Applications & Pathways
The Role of Charging and Refuelling Infrastructure in Supporting Zero-emission Vehicle Sales
Mar 2020
Publication
Widespread uptake of battery electric plug-in hybrid and hydrogen fuel-cell vehicles (collectively zero-emissions vehicles or ZEVs) could help many regions achieve deep greenhouse gas mitigation goals. Using the case of Canada this study investigates the extent to which increasing ZEV charging and refuelling availability may boost ZEV sales relative to other ZEV-supportive policies. We adapt a version of the Respondent-based Preferences and Constraints (REPAC) model using 2017 survey data from 1884 Canadian new vehicle-buyers to simulate the sales impacts of increasing electric vehicle charging access at home work public destinations and on highways as well as increasing hydrogen refuelling station access. REPAC is built from a stated preference choice model and represents constraints in supply and consumer awareness as well as dynamics in ZEV policy out to 2030. Results suggest that new ZEV market share from 2020 to 2030 does not substantially benefit from increased infrastructure. Even when electric charging and hydrogen refuelling access are simulated to reach “universally” available levels by 2030 ZEV sales do not rise by more than 1.5 percentage points above the baseline trajectory. On the other hand REPAC simulates ZEV market share rising as high as 30% by 2030 with strong ZEV-supportive policies even without the addition of charging or refuelling infrastructure. These findings stem from low consumer valuation of infrastructure found in the stated preference model. Results suggest that achieving ambitious ZEV sale targets requires a comprehensive suite of policies beyond a focus on charging and refuelling infrastructure.
Electric and Hydrogen Buses: Shifting from Conventionally Fuelled Cars in the UK
May 2020
Publication
For the UK to meet their national target of net zero emissions as part of the central Paris Agreement target further emphasis needs to be placed on decarbonizing public transport and moving away from personal transport (conventionally fuelled vehicles (CFVs) and electric vehicles (EVs)). Electric buses (EBs) and hydrogen buses (HBs) have the potential to fulfil requirements if powered from low carbon renewable energy sources.
A comparison of carbon dioxide (CO2) emissions produced from conventionally fuelled buses (CFB) EBs and HBs between 2017 and 2050 under four National Grid electricity scenarios was conducted. In addition emissions per person at different vehicle capacity levels (100% 75% 50% and 25%) were projected for CFBs HBs EBs and personal transport assuming a maximum of 80 passengers per bus and four per personal vehicle.
Results indicated that CFVs produced 30 g CO2km−1 per person compared to 16.3 g CO2 km−1 per person by CFBs by 2050. At 100% capacity under the two-degree scenario CFB emissions were 36 times higher than EBs 9 times higher than HBs and 12 times higher than EVs in 2050. Cumulative emissions under all electricity scenarios remained lower for EBs and HBs.
Policy makers need to focus on encouraging a modal shift from personal transport towards sustainable public transport primarily EBs as the lowest level emitting vehicle type. Simple electrification of personal vehicles will not meet the required targets. Simultaneously CFBs need to be replaced with EBs and HBs if the UK is going to meet emission targets.
A comparison of carbon dioxide (CO2) emissions produced from conventionally fuelled buses (CFB) EBs and HBs between 2017 and 2050 under four National Grid electricity scenarios was conducted. In addition emissions per person at different vehicle capacity levels (100% 75% 50% and 25%) were projected for CFBs HBs EBs and personal transport assuming a maximum of 80 passengers per bus and four per personal vehicle.
Results indicated that CFVs produced 30 g CO2km−1 per person compared to 16.3 g CO2 km−1 per person by CFBs by 2050. At 100% capacity under the two-degree scenario CFB emissions were 36 times higher than EBs 9 times higher than HBs and 12 times higher than EVs in 2050. Cumulative emissions under all electricity scenarios remained lower for EBs and HBs.
Policy makers need to focus on encouraging a modal shift from personal transport towards sustainable public transport primarily EBs as the lowest level emitting vehicle type. Simple electrification of personal vehicles will not meet the required targets. Simultaneously CFBs need to be replaced with EBs and HBs if the UK is going to meet emission targets.
Operation Analysis of Selected Domestic Appliances Supplied with Mixture of Nitrogen-Rich Natural Gas with Hydrogen
Dec 2021
Publication
This is article presents the results of the testing of the addition of a hydrogen-to-nitrogen-rich natural gas of the Lw group and its influence on the operation of selected gas-fired domestic appliances. The tests were performed on appliances used for the preparation of meals and hot water production for hygienic and heating purposes. The characteristics of the tested gas appliances are also presented. The burners and their controllers with which the tested appliances were equipped were adapted for the combustion of Lw natural gas. The tested appliances reflected the most popular designs for domestic gas appliances in their group used both in Poland and in other European countries. The tested appliances were supplied with nitrogen-rich natural gas of the Lw group and a mixture of this gas with hydrogen at 13.2% content. The article presents the approximate percentage compositions of the gases used during the tests and their energy parameters. The research was focused on checking the following operating parameters and the safety of the tested appliances: the rated heat input thermal efficiency combustion quality ignition flame stability and transfer. The article contains an analysis of the test results referring in detail to the issue of decreasing the heat input of the appliances by lowering the energy parameters of the nitrogen-rich natural gas of the Lw group mixture with a hydrogen addition and how it influenced the thermal efficiency achieved by the appliances. The conclusions contain an explanation regarding among other things how the design of an appliance influences the thermal efficiency achieved by it in relation to the heat input decrease. In the conclusions on the basis of the research results answers have been provided to the following questions: (1) Whether the hydrogen addition to the nitrogen-rich natural gas of the Lw group will influence the safe and proper operation of domestic gas appliances; (2) What hydrogen percentage can be added to the nitrogen-rich natural gas of the Lw group in order for the appliances adapted for combusting it to operate safely and effectively without the need for modifying them?
Optimized Operation Plan for Hydrogen Refueling Station with On-Site Electrolytic Production
Dec 2022
Publication
The cost reduction of hydrogen refueling stations (HRSs) is very important for the popularization of hydrogen vehicles. This paper proposes an optimized operation algorithm based on hydrogen energy demand estimation for on-site hydrogen refueling stations. Firstly the user’s hydrogen demand was estimated based on the simulation of their hydrogenation behavior. Secondly mixed integer linear programming method was used to optimize the operation of the hydrogen refueling station to minimize the unit hydrogen energy cost by using the peak–valley difference of the electricity price. We then used three typical scenario cases to evaluate the optimized operation method. The results show that the optimized operation method proposed in this paper can effectively reduce the rated configuration of electrolyzer and storage tank for HRS and can significantly reduce the unit hydrogen energy cost considering the construction cost compared with the traditional method. Therefore the optimization operation method of a local hydrogen production and hydrogen refueling station proposed in this paper can reduce the cost of a hydrogen refueling station and accelerate the popularization of hydrogen energy vehicles. Finally the scope of application of the proposed optimization method and the influence of the variation of the electricity price curve and the unit cost of the electrolyzer are discussed.
Propulsion of a Hydrogen-fuelled LH2 Tanker Ship
Mar 2022
Publication
This study aims to present a philosophical and quantitative perspective of a propulsion system for a large-scale hydrogen-fuelled liquid-hydrogen (LH2) tanker ship. Established methods are used to evaluate the design and performance of an LH2-carrier propulsion system for JAMILA a ship designed with four cylindrical LH2 tanks bearing a total capacity of ~280000 m3 along with cargo and using the boil-off as propulsion and power fuel. Additionally the ship propulsion system is evaluated based on the ship resistance requirements and a hydrogen-fuelled combined-cycle gas turbine is modelled to achieve the dual objectives of high efficiency and zero-carbon footprint. The required inputs primarily involve the off-design and degraded performance of the gas-turbine topping cycle and the proposed power plant operates with a total output power of 50 M.W. The results reveal that the output power allows ship operation at a great speed even with a degraded engine and adverse ambient conditions.
Digital Navigation of Energy–structure–function Maps for Hydrogen-bonded Porous Molecular Crystals
Feb 2021
Publication
Energy–structure–function (ESF) maps can aid the targeted discovery of porous molecular crystals by predicting the stable crystalline arrangements along with their functions of interest. Here we compute ESF maps for a series of rigid molecules that comprise either a triptycene or a spiro-biphenyl core functionalized with six different hydrogen-bonding moieties. We show that the positioning of the hydrogen-bonding sites as well as their number has a profound influence on the shape of the resulting ESF maps revealing promising structure–function spaces for future experiments. We also demonstrate a simple and general approach to representing and inspecting the high-dimensional data of an ESF map enabling an efficient navigation of the ESF data to identify ‘landmark’ structures that are energetically favourable or functionally interesting. This is a step toward the automated analysis of ESF maps an important goal for closed-loop autonomous searches for molecular crystals with useful functions.
Energy Essentials: A Guide to Hydrogen
Jan 2020
Publication
Climate change and air quality concerns have pushed clean energy up the global agenda. As we switch over to new cleaner technologies and fuels our experience of using power heat and transport are going to change transforming the way we live work and get from A to B. Explore this guide to find out what hydrogen is how it is made transported and used what the experience would be like in the home for transport and for businesses and discover what the future of hydrogen might be.
Visit the Energy Institute website for more information
Visit the Energy Institute website for more information
Effect of Hydrogen–diesel Dual-fuel Usage on Performance, Emissions and Diesel Combustion in Diesel Engines
Jul 2016
Publication
Diesel engines are inevitable parts of our daily life and will be in the future. Expensive after-treatment technologies to fulfil normative legislations about the harmful tail-pipe emissions and fuel price increase in recent years created expectations from researchers for alternative fuel applications on diesel engines. This study investigates hydrogen as additive fuel in diesel engines. Hydrogen was introduced into intake manifold using gas injectors as additive fuel in gaseous form and also diesel fuel was injected into cylinder by diesel injector and used as igniter. Energy content of introduced hydrogen was set to 0% 25% and 50% of total fuel energy where the 0% references neat diesel operation without hydrogen injection. Test conditions were set to full load at 750 900 1100 1400 1750 and finally 2100 r/min engine speed. Variation in engine performance emissions and combustion characteristics with hydrogen addition was investigated. Hydrogen introduction into the engine by 25% and 50% of total charge energy reveals significant decrease in smoke emissions while dramatic increase in nitrogen oxides. With increasing hydrogen content a slight rise is observed in total unburned hydrocarbons although CO2 and CO gaseous emissions reduced considerably. Maximum in-cylinder gas pressure and rate of heat release peak values raised with hydrogen fraction.
Path to Hydrogen Competitiveness: A Cost Perspective
Jan 2020
Publication
This latest Hydrogen Council report shows that the cost of hydrogen solutions will fall sharply within the next decade – and sooner than previously expected. As scale up of hydrogen production distribution equipment and component manufacturing continues cost is projected to decrease by up to 50% by 2030 for a wide range of applications making hydrogen competitive with other low-carbon alternatives and in some cases even conventional options.
Significant cost reductions are expected across different hydrogen applications. For more than 20 of them such as long-distance and heavy-duty transportation industrial heating and heavy industry feedstock which together comprise roughly 15% of global energy consumption the hydrogen route appears the decarbonisation option of choice – a material opportunity.
The report attributes this trajectory to scale-up that positively impacts the three main cost drivers:
To deliver on this opportunity supporting policies will be required in key geographies together with investment support of around $70 billion in the lead up to 2030 in order to scale up and achieve hydrogen competitiveness. While this figure is sizable it accounts for less than 5% of annual global spending on energy. For comparison support provided to renewables in Germany totalled roughly $30 billion in 2019.
The study is based on real industry data with 25000 data points gathered and analysed from 30 companies using a rigorous methodology. The data was collected and analytical support provided by McKinsey & Company and it represents the entire hydrogen value chain across four key geographies (US Europe Japan/Korea and China). Data was also reviewed by an independent advisory group comprised of recognised hydrogen and energy transition experts.
You can download the full report from the Hydrogen Council website here
The executive summary can be found here
Significant cost reductions are expected across different hydrogen applications. For more than 20 of them such as long-distance and heavy-duty transportation industrial heating and heavy industry feedstock which together comprise roughly 15% of global energy consumption the hydrogen route appears the decarbonisation option of choice – a material opportunity.
The report attributes this trajectory to scale-up that positively impacts the three main cost drivers:
- Strong fall in the cost of producing low carbon and renewable hydrogen;
- Lower distribution and refuelling costs thanks to higher load utilisation and scale effect on infrastructure utilisation; and
- Dramatic drop in the cost of components for end-use equipment under scaling up of manufacturing.
To deliver on this opportunity supporting policies will be required in key geographies together with investment support of around $70 billion in the lead up to 2030 in order to scale up and achieve hydrogen competitiveness. While this figure is sizable it accounts for less than 5% of annual global spending on energy. For comparison support provided to renewables in Germany totalled roughly $30 billion in 2019.
The study is based on real industry data with 25000 data points gathered and analysed from 30 companies using a rigorous methodology. The data was collected and analytical support provided by McKinsey & Company and it represents the entire hydrogen value chain across four key geographies (US Europe Japan/Korea and China). Data was also reviewed by an independent advisory group comprised of recognised hydrogen and energy transition experts.
You can download the full report from the Hydrogen Council website here
The executive summary can be found here
Hydrolysis Hydrogen Production Mechanism of Mg10Ni10Ce Alloy Surface Modified by SnO2 Nanotubes in Different Aqueous Systems
May 2020
Publication
(Mg-10wt.%Ni)-10wt.%Ce (Mg10Ni10Ce) was ball-milled with SnO2 nanotubes and Mg10Ni10Ce-xSnO2 (x=0 5 10 and 15wt.%) composites have been prepared. The phase compositions microstructures morphologies and hydrolysis H2 generation performance in different aqueous systems (distilled water tap water and simulated seawater) have been investigated and the corresponding hydrolysis mechanism of Mg10Ni10Ce and Mg10Ni10Ce-SnO2 has been proposed. Adding a small amount of SnO2 nanotubes can significantly enhance the hydrolysis reaction of Mg10Ni10Ce especially the initial hydrolysis kinetics and the final H2 generation yield. Unfortunately the Mg10Ni10Ce-xSnO2 hardly react with distilled water at room temperature. The hydrolysis reaction rate of Mg10Ni10Ce-5SnO2 composite in tap water is still very slow with only 17.3% generation yield after 1 hour at 303 K. Fortunately in simulated seawater (3.5wt.% NaCl solution) the hydrolytic H2 generation behavior of the Mg10Ni10Ce-5SnO2 composite has been greatly improved which can release as high as 468.6 mL/g H2 with about 60.9% generation yield within 30 s at 303 K. The Cl- destroys the passivation layer on Mg-Ni-Ce alloy surface and the added SnO2 nanotubes accelerate the hydrolysis reaction rate and enhance the H2 generation yield. The Mg10Ni10Ce-5SnO2 composite can rapidly generate a large amount of H2 in simulate seawater in a short time which is expected to be applied on portable H2 generators in the future.
Challenges in the Use of Hydrogen for Maritime Applications
Jan 2021
Publication
Maritime shipping is a key factor that enables the global economy however the pressure it exerts on the environment is increasing rapidly. In order to reduce the emissions of harmful greenhouse gasses the search is on for alternative fuels for the maritime shipping industry. In this work the usefulness of hydrogen and hydrogen carriers is being investigated as a fuel for sea going ships. Due to the low volumetric energy density of hydrogen under standard conditions the need for efficient storage of this fuel is high. Key processes in the use of hydrogen are discussed starting with the production of hydrogen from fossil and renewable sources. The focus of this review is different storage methods and in this work we discuss the storage of hydrogen at high pressure in liquefied form at cryogenic temperatures and bound to liquid or solid-state carriers. In this work a theoretical introduction to different hydrogen storage methods precedes an analysis of the energy-efficiency and practical storage density of the carriers. In the final section the major challenges and hurdles for the development of hydrogen storage for the maritime industry are discussed. The most likely challenges will be the development of a new bunkering infrastructure and suitable monitoring of the safety to ensure safe operation of these hydrogen carriers on board the ship.
Integrated Ni-P-S Nanosheets Array as Superior Electrocatalysts for Hydrogen Generation
Jan 2017
Publication
Searching for efficient and robust non-noble electrocatalysts for hydrogen generation is extremely desirable for future green energy systems. Here we present the synthesis of integrated Ni-P-S nanosheets array including Ni2P and NiS on nickel foam by a simple simultaneous phosphorization and sulfurization strategy. The resultant sample with optimal composition exhibits superior electrocatalytic performance for hydrogen evolution reaction (HER) in a wide pH range. In alkaline media it can generate current densities of 10 20 and 100 mA cm−2 at low overpotentials of only −101.9 −142.0 and −207.8 mV with robust durability. It still exhibits high electrocatalytic activities even in acid or neutral media. Such superior electrocatalytic performances can be mainly attributed to the synergistic enhancement of the hybrid Ni-P-S nanosheets array with integration microstructure. The kind of catalyst gives a new insight on achieving efficient and robust hydrogen generation.
The Curious Case of the Conflicting Roles of Hydrogen in Global Energy Scenarios
Oct 2019
Publication
As energy systems transition from fossil-based to low-carbon they face many challenges particularly concerning energy security and flexibility. Hydrogen may help to overcome these challenges with potential as a transport fuel for heating energy storage conversion to electricity and in industry. Despite these opportunities hydrogen has historically had a limited role in influential global energy scenarios. Whilst more recent studies are beginning to include hydrogen the role it plays in different scenarios is extremely inconsistent. In this perspective paper reasons for this inconsistency are explored considering the modelling approach behind the scenario scenario design and data assumptions. We argue that energy systems are becoming increasingly complex and it is within these complexities that new technologies such as hydrogen emerge. Developing a global energy scenario that represents these complexities is challenging and in this paper we provide recommendations to help ensure that emerging technologies such as hydrogen are appropriately represented. These recommendations include: using the right modelling tools whilst knowing the limits of the model; including the right sectors and technologies; having an appropriate level of ambition; and making realistic data assumptions. Above all transparency is essential and global scenarios must do more to make available the modelling methods and data assumptions used.
Hydrogen Scaling Up: A Sustainable Pathway for the Global Energy Transition
Nov 2017
Publication
Deployed at scale hydrogen could account for almost one-fifth of total final energy consumed by 2050. This would reduce annual CO2 emissions by roughly 6 gigatons compared to today’s levels and contribute roughly 20% of the abatement required to limit global warming to two degrees Celsius.
On the demand side the Hydrogen Council sees the potential for hydrogen to power about 10 to 15 million cars and 500000 trucks by 2030 with many uses in other sectors as well such as industry processes and feedstocks building heating and power power generation and storage. Overall the study predicts that the annual demand for hydrogen could increase tenfold by 2050 to almost 80 EJ in 2050 meeting 18% of total final energy demand in the 2050 two-degree scenario. At a time when global populations are expected to grow by two billion people by 2050 hydrogen technologies have the potential to create opportunities for sustainable economic growth.
“The world in the 21st century must transition to widespread low carbon energy use” said Takeshi Uchiyamada Chairman of Toyota Motor Corporation and co-chair of the Hydrogen Council. “Hydrogen is an indispensable resource to achieve this transition because it can be used to store and transport wind solar and other renewable electricity to power transportation and many other things. The Hydrogen Council has identified seven roles for hydrogen which is why we are encouraging governments and investors to give it a prominent role in their energy plans. The sooner we get the hydrogen economy going the better and we are all committed to making this a reality.”
Achieving such scale would require substantial investments; approximately US$20 to 25 billion annually for a total of about US$280 billion until 2030. Within the right regulatory framework – including long-term stable coordination and incentive policies – the report considers that attracting these investments to scale the technology is feasible. The world already invests more than US$1.7 trillion in energy each year including US$650 billion in oil and gas US$300 billion in renewable electricity and more than US$300 billion in the automotive industry.
“This study confirms the place of hydrogen as a central pillar in the energy transition and encourages us in our support of its large-scale deployment. Hydrogen will be an unavoidable enabler for the energy transition in certain sectors and geographies. The sooner we make this happen the sooner we will be able to enjoy the needed benefits of Hydrogen at the service of our economies and our societies” said Benoît Potier Chairman and CEO Air Liquide. “Solutions are technologically mature and industry players are committed. We need concerted stakeholder efforts to make this happen; leading this effort is the role of the Hydrogen Council.”
The launch of the new roadmap came during the Sustainability Innovation Forum in the presence of 18 senior members of the Hydrogen led by co-chairs Takeshi Uchiyamada Chairman of Toyota and Benoît Potier Chairman and CEO Air Liquide and accompanied by Prof. Aldo Belloni CEO of The Linde Group Woong-chul Yang Vice Chairman of Hyundai Motor Company and Anne Stevens Board Member of Anglo American. During the launch the Hydrogen Council called upon investors policymakers and businesses to join them in accelerating deployment of hydrogen solutions for the energy transition. It was also announced that Woong-chul Yang of Hyundai Motor Company will succeed Takeshi Uchiyamada of Toyota in the rotating role of the Council’s co-chair and preside the group together with Benoit Potier CEO Air Liquide in 2018. Mr Uchiyamada is planning to return as Co-chairman in 2020 coinciding with the Tokyo Olympic and Paalympic Games an important milestone for showcasing hydrogen society and mobility.
You can download the full report from the Hydrogen Council website here
On the demand side the Hydrogen Council sees the potential for hydrogen to power about 10 to 15 million cars and 500000 trucks by 2030 with many uses in other sectors as well such as industry processes and feedstocks building heating and power power generation and storage. Overall the study predicts that the annual demand for hydrogen could increase tenfold by 2050 to almost 80 EJ in 2050 meeting 18% of total final energy demand in the 2050 two-degree scenario. At a time when global populations are expected to grow by two billion people by 2050 hydrogen technologies have the potential to create opportunities for sustainable economic growth.
“The world in the 21st century must transition to widespread low carbon energy use” said Takeshi Uchiyamada Chairman of Toyota Motor Corporation and co-chair of the Hydrogen Council. “Hydrogen is an indispensable resource to achieve this transition because it can be used to store and transport wind solar and other renewable electricity to power transportation and many other things. The Hydrogen Council has identified seven roles for hydrogen which is why we are encouraging governments and investors to give it a prominent role in their energy plans. The sooner we get the hydrogen economy going the better and we are all committed to making this a reality.”
Achieving such scale would require substantial investments; approximately US$20 to 25 billion annually for a total of about US$280 billion until 2030. Within the right regulatory framework – including long-term stable coordination and incentive policies – the report considers that attracting these investments to scale the technology is feasible. The world already invests more than US$1.7 trillion in energy each year including US$650 billion in oil and gas US$300 billion in renewable electricity and more than US$300 billion in the automotive industry.
“This study confirms the place of hydrogen as a central pillar in the energy transition and encourages us in our support of its large-scale deployment. Hydrogen will be an unavoidable enabler for the energy transition in certain sectors and geographies. The sooner we make this happen the sooner we will be able to enjoy the needed benefits of Hydrogen at the service of our economies and our societies” said Benoît Potier Chairman and CEO Air Liquide. “Solutions are technologically mature and industry players are committed. We need concerted stakeholder efforts to make this happen; leading this effort is the role of the Hydrogen Council.”
The launch of the new roadmap came during the Sustainability Innovation Forum in the presence of 18 senior members of the Hydrogen led by co-chairs Takeshi Uchiyamada Chairman of Toyota and Benoît Potier Chairman and CEO Air Liquide and accompanied by Prof. Aldo Belloni CEO of The Linde Group Woong-chul Yang Vice Chairman of Hyundai Motor Company and Anne Stevens Board Member of Anglo American. During the launch the Hydrogen Council called upon investors policymakers and businesses to join them in accelerating deployment of hydrogen solutions for the energy transition. It was also announced that Woong-chul Yang of Hyundai Motor Company will succeed Takeshi Uchiyamada of Toyota in the rotating role of the Council’s co-chair and preside the group together with Benoit Potier CEO Air Liquide in 2018. Mr Uchiyamada is planning to return as Co-chairman in 2020 coinciding with the Tokyo Olympic and Paalympic Games an important milestone for showcasing hydrogen society and mobility.
You can download the full report from the Hydrogen Council website here
A Socio-technical Perspective on the Scope for Ports to Enable Energy Transition
Jan 2021
Publication
The paper applies the multi-level perspective (MLP) in a descriptive study of three Norwegian ports to shed new light on the sociotechnical processes that structure their efforts to develop into zero emission energy hubs. While exogenous pressures cause tensions over port governance the studied ports utilize their full spectre of functions; as landlords operators authorities and community managers to enable transition. The respective approaches vary related to their local context market situation and social networks including port's relations with their owners. Individual orientations and organizational capacity further influence their engagement with radical innovation niches (e.g. OPS hydrogen LNG). The study highlights the active role of ports in sustainability transition. It shows how the interaction between geographical factors and institutional work influences the scope for new solutions around the individual port and how this makes for different feedback loops and contributions to sustainability transition in wider transport and energy systems.
Genome-wide Transcriptome Analysis of Hydrogen Production in the Cyanobacterium Synechocystis: Towards the Identification of New Players
Dec 2012
Publication
We report the development of new tools and methods for facile integration and meaningful representation of high throughput data generated by genome-wide analyses of the model cyanobacterium Synechocystis PCC6803 for future genetic engineering aiming at increasing its level of hydrogen photoproduction. These robust tools comprise new oligonucleotide DNA microarrays to monitor the transcriptomic responses of all 3725 genes of Synechocystis and the SVGMapping method and custom-made templates to represent the metabolic reprogramming for improved hydrogen production. We show for the first time that the AbrB2 repressor of the hydrogenase-encoding operon also regulates metal transport and protection against oxidative stress as well as numerous plasmid genes which have been overlooked so far. This report will stimulate the construction and global analysis of hydrogen production mutants with the prospect of developing powerful cell factories for the sustainable production of hydrogen as well as investigations of the probable role of plasmids in this process.
Mach 4 Simulating Experiment of Pre-Cooled Turbojet Engine Using Liquid Hydrogen
Jan 2022
Publication
This study investigated a pre-cooled turbojet engine for a Mach 5 class hypersonic transport aircraft. The engine was demonstrated under takeoff and Mach 2 flight conditions and a Mach 5 propulsion wind tunnel test is planned. The engine is composed of a pre-cooler a core engine and an afterburner. The engine was tested under simulated Mach 4 conditions using an air supply facility. High-temperature air under high pressure was supplied to the engine components through an airflow control valve and an orifice flow meter and liquid hydrogen was supplied to the pre-cooler and the core engine. The results confirmed that the starting sequence of the engine components was effective under simulated Mach 4 conditions using liquid hydrogen fuel. The pre-cooling effect caused no damage to the rotating parts of the core engine in the experiment.
A Comparison of Alternative Fuels for Shipping in Terms of Lifecycle Energy and Cost
Dec 2021
Publication
Decarbonization of the shipping sector is inevitable and can be made by transitioning into low‐ or zero‐carbon marine fuels. This paper reviews 22 potential pathways including conventional Heavy Fuel Oil (HFO) marine fuel as a reference case “blue” alternative fuel produced from natural gas and “green” fuels produced from biomass and solar energy. Carbon capture technology (CCS) is installed for fossil fuels (HFO and liquefied natural gas (LNG)). The pathways are compared in terms of quantifiable parameters including (i) fuel mass (ii) fuel volume (iii) life cycle (Well‐To‐ Wake—WTW) energy intensity (iv) WTW cost (v) WTW greenhouse gas (GHG) emission and (vi) non‐GHG emissions estimated from the literature and ASPEN HYSYS modelling. From an energy perspective renewable electricity with battery technology is the most efficient route albeit still impractical for long‐distance shipping due to the low energy density of today’s batteries. The next best is fossil fuels with CCS (assuming 90% removal efficiency) which also happens to be the lowest cost solution although the long‐term storage and utilization of CO2 are still unresolved. Biofuels offer a good compromise in terms of cost availability and technology readiness level (TRL); however the non‐GHG emissions are not eliminated. Hydrogen and ammonia are among the worst in terms of overall energy and cost needed and may also need NOx clean‐up measures. Methanol from LNG needs CCS for decarbonization while methanol from biomass does not and also seems to be a good candidate in terms of energy financial cost and TRL. The present analysis consistently compares the various options and is useful for stakeholders involved in shipping decarbonization.
Functional Model of Power Grid Stabilization in the Green Hydrogen Supply Chain System—Conceptual Assumptions
Dec 2022
Publication
Green hydrogen supply chain includes supply sources production and distribution of hydrogen produced from renewable energy sources (RES). It is a promising scientific and application area as it is related to the problem of instability of power grids supplied with RES. The article presents the conceptual assumptions of the research on the design of a functional multi-criteria model of the stabilization model architecture of energy distribution networks based on a hydrogen energy buffer taking into account the applicable use of hydrogen. The aim of the research was to identify the variables contributing to the stabilization of the operation of distribution networks. The method used to obtain this result was a systematic review of the literature using the technique of in-depth analysis of full-text articles and expert consultations. The concept of a functional model was described as a matrix in two dimensions in which the identified variables were embedded. The first dimension covers the phases of the supply chain: procurement and production along with storage and distribution. The second dimension divides the separate factors into technical economic and logistic. The research was conducted in the context of system optimization from the point of view of the operator of the energy distribution system. As a result of the research several benefits resulting from stabilization using a hydrogen buffer were identified. Furthermore the model may be used in designing solutions stabilizing the operation of power grids in which there are surpluses of electricity produced from RES. Due to the applied multidimensional approach the developed model is recommended for use as it enables the design of solutions in a systemic manner. Due to the growing level of energy obtained from renewable energy sources the issue of stabilizing the energy network is becoming increasingly important for energy network distributors.
Measurement Challenges for Hydrogen Vehicles
Apr 2019
Publication
Uptake of hydrogen vehicles is an ideal solution for countries that face challenging targets for carbon dioxide reduction. The advantage of hydrogen fuel cell electric vehicles is that they behave in a very similar way to petrol engines yet they do not emit any carbon containing products during operation. The hydrogen industry currently faces the dilemma that they must meet certain measurement requirements (set by European legislation) but cannot do so due to a lack of available methods and standards. This paper outlines the four biggest measurement challenges that are faced by the hydrogen industry including flow metering quality assurance quality control and sampling.
Study Navigating the Way to a Renewable Future – Solutions to Decarbonise Shipping
Sep 2019
Publication
On average the shipping sector is responsible for 3% of annual global green-house gas emissions on a CO2-equivalent basis. International shipping represents around 9% of the global emissions associated with the transport sector.<br/>This report from the International Renewable Energy Agency (IRENA) explores the impact of maritime shipping on CO2 emissions the structure of the shipping sector and key areas that need to be addressed to reduce the sector’s carbon footprint.<br/>There is no clear-cut path to decarbonisation. Cutting CO2 emissions in half is therefore likely to require a combination of approaches including the use of alternative fuels upgrading of onshore infrastructure and reducing fuel demand by improving operational performance the report finds.<br/>The shipping sector is strategically important for global efforts against climate change and could be crucial in the long-term shift to a zero-carbon economy. Large-scale deployment of low-carbon fuel infrastructure for shipping could also help to build the necessary momentum to decarbonise other sectors.
Adopting Hydrogen Direct Reduction for the Swedish Steel Industry: A Technological Innovation System (TIS) Study
Sep 2019
Publication
The Swedish steel industry stands before a potential transition to drastically lower its CO2 emissions using direct hydrogen reduction instead of continuing with coke-based blast furnaces. Previous studies have identified hydrogen direct reduction as a promising option. We build upon earlier efforts by performing a technological innovation system study to systematically examine the barriers to a transition to hydrogen direct reduction and by providing deepened quantitative empirics to support the analysis. We also add extended paper and patent analysis methodology which is particularly useful for identifying actors and their interactions in a technological system. We conclude that while the innovation system is currently focused on such a transition notable barriers remain particularly in coordination of the surrounding technical infrastructure and the issue of maintaining legitimacy for such a transition in the likely event that policies to address cost pressures will be required to support this development.
Spatially Resolved Optimization for Studying the Role of Hydrogen for Heat Decarbonization Pathways
Apr 2018
Publication
This paper studies the economic feasibility of installing hydrogen networks for decarbonizing heat in urban areas. The study uses the Heat Infrastructure and Technology (HIT) spatially resolved optimization model to trade-off energy supply infrastructure and end-use technology costs for the most important heat-related energy vectors: gas heat electricity and hydrogen. Two model formulations are applied to a UK urban area: one with an independent hydrogen network and one that allows for retrofitting the gas network into hydrogen. Results show that for average hydrogen price projections cost-effective pathways for heat decarbonization toward 2050 include heat networks supplied by a combination of district-level heat pumps and gas boilers in the domestic and commercial sectors and hydrogen boilers in the domestic sector. For a low hydrogen price scenario when retrofitting the gas network into hydrogen a cost-effective pathway is replacing gas by hydrogen boilers in the commercial sector and a mixture of hydrogen boilers and heat networks supplied by district-level heat pumps gas and hydrogen boilers for the domestic sector. Compared to the first modelled year CO2 emission reductions of 88% are achieved by 2050. These results build on previous research on the role of hydrogen in cost-effective heat decarbonization pathways.
Review of the Current Status of Ammonia-Blended Hydrogen Fuel Engine Development
Jan 2022
Publication
As fossil fuels continue to be extracted and used issues such as environmental pollution and energy scarcity are surfacing. For the transportation industry the best way to achieve the goal of “carbon neutrality” is to research efficient power systems and develop new alternative fuels. As the world’s largest product of chemicals ammonia is a new renewable fuel with good combustion energy. It can be used as an alternative fuel to reduce carbon emissions because of its proven production process low production and transportation costs safe storage the absence of carbon-containing compounds in its emissions and its future recyclability. This paper firstly introduces the characteristics of ammonia fuel engine and its problems; then it summarizes the effects of various ammonia-blended fuels on the combustion and emission characteristics of the engine from the combustion problem of ammonia-blended engine; then the fuel storage of ammonia-blended hydrogen is discussed the feasibility of hydrogen production instead of hydrogen storage is introduced.
Direct Ammonia Low-temperature Symmetrical Solid Oxide Fuel Cells with Composite Semiconductor Electrolyte
Jan 2022
Publication
In this work a low-temperature symmetrical solid oxide fuel cell with Ni-NCAL|SDC/NCAL|Ni-NCAL (70 SDC:30 NCAL) configuration was successfully constructed by a simple dry press method. At 500 and 550 ◦C the peak power densities of the cell in ammonia were 501 and 755 mW cm− 2 and in hydrogen were 670 and 895 mW cm− 2 respectively. EIS data showed that the Rp values of the cell in ammonia and hydrogen at 550 ◦C were 0.250 and 0.246 Ω cm− 2 respectively indicating the excellent catalytic activity of the Ni-NCAL electrode toward ammonia decomposition and hydrogen oxidation. The different cell output can be ascribed to additional ammonia decomposition steps compared to hydrogen. The noticeable reaction product on the surface of the Ni foam was detrimental to ammonia decomposition. In summary a symmetrical cell with SDC/NCAL semi-conductor electrolyte and Ni-NCAL electrodes exhibited higher electrochemical performance at low temperature than the results reported to date. Therefore higher electrochemical performance can be expected from this cell configuration with more efficient ammonia decomposition catalysts.
Scottish Hydrogen Assessment
Dec 2020
Publication
During 2020 the Scottish Government in partnership with Highlands and Islands Enterprise and Scottish Enterprise commissioned Arup and E4Tech to carry out a hydrogen assessment to deepen our evidence base in order to inform our policies on hydrogen going forward. The assessment aims to investigate how and where hydrogen may fit within the evolving energy system technically geographically and economically. To assist in this consideration a key part of the Hydrogen Assessment is the development of distinct viable scenarios for hydrogen deployment in Scotland and the economic assessment of those scenarios.<br/>From our assessment it is clear that hydrogen is not just an energy and emissions reduction opportunity; it could also have an important role in generating new economic opportunities in Scotland. The assessment forms an important part of the evidence base that informed the development of the Hydrogen Policy Statement.
Five Minute Guide to Hydrogen
Feb 2016
Publication
Hydrogen is an emerging energy vector many components of which are mature technologies. Current hydrogen technology is already able to provide advantages over other energy vectors and many of its challenges are being actively addressed by research and development.<br/><br/>Hydrogen can be derived stored and converted through various processes each of which represents different levels of carbon intensity efficiency and end use functionality. Our latest five minute guide looks at this energy vector in brief including public perception transportation and storage as well as using hydrogen as a solution.
Scottish Offshore Wind to Green Hydrogen Opportunity Assessment
Dec 2020
Publication
Initial assessment of Scotland’s opportunity to produce green hydrogen from offshore wind
Summary of Key Findings
Summary of Key Findings
- Scotland has an abundant offshore wind resource that has the potential to be a vital component in our net zero transition. If used to produce green hydrogen offshore wind can help abate the emissions of historically challenging sectors such as heating transport and industry.
- The production of green hydrogen from offshore wind can help overcome Scotland’s grid constraints and unlock a massive clean power generation resource creating a clean fuel for Scottish industry and households and a highly valuable commodity to supply rapidly growing UK and European markets.
- The primary export markets for Scottish green hydrogen are expected to be in Northern Europe (Germany Netherlands & Belgium). Strong competition to supply these markets is expected to come from green hydrogen produced from solar energy in Southern Europe and North Africa.
- Falling wind and electrolyser costs will enable green hydrogen production to be cost-competitive in the key transport and heat sectors by 2032. Strategic investment in hydrogen transportation and storage is essential to unlocking the economic opportunity for Scotland.
- Xodus’ analysis supports a long-term outlook of LCoH falling towards £2/kg with an estimated reference cost of £2.3 /kg in 2032 for hydrogen delivered to shore.
- Scotland has extensive port and pipeline infrastructure that can be repurposed for hydrogen export to the rest of UK and to Europe. Pipelines from the ‘90s are optimal for this purpose as they are likely to retain acceptable mechanical integrity and have a metallurgy better suited to hydrogen service. A more detailed assessment of export options should be performed to provide a firm foundation for early commercial green hydrogen projects.
- There is considerable hydrogen supply chain overlap with elements of parallel sectors most notably the oil and gas offshore wind and subsea engineering sectors. Scotland already has a mature hydrocarbon supply chain which is engaged in supporting green hydrogen. However a steady pipeline of early projects supported by a clear financeable route to market will be needed to secure this supply chain capability through to widescale commercial deployment.
- There are gaps in the Scottish supply chain in the areas of design manufacture and maintenance of hydrogen production storage and transportation systems. Support including apprenticeships will be needed to develop indigenous skills and capabilities in these areas.
- The development of green hydrogen from offshore wind has the potential to create high value jobs a significant proportion which are likely to be in remote rural/coastal communities located close to offshore wind resources. These can serve as an avenue for workers to redeploy and develop skills learned from oil and gas in line with Just Transition principles.
Hydrogen for Cooking: A Review of Cooking Technologies, Renewable Hydrogen Systems and Techno-Economics
Dec 2022
Publication
About 3 billion people use conventional carbon-based fuels such as wood charcoal and animal dung for their daily cooking needs. Cooking with biomass causes deforestation and habitat loss emissions of greenhouse gases and smoke pollution that affects people’s health and well-being. Hydrogen can play a role in enabling clean and safe cooking by reducing household air pollution and reducing greenhouse gas emissions. This first-of-a-kind review study on cooking with hydrogen assessed existing cooking technologies and hydrogen systems in developing country contexts. Our critical assessment also included the modelling and experimental studies on hydrogen. Renewable hydrogen systems and their adoptability in developing countries were analysed. Finally we presented a scenario for hydrogen production pathways in developing countries. Our findings indicated that hydrogen is attractive and can be safely used as a cooking fuel. However radical and disruptive models are necessary to transform the traditional cooking landscape. There is a need to develop global south-based hydrogen models that emphasize adoptability and capture the challenges in developing countries. In addition the techno-economic assumptions of the models vary significantly leading to a wide-ranging levelized cost of electricity. This finding underscored the necessity to use comprehensive techno-economic assumptions that can accurately predict hydrogen costs.
Hydrogen for Heating? Decarbonization Options for Households in the European Union in 2050
Mar 2021
Publication
This study compares the cost of several low-greenhouse gas (GHG) or GHG-neutral residential heating technologies in the year 2050: (1) hydrogen boilers (2) hydrogen fuel cells with an auxiliary hydrogen boiler for cold spells (3) air-source heat pumps using renewable electricity and (4) heat pumps with an auxiliary hydrogen boiler for cold spells. The assessment includes low-carbon hydrogen from steam-methane reforming (SMR) using natural gas combined with carbon capture and storage (CCS) or SMR + CCS and zero-carbon hydrogen produced from renewable electricity using electrolysis.
The analysis finds that air-source heat pumps are the most cost-effective residential heating technology in 2050 and are at least 50% lower cost than the hydrogen-only technologies. In a sensitivity analysis we find that even if natural gas costs were 50% lower or renewable electricity prices were 50% higher in 2050 compared to our central assumptions heat pumps would still be more cost-effective than hydrogen boilers or fuel cells. Renewable electrolysis hydrogen can be cost-competitive with SMR + CCS hydrogen in 2050 although electrolysis hydrogen is not produced at scale today. At the same time energy efficiency measures to reduce heat demand would be a more cost-effective strategy for achieving GHG reductions than any of the low-GHG heating pathways we assess in this study.
The analysis shows that all pathways using renewable electricity have a near-zero GHG intensity while SMR + CCS hydrogen could reduce GHG emissions by 69%–93% compared to natural gas if improvements are made in the future to reduce the GHG intensity of this pathway. Quantifying the GHG impact and cost effectiveness of various heating pathways is relevant for European policymakers facing decisions on how to both decarbonize buildings and alleviate energy poverty in line with commitments made in the Renovation Wave Initiative.
The document can be downloaded from the ICCT website
The analysis finds that air-source heat pumps are the most cost-effective residential heating technology in 2050 and are at least 50% lower cost than the hydrogen-only technologies. In a sensitivity analysis we find that even if natural gas costs were 50% lower or renewable electricity prices were 50% higher in 2050 compared to our central assumptions heat pumps would still be more cost-effective than hydrogen boilers or fuel cells. Renewable electrolysis hydrogen can be cost-competitive with SMR + CCS hydrogen in 2050 although electrolysis hydrogen is not produced at scale today. At the same time energy efficiency measures to reduce heat demand would be a more cost-effective strategy for achieving GHG reductions than any of the low-GHG heating pathways we assess in this study.
The analysis shows that all pathways using renewable electricity have a near-zero GHG intensity while SMR + CCS hydrogen could reduce GHG emissions by 69%–93% compared to natural gas if improvements are made in the future to reduce the GHG intensity of this pathway. Quantifying the GHG impact and cost effectiveness of various heating pathways is relevant for European policymakers facing decisions on how to both decarbonize buildings and alleviate energy poverty in line with commitments made in the Renovation Wave Initiative.
The document can be downloaded from the ICCT website
Hydrogen for Heating? Decarbonization Options for Households in the United Kingdom in 2050
Dec 2020
Publication
The heating sector makes up 10% of the United Kingdom’s carbon footprint and residential homes account for a majority of demand. At present central heating from a natural gas-fired boiler is the most common system in the UK but low or zero-carbon hydrogen and renewable electricity are the two primary energy replacement options to reduce the carbon footprint. An important consideration is how using either energy source would affect heating costs. This assessment projects the costs for a typical single-family UK household and climate performance in 2050 using low-GHG or GHG-neutral hydrogen renewable electricity or a combination of both. The cost of using boilers or fuel cells in 2050 with two types of hydrogen are assessed: produced via steam-methane reforming (SMR) combined with carbon capture and storage (CCS) and electrolysis using zero-carbon renewable electricity. The costs of heat pumps the most promising heating technology for the direct use of renewable electricity are also assessed in two scenarios: a heat pump only and a hybrid heat pump with an auxiliary hydrogen boiler.
You can download this document from the International Council On Clean Transportation website linked here
You can download this document from the International Council On Clean Transportation website linked here
Electrification Opportunities in the Medium- and Heavy-Duty Vehicle Segment in Canada
Jun 2021
Publication
The medium- and heavy-duty (MD/HD) vehicle sector is a large emitter of greenhouse gases. It will require drastic emissions reductions to realize a net-zero carbon future. This study conducts fourteen short feasibility investigations in the Canadian context to evaluate the merits of battery electric or hydrogen fuel cell alternatives to conventional city buses inter-city buses school buses courier vehicles (step vans) refuse trucks long-haul trucks and construction vehicles. These “clean transportation alternatives” were evaluated for practicality economics and emission reductions in comparison to their conventional counterparts. Conclusions were drawn on which use cases would be best suited for accelerating the transformation of the MD/HD sector.
Toward a Fossil Free Future with HYBRIT: Development of Iron and Steelmaking Technology in Sweden and Finland
Jul 2020
Publication
The Swedish and Finnish steel industry has a world-leading position in terms of efficient blast furnace operations with low CO2 emissions. This is a result of a successful development work carried out in the 1980s at LKAB (Luossavaara-Kiirunavaara Aktiebolag mining company) and SSAB (steel company) followed by the closing of sinter plants and transition to 100% pellet operation at all of SSAB’s five blast furnaces. However to further reduce CO2 emission in iron production a new breakthrough technology is necessary. In 2016 SSAB teamed up with LKAB and Vattenfall AB (energy company) and launched a project aimed at investigating the feasibility of a hydrogen-based sponge iron production process with fossil-free electricity as the primary energy source: HYBRIT (Hydrogen Breakthrough Ironmaking Technology). A prefeasibility study was carried out in 2017 which concluded that the proposed process route is technically feasible and economically attractive for conditions in northern Sweden/Finland. A decision was made in February 2018 to build a pilot plant and construction started in June 2018 with completion of the plant planned in summer 2020 followed by experimental campaigns the following years. Parallel with the pilot plant activities a four-year research program was launched from the autumn of 2016 involving several research institutes and universities in Sweden to build knowledge and competence in several subject areas.
Microbial Fuel Cells: Technologically Advanced Devices and Approach for Sustainable/renewable Energy Development
Dec 2021
Publication
There is a huge quantity of energy needs/demands for multiple developmental and domestic activities in the modern era. And in this context consumption of more non-renewable energy is reported and created many problems or issues (availability of fossil fuel stocks in the future period causes a huge quantity of toxic gases or particles or climatic change effects) at the global level. And only sustainable or renewable fuel development can provide alternate fuel and we report from various biological agents processes including microbial biofuel cell applications for future energy needs only. These will not cause any interference in natural resources or services. Microbial biofuel cells utilize the living cell to produce bioelectricity via bioelectrochemical system. It can drive electricity or other energy generation currents via lived cell interaction. Microbial fuel cells (MFCs) and enzymatic biofuel cells with their advancement in design can improve sustainable bio-energy production by proving an efficient conversion system compared to chemical fuels into electric power. Different types of MFCs operation are reported in wastewater treatment with biogas biohydrogen and other biofuel/energy generation. Later biogas can convert into electric power. Hybrid microbial biofuel cell utility with photochemical reaction is found for electricity generation. Recent research and development in microbial biofuel design and its application will emphasize bioenergy for the future.
Mapping of Hydrogen Fuel Quality in Europe
Nov 2020
Publication
As part of FCH-JU funded HyCoRA project running from 2014 to 2017 28 gaseous and 13 particulate samples were collected from hydrogen refuelling stations in Europe. Samples were collected with commercial sampling instruments and analysis performed in compliance with prevailing fuel quality standards. Sampling was conducted with focus on diversity in feedstock as well as commissioning date of the HRS. Results indicate that the strategy for sampling was good. No evidence of impurity cross-over was observed. Parallel samples collected indicate some variation in analytical results. It was however found that fuel quality was generally good. Fourteen analytical results were in violation with the fuel tolerance limits. Therefore eight or 29% of the samples were in violation with the fuel quality requirements. Nitrogen oxygen and organics were the predominant impurities quantified. Particulate impurities were found to be within fuel quality specifications. No correlation between fuel quality and hydrogen feedstock or HRS commissioning date was found. Nitrogen to oxygen ratios gave no indication of samples being contaminated by air. A comparison of analytical results between two different laboratories were conducted. Some difference in analytical results were observed.
Towards a CO2-neutral Steel Industry: Justice Aspects of CO2 Capture and Storage, Biomass- and Green Hydrogen-based Emission Reductions
Apr 2022
Publication
A rapid transition towards a CO2-neutral steel industry is required to limit climate change. Such a transition raises questions of justice as it entails positive and negative impacts unevenly distributed across societal stakeholders. To enable stakeholders to address such concerns this paper assesses the justice implications of three options that reduce emissions: CO2 capture and storage (CCS) on steel (up to 70%) bio-based steelmaking (up to 50%) and green hydrogen-based steel production (up to 100%). We select justice indicators from the energy climate labour and environmental justice literature and assess these indicators qualitatively for each of the technological routes based on literature and desk research. We find context-dependent differences in justness between the different technological routes. The impact on stakeholders varies across regions. There are justice concerns for local communities because of economic dependence on and environmental impact of the industry. Communities elsewhere are impacted through the siting of infrastructure and feedstock production. CCS and bio-based steelmaking routes can help retain industry and associated economic benefits on location while hydrogen-based steelmaking may deal better with environmental concerns. We conclude that besides techno-economic and environmental information transparency on sector-specific justice implications of transforming steel industries is essential for decision-making on technological routes
Electricity-based Plastics and their Potential Demand for Electricity and Carbon Dioxide
Apr 2020
Publication
In a future fossil-free circular economy the petroleum-based plastics industry must be converted to non-fossil feedstock. A known alternative is bio-based plastics but a relatively unexplored option is deriving the key plastic building blocks hydrogen and carbon from electricity through electrolytic processes combined with carbon capture and utilization technology. In this paper the future demand for electricity and carbon dioxide is calculated under the assumption that all plastic production is electricity-based in the EU by 2050. The two most important input chemicals are ethylene and propylene and the key finding of this paper is that the electricity demand to produce these are estimated to 20 MWh/ton ethylene and 38 MWh/ton propylene and that they both could require about 3 tons of carbon dioxide/ton product. With constant production levels this implies an annual demand of about 800 TWh of electricity and 90 Mton of carbon dioxide by 2050 in the EU. If scaled to the total production of plastics including all input hydrocarbons in the EU the annual demand is estimated to 1600 TWh of electricity and 180 Mton of carbon dioxide. This suggests that a complete shift to electricity-based plastics is possible from a resource and technology point of view but production costs may be 2 to 3 times higher than today. However the long time frame of this paper creates uncertainties regarding the results and how technical economic and social development may influence them. The conclusion of this paper is that electricity-based plastics integrated with bio-based production can be an important option in 2050 since biomass resources are scarce but electricity from renewable sources is abundant.
Comparative Technical and Economic Analyses of Hydrogen-Based Steel and Power Sectors
Mar 2024
Publication
Decarbonizing the current steel and power sectors through the development of the hydrogen direct-reduction iron ore–electric arc furnace route and the 100% hydrogen-fired gas turbine cycle is crucial. The current study focuses on three clusters of research works. The first cluster covers the investigation of the mass and energy balance of the route and the subsequent application of these values in experiments to optimize the reduction yield of iron ore. In the second cluster the existing gas turbine unit was selected for the complete replacement of natural gas with hydrogen and for finding the most optimal mass and energy balance in the cycle through an Aspen HYSYS model. In addition the chemical kinetics in the hydrogen combustion process were simulated using Ansys Chemkin Pro to research the emissions. In the last cluster a comparative economic analysis was conducted to identify the levelized cost of production of the route and the levelized cost of electricity of the cycle. The findings in the economic analysis provided good insight into the details of the capital and operational expenditures of each industrial sector in understanding the impact of each kg of hydrogen consumed in the plants. These findings provide a good basis for future research on reducing the cost of hydrogen-based steel and power sectors. Moreover the outcomes of this study can also assist ongoing large-scale hydrogen and ammonia projects in Uzbekistan in terms of designing novel hydrogen-based industries with cost-effective solutions.
Comparative Life Cycle Assessment of Hydrogen-fuelled Passenger Cars
Feb 2021
Publication
In order to achieve gradual but timely decarbonisation of the transport sector it is essential to evaluate which types of vehicles provide a suitable environmental performance while allowing the use of hydrogen as a fuel. This work compares the environmental life-cycle performance of three different passenger cars fuelled by hydrogen: a fuel cell electric vehicle an internal combustion engine car and a hybrid electric vehicle. Besides two vehicles that use hydrogen in a mixture with natural gas or gasoline were considered. In all cases hydrogen produced by wind power electrolysis was assumed. The resultant life-cycle profiles were benchmarked against those of a compressed natural gas car and a hybrid electric vehicle fed with natural gas. Vehicle infrastructure was identified as the main source of environmental burdens. Nevertheless the three pure hydrogen vehicles were all found to be excellent decarbonisation solutions whereas vehicles that use hydrogen mixed with natural gas or gasoline represent good opportunities to encourage the use of hydrogen in the short term while reducing emissions compared to ordinary vehicles.
Recyclable Metal Fuels for Clean and Compact Zero-carbon Power
Jun 2018
Publication
Metal fuels as recyclable carriers of clean energy are promising alternatives to fossil fuels in a future low-carbon economy. Fossil fuels are a convenient and widely-available source of stored solar energy that have enabled our modern society; however fossil-fuel production cannot perpetually keep up with increasing energy demand while carbon dioxide emissions from fossil-fuel combustion cause climate change. Low-carbon energy carriers with high energy density are needed to replace the multiple indispensable roles of fossil fuels including for electrical and thermal power generation for powering transportation fleets and for global energy trade. Metals have high energy densities and metals are therefore fuels within many batteries energetic materials and propellants. Metal fuels can be burned with air or reacted with water to release their chemical energy at a range of power-generation scales. The metal-oxide combustion products are solids that can be captured and then be recycled using zero-carbon electrolysis processes powered by clean energy enabling metals to be used as recyclable zero-carbon solar fuels or electrofuels. A key technological barrier to the increased use of metal fuels is the current lack of clean and efficient combustor/reactor/engine technologies to convert the chemical energy in metal fuels into motive or electrical power (energy). This paper overviews the concept of low-carbon metal fuels and summarizes the current state of our knowledge regarding the reaction of metal fuels with water to produce hot hydrogen on demand and the combustion of metal fuels with air in laminar and turbulent flames. Many important questions regarding metal-fuel combustion processes remain unanswered as do questions concerning the energy-cycle efficiency and life-cycle environmental impacts and economics of metals as recyclable fuels. Metal fuels can be an important technology option within a future low-carbon society and deserve focused attention to address these open questions.
Market Segmentation of Domestic and Commercial Natural Gas Appliances
Jan 2021
Publication
The main goal of the project is to enable the wide adoption of H2NG (hydrogen in natural gas) blends by closing knowledge gaps regarding technical impacts on residential and commercial gas appliances. The project consortium will identify and recommend appropriate codes and standards that should be adapted to answer the needs and develop a strategy for addressing the challenges for new and existing appliances.<br/>This deliverable on market segmentation is part of work package 2 and provides a quantitative segmentation of the gas appliance market in terms of appliance population numbers. It therefore prepares the project partners to perform the subsequent selection of the most representative product types to be tested in the laboratories of the THyGA partners.<br/>The classification is developed to categorise appliances installed in the field based on available statistics calculation methods and estimations. As a result appliance populations are provided for each technology segment that draw a representative picture of the installed end-use appliances within the European Union in 2020.
Application of Liquid Hydrogen Carriers in Hydrogen Steelmaking
Mar 2021
Publication
Steelmaking is responsible for approximately one third of total industrial carbon dioxide (CO2) emissions. Hydrogen (H2) direct reduction (H-DR) may be a feasible route towards the decarbonization of primary steelmaking if H2 is produced via electrolysis using fossil-free electricity. However electrolysis is an electricity-intensive process. Therefore it is preferable that H2 is predominantly produced during times of low electricity prices which is enabled by the storage of H2. This work compares the integration of H2 storage in four liquid carriers methanol (MeOH) formic acid (FA) ammonia (NH3) and perhydro-dibenzyltoluene (H18-DBT) in H-DR processes. In contrast to conventional H2 storage methods these carriers allow for H2 storage in liquid form at moderate overpressures reducing the storage capacity cost. The main downside to liquid H2 carriers is that thermochemical processes are necessary for both the storage and release processes often with significant investment and operational costs. The carriers are compared using thermodynamic and economic data to estimate operational and capital costs in the H-DR context considering process integration options. It is concluded that the use of MeOH is promising compared to the other considered carriers. For large storage volumes MeOH-based H2 storage may also be an attractive option to the underground storage of compressed H2. The other considered liquid H2 carriers suffer from large thermodynamic barriers for hydrogenation (FA) or dehydrogenation (NH3 H18-DBT) and higher investment costs. However for the use of MeOH in an H-DR process to be practically feasible questions regarding process flexibility and the optimal sourcing of CO2 and heat must be answered
Opportunities and Barriers of Hydrogen–Electric Hybrid Powertrain Vans: A Systematic Literature Review
Oct 2020
Publication
The environmental impact of the road transport sector together with urban freight transport growth has a notable repercussions in global warming health and economy. The need to reduce emissions caused by fossil fuel dependence and to foster the use of renewable energy sources has driven the development of zero-emissions powertrains. These clean transportation technologies are not only necessary to move people but to transport the increasing demand for goods and services that is currently taking place in the larger cities. Full electric battery-powered vans seem to be the best-placed solution to the problem. However despite the progress in driving range and recharge options those and other market barriers remain unsolved and the current market share of battery electric vehicles (BEVs) is not significant. Based on the development of hydrogen fuel cell stacks this work explains an emerging powertrain architecture concept for N1 class type vans that combines a battery-electric configuration with a fuel cell stack powered by hydrogen that works as a range extender (FC-EREV). A literature review is conducted with the aim to shed light on the possibilities of this hybrid light-duty commercial van for metropolitan delivery tasks providing insights into the key factors and issues for sizing the powertrain components and fuel management strategies to meet metropolitan freight fleet needs.
Hydrogen Station Technology Development Review Through Patent Analysis
May 2018
Publication
This study is a review of hydrogen station patents using the Derwent Innovation system and also a secondary screening. This was undertaken by the researchers to better understand and identify hydrogen station trends. The review focuses on analyzing the developing trends of patent technologies associated with a hydrogen station. The results of the review indicated that the countries with the major distribution of patents were Japan China the USA and Europe. Japan is leading the developmental trajectory of hydrogen stations. The results of the analysis found the leading developers of these patented technologies are Kobe Steel Nippon Oil Toyota and Honda. Other active patent developers analyzed include Linde Hyundai and Texaco. The review concludes with a suggestion that using a patent analysis methodology is a good starting point to identify evaluate and measure the trend in hydrogen station commercial development.
Assessment of Full Life-cycle Air Emissions of Alternative Shipping Fuels
Oct 2017
Publication
There is a need for alternative fuels in the shipping sector for two main motivations: to deliver a reduction in local pollutants and comply with existing regulation; and to mitigate climate change and cut greenhouse gas emissions. However any alternative fuel must meet a range of criteria to become a viable option. Key among them is the requirement that it can deliver emissions reductions over its full life-cycle. For a set of fuels comprising both conventional and alternative fuels together with associated production pathways this paper presents a life-cycle assessment with respect to six emissions species: local pollutants sulphur oxides nitrogen oxides and particulate matter; and greenhouse gases carbon dioxide methane and nitrous oxide. While the analysis demonstrates that no widely available fuel exists currently to deliver on both motivations some alternative fuel options have the potential if key barriers can be overcome. Hydrogen or other synthetic fuels rely on decarbonisation of both energy input to production and other feedstock materials to deliver reductions in greenhouse gas emissions. Similarly bio-derived fuels can be an abatement option but only if it can be ensured that land-use change whilst growing biomass does not impact wider potential savings and the sector is able to compete sufficiently for their use. These examples show that crucial barriers are located upstream in the respective fuel life-cycle and that the way to overcome them may reside beyond the scope of the shipping sector alone.
Fuel Cell and Hydrogen Technology- Europe's Journey to a Greener World
Nov 2017
Publication
On the occasion of its 10th Stakeholder forum the FCH JU published a unique and exclusive book. This book sets out the story behind both the FCH JU and fuel cell and hydrogen technology in Europe. It reviews the events leading to its creation and examines the achievements that have allowed Europe to take a leading role in fuel cell and hydrogen excellence. It also looks at what this investment in fuel cell technology will mean for the EU in the coming years
Fuel Cells and Hydrogen Technologies in Europe: Financial and Technology Outlook on the European Sector Ambition 2014-2020
Nov 2011
Publication
Sustainable secure and competitive energy supply and transport services are at the heart of the EU2020 strategy towards a low carbon and inclusive economy geared towards a reduction of 80% of CO2 emissions by 2050. This objective has been endorsed by the European Institutions and Member States. It is widely recognised that a technological shift and the deployment of new clean technologies are critical for a successful transition to such a new sustainable economy. Furthermore in addition to bringing a healthier environment and securing energy supply innovation will provide huge opportunities for the European economy. However this paradigm shift will not be purely driven by the market. A strong and determined commitment of public institutions and the private sector together are necessary to support the European political ambition. The period 2014-2020 will be critical to ensure that the necessary investments are realized to support the EU2020 vision. In terms of hydrogen and fuel cell technologies significant investments are required for (a) transportation for scaling up the car fleet and building up of refuelling infrastructure needs (b) hydrogen production technologies to integrate renewable intermittent power sources to the electrical grid (wind and solar) (c) stationary fuel cell applications with large demonstration projects in several European cities and (d) identified early markets (material handling vehicles back-up power systems) to allow for volume developments and decrease of system-costs.<br/>This Report summarizes the sector’s financial ambition to reach Europe’s objectives in 2020.
Strategies for Joint Procurement of Fuel Cell Buses
Jun 2018
Publication
The Fuel Cells and Hydrogen Joint Undertaking (FCH JU) has supported a range of initiatives in recent years designed to develop hydrogen fuel cell buses to a point where they can fulfil their promise as a mainstream zero emission vehicle for public transport.<br/>Within this study 90 different European cities and regions have been supported in understanding the business case of fuel cell bus deployment and across these locations. The study analyses the funding and financing for fuel cell bus deployment to make them become a mainstream zero emission choice for public transport providers in cities and regions across Europe. It also outlines possible solutions for further deployment of FC buses beyond the subsidised phase.<br/>In the light of the experience of the joint tender process in the UK and in Germany the study highlights best practices for ordering fuel cell buses. Other innovative instruments explored in other countries for the orders of large quantities of fuel cells buses are presented: Special Purpose Vehicles and centralised purchase office. Finally the study deeply analyses the funding and financing for fuel cell bus deployment to make them become a mainstream zero emission choice for public transport providers in cities and regions across Europe.
CFD Simulations of Filling and Emptying of Hydrogen Tanks
Jun 2016
Publication
During the filling of hydrogen tanks high temperatures can be generated inside the vessel because of the gas compression while during the emptying low temperatures can be reached because of the gas expansion. The design temperature range goes from −40 °C to 85 °C. Temperatures outside that range could affect the mechanical properties of the tank materials. CFD analyses of the filling and emptying processes have been performed in the HyTransfer project. To assess the accuracy of the CFD model the simulation results have been compared with new experimental data for different filling and emptying strategies. The comparison between experiments and simulations is shown for the temperatures of the gas inside the tank for the temperatures at the interface between the liner and the composite material and for the temperatures on the external surface of the vessel.
Influence of the Gas Injector Configuration on the Temperature Evolution During Refueling of On-board Hydrogen Tanks
Jul 2016
Publication
In this article we show a refuelling strategy analysis using different injector configurations to refuel a 70 MPa composite reinforced type 4 tank. The gas has been injected through single openings of different diameters (3 mm 6 mm and 10 mm) and alternatively through multiple small holes (4 × 3 mm). For each injector configuration slow (12 min) and faster (3 min) fillings have been performed. The gas temperature has been measured at different positions inside the tank as well as the temperatures of the wall materials at various locations: on the external surface and at the interface between the liner and the fiber reinforced composite. In general the larger the injector diameter and the slower the filling the higher the chance that the gas develops vertical temperature gradients (a so-called gas temperature stratification) resulting in higher than average temperatures near the top of the tank and lower than average at its bottom. While the single 3 mm opening injector causes homogeneous gas temperatures for both filling speeds both the 6 mm and 10 mm opening injectors induce gas temperature stratification during the 12 min fillings. The injector with multiple holes has an area comparable to the 6 mm single opening injector: in general this more complex geometry tends to limit the inhomogeneity of gas temperatures during slow fillings. When gas temperature stratification develops the wall materials temperature is also locally affected. This results in a higher than average temperature at the top of the tank and higher the slower the filling.
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