Applications & Pathways

Conventional technologies are largely powered by fossil fuel exploitation and have ultimately led to extensive environmental concerns. Hydrogen is an excellent carbon-free energy carrier but its storage and long-distance transportation remain big challenges. Ammonia however is a promising indirect hydrogen storage medium that has well-established storage and transportation links to make it an accessible fuel source. Moreover the notion of ‘green ammonia’ synthesised from renewable energy sources is an emerging topic that may open significant markets and provide a pathway to decarbonise a variety of applications reliant on fossil fuels. Herein a comparative study based on the chosen design working principles advantages and disadvantages of direct ammonia fuel cells is summarised. This work aims to review the most recent advances in ammonia fuel cells and demonstrates how close this technology type is to integration with future applications. At present several challenges such as material selection NO_x formation CO₂ tolerance limited power densities and long term stability must still be overcome and are also addressed within the contents of this review.

This report is the public version of the deliverable B.3.7 'Life cycle assessment of Hydrogen and Fuel Cell Technologies - Inventory of work performed by projects funded under FCH JU'; it provides an overview of the progress achieved so far and a comprehensive analysis on Life Cycle Assessment (LCA) for various hydrogen technologies and processes. The review considers 73 Fuel Cells and Hydrogen 2 Joint Undertaking (FCH 2 JU) founded projects: for some of those the LCA study was requested in the call topic while other projects decided to perform the LCA study on a voluntary basis. The LCAs have been assessed regarding the adherence to guideline recommendations (e.g. reported properties system boundary definitions goal and scope definitions) methodology and overall quality of the work. Methodology is a critical issue for the comparability of results as this is only possible if all LCAs follow the same guidelines; in addition LCAs were often only partially fulfilling the selected guideline requirements. It is recommended that future FCH 2 JU call topics asking for environmental analysis to be performed are setting out some minimum requirements such as the guidelines to be used and the impacts to be assessed. Based on the outcome of this analysis a harmonisation effort in the approach to LCA for the FCH JU founded projects is proposed; in particular a Life Cycle Inventory (LCI) database useful for the projects is required togheter with the identification of a reference cases to be used as benchmark for future LCAs.

A major transformation and redesign of the global energy system is required towards decarbonisation and to achieve the Paris Agreement targets. This Grand Transition is a complex pressing issue where global joint efforts and system solutions are essential; with hydrogen being one of them.<br/>Hydrogen has the potential to be a powerful effective accelerator towards a low-carbon energy system capable of addressing multiple energy challenges: from facilitating the massive integration of renewables and decarbonisation of energy production to energy transportation in a zero-carbon energy economy to electrification of end uses.

The development of new infrastructure is often a consideration in the introduction of new innovations. Currently there is some confusion around how to develop a hydrogen infrastructure to support the introduction of FCVs. Lessons can be learned from similar technology introduction in the past and therefore this paper investigates how mobile phone infrastructure was developed allowing the mass-market penetration of mobile phones. Based on this successful infrastructural development suggestions can be made on the development of a hydrogen infrastructure. It is suggested that a hydrogen infrastructure needs to be pre-developed 3–5 years before the market introduction of FCVs can successfully occur. A lack of infrastructural pre-development will cause to the market introduction of FCVs to fail.

Improving energy system modelling capabilities can directly affect the quality of applied studies. However some modelling trade-offs are necessary as the computational capacity and data availability are constrained. In this paper we demonstrate modelling trade-offs resulting from the modification in the resolution of four modelling capabilities namely transitional scope European electricity interconnection hourly demand-side flexibility description and infrastructure representation. We measure the cost of increasing resolution in each capability in terms of computational time and several energy system modelling indicators notably system costs emission prices and electricity import and export levels. The analyses are performed in a national-level integrated energy system model with a linear programming approach that includes the hourly electricity dispatch with European nodes. We determined that reducing the transitional scope from seven to two periods can reduce the computational time by 75% while underestimating the objective function by only 4.6%. Modelers can assume a single European Union node that dispatches electricity at an aggregated level which underestimates the objective function by 1% while halving the computational time. Furthermore the absence of shedding and storage flexibility options can increase the curtailed electricity by 25% and 8% respectively. Although neglecting flexibility options can drastically decrease the computational time it can increase the sub-optimality by 31%. We conclude that an increased resolution in modelling flexibility options can significantly improve the results. While reducing the computational time by half the lack of electricity and gas infrastructure representation can underestimate the objective function by 4% and 6% respectively.

Steelmaking is responsible for around 7% of the global emissions of carbon dioxide and new steelmaking processes are necessary to reach international climate targets. As a response to this steelmaking processes based on the direct reduction of iron ore by hydrogen produced via water electrolysis powered by renewable electricity have been suggested. Here we present a novel variant of hydrogen-based steelmaking incorporating methanol as a hydrogen and carbon carrier together with high-temperature co-electrolysis of water and carbon dioxide and biomass oxy-fuel combustion. The energy and mass balances of the process are analyzed. It is found that this methanol-based direct reduction process may potentially offer a number of process-related advantages over a process based on pure hydrogen featuring several process integration options. Notably the electricity and total energy use of the steelmaking process could be reduced by up to 25% and 8% compared to a reference pure hydrogen process respectively. The amount of high-temperature (> 200 °C) heat that must be supplied to the process could also be reduced by up to approximately 34% although the demand for medium-temperature heat is substantially increased. Furthermore the suggested process could allow for the production of high-quality direct reduced iron with appropriate carburization to alleviate downstream processing in an electric arc furnace which is not the case for a process based on pure hydrogen.

Ammonia borane (AB) can be catalytically hydrolyzed to provide hydrogen at room temperature due to its high potentaial for hydrogen storage. Non-precious metal heterogeneous catalysts have broad application in the field of energy catalysis. In this article catalysts precursor is obtained from Co-Ti-resorcinol-formaldehyde resin by sol–gel method. Co/TiO2@N-C (CTC) catalyst is prepared by calcining the precursor under high temperature conditions in nitrogen atmosphere. Co-CoOx/TiO2@N-C (COTC) is generated by the controllable oxidation reaction of CTC. The catalyst can effectively promote the release of hydrogen during the hydrolytic dehydrogenation of AB. High hydrogen generation at a specific rate of 5905 mL min−1 gCo−1 is achieved at room temperature. The catalyst retains its 85% initial catalytic activity even for its fifth time use in AB hydrolysis. The synergistic effect among Co Co3O4 and TiO2 promotes the rate limiting step with dissociation and activation of water molecules by reducing its activation energy. The applied method in this study promotes the development of non-precious metals in catalysis for utilization in clean energy sources.

The production of hydrogen through water electrolysis is a promising pathway to decarbonize the energy sector. This paper presents a techno-economic model of electrolysis plants based on multiple states of operation: production hot standby and idle. The model enables the calculation of the optimal hourly dispatch of electrolyzers to produce hydrogen for different end uses. This model has been tested with real data from an existing installation and compared with a simpler electrolyzer model that is based on two states. The results indicate that an operational strategy that considers the multi-state model leads to a decrease in final hydrogen production costs. These reduced costs will benefit businesses especially while electrolysis plants grow in size to accommodate further increases in demand.

This paper presents a simulation tool for marine hybrid power-plants equipped with polymer exchange membrane fuel cells and batteries. The virtual model through the combination of operational data and dynamically modelled subsystems can simulate power-plants of different sizes and configurations in order to analyze the response of different energy management strategies. The model aims to replicate the realistic behavior of the components included in the vessel's grid to asses if the hardware selected by the user is capable of delivering the power set-point requested by the energy management system. The model can then be used to optimize key factors such as hydrogen consumption. The case study presented in the paper demonstrates how the model can be used for the evaluation of a retrofitting operation replacing a diesel electric power-plant with fuel cells and batteries. The vessel taken into consideration is a domestic ferry operating car and passenger transport in Denmark. The vessel is outfitted with a diesel electric plant and an alternative hybrid power-plant is proposed. The hybrid configuration is tested using the model in a discrete time-domain.

The maritime shipping sector is a major contributor to CO₂ emissions and this figure is expected to rise in coming decades. With the intent of reducing emissions from this sector this research proposes the utilization of the jet stream to transport a combination of cargo and hydrogen using airships or balloons at altitudes of 10–20 km. The jet streams flow in the mid-latitudes predominantly in a west–east direction reaching an average wind speed of 165 km/h. Using this combination of high wind speeds and reliable direction hydrogen-filled airships or balloons could carry hydrogen with a lower fuel requirement and shorter travel time compared to conventional shipping. Jet streams at different altitudes in the atmosphere were used to identify the most appropriate circular routes for global airship travel. Round-the-world trips would take 16 days in the Northern Hemisphere and 14 in the Southern Hemisphere. Hydrogen transport via the jet stream due to its lower energy consumption and shorter cargo delivery time access to cities far from the coast could be a competitive alternative to maritime shipping and liquefied hydrogen tankers in the development of a sustainable future hydrogen economy.