industry is responsible for ~7–11% of global CO2 emissions due to high fossil-fuel and energy consumption. The onus is therefore on industry to remedy the environmental damage caused and to decarbonise production. This desk research report explores the Bio Steel Cycle (BiSC) and proposes a seven-step-strategy to overcome the emission challenges within the iron and steel industry. The true levels of combined CO2 emissions from the blast-furnace and basic-oxygen-furnace operation at 4.61 t of CO2 emissions/t of steel produced are calculated in detail. The BiSC includes CO2 capture implementing renewable energy sources (solar wind green H2 ) and plantation for CO2 absorption and provision of biomass. The 7-step-implementation-strategy starts with replacing energy sources develops over process improvement and installation of flue gas carbon capture and concludes with utilising biogas-derived hydrogen as a product from anaerobic digestion of the grown agrifood in the cycle. In the past CO2 emissions have been seemingly underreported and underestimated in the heavy industries and implementing the BiSC using the provided seven-steps-strategy will potentially result in achieving net-zero CO2 emissions in steel manufacturing by 2030.

Future liquid hydrogen-powered aircraft requires the design and optimization of a large number of systems and subsystems with cryogenic tanks being one of the largest and most critical. Considering previous space applications these tanks are usually stiffened by internal members such as stringers frames and stiffeners resulting in a complex geometry that leads to an eventual reduction in weight. Cryogenic tanks experience a variety of mechanical and thermal loading conditions and are usually constructed out of several different materials. The complexity of the geometry and the loads highlights the necessity for a computational tool in order to conduct analysis. In this direction the present work describes the development of a multi-physics finite element digital simulation conducting heat transfer and structural analysis in a fully parametric manner in order to be able to support the investigation of different design concepts materials geometries etc. The capabilities of the developed model are demonstrated by the design process of an independent-type aluminum 2219 cryogenic tank for commuter aircraft applications. The designed tank indicates a potential maximum take-off weight reduction of about 8% for the commuter category and demonstrates that aluminum alloys are serious candidate materials for future aircraft.

This paper investigates the economic competitiveness of hydrogen-powered trucks. It reviews the growing number of papers that provide an estimate of the total cost of ownership (TCO) of hydrogen-powered trucks relative to their diesel equivalents. It examines the methodology applied the variables considered the data used for estimation and the results obtained. All reviewed studies conclude that hydrogen-powered trucks are not currently cost-competitive while they might become competitive after 2030. The conclusion holds across truck types and sizes hydrogen pathways mission profiles and countries. However we find that there is still a huge area of uncertainty regarding the purchase price of hydrogen-powered trucks and the cost of hydrogen which hampers the reliability of the results obtained. Various areas of methodological improvements are suggested.

The integration of various renewable energy sources as well as the liberalization of electricity markets are established facts in modern electrical power systems. The increased share of renewable sources within power systems intensifies the supply variability and intermittency. Therefore energy storage is deemed as one of the solutions for stabilizing the supply of electricity to maintain generation-demand balance and to guarantee uninterrupted supply of energy to users. In the context of sustainable development and energy resources depletion the question of the growth of renewable energy electricity production is highly linked to the ability to propose new and adapted energy storage solutions. The purpose of this multidisciplinary paper is to highlight the new hydrogen production and storage technology its efficiency and the impact of the policy context on its development. A comprehensive techno/socio/economic study of long term hydrogen based storage systems in electrical networks is addressed. The European policy concerning the different energy storage systems and hydrogen production is explicitly discussed. The state of the art of the techno-economic features of the hydrogen production and storage is introduced. Using Matlab-Simulink for a power system of rated 70 kW generator the excess produced hydrogen during high generation periods or low demand can be sold either directly to the grid owners or as filled hydrogen bottles. The affordable use of Hydrogen-based technologies for long term electricity storage is verified.

The use of aluminum-based products is widespread and growing particularly in industries such as automotive food packaging and construction. Obtaining aluminum is expensive and energy-intensive making the recycling of existing products essential for economic and environmental viability. This work explores the potential of using green hydrogen as a replacement for natural gas in the smelting and refining furnaces in aluminum recycling facilities. The adoption of green hydrogen has the potential to curtail approximately 4.54 Ktons/year of CO2 emissions rendering it a sustainable and economically advantageous solution. The work evaluates the economic viability of a case study through assessing the Net Present Value (NPV) and the Internal Rate of Return (IRR). Furthermore it is employed single- and multi-parameter sensitivity analyses to obtain insight on the most relevant conditions to achieve economic viability. Results demonstrate that integrating on-site green hydrogen generation yields a favorable NPV of €57370 an IRR of 9.83% and a 19.63-year payback period. The primary factors influencing NPV are the initial electricity consumption stack and the H2 price.

Limiting global warming and the pursuit of a net-zero global society by 2050 emphasizes the need to transform the hard-to-abate industrial sectors. The cement sector is the second-largest source of global industrial emissions accounting for 8% of worldwide greenhouse gas emissions. Fuel switching in the cement sector is a decarbonization pathway that has not been explored in detail; previous studies involving fuel switching in the sector either view it from an energy efficiency lens or focus on a single technology. In this study a framework is developed to evaluate and directly compare six fuel switching options (including hydrogen biomass municipal solid waste and natural gas) from 2020 to 2050. Capital costs non-energy operating costs energy costs and carbon costs are used to calculate marginal abatement costs and emulate cost based-market decisions. The developed framework is used to conduct a case study for Canada using the LEAP-Canada model. This study shows that cumulative energy-related greenhouse gas emissions can be reduced by up to 21% between 2020 and 2050 with negative marginal abatement costs. Multiple fuel switching decarbonization pathways were established reducing the likelihood that locality prevents meaningful emissions reduction and suggesting that with low-carbon fuel and electricity policies the sector can take significant steps towards emissions reduction. The developed framework can be applied to jurisdictions around the world for decision making as nations move towards eliminating emissions from cement production.

Due to the increase in electric energy consumption and the significant growth in the number of electric vehicles (EV) at the level of the distribution network new networks have started using new fuels such as hydrogen to improve environmental indicators and at the same time better efficiency from the excess capacity of renewable resources. In this article the services that can be provided by hydrogen refueling stations and charging electric vehicles in the optimal performance of microgrids have been investigated. The model proposed in this paper includes a two-stage stochastic framework for scheduling resources in microgrids especially hydrogen refueling stations and electric vehicle charging. In this model two main goals of cost minimization and greenhouse gas emissions are considered. In the proposed framework and in the first stage the service range of microgrids is determined precisely according to the electrical limitations of distribution systems in emergency situations. Then in the second stage the problem of energy management in each microgrid will be solved centrally. In this situation various indicators including the output energy of renewable sources smart charging of hydrogen and electric vehicle charging stations (EV/FCV) and flexible loads (FL) are evaluated. The final mathematical model is implemented as a multivariate integer multiple linear problem (MILP) using the GUROBI solver in GAMS software. The simulation results on the modified IEEE 118-Bus network show the positive effect of the presence of flexible loads and smart charging strategies by charging stations. Also the numerical derivation shows that the operating costs of the entire system can be reduced by 4.77% and the use of smart charging strategies can reduce greenhouse gas emissions by 49.13%.

In this work the Design and Operation of Integrated Technologies (DO-IT) framework is developed a comprehensive tool to support short- and long-term technology investment and operation decisions for integrated energy generation conversion and storage technologies in buildings. The novelty of this framework lies in two key aspects: firstly it integrates essential open-source modelling tools covering energy end uses in buildings technology performance and cost and energy system design optimisation into a unified and easily-reproducible framework. Secondly it introduces a novel optimisation tool with a concise and generic mathematical formulation capable of modelling multi-energy vector systems capturing interdependencies between different energy vectors and technologies. The model formulation which captures both short- and long-term energy storage facilitates the identification of smart design and operation strategies with low computational cost. Different building energy demand and price scenarios are investigated and the economic and energy benefits of using a holistic multi-energy-vector approach are quantified. Technology combinations under consideration include: (i) a photovoltaic-electric heat pump-battery system (ii) a photovoltaic-electric heat pump-battery-hot water cylinder system (iii) a photovoltaic-electrolyser‑hydrogen storage-fuel cell system and (iv) a system with all above technology options. Using a university building as a case study it is shown that the smart integration of electricity heating cooling and hydrogen generation and storage technologies results in a total system cost which is >25% lower than the scenario of only importing grid electricity and using a fuel oil boiler. The battery mitigates intra-day fluctuations in electricity demand and the hot-water cylinder allows for efficiently managing heat demand with a small heat pump. In order to avoid PV curtailment excess PV-generated electricity can also be stored in the form of green hydrogen providing a long-term energy storage solution spanning days weeks or even seasons. Results are useful for end-users investment decision makers and energy policy makers when selecting building-integrated low-carbon technologies and relevant policies.

This article presents a novel approach to the analysis of heat release in a hydrogen-fueled internal combustion spark-ignition engine with exhaust gas recirculation (EGR). It also discusses aspects of thermodynamic analysis common to modeling and empirical analysis. This new approach concerns a novel method of calculating the specific heat ratio (cp/cv) and takes into account the reduction in the number of moles during combustion which is characteristic of hydrogen combustion. This reduction in the number of moles was designated as a molar contraction. This is particularly crucial when calculating the average temperature during combustion. Subsequently the outcomes of experimental tests including the heat-release rate the initial combustion phase (denoted CA0- 10) and the main combustion phase (CA10-90) are presented. Furthermore the impact of exhaust gas recirculation on the combustion process in the engine is also discussed. The efficacy of the proposed measures was validated by analyzing the heat-release rate and calculating the mean combustion temperature in the engine. The application of EGR in the range 0-40% resulted in a notable prolongation of both the initial and main combustion phases which consequently influenced the mean combustion temperature.