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A New Path towards Sustainable Energy Transition: Techno-Economic Feasibility of a Complete Hybrid Small Modular Reactor/Hydrogen (SMR/H2) Energy System
Oct 2023
Publication
Small modular reactors (SMRs) are nuclear reactors with a smaller capacity than traditional large-scale nuclear reactors offering advantages such as increased safety flexibility and cost-effectiveness. By producing zero carbon emissions SMRs represent an interesting alternative for the decarbonization of power grids. Additionally they present a promising solution for the production of hydrogen by providing large amounts of energy for the electrolysis of water (pink hydrogen). The above hint at the attractiveness of coupling SMRs with hydrogen production and consumption centers in order to form clusters of applications which use hydrogen as a fuel. This work showcases the techno-economic feasibility of the potential installation of an SMR system coupled with hydrogen production the case study being the island of Crete. The overall aim of this approach is the determination of the optimal technical characteristics of such a system as well as the estimation of the potential environmental benefits in terms of reduction of CO2 emissions. The aforementioned system which is also connected to the grid is designed to serve a portion of the electric load of the island while producing enough hydrogen to satisfy the needs of the nearby industries and hotels. The results of this work could provide an alternative sustainable approach on how a hydrogen economy which would interconnect and decarbonize several industrial sectors could be established on the island of Crete. The proposed systems achieve an LCOE between EUR 0.046/kWh and EUR 0.052/kWh while reducing carbon emissions by more than 5 million tons per year in certain cases.
Safety Challenges Related to the Use of Hydrogen-Natural Gas Blends in Gas Turbines
Sep 2023
Publication
In a context of the decarbonization of the power sector the gas turbine manufacturers are expected tohandle and burn hydrogen or hydrogen/natural gas mixtures. This evolution is conceptually simple in order to displace CO2 emissions by H2O in the combustion exhaust but raises potential engineering andsafety related questions. Concerning the safety aspect the flammability domain is wider and the laminar flame speed is higher for hydrogen than for natural gas. As a result handling fuels with increased hydrogen concentration should a priori lead to an increased the risk of flammable cloud formation with air and also increase the potential explosion violence.<br/>A central topic for the gas turbine manufacturer is the quantification of the hydrogen fuel content from which the explosion risk increases significantly when compared with the use of natural gas. This work will be focused on a risk study of the fuel supply piping of a gas turbine in a scenario where mixing between fuel and air would occur. The pipes are a few dozens of meters long and show singularities: elbows connections with other lines … They are operated at high temperature and atmospheric or high pressure.<br/>The paper will first highlight through CFD modelling the impact of increasing hydrogen content in the fuel on the explosion risk based on a geometry representative of a realistic system. Second the quantification of the explosion effects will be addressed. Some elements of the bibliography relative to flame propagation in pipes will be recalled and put in sight of the characteristics of the industrial case. Finally a CFD model proposed recently for accounting for methane or hydrogen flames propagating in long open steel tubes was used to assess a hydrogen fuel content from which the flame can strongly accelerate and generate significative pressure effects for a flammable mixture initially at atmospheric conditions.
Energy and Greenhouse Gases Life Cycle Assessment of Electric and Hydrogen Buses: A Real-world Case Study in Bolzano Italy
May 2023
Publication
The transportation sector plays an important role in the current effort towards the control of global warming. Against this backdrop electrification is currently attracting attention as the life cycle environmental performance of different powertrain technologies is critically assessed. In this study a life cycle analysis of the public transportation buses was performed. The scope of the analysis is to compare the energy and global warming performances of the different powertrain technologies in the city fleet: diesel full electric and hydrogen buses. Real world monitored data were used in the analysis for the energy consumptions of the buses and to produce hydrogen in Bolzano. Compared to the traditional diesel buses the electric vehicles showed a 43% reduction of the non-renewable primary energy demand and a 33% of the global warming potential even in the worst consequential scenario considered. The switch to hydrogen buses leads to very different environmental figures: from very positive if it contributes to a further penetration of renewable electricity to hardly any difference if hydrogen from steam-methane reforming is used to clearly negative ones (approximately doubling the impacts) if a predominantly fossil electricity mix is used in the electrolysis.
Computational Fluid Dynamics Simulations of Hydrogen Releases and Vented Deflagrations in Large Enclosures
Nov 2019
Publication
This paper presents model predictions obtained with the CFD tool FLACS for hydrogen releases and vented deflagrations in containers and larger enclosures. The paper consists of two parts. The first part compares experimental results and model predictions for two test cases: experiments performed by Gexcon in 20-foot ISO containers (volume 33 m3 ) as part of the HySEA project and experiments conducted by SRI International and Sandia National Laboratories in a scaled warehouse geometry (volume 45.4 m3 ). The second part explores the use of the model system validated in the first part to accidental releases of hydrogen from forklift trucks inside a full-scale warehouse geometry (32 400 m3 ). The results demonstrate the importance of using realistic and reasonably accurate geometry models of the systems under consideration when performing CFD-based risk assessment studies. The discussion highlights the significant inherent uncertainty associated with quantitative risk assessments for vented hydrogen deflagrations in complex geometries. The suggestions for further work include a pragmatic approach for developing empirical correlations for pressure loads from vented hydrogen deflagrations in industrial warehouses with hydrogen-powered forklift trucks.
Energy Management in a Super-Tanker Powered by Solar, Wind, Hydrogen and Boil-Off Gas for Saving CO2 Emissions
Apr 2024
Publication
In terms of energy generation and consumption ships are autonomous isolated systems with power demands varying according to the type of ship: passenger or commercial. The power supply in modern ships is based on thermal engines-generators which use fossil fuels marine diesel oil (MDO) and liquefied natural gas (LNG). The continuous operation of thermal engines on ships during cruises results in increased emissions of polluting gases mainly CO/CO2 . The combination of renewable energy sources (REs) and triple-fuel diesel engines (TFDEs) can reduce CO/CO2 emissions resulting in a “greener” interaction between ships and the ecosystem. This work presents a new control method for balancing the power generation and the load demands of a ship equipped with TFDEs fuel cells (FCs) and REs based on a real and accurate model of a super-tanker and simulation of its operation in real cruise conditions. The new TFDE technology engines are capable of using different fuels (marine diesel oil heavy fuel oil and liquified natural gas) producing the power required for ship operation as well as using compositions of other fuels based on diesel aiming to reduce the polluting gases produced. The energy management system (EMS) of a ship is designed and implemented in the structure of a finite state machine (FSM) using the logical design of transitions from state to state. The results demonstrate that further reductions in fossil fuel consumption as well as CO2 emissions are possible if ship power generation is combined with FC units that consume hydrogen as fuel. The hydrogen is produced locally on the ship through electrolysis using the electric power generated by the on-board renewable energy sources (REs) using photovoltaic systems (PVs) and wind energy conversion turbines (WECs).
Energy Storage Strategy - Phase 3
Feb 2023
Publication
This report evaluates the main options to provide required hydrogen storage capacity including the relevant system-level considerations and provides recommendations for further actions including low-regrets actions that are needed in a range of scenarios.
The Role of Electricity-based Hydrogen in the Emerging Power-to-X Economy
Aug 2023
Publication
As energy system research into high shares of renewables has developed so have the perspectives of the fundamental nature of a highly renewable economy. Early energy system transition research suggested that current fossil fuel energy systems would transition to a ‘Hydrogen Economy’ whereas more recent insights suggest that a ‘Power-to-X Economy’ may be a more appropriate term as renewable electricity will become both the most important primary and final energy carrier through various Power-to-X conversion routes across the energy system. This paper provides a detailed overview on research insights of recent years on the core elements of the Power-to-X Economy and the role of hydrogen based on latest research results. These results suggest that by 2050 upwards of 61737 TWhLHV of hydrogen will be required to fully defossilise the global energy-industry system. Hydrogen therefore emerges as a central intermediate energy carrier and its relevance is driven by significant cost reductions in renewable electricity especially of solar photovoltaics and wind power. Efficiency and cost drivers position direct electrification as the primary solution for defossilisation of the global energy-industry system; however electron-to-molecule routes are essential for the large subset of remaining energy-related demands including chemical production marine and aviation fuels and steelmaking.
Linking Cost Decline and Demand Surge in the Hydrogen Market: A Case Study in China
Jun 2023
Publication
Hydrogen is crucial in achieving global energy transition and carbon neutrality goals. Existing market estimates typically presume linear or exponential growth but fail to consider how market demand responds to the declining cost of underlying technologies. To address this this study utilizes a learning curve model to project the cost of electrolyzers and its subsequent impact on hydrogen market aligning with a premise that the market demand is proportional to the cost of hydrogen. In a case study of China’s hydrogen market projecting from 2020 to 2060 we observed substantial differences in market evolution compared to exponential growth scenarios. Contrary to exponential growth scenarios China’s hydrogen market experiences faster growth during the 2020–2040 period rather than later. Such differences underscore the necessity for proactive strategic planning in emerging technology markets particularly for those experiencing rapid cost decline such as hydrogen. The framework can also be extended to other markets by using local data providing valuable insights to investors policymakers and developers engaged in the hydrogen market.
Renewable Methanol Synthesis
Oct 2019
Publication
Renewable methanol production is an emerging technology that bridges the gap in the shift from fossil fuel to renewable energy. Two thirds of the global emission of CO2 stems from humanity’s increasing energy need from fossil fuels. Renewable energy mainly from solar and wind energy suffers from supply intermittency which current grid infrastructures cannot accommodate. Excess renewable energy can be harnessed to power the electrolysis of water to produce hydrogen which can be used in the catalytic hydrogenation of waste CO2 to produce renewable methanol. This review considers methanol production in the current context regionally for Europe which is dominated by Germany and globally by China. Appropriate carbon-based feedstock for renewable methanol production is considered as well as state-of-the-art renewable hydrogen production technologies. The economics of renewable methanol production necessitates the consideration of regionally relevant methanol derivatives. The thermodynamics kinetics catalytic reaction mechanism operating conditions and reactor design are reviewed in the context of renewable methanol production to reveal the most up to date understanding.
A Techno-economic Analysis of Cross-regional Renewable Hydrogen Supply Routes in China
Jun 2023
Publication
The cross-regional renewable hydrogen supply is significant for China to resolve the uneven distribution of renewable energy and decarbonize the transportation sector. Yet the economic comparison of various hydrogen supply routes remains obscure. This paper conducts a techno-economic analysis on six hydrogen supply routes for hydrogen refueling stations including gas-hydrogen tube-trailer gas-hydrogen pipeline liquid-hydrogen truck natural gas pipeline MeOH truck and NH3 truck. Furthermore the impacts of three critical factors are examined including electrolyzer selection transportation distance and electricity price. The results indicate that with a transport distance of 2000 km the natural gas pipeline route offers the lowest cost while the gas-hydrogen tube-trailer route is not economically feasible. The gas-hydrogen pipeline route shows outstanding cost competitiveness between 200 and 2000 km while it is greatly influenced by the utilization rate. The liquid-hydrogen truck route demonstrates great potential with the electricity price decreasing. This study may provide guidance for the development of the cross-regional renewable hydrogen supply for hydrogen refueling stations in China.
Modelling Methodologies to Design and Control Renewables and Hydrogen-Based Telecom Towers Power Supply Systems
Aug 2023
Publication
Proton exchange membrane fuel cell (PEMFCS) and electrolyser (PEMELS) systems together with a hydrogen storage tank (HST) are suitable to be integrated with renewable microgrids to cover intermittency and fully exploit the excess of electrical energy. Such an integration perfectly fits telecom tower power supply needs both in off-grid and grid-connected sites. In this framework a model-based tool enabling both optimal sizing and proper year-through energy management of both the above applications is proposed. Respectively the islanded optimisation is performed considering two economic indices i.e. simple payback (SPB) and levelised cost of energy (LCOE) together with two strategies of hydrogen tank management charge sustaining and depleting and also accounting for the impact of grid extension distance. On the other hand the grid connection is addressed through the dynamic programming method while downsizing PEMELS and HST sizes to improve techno-economic effectiveness thanks to grid contribution towards renewables curtailment issues mitigation. For both the above introduced HST management strategies a reduction of more than 70% of the nominal PEMELS power and 90% of the HST size which will in turn lead to SPB and LCOE being reduced by 80% and 60% in comparison to the islanded case respectively is achieved. Furthermore the charge depleting strategy relying on possible hydrogen purchase interestingly provides an SPB and LCOE of 9% and 7% lower than the charge sustaining one.
Jet Flame Risk Analysis for Safe Response to Hydrogen Vehicle Accidents
Jun 2023
Publication
With an increase in the use of eco-friendly vehicles such as hybrid electric and hydrogen vehicles in response to the global climate crisis accidents related to these vehicles have also increased. Numerical analysis was performed to optimize the safety of first responders responding to hydrogen vehicle accidents wherein hydrogen jet flames occur. The influence range of the jet flame generated through a 1.8-mm-diameter nozzle was analyzed based on five discharge angles (90 75 60 45 and 30◦ ) between the road surface and the downward vertical. As the discharge angle decreases toward the road surface the risk area that could cause damage moves from the center of the vehicle to the rear; at a discharge angle of 90◦ the range above 9.5 kW/m2 was 1.59 m and 4.09 m to the front and rear of the vehicle respectively. However at a discharge angle of 30◦ it was not generated at the front but was 10.39 m to the rear. In response to a hydrogen vehicle accident first responders should perform rescue activities approaching from a diagonal direction to the vehicle front to minimize injury risk. This study can be used in future hydrogen vehicle design to develop the response strategy of the first responders.
A Model for Assessing the Risk of Liquid Hydrogen Transport through Road Tunnels
Sep 2023
Publication
Among the new energy carriers aimed at reducing greenhouse gas emissions the use of hydrogen is expected to grow significantly in various applications and sectors (i.e. industrial commercial transportation etc.) due to its high energy content by weight and zero carbon emissions. The increasingly widespread use of hydrogen will require massive distribution from production sites to final consumers and the delivery by means of liquid hydrogen road tankers may be a suitable cost-effective option for market penetration in the short-medium term. Liquid hydrogen (LH2) presents different hazards compared to gaseous hydrogen and an accidental release in confined spaces such as road tunnels might lead to the formation of a flammable hydrogen cloud that might deflagrate or even detonate. Nevertheless the potential negative effects on users in the event of accidental leakage of liquid hydrogen from a tanker in road tunnels so far have not been sufficiently investigated. Therefore a 3D Computational Fluid Dynamics model for the release of LH2 and its dispersion within a road tunnel was developed in this study. The proposed model was validated by a comparison with certain experimental and numerical studies found in the literature. Such modeling is demanding for long tunnels. Therefore the results of the simulations (e.g. the amount of hydrogen contained within the cloud) were combined with established simplified consequence methods to estimate the overpressures generated from a potential hydrogen deflagration. This was then used to evaluate the effects on users while evacuating from the tunnel. The findings showed that the worst scenario is when the release is in the middle of the tunnel length and the ignition occurs 90 s after the leakage.
A Review of Current Advances in Ammonia Combustion from the Fundamentals to Applications in Internal Combustion Engines
Aug 2023
Publication
The energy transition from hydrocarbon-based energy sources to renewable and carbon-free energy sources such as wind solar and hydrogen is facing increasing demands. The decarbonization of global transportation could come true via applying carbon-free fuel such as ammonia especially for internal combustion engines (ICEs). Although ammonia has advantages of high hydrogen content high octane number and safety in storage it is uninflammable with low laminar burning velocity thus limiting its direct usage in ICEs. The purpose of this review paper is to provide previous studies and current research on the current technical advances emerging in assisted combustion of ammonia. The limitation of ammonia utilization in ICEs such as large minimum ignition energy lower flame speed and more NOx emission with unburned NH3 could be solved by oxygen-enriched combustion ammonia–hydrogen mixed combustion and plasma-assisted combustion (PAC). In dual-fuel or oxygen-enriched NH3 combustion accelerated flame propagation speeds are driven by abundant radicals such as H and OH; however NOx emission should be paid special attention. Furthermore dissociating NH3 in situ hydrogen by non-noble metal catalysts or plasma has the potential to replace dual-fuel systems. PAC is able to change classical ignition and extinction S-curves to monotonic stretching which makes low-temperature ignition possible while leading moderate NOx emissions. In this review the underlying fundamental mechanism under these technologies are introduced in detail providing new insight into overcoming the bottleneck of applying ammonia in ICEs. Finally the feasibility of ammonia processing as an ICE power source for transport and usage highlights it as an appealing choice for the link between carbon-free energy and power demand.
Study on Hydrogen Substitution in a Compressed Natural Gas Spark-ignition Passenger Car Engine
Jun 2023
Publication
Hydrogen substitution in applications fueled by compressed natural gas arises as a potential alternative to fossil fuels and it may be the key to an effective hydrogen economy transition. The reduction of greenhouse gas emissions especially carbon dioxide and unburned methane as hydrogen is used in transport and industry applications makes its use an attractive option for a sustainable future. The purpose of this research is to examine the gradual adoption of hydrogen as a fuel for light-duty transportation. Particularly the study focuses on evaluating the performance and emissions of a single-cylinder port fuel injection spark-ignition engine as hydrogen is progressively increased in the natural gas-based fuel blend. Results identify the optimal conditions for air dilution and engine operation parameters to achieve the best performance. They corroborate that the dilution rate has to be adjusted to control pollutant emissions as the percentage of hydrogen is increased. Moreover the study identifies the threshold for hydrogen substitution below which the reduction of carbon dioxide emissions due to efficiency gains is negligible compared to the reduction of the carbon content in the fuel blend. These findings will help reduce the environmental footprint of light-duty transportation not only in the long term but also in the short and medium terms.
Review of Fuel Cell Technologies and Applications for Sustainable Microgrid Systems
Aug 2020
Publication
The shift from centralized to distributed generation and the need to address energy shortage and achieve the sustainability goals are among the important factors that drive increasing interests of governments planners and other relevant stakeholders in microgrid systems. Apart from the distributed renewable energy resources fuel cells (FCs) are a clean pollution-free highly efficient flexible and promising energy resource for microgrid applications that need more attention in research and development terms. Furthermore they can offer continuous operation and do not require recharging. This paper examines the exciting potential of FCs and their utilization in microgrid systems. It presents a comprehensive review of FCs with emphasis on the developmental status of the different technologies comparison of operational characteristics and the prevailing techno-economic barriers to their progress and the future outlook. Furthermore particular attention is paid to the applications of the FC technologies in microgrid systems such as grid-integrated grid-parallel stand-alone backup or emergency power and direct current systems including the FC control mechanisms and hybrid designs and the technical challenges faced when employing FCs in microgrids based on recent developments. Microgrids can help to strengthen the existing power grid and are also suitable for mitigating the problem of energy poverty in remote locations. The paper is expected to provide useful insights into advancing research and developments in clean energy generation through microgrid systems based on FCs.
Divergent Consumer Preferences and Visions for Cooking and Heating Technologies in the United Kingdom: Make Our Homes Clean, Safe, Warm and Smart!
Aug 2023
Publication
Decarbonising the global housing stock is imperative for reaching climate change targets. In the United Kingdom hydrogen is currently being tested as a replacement fuel for natural gas which could be used to supply low-carbon energy to parts of the country. Transitioning the residential sector towards a net-zero future will call for an inclusive understanding of consumer preferences for emerging technologies. In response this paper explores consumer attitudes towards domestic cooking and heating technologies and energy appliances of the future which could include a role for hydrogen hobs and boilers in UK homes. To access qualitative evidence on this topic we conducted ten online focus groups (N = 58) with members of the UK public between February and April 2022. The study finds that existing gas users wish to preserve the best features of gas cooking such as speed responsiveness and controllability but also desire the potential safety and aesthetic benefits of electric systems principally induction hobs. Meanwhile future heating systems should ensure thermal comfort ease of use energy efficiency and smart performance while providing space savings and noise reduction alongside demonstrable green benefits. Mixed-methods multigroup analysis suggests divergence between support levels for hydrogen homes which implies a degree of consumer heterogeneity. Foremost we find that domestic hydrogen acceptance is positively associated with interest and engagement with renewable energy and fuel poverty pressures. We conclude that internalising the perspectives of consumers is critical to enabling constructive socio-technical imaginaries for low-carbon domestic energy futures.
The Economic Impact and Carbon Footprint Dependence of Energy Management Strategies in Hydrogen-Based Microgrids
Sep 2023
Publication
This paper presents an economic impact analysis and carbon footprint study of a hydrogenbased microgrid. The economic impact is evaluated with respect to investment costs operation and maintenance (O&M) costs as well as savings taking into account two different energy management strategies (EMSs): a hydrogen-based priority strategy and a battery-based priority strategy. The research was carried out in a real microgrid located at the University of Huelva in southwestern Spain. The results (which can be extrapolated to microgrids with a similar architecture) show that although both strategies have the same initial investment costs (EUR 52339.78) at the end of the microgrid lifespan the hydrogen-based strategy requires higher replacement costs (EUR 74177.4 vs. 17537.88) and operation and maintenance costs (EUR 35254.03 vs. 34877.08) however it provides better annual savings (EUR 36753.05 vs. 36282.58) and a lower carbon footprint (98.15% vs. 95.73% CO2 savings) than the battery-based strategy. Furthermore in a scenario where CO2 emission prices are increasing the hydrogen-based strategy will bring even higher annual cost savings in the coming years.
Numerical Simulation of Hydrogen Diffusion in Cement Sheath of Wells Used for Underground Hydrogen Storage
Jul 2023
Publication
The negative environmental impact of carbon emissions from fossil fuels has promoted hydrogen utilization and storage in underground structures. Hydrogen leakage from storage structures through wells is a major concern due to the small hydrogen molecules that diffuse fast in the porous well cement sheath. The second-order parabolic partial differential equation describing the hydrogen diffusion in well cement was solved numerically using the finite difference method (FDM). The numerical model was verified with an analytical solution for an ideal case where the matrix and fluid have invariant properties. Sensitivity analyses with the model revealed several possibilities. Based on simulation studies and underlying assumptions such as non-dissolvable hydrogen gas in water present in the cement pore spaces constant hydrogen diffusion coefficient cement properties such as porosity and saturation etc. hydrogen should take about 7.5 days to fully penetrate a 35 cm cement sheath under expected well conditions. The relatively short duration for hydrogen breakthrough in the cement sheath is mainly due to the small molecule size and high hydrogen diffusivity. If the hydrogen reaches a vertical channel behind the casing a hydrogen leak from the well is soon expected. Also the simulation result reveals that hydrogen migration along the axial direction of the cement column from a storage reservoir to the top of a 50 m caprock is likely to occur in 500 years. Hydrogen diffusion into cement sheaths increases with increased cement porosity and diffusion coefficient and decreases with water saturation (and increases with hydrogen saturation). Hence cement with a low water-to-cement ratio to reduce water content and low cement porosity is desirable for completing hydrogen storage wells.
Flame Visibility in Hydrogen Appliances
Sep 2023
Publication
One of the benefits of the direct use of hydrogen is its ability to be burned in a similar way to natural gas using appliances with which the community is already familiar. This is particularly true for applications where electrification is neither practicable nor desirable. One common example is domestic cooking stoves where the open flame offers numerous real and perceived benefits to the chef. Similarly many commercial and industrial appliances rely on the unique properties of combustion to achieve a desired purpose that cannot readily be replaced by an alternative to an open flame. Despite the enormous decarbonisation potential of the direct replacement of natural gas with hydrogen there are some operational constraints due to the different burning characteristics of hydrogen. One of the challenges is the low visible light emission from hydrogen flames. The change in visible radiation from the combustion of hydrogen compared with natural gas is a safety concern whereby visual observation of a flame may be difficult. This paper aims to provide clarity on the visual appearance of hydrogen flames via a series of measurements of flame visibility and emission spectra accompanied by the assessment of strategies to improve the safe use of hydrogen.
Investigation of the Suitability of Viper: Blast CFD Software for Hydrogen and Vapor Cloud Explosions
Sep 2023
Publication
Many simplified methods for estimating blast loads from a hydrogen or vapor cloud explosion are unable to take into account the accurate geometry of confining spaces obstacles or landscape that may significantly interact with the blast wave and influence the strength of blast loads. Computation fluid dynamics (CFD) software Viper::Blast which was originally developed for the simulation of the detonation of high explosives is able to quickly and easily model geometry for blast analyses however its use for vapor cloud explosions and deflagrations is not well established. This paper describes the results of an investigation into the suitability of Viper::Blast for use in modeling hydrogen deflagration and detonation events from various experiments in literature. Detonation events have been captured with a high degree of detail and relatively little uncertainty in inputs while deflagration events are significantly more complex. An approach is proposed that may allow for a reasonable bounding of uncertainty potentially leading to an approach to CFD-based Monte Carlo analyses that are able to address a problem’s true geometry while remaining reasonably pragmatic in terms of run-time and computational investment. This will allow further exploration of practical CFD application to inform hydrogen safety in the engineering design assessment and management of energy mobility and transport systems infrastructure and operations.
Mechanistic Evaluation of the Reservoir Engineering Performance for the Underground Hydrogen Storage in a Deep North Sea Aquifer
Jul 2023
Publication
Underground hydrogen storage (UHS) in aquifers salt caverns and depleted hydrocarbon reservoirs allows for the storage of larger volumes of H2 compared to surface storage in vessels. In this work we investigate the impact of aquifer-related mechanisms and parameters on the performance of UHS in an associated North Sea aquifer using 3D numerical compositional simulations. Simulation results revealed that the aquifer's permeability heterogeneity has a significant impact on the H2 recovery efficiency where a more homogenous rock would lead to improved H2 productivity. The inclusion of relative permeability hysteresis resulted in a drop in the H2 injectivity and recovery due to H2 discontinuity inside the aquifer which leads to residual H2 during the withdrawal periods. In contrast the effects of hydrogen solubility and hydrogen diffusion were negligible when studied each in isolation from other factors. Hence it is essential to properly account for hysteresis and heterogeneity when evaluating UHS in aquifers.
Optimization of a Hydrogen-based Hybrid Propulsion System Under Aircraft Performance Constraints
Aug 2021
Publication
This paper addresses the topic of the conceptual design of a regional aircraft with hybrid electric propulsion based on hydrogen fuel cells. It aims at providing an optimization-based method to design a hybrid propulsive system comprising two power sources (jet fuel and hydrogen) for the generation of the required propulsive power and at studying the impact of fuel cell technologies on the aircraft performances. Indeed by performing optimizations for two hybrid propulsive systems using either low temperature or high temperature Proton-exchange membrane fuel cells this study provides a preliminary assessment of the impact of the fuel cell operating temperature on the system design and the overall aircraft performance. First this paper gives a description of the baseline turboprop regional aircraft with a focus on its high speed and low speed flight performances which will serve as requirements for the design of the hybrid aircraft. Then the hybrid electric architecture and the sizing models of the propulsion system are presented. Finally optimizations are performed to design two parallel hybrid propulsive systems based on different fuel cells technologies and aimed at minimizing the block fuel per passenger over a mission of 200 nm. Results show how the proposed methodology and models lead to design two propulsive systems capable of reducing the fuel consumption per passenger by more than 30% compared to the baseline aircraft. The study also shows that the choice of fuel cell operating temperature has a first-order impact on the total mass of the propulsive system due to the higher cooling requirement of the low temperature fuel cells.
Assessing Techno-economic Feasibility of Cogeneration and Power to Hydrogen Plants: A Novel Dynamic Simulation Model
Aug 2023
Publication
Green hydrogen technologies are crucial for decarbonization purposes while cogeneration offers efficient heat and power generation. Integrating green hydrogen and cogeneration brings numerous benefits optimizing energy utilization reducing emissions and supporting the transition to a sustainable future. While there are numerous studies examining the integration of combined heat and power with Power to Gas certain aspects still requires a more detailed analysis especially for internal combustion engines fuelled by natural gas due to their widespread adoption as one of the primary technologies in use. Therefore this paper presents a comprehensive numerical 0-D dynamic simulation model implemented within the TRNSYS environment considering internal combustion engines fuelled by natural gas. Specifically the study focuses on capturing CO2 from exhaust gases and producing green hydrogen from electrolysis. Based on these considerations two configurations are proposed: the first involves the methanation reaction while the second entails the production of a hydromethane mixture. The aim is to evaluate the technical and economic feasibility of these configurations and compare their performance within the Power to Gas framework. Self-sufficiency from the national electricity grid has been almost achieved for the two configurations considering an industrial case. The production of hydromethane allows smaller photovoltaic plant (81 kWp) compared to the production of synthetic methane (670 kWp) where a high quantity of hydrogen is required especially if all the carbon dioxide captured is used in the methanation process. Encouraging economic results with payback times below ten years have been obtained with the use of hydromethane. Moreover hydromethane shows potential residential applications with small required photovoltaic sizes.
Economic Analysis of a Photovoltaic Hydrogen Refueling Station Based on Hydrogen Load
Sep 2023
Publication
With the goal of achieving “carbon peak in 2030 and carbon neutrality in 2060” as clearly proposed by China the transportation sector will face long–term pressure on carbon emissions and the application of hydrogen fuel cell vehicles will usher in a rapid growth period. However true “zero carbon” emissions cannot be separated from “green hydrogen”. Therefore it is of practical significance to explore the feasibility of renewable energy hydrogen production in the context of hydrogen refueling stations especially photovoltaic hydrogen production which is applied to hydrogen refueling stations (hereinafter referred to “photovoltaic hydrogen refueling stations”). This paper takes a hydrogen refueling station in Shanghai with a supply capacity of 500 kg/day as the research object. Based on a characteristic analysis of the hydrogen demand of the hydrogen refueling station throughout the day this paper studies and analyzes the system configuration operation strategy environmental effects and economics of the photovoltaic hydrogen refueling station. It is estimated that when the hydrogen price is no less than 6.23 USD the photovoltaic hydrogen refueling station has good economic benefits. Additionally compared with the conventional hydrogen refueling station it can reduce carbon emissions by approximately 1237.28 tons per year with good environmental benefits.
Improvement of MC Method in SAE J2601 Hydrogen Refuelling Protocol Using Dual-zone Dual-Temperature Model
Sep 2023
Publication
The MC method refuelling protocol in SAE J2601 has been published by the Society of Automotive Engineers (SAE) in order to safely and quickly refuel hydrogen vehicles. For the calculation method of the pressure target to control the refuelling stop we introduced a dual-zone dual-temperature model that distinguishes the hydrogen temperature in the tank from the wall temperature to replace the dual-zone single-temperature model of the original MC method. The total amount of heat transferred by convection between hydrogen and the inner tank wall during the filling process was expressed as an equation of final hydrogen temperature final wall temperature final refuelling time tank inner surface area and the correction factor. The correction factor equations were determined by fitting simulation data from the 0D1D model where hydrogen inside the tank is lumped parameter model (0D) and the tank wall is a one-dimensional model (1D). For the correction factor of the linear equation its first-order coefficient and constant term have a linear relationship with the initial pressure of the storage tank and their R2 values obtained from the fitting are greater than 0.99. Finally we derived a new equation to calculate the final hydrogen temperature which can be combined with the 100% SOC inside the vehicle tank to determine the pressure target. The simulation results show that the final SOC obtained are all greater than 96% using the modified pressure target and the correction factor of the linear equation.
Engineering Models for Refueling Protocol Development: Validation and Recommendations
Sep 2023
Publication
Fouad Ammouri,
Nicola Benvenuti,
Elena Vyazmina,
Vincent Ren,
Guillaume Lodier,
Quentin Nouvelot,
Thomas Guewouo,
Dorine Crouslé,
Rony Tawk,
Nicholas Hart,
Steve Mathison,
Taichi Kuroki,
Spencer Quong,
Antonio Ruiz,
Alexander Grab,
Alexander Kvasnicka,
Benoit Poulet,
Christopher Kutz and
Martin Zerta
The PRHYDE project (PRotocol for heavy duty HYDrogEn refueling) funded by the Clean Hydrogen partnership aims at developing recommendations for heavy-duty refueling protocols used for future standardization activities for trucks and other heavy duty transport systems applying hydrogen technologies. Development of a protocol requires a validated approach. Due to the limited time and budget the experimental data cannot cover the whole possible ranges of protocol parameters such as initial vehicle pressure and temperature ambient and precooling temperatures pressure ramp refueling time hardware specifications etc. Hence a validated numerical tool is essential for a safe and efficient protocol development. For this purpose engineering tools are used. They give good results in a very reasonable computation time of several seconds or minutes. These tools provide the heat parameters estimation in the gas (volume average temperature) and 1D temperature distribution in the tank wall. The following models were used SOFIL (Air Liquide tool) HyFill (by ENGIE) and H2Fills (open access code by NREL). The comparison of modelling results and experimental data demonstrated a good capability of codes to predict the evolution of average gas temperature in function of time. Some recommendations on model validation for the future protocol development are given.
Thermodynamic and Emission Analysis of a Hydrogen/Methane Fueled Gas Turbine
May 2023
Publication
The importance of hydrogen in the effort to decarbonize the power sector has grown immensely in recent years. Previous studies have investigated the effects of mixing hydrogen into natural gas for gas turbine combustors but limited studies have examined the resulting effects hydrogen addition has on the entire system. In this work a thermodynamic model of a gas turbine with combustion chemical kinetics integrated is created and the effects hydrogen addition (0-100 volume percent addition) has on the system performance emissions and combustion kinetics are analyzed. The maximum system performance is achieved when the maximum turbine inlet temperature is reached and the resulting optimal fuel/air equivalence ratio is determined. As hydrogen is added to the fuel mixture the optimal equivalence ratio shifts leaner causing non-linearity in emissions and system performance at optimal conditions. An analysis of variance is conducted and it is shown that isentropic efficiencies of the turbine and compressor influences the system performance the most out of any system parameter. While isentropic efficiencies of the turbine and compressor increase towards 100% an operating regime where the optimal system efficiency cannot be achieved is discovered due to the lower flammability limit of the fuel being reached. This can be overcome by mixing hydrogen into the fuel.
A Hydrogen Vision for the UK
Apr 2023
Publication
This report shows how the infrastructure that exists today can evolve from one based on the supply of fossil fuels to one providing the backbone of a clean hydrogen system. The ambitious government hydrogen targets across the UK will only be met with clarity focus and partnership. The gas networks are ready to play their part in the UK’s energy future. They have a plan know what is needed to deliver it and are taking the necessary steps to do just that.
Comprehensive Techno-economic Assessment of Power Technologies and Synthetic Fuels under Discussion for Ship Applications
Jun 2023
Publication
The decarbonization of the global ship traffic is one of the industry’s greatest challenges for the next decades and will likely only be achieved with the introduction of synthetic fuels. Until now however not one single best technology solution emerged to ideally fit this task. Instead different energy carriers including hydrogen ammonia methanol methane and synthetic diesel are subject of discussion for usage in either internal combustion engines or fuel cells. In order to drive the selection procedure a case study for the year 2030 with all eligible combinations of power technologies and fuels is conducted. The assessment quantifies the technologies’ economic performances for cost-optimized system designs and in dependence of a ship’s mission characteristics. Thereby the influence of trends for electrofuel prices and shipboard volume opportunity costs are examined. Even if gaseous hydrogen is often considered not suitable for large ship applications due to its low volumetric energy density both the comparatively small fuel price and the high efficiency of fuel cells lead to the overall smallest system costs for passages up to 21 days depending on assumed cost parameters. Only for missions longer than seven days fuel cells operating on methanol or ammonia can compete with gaseous hydrogen economically.
CO2 Emissions of Battery Electric Vehicles and Hydrogen Fuel Cell Vehicles
Jun 2023
Publication
During the last few years electric and hydrogen vehicles have become an alternative to cars that use internal combustion engines. The number of electric and hydrogen vehicles sold has increased due to support from local governments and because car manufacturers will stop the production of internal combustion engines in the near future. The emissions of these vehicles while being driven are zero but they still have an impact on the environment due to their fuel. In this article an analysis of carbon dioxide (CO2 ) emissions for two types of vehicles: battery electric vehicles (BEVs) powered by electricity and fuel cell electric vehicles (FCEVs) powered by hydrogen is presented. The analysis considers different values for the mix of power generation and hydrogen production options in comparison to other studies. The CO2 emissions were calculated and compared for the two types of vehicles. The results show that the CO2 emissions of BEVs are lower when compared to FCEVs if the hydrogen is obtained from pollutant sources and is higher if the hydrogen is obtained from nuclear power and renewable energy sources. When compared to conventional combustion engine vehicles BEVs have lower CO2 emissions while the emissions of FCEVs are dependent on the hydrogen production method.
Hydrogenerally - Episode 7: Hydrogen for Heat
Dec 2022
Publication
In this seventh episode Steffan Eldred Hydrogen Innovation Network Knowledge Transfer Manager and Jenni McDonnell MBE Heating and Cooling Knowledge Transfer Manager from Innovate UK KTN discuss why using hydrogen to generate heat is so important and explore the hydrogen economy opportunities and challenges within this sector alongside their special guest Jeff House Head of External Affairs Baxi Boilers.
The podcast can be found on their website.
The podcast can be found on their website.
How to Power the Energy–Water Nexus: Coupling Desalination and Hydrogen Energy Storage in Mini-Grids with Reversible Solid Oxide Cells
Nov 2020
Publication
Sustainable Development Goals establish the main challenges humankind is called to tackle to assure equal comfort of living worldwide. Among these the access to affordable renewable energy and clean water are overriding especially in the context of developing economies. Reversible Solid Oxide Cells (rSOC) are a pivotal technology for their sector-coupling potential. This paper aims at studying the implementation of such a technology in new concept PV-hybrid energy storage mini-grids with close access to seawater. In such assets rSOCs have a double useful effect: charge/discharge of the bulk energy storage combined with seawater desalination. Based on the outcomes of an experimental proof-of-concept on a single cell operated with salty water the operation of the novel mini-grid is simulated throughout a solar year. Simulation results identify the fittest mini-grid configuration in order to achieve energy and environmental optimization hence scoring a renewable penetration of more than 95% marginal CO2 emissions (13 g/kWh) and almost complete coverage of load demand. Sector-coupling co-production rate (desalinated water versus electricity issued from the rSOC) is 0.29 L/kWh.
Exploring the Complexity of Hydrogen Perception and Acceptance Among Key Stakeholders in Norway
Nov 2022
Publication
This article explores the complexity of factors or mechanisms that can influence hydrogen stakeholder perception and acceptance in Norway. We systematically analyze 16 semi-structured in-depth interviews with industry stakeholders at local municipal regional and national levels of interest and authority in Norway. Four empirical dimensions are identified that highlight the need for whole system approaches in hydrogen technology research: (1) several challenges incentives and synergy effects influence the hydrogen transition; (2) transport preferences are influenced by combined needs and limitations; (3) levels of knowledge and societal trust determinant to perceptions of risk and acceptance; and (4) national and international hydrogen stakeholders are crucial to building incentives and securing commitment among key actors. Our findings imply that project management planners engineers and policymakers need to apply a whole system perspective and work across local regional and national levels before proceeding with large-scale development and implementation of the hydrogen supply chain.
Blending Hydrogen from Electrolysis into the European Gas Grid
Jan 2022
Publication
In 2020 the European Commission launched a hydrogen strategy for a climate-neutral Europe setting out the conditions and actions for mainstreaming clean hydrogen along with targets for installing renewable hydrogen electrolysers by 2024 and 2030. Blending hydrogen alongside other gases into the existing gas grid is considered a possible interim first step towards decarbonising natural gas. In the present analysis we modelled electrolytic hydrogen generation as a process connecting two separate energy systems (power and gas). The analysis is based on a projection of the European power and gas systems to 2030 based on the EUCO3232.5 scenario. Multiple market configurations were introduced in order to assess the interplay between diverse power market arrangements and constraints imposed by the upper bound on hydrogen concentration. The study identifies the maximum electrolyser capacity that could be integrated in the power and gas systems the impact on greenhouse gas emissions and the level of price support that may be required for a broad range of electrolyser configurations. The study further attempts to shed some light on the potential side effects of having non-harmonised H2 blending thresholds between neighbouring Member States.
Small-Scale Hybrid and Polygeneration Renewable Energy Systems: Energy Generation and Storage Technologies, Applications, and Analysis Methodology
Dec 2022
Publication
The energy sector is nowadays facing new challenges mainly in the form of a massive shifting towards renewable energy sources as an alternative to fossil fuels and a diffusion of the distributed generation paradigm which involves the application of small-scale energy generation systems. In this scenario systems adopting one or more renewable energy sources and capable of producing several forms of energy along with some useful substances such as fresh water and hydrogen are a particularly interesting solution. A hybrid polygeneration system based on renewable energy sources can overcome operation problems regarding energy systems where only one energy source is used (solar wind biomass) and allows one to use an all-in-one integrated systems in order to match the different loads of a utility. From the point of view of scientific literature medium and large-scale systems are the most investigated; nevertheless more and more attention has also started to be given to small-scale layouts and applications. The growing diffusion of distributed generation applications along with the interest in multipurpose energy systems based on renewables and capable of matching different energy demands create the necessity of developing an overview on the topic of small-scale hybrid and polygeneration systems. Therefore this paper provides a comprehensive review of the technology operation performance and economical aspects of hybrid and polygeneration renewable energy systems in small-scale applications. In particular the review presents the technologies used for energy generation from renewables and the ones that may be adopted for energy storage. A significant focus is also given to the adoption of renewable energy sources in hybrid and polygeneration systems designs/modeling approaches and tools and main methodologies of assessment. The review shows that investigations on the proposed topic have significant potential for expansion from the point of view of system configuration hybridization and applications.
China's Hydrogen Development Strategy in the Context of Double Carbon Targets
Dec 2022
Publication
As a clean low-carbon efficient and renewable energy source hydrogen has gradually become an important energy carrier to combat climate change and achieve sustainable development in the world. China is now facing the stress of realizing the carbon peak and carbon neutrality goals where hydrogen will play a significant role. Against this backdrop to develop China's hydrogen strategy under the carbon peak and carbon neutrality goals this paper explores the hydrogen resource endowment in China presents the concepts such as Hydrogen Ethics and the Hu's Hydrogen Line and discusses the status quo and existing advantages in hydrogen production storage transport and utilization in China. Six major obstacles and challenges that China's hydrogen energy industry is facing are pointed out i.e. cost problem inadequate hydrogen infrastructures low energy efficiency mismatching the development progress of renewable energy insufficient market demand shortcomings in technology and imperfect policy system. Finally five policy suggestions for the future development of China's hydrogen energy industry are proposed as follows: (1) make an action plan as a response to the national hydrogen development plan; (2) build an international and domestic double-cycle hydrogen economic system; (3) incorporate hydrogen into the establishment of a clean low-carbon safe and efficient energy system; (4) accelerate the technological innovation to form advanced hydrogen technologies; and (5) construct hydrogen-oriented industrial clusters/parks to expand the hydrogen utilization market. It is concluded that for meeting the carbon peak and carbon neutrality goals China should leverage the dual advantages of hydrogen as an energy carrier and an industrial raw material allowing the hydrogen industry to play a synergistic role in ensuring the country's energy security promoting the socio-economic transformation and upgrading and protecting the ecological environment thereby providing a technical option and support for China to achieve the ultimate goal of carbon neutrality.
Recent Progress in Catalysts for Hydrogen-Chlorine Regenerative Fuel Cells
Oct 2020
Publication
The increasing energy demand and the subsequent climate change consequences are supporting the search for sustainable alternatives to fossil fuels. In this scenario the link between hydrogen and renewable energy is playing a key role and unitized hydrogen-chlorine (H2-Cl2) regenerative cells (RFCs) have become promising candidates for renewable energy storage. Described herein are the recent advances in cell configurations and catalysts for the different reactions that may take place in these systems that work in both modes: electrolysis and fuel cell. It has been found that platinum (Pt)-based catalysts are the best choice for the electrode where hydrogen is involved whereas for the case of chlorine ruthenium (Ru)-based catalysts are the best candidates. Only a few studies were found where the catalysts had been tested in both modes and recent advances are focused on decreasing the amount of precious metals contained in the catalysts. Moreover the durability of the catalysts tested under realistic conditions has not been thoroughly assessed becoming a key and mandatory step to evaluate the commercial viability of the H2-Cl2 RFC technology.
Net Hydrogen Consumption Minimization of Fuel Cell Hybrid Trains Using a Time-Based Co-Optimization Model
Apr 2022
Publication
With increasing concerns on transportation decarbonization fuel cell hybrid trains (FCHTs) attract many attentions due to their zero carbon emissions during operation. Since fuel cells alone cannot recover the regenerative braking energy (RBE) energy storage devices (ESDs) are commonly deployed for the recovery of RBE and provide extra traction power to improve the energy efficiency. This paper aims to minimize the net hydrogen consumption (NHC) by co-optimizing both train speed trajectory and onboard energy management using a time-based mixed integer linear programming (MILP) model. In the case with the constraints of speed limits and gradients the NHC of co-optimization reduces by 6.4% compared to the result obtained by the sequential optimization which optimizes train control strategies first and then the energy management. Additionally the relationship between NHC and employed ESD capacity is studied and it is found that with the increase of ESD capacity the NHC can be reduced by up to 30% in a typical route in urban railway transit. The study shows that ESDs play an important role for FCHTs in reducing NHC and the proposed time-based co-optimization model can maximize the energy-saving benefits for such emerging traction systems with hybrid energy sources including both fuel cells and ESD.
Influence of Hydrogen Enrichment Strategy on Performance Characteristics, Combustion and Emissions of a Rotary Engine for Unmanned Aerial Vehicles (UAVs)
Dec 2022
Publication
In recent years there has been great interest in Wankel-type rotary engines which are one of the most suitable power sources for unmanned aerial vehicle (UAV) applications due to their high power-to-size and power-to-weight ratios. The purpose of the present study was to investigate the potential of a hydrogen enrichment strategy for the improvement of the performance and reduction of the emissions of Wankel engines. The main motivation behind this study was to make Wankel engines which are already very advantageous for UAV applications even more advantageous by applying the hydrogen enrichment technique. In this study hydrogen addition was implemented in a spark-ignition rotary engine model operating at a constant engine speed of 6000 rpm. The mass fraction of hydrogen in the intake gradually increased from 0% to 10%. Simulation results revealed that addition of hydrogen to the fuel accelerated the flame propagation and increased the burning speed of the fuel the combustion temperature and the peak pressure in the working chamber. These phenomena had a very positive effect on the performance and emissions of the Wankel engine. The indicated mean effective pressure (IMEP) increased by 8.18% and 9.68% and the indicated torque increased by 6.15% and 7.99% for the 5% and 10% hydrogen mass fraction cases respectively compared to those obtained with neat gasoline. In contrast CO emissions were reduced by 33.35% and 46.21% and soot emissions by 11.92% and 20.06% for 5% and 10% hydrogen additions respectively. NOx emissions increased with the application of the hydrogen enrichment strategy for the Wankel engine.
Prospects for the Implementation of Underground Hydrogen Storage in the EU
Dec 2022
Publication
The hydrogen economy is one of the possible directions of development for the European Union economy which in the perspective of 2050 can ensure climate neutrality for the member states. The use of hydrogen in the economy on a larger scale requires the creation of a storage system. Due to the necessary volumes the best sites for storage are geological structures (salt caverns oil and gas deposits or aquifers). This article presents an analysis of prospects for large-scale underground hydrogen storage in geological structures. The political conditions for the implementation of the hydrogen economy in the EU Member States were analysed. The European Commission in its documents (e.g. Green Deal) indicates hydrogen as one of the important elements enabling the implementation of a climate-neutral economy. From the perspective of 2050 the analysis of changes and the forecast of energy consumption in the EU indicate an increase in electricity consumption. The expected increase in the production of energy from renewable sources may contribute to an increase in the production of hydrogen and its role in the economy. From the perspective of 2050 discussed gas should replace natural gas in the chemical metallurgical and transport industries. In the longer term the same process will also be observed in the aviation and maritime sectors. Growing charges for CO2 emissions will also contribute to the development of underground hydrogen storage technology. Geological conditions especially wide-spread aquifers and salt deposits allow the development of underground hydrogen storage in Europe.
Economic Complexity of Green Hydrogen Production Technologies - A Trade Data-based Analysis of Country-sepcific Industrial Preconditions
May 2023
Publication
Countries with high energy demand but limited renewable energy potential are planning to meet part of their future energy needs by importing green hydrogen. For potential exporting countries in addition to sufficient renewable resources industrial preconditions are also relevant for the successful implementation of green hydrogen production value chains. A list of 36 “Green H2 Products” needed for stand-alone hydrogen production plants was defined and their economic complexity was analyzed using international trade data from 1995 to 2019. These products were found to be comparatively complex to produce and represent an opportunity for countries to enter new areas of the product space through green diversification. Large differences were revealed between countries in terms of industrial preconditions and their evolution over time. A detailed analysis of nine MENA countries showed that Turkey and Tunisia already possess industrial know-how in various green hydrogen technology components and perform only slightly worse than potential European competitors while Algeria Libya and Saudi Arabia score the lowest in terms of calculated hydrogen-related green complexity. These findings are supported by statistical tests showing that countries with a higher share of natural resources rents in their gross domestic product score significantly lower on economic and green complexity. The results thus provide new perspectives for assessing the capabilities of potential hydrogen-producing countries which may prove useful for policymakers and investors. Simultaneously this paper contributes to the theory of economic complexity by applying its methods to a new subset of products and using a dataset with long-term coverage.
Thermo-physical Numerical Model for Hydrogen Storage in Underground Tanks and Caverns
Apr 2024
Publication
Compressed hydrogen storage is an energy-efficient alternative to liquefaction and in the absence of underground salt formations reservoirs like rock caverns mining shafts and cased boreholes are gaining traction. The limited reservoir volume constrained by excavation or drilling results in short high-pressure cycles. Thus effective temperature control is crucial to maintain integrity and maximize hydrogen density. This study presents a validated numerical model with open-access code for simulating heat exchange and predicting operating pressure and temperature for underground hydrogen storage in tanks or caverns. The validation encompasses analytical solutions and existing cylindrical models. Results highlight the heat transfer’s impact on hydrogen density and the limited penetration depth of the thermal perturbation underscoring the need for simulating heat transfer across multiple layers especially in restrictive media like cement. Managing injection and extraction flow rates is crucial to limit temperature peaks for larger radius reservoirs where heat transfer is less efficient.
Cryogenic Hydrogen Jet and Flame for Clean Energy Applications: Progress and Challenges
May 2023
Publication
Industries across the world are making the transition to net-zero carbon emissions as government policies and strategies are proposed to mitigate the impact of climate change on the planet. As a result the use of hydrogen as an energy source is becoming an increasingly popular field of research particularly in the aviation sector where an alternative green renewable fuel to the traditional hydrocarbon fuels such as kerosene is essential. Hydrogen can be stored in multiple ways including compressed gaseous hydrogen cryo-compressed hydrogen and cryogenic liquid hydrogen. The infrastructure and storage of hydrogen will play a pivotal role in the realisation of large-scale conversion from traditional fuels with safety being a key consideration. This paper provides a review on previous work undertaken to study the characterisation of both unignited and ignited hydrogen jets which are fundamental phenomena for the utilisation of hydrogen. This includes work that focuses on the near-field flow structure dispersion in the far-field ignition and flame characteristics with multi-physics. The safety considerations are also included. The theoretical models and computational fluid dynamics (CFD) multiphase and reactive flow approaches are discussed. Then an overview of previous experimental work is provided before focusing the review on the existing computational results with comparison to experiments. Upon completion of this review it is highlighted that the complex near-field physics and flow phenomena are areas lacking in research. The near-field flow properties and characteristics are of significant importance with respect to the ignition and combustion of hydrogen.
Preventing Hydrogen Embrittlement: The Role of Barrier Coatings for the Hydrogen Economy
May 2023
Publication
Hydrogen barrier coatings are protective layers consisting of materials with a low intrinsic hydrogen diffusivity and solubility showing the potential to delay reduce or hinder hydrogen permeation. Hydrogen barrier coatings are expected to enable steels which are susceptible to hydrogen embrittlement specifically cost-effective low alloy-steels or light-weight high-strength steels for applications in a hydrogen economy. Predominantly ceramic coating materials have been investigated for this purpose including oxides nitrides and carbides. In this review the state of the art with respect to hydrogen permeation is discussed for a variety of coatings. Al2O3 TiAlN and TiC appear to be the most promising candidates from a large pool of ceramic materials. Coating methods are compared with respect to their ability to produce layers with suitable quality and their potential for scaling up for industrial use. Different setups for the characterisation of hydrogen permeability are discussed using both gaseous hydrogen and hydrogen originating from an electrochemical reaction. Finally possible pathways for improvement and optimisation of hydrogen barrier coatings are outlined.
On the Use of a Hydrogen-Fueled Engine in a Hybrid Electric Vehicle
Dec 2022
Publication
Hybrid electric vehicles are currently one of the most effective ways to increase the efficiency and reduce the pollutant emissions of internal combustion engines. Green hydrogen produced with renewable energies is an excellent alternative to fossil fuels in order to drastically reduce engine pollutant emissions. In this work the author proposes the implementation of a hydrogen-fueled engine in a hybrid vehicle; the investigated hybrid powertrain is the power-split type in which the engine two electric motor/generators and the drive shaft are coupled together by a planetary gear set; this arrangement allows the engine to operate independently from the wheels and thus to exploit the best efficiency operating points. A set of numeric simulations were performed in order to compare the gasoline-fueled engine with the hydrogen-fueled one in terms of the thermal efficiency and total energy consumed during a driving cycle. The simulation results show a mean engine efficiency increase of around 17% when fueled with hydrogen with respect to gasoline and an energy consumption reduction of around 15% in a driving cycle.
Environmental Sustainability Assessment of Large-scale Hydrogen Production Using Prospective Life Cycle Analysis
Nov 2022
Publication
The need for a rapid transformation to low-carbon economies has rekindled hydrogen as a promising energy carrier. Yet the full range of environmental consequences of large-scale hydrogen production remains unclear. Here prospective life cycle analysis is used to compare different options to produce 500 Mt/yr of hydrogen including scenarios that consider likely changes to future supply chains. The resulting environmental and human health impacts of such production levels are further put into context with the Planetary Boundaries framework known human health burdens the impacts of the world economy and the externality-priced production costs that embody the environmental impact. The results indicate that climate change impacts of projected production levels are 3.3–5.4 times higher than the allocated planetary boundary with only green hydrogen from wind energy staying below the boundary. Human health impacts and other environmental impacts are less severe in comparison but metal depletion and ecotoxicity impacts of green hydrogen deserve further attention. Priced-in environmental damages increase the cost most strongly for blue hydrogen (from ∼2 to ∼5 USD/kg hydrogen) while such true costs drop most strongly for green hydrogen from solar photovoltaic (from ∼7 to ∼3 USD/kg hydrogen) when applying prospective life cycle analysis. This perspective helps to evaluate potentially unintended consequences and contributes to the debate about blue and green hydrogen.
Earth-Abundant Electrocatalysts in Proton Exchange Membrane Electrolyzers
Dec 2018
Publication
In order to adopt water electrolyzers as a main hydrogen production system it is critical to develop inexpensive and earth-abundant catalysts. Currently both half-reactions in water splitting depend heavily on noble metal catalysts. This review discusses the proton exchange membrane (PEM) water electrolysis (WE) and the progress in replacing the noble-metal catalysts with earth-abundant ones. The efforts within this field for the discovery of efficient and stable earth-abundant catalysts (EACs) have increased exponentially the last few years. The development of EACs for the oxygen evolution reaction (OER) in acidic media is particularly important as the only stable and efficient catalysts until now are noble-metal oxides such as IrOx and RuOx. On the hydrogen evolution reaction (HER) side there is significant progress on EACs under acidic conditions but there are very few reports of these EACs employed in full PEM WE cells. These two main issues are reviewed and we conclude with prospects for innovation in EACs for the OER in acidic environments as well as with a critical assessment of the few full PEM WE cells assembled with EACs.
Fuel Cell Products for Sustainable Transportation and Stationary Power Generation: Review on Market Perspective
Mar 2023
Publication
The present day energy supply scenario is unsustainable and the transition towards a more environmentally friendly energy supply system of the future is inevitable. Hydrogen is a potential fuel that is capable of assisting with this transition. Certain technological advancements and design challenges associated with hydrogen generation and fuel cell technologies are discussed in this review. The commercialization of hydrogen-based technologies is closely associated with the development of the fuel cell industry. The evolution of fuel cell electric vehicles and fuel cell-based stationary power generation products in the market are discussed. Furthermore the opportunities and threats associated with the market diffusion of these products certain policy implications and roadmaps of major economies associated with this hydrogen transition are discussed in this review.
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