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Compact Heat Integrated Reactor System of Steam Reformer, Shift Reactor and Combustor for Hydrogen Production from Ethanol
Jun 2020
Publication
A compact heat integrated reactor system (CHIRS) of a steam reformer a water gas shift reactor and a combustor were designed for stationary hydrogen production from ethanol. Different reactor integration concepts were firstly studied using Aspen Plus. The sequential steam reformer and shift reactor (SRSR) was considered as a conventional system. The efficiency of the SRSR could be improved by more than 12% by splitting water addition to the shift reactor (SRSR-WS). Two compact heat integrated reactor systems (CHIRS) were proposed and simulated by using COMSOL Multiphysics software. Although the overall efficiency of the CHIRS was quite a bit lower than the SRSR-WS the compact systems were properly designed for portable use. CHIRS (I) design combining the reactors in a radial direction was large in reactor volume and provided poor temperature control. As a result the ethanol steam reforming and water gas shift reactions were suppressed leading to lower hydrogen selectivity. On the other hand CHIRS (II) design combining the process in a vertical direction provided better temperature control. The reactions performed efficiently resulting in higher hydrogen selectivity. Therefore the high performance CHIRS (II) design is recommended as a suitable stationary system for hydrogen production from ethanol.
Installation Permitting Guidance for Hydrogen and Fuel Cell Stationary Applications: UK Version
Jan 2009
Publication
The HYPER project a specific targeted research project (STREP) funded by the European Commission under the Sixth Framework Programme developed an Installation Permitting Guide (IPG) for hydrogen and fuel cell stationary applications. The IPG was developed in response to the growing need for guidance to foster the use and facilitate installation of these systems in Europe. This document presents a modified version of the IPG specifically intended for the UK market. For example reference is made to UK national regulations standards and practices when appropriate as opposed to European ones.<br/>The IPG applies to stationary systems fuelled by hydrogen incorporating fuel cell devices with net electrical output of up to 10 kWel and with total power outputs of the order of 50 kW (combined heat + electrical) suitable for small back up power supplies residential heating combined heat-power (CHP) and small storage systems. Many of the guidelines appropriate for these small systems will also apply to systems up to 100 kWel which will serve small communities or groups of households. The document is not a standard but is a compendium of useful information for a variety of users with a role in installing these systems including design engineers manufacturers architects installers operators/maintenance workers and regulators.<br/>This report and the work it describes were funded by the Health and Safety Executive (HSE). Its contents including any opinions and/or conclusions expressed are those of the authors alone and do not necessarily reflect HSE policy.
Efficient Hydrogen Production Through the Chemical Looping Redox Cycle of YSZ Supported Iron Oxides
Jul 2020
Publication
The chemical looping process where an oxygen carrier is reduced and oxidized in a cyclic manner offers a promising option for hydrogen production through splitting water because of the much higher water splitting efficiency than solar electrocatalytic and photocatalytic process. A typical oxygen carrier has to comprise a significant amount of inert support to maintain stability in multiple redox cycles thereby resulting in a trade-off between the reaction reactivity and stability. Herein we proposed the use of ion-conductive yttria-stabilized zirconia (YSZ) support Fe2O3 to prepare oxygen carriers materials. The obtained Fe2O3/YSZ composites showed high reactivity and stability. Particularly Fe2O3/YSZ-20 (oxygen storage capacity 24.13%) exhibited high hydrogen yield of ∼10.30 mmol·g-1 and hydrogen production rate of ∼0.66 mmol·g-1·min-1 which was twice as high as that of Fe2O3/Al2O3. Further the transient pulse test indicated that active oxygen diffusion was the rate-limiting step during the redox process. The electrochemical impedance spectroscopy (EIS) measurement revealed that the YSZ support addition facilitated oxygen diffusion of materials which contributed to the improved hydrogen production performance. The support effect obtained in this work provides a potentially efficient route for the modification of oxygen carrier materials.
Gas Goes Green: Britain's Hydrogen Network Plan Report
Jan 2021
Publication
Britain stands on the cusp of a world-leading hydrogen revolution and one which we are almost uniquely positioned to take advantage of. With an extensive world-leading gas grid huge amounts of offshore wind resource and liquid energy markets there are few other places as well positioned as the UK to lead the international race to build a hydrogen economy. Published as part of Energy Networks Association’s Gas Goes Green programme Britain’s Hydrogen Network Plan will play a vital role in delivering the UK’s ambitions for hydrogen as set out in the Prime Minister’s Ten Point Plan For A Green Industrial Revolution.<br/>This Plan sets out how Britain’s gas network companies will enable 100% hydrogen to be transported for use in different sectors of the UK economy. It also identifies the wider actions needed to provide hydrogen production and storage showing how transitioning the gas networks to hydrogen will allow hydrogen to play a full role in achieving net zero in the hard to decarbonise sectors such as industry heavy transport and domestic heating saving an estimated 40 million tonnes of CO2 emissions every year. All five of Britain’s gas network companies responsible for owning and operating £24bn of critical national energy infrastructure are committing through this Plan to delivering this work. It forms a key part of their ambition to building the world’s first zero carbon gas grid here in the UK.<br/>Britain’s Hydrogen Network Plan is founded on four tenets that will underpin the role of Britain’s gas network infrastructure in a hydrogen economy. These tenets reflect the breadth and scale of the impact that the transformation of our gas networks will have. They will guide how gas network companies ensure people’s safety in a fast moving and changing energy system. They reflect how the companies will maintain security of supply to our homes and businesses as we move away from the natural gas that has been the bedrock of our energy system for half a century. They will support the public’s ability to choose the right technology so households and businesses can choose the low carbon technologies that are best suited to their needs. And they will deliver jobs and investment so the transition of our gas networks has a lasting and enduring economic impact in communities across the country.<br/>As we look to the future the exciting role that hydrogen has to play in delivering a net zero economy is becoming increasingly clear. We look forward to working closely with the customers we serve the Government and the wider energy industry to turn that ambition into reality.
LES Simulation of Buoyancy Jet From Unintended Hydrogen Release with GASFLOW-MPI
Sep 2017
Publication
Hydrogen leakage is a key safety issue for hydrogen energy application. For hydrogen leakage hydrogen releases with low momentum hence the development of the leakage jet is dominated by both initial momentum and buoyancy. It is important for a computational code to capture the flow characteristics transiting from momentum-dominated jet to buoyancy dominated plume during leakage. GASFLOW-MPI is a parallel computational fluid dynamics (CFD) code which is well validated and widely used for hydrogen safety analysis. In this paper its capability for small scale hydrogen leakage is validated with unintended hydrogen release experiment. In the experiment pure hydrogen is released into surrounding stagnant air through a jet tube on a honeycomb plate with various Froude numbers (Fr). The flow can be fully momentum-dominated at the beginning while the influence of buoyancy increases with the Fr decreases along the streamline. Several quantities of interest including velocity along the centerline radial profiles of the time-averaged H2 mass fraction are obtained to compare with experimental data. The good agreement between the numerical results and the experimental data indicates that GASFLOW-MPI can successfully simulate hydrogen turbulent dispersion driven by both momentum and buoyant force. Different turbulent models i.e. k-ε LES and DES model are analyzed for code performance the result shows that all these three models are adequate for hydrogen leakage simulation k-ε simulation is sufficient for industrial applications while LES model can be adopted for detail analysis for a jet/plume study like entrainment. The DES model possesses both characters of the former two model only the performance of its result depends on the grid refinement.
Non-steady Characteristics of Dispersion and Ignitability for High-pressurized Hydrogen Jet Discharged From a Pinhole
Sep 2017
Publication
Hydrogen gas concentrations and jet velocities were measured downstream by a high response speed flame ionization detector and PIV (Particle Image Velocimetry) in order to investigate the characteristics of dispersion and ignitability for 40–82 MPa high-pressurized hydrogen jet discharged from a nozzle with 0.2 mm diameter. The light emitted from both OH radical and water vapor species yielded from hydrogen combustion ignited by an electric spark were recorded by two high speed cameras. From the results the empirical formula concerning the relationships for time-averaged concentrations concentration fluctuations and ignition probability were obtained to suggest that they would be independent of hydrogen discharge pressure.
Debunking the Myths of Hydrogen Production and Water Consumption
Dec 2020
Publication
In our factsheet where we debunk 3 myths around hydrogen production and water consumption: electrolysis uses vast amounts of water; electrolysis uses freshwater resources only and electrolysis is bound to create water stress in water-scarce regions.
Numerical study of the release and dispersion of a light gas using 3D CFD code GASFLOW-MPI
Sep 2017
Publication
With the development of the hydrogen economy it requires a better understanding of the potential for fires and explosions associated with the unintended release of hydrogen within a partially confined space. In order to mitigate the hydrogen fire and explosion risks effectively accurate predictions of the hydrogen transport and mixing processes are crucial. It is well known that turbulence modelling is one of the key elements for a successful simulation of gas mixing and transport. GASFLOW-MPI is a scalable CFD software solution used to predict fluid dynamics conjugate heat and mass transfer chemical kinetics aerosol transportation and other related phenomena. In order to capture more turbulence information the Large Eddy Simulation (LES) model and LES/RANS hybrid model Detached Eddy Simulation (DES) have been implemented and validated in 3-D CFD code GASFLOW-MPI. The standard Smagorisky SGS model is utilized in LES turbulence model. And the k-epsilon based DES model is employed. This paper assesses the capability of algebraic k-epsilon DES and LES turbulence model to simulate the mixing and transport behavior of highly buoyant gases in a partially confined geometry. Simulation results agree well with the overall trend measured in experiments conducted in a reduced scale enclosure with idealized leaks which shows that all these four turbulent models are validated and suitable for the simulation of light gas behavior. Furthermore the numerical results also indicate that the LES and DES model could be used to analysis the turbulence behavior in the hydrogen safety problems.
Hydrogen Bubble Dispersion and Surface Bursting Behaviour
Sep 2013
Publication
In many processes where hydrogen may be released from below a liquid surface there has been concern regarding how such releases might ultimately disperse in an ullage space. Knowledge of the extent and persistence of any flammable volume formed is needed for hazardous area classification as well as for validation of explosion modelling or experiments. Following an initial release of hydrogen the overall process can be subdivided into three stages (i) rise and possible break-up of a bubble in the liquid (ii) formation and bursting of a thin gas-liquid-gas interface at the liquid surface and (iii) dispersion of the released gas. An apparatus based on a large glass sided water tank has been constructed which employs two synchronised high-speed imaging systems to record the behaviour of hydrogen bubble release and dispersion. A high-speed digital video system records the rising of the bubbles and the formation and bursting of the gas-liquid-gas interface at the liquid surface. An additional schlieren system is used to visualise the hydrogen release as bubbles burst at the liquid surface. The bubble burst mechanism can clearly be described from the results obtained. Following the nucleation of a hole surface tension causes the liquid film to peel back rapidly forming a ring/torus of liquid around the enlarging hole. This process lasts only a few milliseconds. Although some hydrogen can be seen to be expelled from the bubble much seems to remain in place as the film peels away. To assess the extent of the flammable plume following a bubble burst the apparatus was modified to include an electric-arc igniter. In order to identify plumes coincident in space with the igniter a schlieren system was built capable of recording simultaneously in two orthogonal directions. This confirmed that clouds undetected by the schlerien imaging could not be ignited with the electric arc igniter.
Innovation Insights Brief: Energy Scenarios Comparison Review
Apr 2019
Publication
Energy transition is a part of a much wider Grand Transition which is not all about energy. Energy transition cannot be achieved all at once or by any one actor. Relying only on better energy modelling and forecasting to guide successful transition will be fatal even in a data-rich era.<br/>It is timely for energy leaders to ask:<br/>Are global energy scenarios achieving their potential in opening up action on new energy futures?<br/>How do the Council’s World Energy Scenarios compare with global energy outlooks scenarios and normative visions used by others and what can we learn by contrasting the increasing richness of energy futures thinking?<br/>In anticipation of the 24th World Energy Congress the Council is refreshing its global energy foresight and updating its global scenarios narratives. The focus is on an ‘innovation twist to 2040’ and the use of scenarios to explore and navigate new exponential growth opportunities for accelerating successful energy transition in an era of epic and disruptive innovation.<br/>As a part of the refresh the Council has conducted a comparison study of global energy scenarios in order to test the continued plausibility relevance and challenge of its own existing scenario set the World Energy Scenarios 2016 launched at the 23rd World Energy Congress in Istanbul in 2016.<br/>By comparing the methods narratives and assumptions associated with a benchmarkable set of global energy futures initiatives and studies the Council seeks to provide our members with clearer understanding and new insights on energy transition while preparing them to better engage with leadership dialogues which pivot on visions of a new energy future.<br/>The review also provides an opportunity to reflect on the challenges and obstacles for utilising global energy scenarios to drive impact and the challenges in bridging agile and flexible qualitative storytelling with long term quantitative energy modelling."
A New Approach to Vented Deflagration Modeling
Sep 2017
Publication
In the present work CFD simulations of a hydrogen deflagration experiment are performed. The experiment carried out by KIT was conducted in a 1 m3 enclosure with a square vent of 0.5 m2 located in the center of one of its walls. The enclosure was filled with homogeneous hydrogen-air mixture of 18% v/v before ignition at its back-wall. As the flame propagates away from the ignition point unburned mixture is forced out through the vent. This mixture is ignited when the flame passes through the vent initiating a violent external explosion which leads to a rapid increase in pressure. The work focuses on the modeling of the external explosion phenomenon. A new approach is proposed in order to predict with accuracy the strength of external explosions using Large Eddy Simulation. The new approach introduces new relations to account for the interaction between the turbulence and the flame front. CFD predictions of the pressure inside and outside the enclosure and of the flame front shape are compared against experimental measurements. The comparison indicates a much better performance of the new approach compared to the initial model.
Technologies and Infrastructures Underpinning Future CO2 Value Chains: A Comprehensive Review and Comparative Analysis
Feb 2018
Publication
In addition to carbon capture and storage efforts are also being focussed on using captured CO2 both directly as a working fluid and in chemical conversion processes as a key strategy for mitigating climate change and achieving resource efficiency. These processes require large amounts of energy which should come from sustainable and ideally renewable sources. A strong value chain is required to support the production of valuable products from CO2 . A value chain is a network of technologies and infrastructures (such as conversion transportation storage) along with its associated activities (such as sourcing raw materials processing logistics inventory management waste management) required to convert low-value resources to high-value products and energy services and deliver them to customers. A CO2 value chain involves production of CO2 (involving capture and purification) technologies that convert CO2 and other materials into valuable products sourcing of low-carbon energy to drive all of the transformation processes required to convert CO2 to products (including production of hydrogen syngas methane etc.) transport of energy and materials to where they are needed managing inventory levels of resources and delivering the products to customers all in order to create value (economic environmental social etc.).
Technologies underpinning future CO2 value chains were examined. CO2 conversion technologies such as urea production Sabatier synthesis Fischer-Tropsch synthesis hydrogenation to methanol dry reforming hydrogenation to formic acid and electrochemical reduction were assessed and compared based on key performance indicators such as: CAPEX OPEX electricity consumption TRL product price net CO2 consumption etc. Technologies for transport and storage of key resources are also discussed. This work lays the foundation for a comprehensive whole-system value chain analysis modelling and optimisation.
Technologies underpinning future CO2 value chains were examined. CO2 conversion technologies such as urea production Sabatier synthesis Fischer-Tropsch synthesis hydrogenation to methanol dry reforming hydrogenation to formic acid and electrochemical reduction were assessed and compared based on key performance indicators such as: CAPEX OPEX electricity consumption TRL product price net CO2 consumption etc. Technologies for transport and storage of key resources are also discussed. This work lays the foundation for a comprehensive whole-system value chain analysis modelling and optimisation.
Vented Explosion of Hydrogen/Air Mixture: An Inter Comparison Benchmark Exercise
Sep 2017
Publication
Explosion venting is a widely used mitigation solution in the process industry to protect indoor equipment or buildings from excessive internal pressure caused by accidental explosions. However vented explosions are very complicated to model using computational fluid dynamics (CFD). In the framework of a French working group the main target of this investigation is to assess the predictive capabilities of five CFD codes used by five different organizations by means of comparison with recent experimental data. On this basis several recommendations for the CFD modelling of vented explosions are suggested.
A Review of the Impact of Hydrogen Integration in Natural Gas Distribution Networks and Electric Smart Grids
Apr 2022
Publication
Hydrogen technologies have been rapidly developing in the past few decades pushed by governments’ road maps for sustainability and supported by a widespread need to decarbonize the global energy sector. Recent scientific progress has led to better performances and higher efficiencies of hydrogen-related technologies so much so that their future economic viability is now rarely called into question. This article intends to study the integration of hydrogen systems in both gas and electric distribution networks. A preliminary analysis of hydrogen’s physical storage methods is given considering both the advantages and disadvantages of each one. After examining the preeminent ways of physically storing hydrogen this paper then contemplates two primary means of using it: integrating it in Power-to-Gas networks and utilizing it in Power-to-Power smart grids. In the former the primary objective is the total replacement of natural gas with hydrogen through progressive blending procedures from the transmission pipeline to the domestic burner; in the latter the set goal is the expansion of the implementation of hydrogen systems—namely storage—in multi-microgrid networks thus helping to decarbonize the electricity sector and reducing the impact of renewable energy’s intermittence through Demand Side Management strategies. The study concludes that hydrogen is assumed to be an energy vector that is inextricable from the necessary transition to a cleaner more efficient and sustainable future.
Hydrogen-related Challenges for the Steelmaker: The Search for Proper Testing
Jun 2017
Publication
The modern steelmaker of advanced high-strength steels has always been challenged with the conflicting targets of increased strength while maintaining or improving ductility. These new steels help the transportation sector including the automotive sector to achieve the goals of increased passenger safety and reduced emissions. With increasing tensile strengths certain steels exhibit an increased sensitivity towards hydrogen embrittlement (HE). The ability to characterize the material's sensitivity in an as-delivered condition has been developed and accepted (SEP1970) but the complexity of the stress states that can induce an embrittlement together with the wide range of applications for high-strength steels make the development of a standardized test for HE under in-service conditions extremely challenging. Some proposals for evaluating the material's sensitivity give an advantage to materials with a low starting ductility. Despite this newly developed materials can have a higher original elongation with only a moderate reduction in elongation due to hydrogen. This work presents a characterization of new materials and their sensitivity towards HE.
This article is part of the themed issue ‘The challenges of hydrogen and metals’.
Link to document download on Royal Society Website
This article is part of the themed issue ‘The challenges of hydrogen and metals’.
Link to document download on Royal Society Website
Reversible Ammonia-based and Liquid Organic Hydrogen Carriers for High-density Hydrogen Storage: Recent Progress
Feb 2019
Publication
Liquid hydrogen carriers are considered to be attractive hydrogen storage options because of their ease of integration into existing chemical transportation infrastructures when compared with liquid or compressed hydrogen. The development of such carriers forms part of the work of the International Energy Agency Task 32: Hydrogen-Based Energy Storage. Here we report the state-of-the-art for ammonia-based and liquid organic hydrogen carriers with a particular focus on the challenge of ensuring easily regenerable high-density hydrogen storage.
Flexible Power and Hydrogen Production: Finding Synergy Between CCS and Variable Renewables
Dec 2019
Publication
The expansion of wind and solar power is creating a growing need for power system flexibility. Dispatchable power plants with CO2 capture and storage (CCS) offer flexibility with low CO2 emissions but these plants become uneconomical at the low running hours implied by renewables-based power systems. To address this challenge the novel gas switching reforming (GSR) plant was recently proposed. GSR can alternate between electricity and hydrogen production from natural gas offering flexibility to the power system without reducing the utilization rate of the capital stock embodied in CCS infrastructure. This study assesses the interplay between GSR and variable renewables using a power system model which optimizes investment and hourly dispatch of 13 different technologies. Results show that GSR brings substantial benefits relative to conventional CCS. At a CO2 price of V100/ton inclusion of GSR increases the optimal wind and solar share by 50% lowers total system costs by 8% and reduces system emissions from 45 to 4 kgCO2/MWh. In addition GSR produces clean hydrogen equivalent to about 90% of total electricity demand which can be used to decarbonize transport and industry. GSR could therefore become a key enabling technology for a decarbonization effort led by wind and solar power.
Consequence Models for Vented Hydrogen Deflagrations: CFD vs. Engineering Models
Sep 2017
Publication
This paper compares two approaches for predicting the consequences of vented hydrogen deflagrations: empirical engineering models (EMs) and computational fluid dynamics (CFD) simulations. The study is part of the project ‘Improving hydrogen safety for energy applications through pre-normative research on vented deflagrations’ (HySEA) funded by the Fuel Cells and Hydrogen 2 Joint Undertaking (FCH JU) under grant agreement No 671461. The HySEA project focuses on vented hydrogen deflagrations in containers and smaller enclosures with internal congestion representative of industrial applications. Data from experiments conducted as part of the HySEA project are used to evaluate predictions from a selection of EMs and the CFD tool FLACS. The experiments involve various obstacle and venting configurations and initially quiescent homogeneous hydrogen-air mixtures with hydrogen concentrations in the range 15–24 vol%. There is a significant scatter in the maximum reduced overpressures predicted by the different EMs in the present study. For certain configurations there is an order of magnitude difference between the different EM predictions. Two versions of the CFD tool FLACS are used in the present study: i) the standard commercial release FLACS v10.7r2 and ii) an in-house development version termed FLACS-beta. The commercial release generally over-predicts the maximum overpressures measured in the experiments while the development version of FLACS gives improved results for several configurations.
Experimental Research on Low Calorific Value Gas Blended with Hydrogen Engine
Mar 2019
Publication
Experimental research on performance and emissions of engine fuelled with low calorific value gas blended with hydrogen was carried out and indicated thermal efficiency engine torque indicator diagram pressure rise rate and emissions with different hydrogen ratios were also analyzed. Experimental results show that with the increase of hydrogen fraction and CNG fraction in mixtures the indicated thermal efficiency increased. The engine power output is influenced by both low calorific value and hydrogen fractions. With the increase of hydrogen fraction in mixtures HC emissions decrease CO and NOx emissions increase. An engine operating on lean-burn low calorific value gas blended with hydrogen is favourable for getting lower emissions.
Performance Tests of Catalysts for the Safe Conversion of Hydrogen Inside the Nuclear Waste Containers in Fukushima Daiichi
Sep 2019
Publication
The safe decommissioning as well as decontamination of the radioactive waste resulting from the nuclear accident in Fukushima Daiichi represents a huge task for the next decade. At present research and development on long-term safe storage containers has become an urgent task with international cooperation in Japan. One challenge is the generation of hydrogen and oxygen in significant amounts by means of radiolysis inside the containers as the nuclear waste contains a large portion of sea water. The generation of radiolysis gases may lead to a significant pressure build-up inside the containers and to the formation of flammable gases with the risk of ignition and the loss of integrity.
In the framework of the project “R&D on technology for reducing concentration of flammable gases generated in long-term waste storage containers” funded by the Japanese Ministry of Education Culture Sports Science and Technology of Japan (MEXT) the potential application of catalytic recombiner devices inside the storage containers is investigated. In this context a suitable catalyst based on the so-called intelligent automotive catalyst for use in a recombiner is under consideration. The catalyst is originally developed and mass-produced for automotive exhaust gas purification and is characterized by having a self-healing function of precious metals (Pd Pt and Rh) dissolved as a solid solution in the perovskite type oxides. The basic features of this catalyst have been tested in an experimental program. The test series in the REKO-4 facility has revealed the basic characteristics of the catalyst required for designing the recombiner system.
In the framework of the project “R&D on technology for reducing concentration of flammable gases generated in long-term waste storage containers” funded by the Japanese Ministry of Education Culture Sports Science and Technology of Japan (MEXT) the potential application of catalytic recombiner devices inside the storage containers is investigated. In this context a suitable catalyst based on the so-called intelligent automotive catalyst for use in a recombiner is under consideration. The catalyst is originally developed and mass-produced for automotive exhaust gas purification and is characterized by having a self-healing function of precious metals (Pd Pt and Rh) dissolved as a solid solution in the perovskite type oxides. The basic features of this catalyst have been tested in an experimental program. The test series in the REKO-4 facility has revealed the basic characteristics of the catalyst required for designing the recombiner system.
Performance Evaluation of Empirical Models for Vented Lean Hydrogen Explosions
Sep 2017
Publication
Explosion venting is a method commonly used to prevent or minimize damage to an enclosure caused by an accidental explosion. An estimate of the maximum overpressure generated though explosion is an important parameter in the design of the vents. Various engineering models (Bauwens et al. 2012 Molkov and Bragin 2015) and European (EN 14994 ) and USA standards (NFPA 68) are available to predict such overpressure. In this study their performance is evaluated using a number of published experiments. Comparison of pressure predictions from various models have also been carried out for the recent experiments conducted by GexCon using a 20 feet ISO container. The results show that the model of Bauwens et al. (2012) predicts well for hydrogen concentration between 16% and 21% and in the presence of obstacles. The model of Molkov et al. (2015) is found to work well for hydrogen concentrations between 10% and 30% without obstacles. In the presence of obstacles as no guidelines are given to set the coefficient for obstacles in the model it was necessary to tune the coefficient to match the experimental data. The predictions of the formulas in NFPA 68 show a large scatter across different tests. The current version of both EN 14994 and NFPA 68 are found to have very limited range of applicability and can hardly be used for vent sizing of hydrogen-air deflagrations. Overall the accuracy of all the engineering models was found to be limited. Some recommendations concerning their applicability will be given for vented lean-hydrogen explosion concentrations of interest to practical applications.
OIES Podcast – Hydrogen: Current Challenges in Creating Viable Business Cases
Apr 2022
Publication
In this podcast David Ledesma talks to Martin Lambert Head of OIES Hydrogen Research about the key messages from the recent European Hydrogen Conference and how they fit with the ongoing research in OIES. In particular they cover the heightened energy security concerns following the Russian invasion of Ukraine and hydrogen ambitions in the REPowerEU document published by the European Commission in early March 2002. They then go on to talk about the growing realism about where hydrogen is more likely to play a role and some of the key challenges to be overcome. Addressing the challenges of creating business cases for use of hydrogen in specific sectors and for transporting it to customers the conversation also addresses the importance of hydrogen storage and the recognition that this area needs more focus both technically and commercially. Finally they talk about the geopolitics of hydrogen and how energy security concerns may influence future development pathways.
The podcast can be found on their website
The podcast can be found on their website
Oxford Energy Podcast – The Role of Ammonia and Hydrogen in Meeting International Maritime Organisation Targets for Decarbonising Shipping
Jul 2021
Publication
The world’s shipping fleet is responsible for approximately 0.9 Gt of CO2 emissions annually around 2.9 per cent of the world’s man-made emissions. Under an IEA ‘business as usual’ scenario this is forecast to rise to almost 1.7 Gt per year by 2050. The industry’s principal regulatory body the International Maritime Organization (IMO) aims to reduce world shipping’s greenhouse gas emissions in line with the 2015 Paris Agreement targeting a 50 per cent reduction compared with 2008 levels by 2050. The cost of achieving these emission targets however is about $1 trillion and will require focus from regulators operators and end consumers who in the end will have to pay. In this podcast David Ledesma talks to Bruce Moore Howe Robinson Partners to discuss these issues and ask in such a fragmented industry what the immediate priorities for the marine sector must be and how can it bring about a mix of commercial incentives and regulatory change that result in tangible emissions reductions.
The podcast can be found on their website
The podcast can be found on their website
H2FC SUPERGEN- The Role of Hydrogen and Fuel Cells in Providing Affordable, Secure Low-carbon Heat
May 2014
Publication
This White Paper has been commissioned by the UK Hydrogen and Fuel Cell (H2FC) SUPERGEN Hub to examine the roles and potential benefits of hydrogen and fuel cell technologies for heat provision in future low-carbon energy systems. The H2FC SUPERGEN Hub is an inclusive network encompassing the entire UK hydrogen and fuel cells research community with around 100 UK-based academics supported by key stakeholders from industry and government. It is funded by the UK EPSRC research council as part of the RCUK Energy Programme. This paper is the first of four that will be published over the lifetime of the Hub with the others examining: (i) low-carbon energy systems (including balancing renewable intermittency); (ii) low-carbon transport systems; and (iii) the provision of secure and affordable energy supplies for the future
- Hydrogen and fuel cells are part of the cost-optimal heating technology portfolio in long-term UK energy system scenarios.
- Fuel cell CHP is already being deployed commercially around the world.
- Hydrogen can be a zero-carbon alternative to natural gas. Most technologies that use natural gas can be adapted to use hydrogen and still provide the same level of service.
- Hydrogen and fuel cell technologies avoid some of the disadvantages of other low-carbon heating technologies.
Thermal Radiation from Cryogenic Hydrogen Jet Fires
Sep 2017
Publication
The thermal hazards from ignited under-expanded cryogenic releases are not yet fully understood and reliable predictive tools are missing. This study aims at validation of a CFD model to simulate flame length and radiative heat flux for cryogenic hydrogen jet fires. The simulation results are compared against the experimental data by Sandia National Laboratories on cryogenic hydrogen fires from storage with pressure up to 5 bar abs and temperature in the range 48–82 K. The release source is modelled using the Ulster's notional nozzle theory. The problem is considered as steady-state. Three turbulence models were applied and their performance was compared. The realizable k-ε model showed the best agreement with experimental flame length and radiative heat flux. Therefore it has been employed in the CFD model along with Eddy Dissipation Concept for combustion and Discrete Ordinates (DO) model for radiation. A parametric study has been conducted to assess the effect of selected numerical and physical parameters on the simulations capability to reproduce experimental data. DO model discretisation is shown to strongly affect simulations indicating 10 × 10 as minimum number of angular divisions to provide a convergence. The simulations have shown sensitivity to experimental parameters such as humidity and exhaust system volumetric flow rate highlighting the importance of accurate and extended publication of experimental data to conduct precise numerical studies. The simulations correctly reproduced the radiative heat flux from cryogenic hydrogen jet fire at different locations.
A Simple Model for Calculating Peak Pressure in Vented Explosions of Hydrogen and Hydrocarbons
Apr 2019
Publication
The authors presented a basic mathematical model for estimating peak overpressure attained in vented explosions of hydrogen in a previous study (Sinha et al. [1]). The model focussed on idealized cases of hydrogen and was not applicable for realistic accidental scenarios like presence of obstacles initial turbulent mixture etc. In the present study the underlying framework of the model is reformulated to overcome these limitations. The flame shape computations are simplified. A more accurate and simpler formulation for venting is also introduced. Further by using simplifying assumptions and algebraic manipulations the detailed model consisting of several equations is reduced to a single equation with only four parameters. Two of these parameters depend only on fuel properties and a standard table provided in the Appendix can be used. Therefore to compute the overpressure only the two parameters based on enclosure geometry need to be evaluated. This greatly simplifies the model and calculation effort. Also since the focus of previous investigation was hydrogen properties of hydrocarbon fuels which are much more widely used were not accounted for. The present model also accounts for thermo-physical properties of hydrocarbons and provides table for fuel parameters to be used in the final equation for propane and methane. The model is also improved by addition of different sub-models to account for various realistic accidental scenarios. Moreover no adjustable parameters are used; the same equation is used for all conditions and all gases. Predictions from this simplified model are compared with experimentally measured values of overpressure for hydrogen and hydrocarbons and found to be in good agreement. First the results from experiments focussing on idealized conditions of uniformly mixed fuel in an empty enclosure under quiescent conditions are considered. Further the model applicability is also tested for realistic conditions of accidental explosion consisting of obstacles inside the enclosure non-uniform fuel distribution initial turbulent mixture etc. For all the cases tested the new simple model is found to produce reasonably good predictions.
Experimental Investigation of Nonideality and Nonadiabatic Effects Under High Pressure Releases
Sep 2013
Publication
Due to the nonideality of a high pressure hydrogen release the possibility of a two-phase flow and its effect on the dynamics of the discharge process was experimentally investigated. A small-scale facility was designed and constructed to simulate the transient blow-down of a cryogenic fluid through a small break. Gaseous and liquid nitrogen were planned to were used as a surrogate for GH2 and LH2. The results will complement the quasi-stationary safety regulation tests and will provide time-dependent data for verification of the theoretical models. Different orifice sizes (0.5 1 2 4 mm) and initial N2 pressures (30 – 200 bar) were used in the tests. The measured time-dependent data for vessel discharge pressure thrust discharge mass flow rate and gas temperatures were compared against a theoretical model for high pressure nitrogen release. This verification for nitrogen also assures the equation of state for hydrogen which is based on the same methodology.
The Role of the Flow Field Generated by Venting Process on the Pressure Time History of a Vented Deflagration
Sep 2017
Publication
Vented deflagrations are one of the most challenging phenomenon to be replicated numerically in order to predict its resulting pressure time history. As a matter of fact a number of different phenomena can contribute to modify the burning velocity of a gas mixture undergoing a deflagration especially when the flame velocity is considerably lower than the speed of sound. In these conditions acceleration generated by both the flow field induced by the expanding flame and from discontinuities as the vent opening and the venting of the combustion products affect the burning velocity and the burning behaviour of the flame. In particular the phenomena affecting the pressure time history of a deflagration after the flame front reaches the vent area such as flame acoustic interaction and local pressure peaks seem to be closely related to a change in the burning behaviour induced by the venting process. Flame acoustic interaction and local pressure peaks arise as a consequence of the change in the burning behaviour of the flame. This paper analyses the video recording of the flame front produced during the TP experimental campaign performed by UNIPI in the project HySEA to analyse qualitatively the contribution of the generated flow field in a vented deflagration in its pressure-time history.
A Host-guest Approach to Fabricate Metallic Cobalt Nanoparticles Embedded in Silk-derived N-doped Carbon Fibers for Efficient Hydrogen Evolution
Feb 2017
Publication
Hydrogen evolution reaction (HER) plays a key role in generating clean and renewable energy. As the most effective HER electrocatalysts Pt group catalysts suffer from severe problems such as high price and scarcity. It is highly desirable to design and synthesize sustainable HER electrocatalysts to replace the Pt group catalysts. Due to their low cost high abundance and high activities cobalt-incorporated N-doped nanocarbon hybrids are promising candidate electrocatalysts for HER. In this report we demonstrated a robust and eco-friendly host-guest approach to fabricate metallic cobalt nanoparticles embedded in N-doped carbon fibers derived from natural silk fibers. Benefiting from the one-dimensional nanostructure the well-dispersed metallic cobalt nanoparticles and the N-doped thin graphitized carbon layer coating the best Co-based electrocatalyst manifests low overpotential (61 mV@10 mA/cm2) HER activity that is comparable with commercial 20% Pt/C and good stability in acid. Our findings provide a novel and unique route to explore high-performance noble-metal-free HER electrocatalysts.
The Role of the Substrate on the Mechanical and Thermal Stability of Pd Thin Films During Hydrogen (De)sorption
Nov 2020
Publication
In this work we studied the mechanical and thermal stability of ~100 nm Pd thin films magnetron sputter deposited on a bare oxidized Si(100) wafer a sputtered Titanium (Ti) intermediate layer and a spin-coated Polyimide (PI) intermediate layer. The dependence of the film stability on the film morphology and the film-substrate interaction was investigated. It was shown that a columnar morphology with elongated voids at part of the grain boundaries is resistant to embrittlement induced by the hydride formation (α↔β phase transitions). For compact film morphology depending on the rigidity of the intermediate layer and the adherence to the substrate complete transformation (Pd-PI-SiO2/Si) or partly suppression (Pd-Ti-SiO2/Si) of the α to β-phase was observed. In the case of Pd without intermediate layer (Pd-SiO2/Si) buckling delamination occurred. The damage and deformation mechanisms could be understood by the analysis of the stresses and dislocation (defects) behavior near grain boundaries and the film-substrate interface. From diffraction line-broadening combined with microscopy analysis we showed that in Pd thin films stresses relax at critical stress values via different relaxation pathways depending on film-microstructure and film-substrate interaction. On the basis of the in-situ hydriding experiments it was concluded that a Pd film on a flexible PI intermediate layer exhibits free-standing film-like behavior besides being strongly clamped on a stiff SiO2/Si substrate.
The Influence of Refractory Metals on the Hydrogen Storage Characteristics of FeTi-based Alloys Prepared by Suspended Droplet Alloying
Jun 2020
Publication
The influence of the addition of refractory metals (molybdenum and tantalum) on the hydrogenation properties of FeTi intermetallic phase-based alloys was investigated. The suspended droplet alloying technique was applied to fabricate FeTiTa-based and FeTiMo-based alloys. The phase composition and hydrogen storage properties of the samples were investigated. The samples modified with the refractory metals exhibited lower plateau pressures and lower hydrogen storage capacities than those of the FeTi reference sample due to solid solution formation. It was observed that the equilibrium pressures decreased with the amount of molybdenum which is in good agreement with the increase in the cell parameters of the TiFe phase. Suspended droplet alloying was found to be a practical method to fabricate alloys with refractory metal additions; however it is appropriate for screening samples with desired chemical and phase compositions rather than for manufacturing purposes.
Investigation of Mechanical Tests for Hydrogen Embrittlement in Automotive PHS Steels
Aug 2019
Publication
The problem of hydrogen embrittlement in ultra-high-strength steels is well known. In this study slow strain rate four-point bending and permeation tests were performed with the aim of characterizing innovative materials with an ultimate tensile strength higher than 1000 MPa. Hydrogen uptake in the case of automotive components can take place in many phases of the manufacturing process: during hot stamping due to the presence of moisture in the furnace atmosphere high-temperature dissociation giving rise to atomic hydrogen or also during electrochemical treatments such as cataphoresis. Moreover possible corrosive phenomena could be a source of hydrogen during an automobile’s life. This series of tests was performed here in order to characterize two press-hardened steels (PHS)—USIBOR 1500® and USIBOR 2000®—to establish a correlation between ultimate mechanical properties and critical hydrogen concentration.
Mechanical Properties of Gas Main Steels after Long-Term Operation and Peculiarities of Their Fracture Surface Morphology
Feb 2019
Publication
Regularities of steel structure degradation of the “Novopskov-Aksay-Mozdok” gas main pipelines (Nevinnomysskaya CS) as well as the “Gorky-Center” pipelines (Gavrilovskaya CS) were studied. The revealed peculiarities of their degradation after long-term operation are suggested to be treated as a particular case of the damage accumulation classification (scheme) proposed by prof. H.M. Nykyforchyn. It is shown that the fracture surface consists of sections of ductile separation and localized zones of micro-spalling. The presence of the latter testifies to the hydrogen-induced embrittlement effect. However the steels under investigation possess sufficiently high levels of the mechanical properties required for their further safe exploitation both in terms of durability and cracking resistance.
Hydrogen Transport - Fuelling The Future
Dec 2020
Publication
Through the combustion of fossil fuels the transport sector is responsible for 20-30% of global CO2 emissions. We can support the net-zero one ambition by decarbonising transport modes using green hydrogen fuelled options – hydrogen generated from renewable energy sources such as offshore wind.<br/><br/>We have been working with clients across the hydrogen industry for several years specifically around the generation dispatch and use of hydrogen within energy systems. However interest is swiftly moving to wider hydrogen based solutions including within the fleet rail aviation and maritime sectors.<br/><br/>Our latest ‘Future of Energy’ series explores the opportunity for green fuelled hydrogen transport. We look at each industry in detail the barriers to uptake market conditions and look at how the transport industry could adapt and develop to embrace a net-zero future.
Hydrogen for Heating? Decarbonization Options for Households in the United Kingdom in 2050
Dec 2020
Publication
The heating sector makes up 10% of the United Kingdom’s carbon footprint and residential homes account for a majority of demand. At present central heating from a natural gas-fired boiler is the most common system in the UK but low or zero-carbon hydrogen and renewable electricity are the two primary energy replacement options to reduce the carbon footprint. An important consideration is how using either energy source would affect heating costs. This assessment projects the costs for a typical single-family UK household and climate performance in 2050 using low-GHG or GHG-neutral hydrogen renewable electricity or a combination of both. The cost of using boilers or fuel cells in 2050 with two types of hydrogen are assessed: produced via steam-methane reforming (SMR) combined with carbon capture and storage (CCS) and electrolysis using zero-carbon renewable electricity. The costs of heat pumps the most promising heating technology for the direct use of renewable electricity are also assessed in two scenarios: a heat pump only and a hybrid heat pump with an auxiliary hydrogen boiler.
You can download this document from the International Council On Clean Transportation website linked here
You can download this document from the International Council On Clean Transportation website linked here
Are We Building Back Better? Evidence from 2020 and Pathways for Inclusive Green Recovery Spending
Mar 2021
Publication
COVID-19 has led to a global crisis threatening the lives and livelihoods of the most vulnerable by increasing poverty exacerbating inequalities and damaging long-term economic growth prospects. The report Are We Building Back Better? Evidence from 2020 and Pathways for Inclusive Green Recovery Spending provides an analysis of over 3500 fiscal policies announced by leading economies in 2020 and calls for governments to invest more sustainably and tackle inequalities as they stimulate growth in the wake of the devastation wrought by the pandemic.
Evaluation of Sorbents for High Temperature Removal of Tars, Hydrogen Sulphide, Hydrogen Chloride and Ammonia from Biomass-derived Syngas by Using Aspen Plus
Jan 2020
Publication
Biomass gasification is a promising technology to produce secondary fuels or heat and power offering considerable advantages over fossil fuels. An important aspect in the usage of producer gas is the removal of harmful contaminants from the raw syngas. Thus the object of this study is the development of a simulation model for a gasifier including gas clean-up for which a fluidized-bed gasifier for biomass-derived syngas production was considered based on a quasi-equilibrium approach through Gibbs free energy minimisation and including an innovative hot gas cleaning constituted by a combination of catalyst sorbents inside the gasification reactor catalysts in the freeboard and subsequent sorbent reactors by using Aspen Plus software. The gas cleaning chain simulates the raw syngas clean-up for several organic and inorganic contaminants i.e. toluene benzene naphthalene hydrogen sulphide hydrogen chloride and ammonia. The tar and inorganic contaminants final values achieved are under 1 g/Nm3 and 1 ppm respectively.
Strategic Research and Innovation Agenda
Jul 2020
Publication
The FCH1JU and FCH2JU have proven effective in developing hydrogen technologies to a high Technology Readiness Level (TRL) allowing for large-scale deployment. Yet there is still an important work to be performed in terms of Research and Innovation in order to develop the next generation of products as well as technologies that did not reach a sufficiently high TRL to envisage a large-scale deployment.<br/><br/>Within the framework of the preparation of the foreseen Clean Hydrogen for Europe (the third public-private partnership continuation of the FCH2JU) Hydrogen Europe and Hydrogen Europe Research have prepared their Strategic Research and Innovation Agenda (SRIA) which is made of a set of approximately 20 roadmaps. This SRIA represents the view of the private partner and will be used as a basis to develop the Multi Annual Work Plan (MAWP) of the Clean Hydrogen for Europe partnership. The current version (July 2020) is the final draft that has been submitted to the European Commission.
Effects of Quantum Confinement of Hydrogen in Nanocavities – Experimental INS Results and New Insights
Jun 2020
Publication
Current developments of non-relativistic quantum mechanics appear to predict and reveal counter-intuitive dynamical effects of hydrogen in nanostructured materials that are of considerable importance for basic research as well as for technological applications. In this review the experimental focus is on H2O and H molecules in carbon nanotubes and other nanocavities that have been experimentally investigated using the well-established technique of incoherent inelastic neutron scattering (INS). For instance the momentum and energy transfers as obtained from the commonly used standard data analysis techniques from a
(I) H2 molecule in a C-nanotube resulting in a roto-translational motion along the nanotube axis seems to (1) either violate the standard conservation laws or (2) to attribute to the H molecule undergoing translation the effective mass a.m.u. (atomic mass units) instead of the expected 2 a.m.u. A similar striking anomalous effect has been found in the neutron-H scattering from the
(II) H2O molecules in nano-channels of some solid materials in which O-H stretching vibrations along the channel axis are created.
The results of this scattering process seem to once again either violate the standard conservation laws or to attribute to the effective mass of the struck H2 molecule as a.m.u. instead of the expected value of 1 a.m.u. We show that these counterintuitive observations from the INS studies have no conventional interpretation within the standard non-relativistic scattering theory. However they can be qualitatively interpreted “from first principles” within the framework of modern theories of
(III) time-symmetric quantum dynamics as provided by the weak values (WV) and two-state- vector formalism (TSVF)
and/or
(IV) quantum correlations especially quantum discord (QD) and quantum thermodynamics (QTD).
The theoretical analysis provides an intuitive understanding of the experimental results gives strong evidence that the nano-structured cavities do represent quantum systems which participate significantly in the dynamics of the neutron-H scattering and surprisingly shows that new physical information can be derived from the experimental data. This latter point may also have far-reaching consequences for technology and material sciences (e.g. fuel cells H storage materials etc.). Moreover novel insights into the short-lived quantum dynamics and/or quantum information theory can be gained.
(I) H2 molecule in a C-nanotube resulting in a roto-translational motion along the nanotube axis seems to (1) either violate the standard conservation laws or (2) to attribute to the H molecule undergoing translation the effective mass a.m.u. (atomic mass units) instead of the expected 2 a.m.u. A similar striking anomalous effect has been found in the neutron-H scattering from the
(II) H2O molecules in nano-channels of some solid materials in which O-H stretching vibrations along the channel axis are created.
The results of this scattering process seem to once again either violate the standard conservation laws or to attribute to the effective mass of the struck H2 molecule as a.m.u. instead of the expected value of 1 a.m.u. We show that these counterintuitive observations from the INS studies have no conventional interpretation within the standard non-relativistic scattering theory. However they can be qualitatively interpreted “from first principles” within the framework of modern theories of
(III) time-symmetric quantum dynamics as provided by the weak values (WV) and two-state- vector formalism (TSVF)
and/or
(IV) quantum correlations especially quantum discord (QD) and quantum thermodynamics (QTD).
The theoretical analysis provides an intuitive understanding of the experimental results gives strong evidence that the nano-structured cavities do represent quantum systems which participate significantly in the dynamics of the neutron-H scattering and surprisingly shows that new physical information can be derived from the experimental data. This latter point may also have far-reaching consequences for technology and material sciences (e.g. fuel cells H storage materials etc.). Moreover novel insights into the short-lived quantum dynamics and/or quantum information theory can be gained.
Hydrogen Diffusion Mechanism around a Crack Tip in Type 304L Austenite Stainless Steel Considering the Influence of the Volume Expansion of Strain-Induced Martensite Transformation
Sep 2019
Publication
Strain-induced martensite transformation (SIMT) commonly exists around a crack tip of metastable austenite stainless steels. The influence of the volume expansion of the SIMT on the hydrogen diffusion was investigated by hydrogen diffusion modelling around a crack tip in type 304L austenite stainless steel. The volume expansion changed the tensile stress state into pressure stress state at the crack tip resulting in a large stress gradient along the crack propagation direction. Compared to the analysis without considering the volume expansion effect this volume expansion further accelerated the hydrogen transport from the inner surface to a critical region ahead of the crack tip and further increased the maximum value of the hydrogen concentration at the critical position where the strain-induced martensite fraction approximates to 0.1 indicating that the volume expansion of the SIMT further increased the hydrogen embrittlement susceptibility.
H21- Leeds City Gate Project Report
Jul 2016
Publication
The H21 Leeds City Gate project is a study with the aim of determining the feasibility from both a technical and economic viewpoint of converting the existing natural gas network in Leeds one of the largest UK cities to 100% hydrogen. The project has been designed to minimise disruption for existing customers and to deliver heat at the same cost as current natural gas to customers. The project has shown that:
The project has provided costs for the scheme and has modelled these costs in a regulatory finance model. In addition the availability of low-cost bulk hydrogen in a gas network could revolutionise the potential for hydrogen vehicles and via fuel cells support a decentralised model of combined heat and power and localised power generation.
This report and any attachment is freely available on the ENA Smarter Networks Portal here. IGEM Members can download the report and any attachment directly by clicking on the pdf icon above.
- The gas network has the correct capacity for such a conversion
- It can be converted incrementally with minimal disruption to customers
- Minimal new energy infrastructure will be required compared to alternatives
- The existing heat demand for Leeds can be met via steam methane reforming and salt cavern storage using technology in use around the world today
The project has provided costs for the scheme and has modelled these costs in a regulatory finance model. In addition the availability of low-cost bulk hydrogen in a gas network could revolutionise the potential for hydrogen vehicles and via fuel cells support a decentralised model of combined heat and power and localised power generation.
This report and any attachment is freely available on the ENA Smarter Networks Portal here. IGEM Members can download the report and any attachment directly by clicking on the pdf icon above.
Hydrolysis-Based Hydrogen Generation Investigation of Aluminium System Adding Low-Melting Metals
Mar 2021
Publication
In this age of human civilization there is a need for more efficient cleaner and renewable energy as opposed to that provided by nonrenewable sources such as coal and oil. In this sense hydrogen energy has been proven to be a better choice. In this paper a portable graphite crucible metal smelting furnace was used to prepare ten multi-element aluminum alloy ingots with different components. The microstructure and phase composition of the ingots and reaction products were analyzed by X-ray diffraction (XRD) scanning electron microscopy (SEM) and differential scanning calorimetry (DSC). The reaction was carried out in a constant temperature water bath furnace at 60°C and the hydrogen production performance of the multi-element aluminum alloys in different proportions was compared by the drainage gas collection method. The experimental results show that the as-cast microstructure of Al–Ga–In–Sn aluminum alloy is composed of a solid solution of Al and part of Ga and a second phase of In3Sn. After the hydrolysis reaction the products were dried at 150°C and then analyzed by XRD. The products were mainly composed of AlOOH and In3Sn. Alloys with different compositions react at the same hydrolysis temperature and the hydrogen production performance is related to the ratio of low-melting-point metal elements. By comparing two different ratios of Ga–In–Sn (GIS) the hydrogen production capacity and production rate when the ratio is 6:3:1 are generally higher than those when the ratio is 7:2:1. The second phase content affects the hydrogen production performance.
Analysis of the Hydrogen Induced Cracking by Means of the Small Punch Test: Effect of the Specimen Geometry and the Hydrogen Pre-Charge Mode
Nov 2018
Publication
This paper presents a simplified procedure to analyse the Hydrogen Induced Cracking (HIC) of structural steels by means of the Small Punch Test (SPT). Two types of notched specimens were used: one with through-thickness lateral notch and another with surface longitudinal notch. The results for conventional specimens were compared with those for hydrogen pre-charged specimens. For this purpose two different methods to introduce hydrogen in the specimens were used: cathodic/electrochemical pre-charging and pressurized gaseous hydrogen pre-charging. The results obtained with both methods are also discussed.
Hydrogen from Renewable Power
Sep 2018
Publication
As the world strives to cut carbon emissions electric power from renewables has emerged as a vital energy source. Yet transport and industry will still require combustible fuels for many purposes. Such needs could be met with hydrogen which itself can be produced using renewable power.
Hydrogen provides high-grade heat helping to meet a range of energy needs that would be difficult to address through direct electrification. This could make hydrogen the missing link in the transformation of the global energy system.
Key sectors for renewable-based hydrogen uptake include:
Electrolysers – which split hydrogen and oxygen – can make power systems more flexible helping to integrate high shares of variable renewables. Power consumption for electrolysis can be adjusted to follow actual solar and wind output while producing the hydrogen needed for transport industry or injection into the gas grid.
In the long run hydrogen could become a key element in 100% renewable energy systems. With technologies maturing actual scale-up should yield major cost reductions. The right policy and regulatory framework however remains crucial to stimulate private investment in in hydrogen production in the first place.
Hydrogen provides high-grade heat helping to meet a range of energy needs that would be difficult to address through direct electrification. This could make hydrogen the missing link in the transformation of the global energy system.
Key sectors for renewable-based hydrogen uptake include:
- Industry where it could replace fossil-based feedstocks including natural gas in high-emission applications.
- Buildings and power where it could be mixed with natural gas or combined with industrial carbon dioxide (CO2) emissions to produce syngas.
- Transport where it can provide low-carbon mobility through fuel-cell electric vehicles.
Electrolysers – which split hydrogen and oxygen – can make power systems more flexible helping to integrate high shares of variable renewables. Power consumption for electrolysis can be adjusted to follow actual solar and wind output while producing the hydrogen needed for transport industry or injection into the gas grid.
In the long run hydrogen could become a key element in 100% renewable energy systems. With technologies maturing actual scale-up should yield major cost reductions. The right policy and regulatory framework however remains crucial to stimulate private investment in in hydrogen production in the first place.
Cost Optimization of a Stand-Alone Hybrid Energy System with Fuel Cell and PV
Mar 2020
Publication
Renewable energy has become very popular in recent years. The amount of renewable generation has increased in both grid-connected and stand-alone systems. This is because it can provide clean energy in a cost-effective and environmentally friendly fashion. Among all varieties photovoltaic (PV) is the ultimate rising star. Integration of other technologies with solar is enhancing the efficiency and reliability of the system. In this paper a fuel cell–solar photovoltaic (FC-PV)-based hybrid energy system has been proposed to meet the electrical load demand of a small community center in India. The system is developed with PV panels fuel cell an electrolyzer and hydrogen storage tank. Detailed mathematical modeling of this system as well as its operation algorithm have been presented. Furthermore cost optimization has been performed to determine ratings of PV and Hydrogen system components. The objective is to minimize the levelized cost of electricity (LCOE) of this standalone system. This optimization is performed in HOMER software as well as another tool using an artificial bee colony (ABC). The results obtained by both methods have been compared in terms of cost effectiveness. It is evident from the results that for a 68 MWh/yr of electricity demand is met by the 129 kW Solar PV 15 kW Fuel cell along with a 34 kW electrolyzer and a 20 kg hydrogen tank with a LPSP of 0.053%. The LCOE is found to be in 0.228 $/kWh. Results also show that use of more sophisticated algorithms such as ABC yields more optimized solutions than package programs such as HOMER. Finally operational details for FC-PV hybrid system using IEC 61850 inter-operable communication is presented. IEC 61850 information models for FC electrolyzer hydrogen tank were developed and relevent IEC 61850 message exchanges for energy management in FC-PV hybrid system are demonstrated.
Scottish Hydrogen Assessment
Dec 2020
Publication
During 2020 the Scottish Government in partnership with Highlands and Islands Enterprise and Scottish Enterprise commissioned Arup and E4Tech to carry out a hydrogen assessment to deepen our evidence base in order to inform our policies on hydrogen going forward. The assessment aims to investigate how and where hydrogen may fit within the evolving energy system technically geographically and economically. To assist in this consideration a key part of the Hydrogen Assessment is the development of distinct viable scenarios for hydrogen deployment in Scotland and the economic assessment of those scenarios.<br/>From our assessment it is clear that hydrogen is not just an energy and emissions reduction opportunity; it could also have an important role in generating new economic opportunities in Scotland. The assessment forms an important part of the evidence base that informed the development of the Hydrogen Policy Statement.
A Production and Delivery Model of Hydrogen from Solar Thermal Energy in the United Arab Emirates
May 2022
Publication
Hydrogen production from surplus solar electricity as energy storage for export purposes can push towards large-scale application of solar energy in the United Arab Emirates and the Middle East region; this region’s properties of high solar irradiance and vast empty lands provide a good fit for solar technologies such as concentrated solar power and photovoltaics. However a thorough comparison between the two solar technologies as well as investigating the infrastructure of the United Arab Emirates for a well-to-ship hydrogen pathway is yet to be fully carried out. Therefore in this study we aim to provide a full model for solar hydrogen production and delivery by evaluating the potential of concentrated solar power and photovoltaics in the UAE then comparing two different pathways for hydrogen delivery based on the location of hydrogen production sites. A Solid Oxide Cell Electrolyzer (SOEC) is used for technical comparison while the shortest routes for hydrogen transport were analyzed using Geographical Information System (GIS). The results show that CSP technology coupled with SOEC is the most favorable pathway for large-scale hydrogen from solar energy production in the UAE for export purposes. Although PV has a slightly higher electricity potential compared to CSP around 42 GWh/km2 to 41.1 GWh/km2 respectively CSP show the highest productions rates of over 6 megatons of hydrogen when the electrolyzer is placed at the same site as the CSP plant while PV generates 5.15 megatons when hydrogen is produced at the same site with PV plants; meanwhile hydrogen from PV and CSP shows similar levels of 4.8 and 4.6 megatons of hydrogen respectively when electrolyzers are placed at port sites. Even considering the constraints in the UAE’s infrastructure and suggesting new shorter electrical transmission lines that could save up to 0.1 megatons of hydrogen in the second pathway production at the same site with CSP is still the most advantageous scenario.
Towards a CO2-neutral Steel Industry: Justice Aspects of CO2 Capture and Storage, Biomass- and Green Hydrogen-based Emission Reductions
Apr 2022
Publication
A rapid transition towards a CO2-neutral steel industry is required to limit climate change. Such a transition raises questions of justice as it entails positive and negative impacts unevenly distributed across societal stakeholders. To enable stakeholders to address such concerns this paper assesses the justice implications of three options that reduce emissions: CO2 capture and storage (CCS) on steel (up to 70%) bio-based steelmaking (up to 50%) and green hydrogen-based steel production (up to 100%). We select justice indicators from the energy climate labour and environmental justice literature and assess these indicators qualitatively for each of the technological routes based on literature and desk research. We find context-dependent differences in justness between the different technological routes. The impact on stakeholders varies across regions. There are justice concerns for local communities because of economic dependence on and environmental impact of the industry. Communities elsewhere are impacted through the siting of infrastructure and feedstock production. CCS and bio-based steelmaking routes can help retain industry and associated economic benefits on location while hydrogen-based steelmaking may deal better with environmental concerns. We conclude that besides techno-economic and environmental information transparency on sector-specific justice implications of transforming steel industries is essential for decision-making on technological routes
Progress in Biofuel Production from Gasification
May 2017
Publication
Biofuels from biomass gasification are reviewed here and demonstrated to be an attractive option. Recent progress in gasification techniques and key generation pathways for biofuels production process design and integration and socio-environmental impacts of biofuel generation are discussed with the goal of investigating gasification-to-biofuels’ credentials as a sustainable and eco-friendly technology. The synthesis of important biofuels such as bio-methanol bio-ethanol and higher alcohols bio-dimethyl ether Fischer Tropsch fuels bio-methane bio-hydrogen and algae-based fuels is reviewed together with recent technologies catalysts and reactors. Significant thermodynamic studies for each biofuel are also examined. Syngas cleaning is demonstrated to be a critical issue for biofuel production and innovative pathways such as those employed by Choren Industrietechnik Germany and BioMCN the Netherlands are shown to allow efficient methanol generation. The conversion of syngas to FT transportation fuels such as gasoline and diesel over Co or Fe catalysts is reviewed and demonstrated to be a promising option for the future of biofuels. Bio-methane has emerged as a lucrative alternative for conventional transportation fuel with all the advantages of natural gas including a dense distribution trade and supply network. Routes to produce H2 are discussed though critical issues such as storage expensive production routes with low efficiencies remain. Algae-based fuels are in the research and development stage but are shown to have immense potential to become commercially important because of their capability to fix large amounts of CO2 to rapidly grow in many environments and versatile end uses. However suitable process configurations resulting in optimal plant designs are crucial so detailed process integration is a powerful tool to optimize current and develop new processes. LCA and ethical issues are also discussed in brief. It is clear that the use of food crops as opposed to food wastes represents an area fraught with challenges which must be resolved on a case by case basis.
A Developed Plasmatron Design to Enhance Production of Hydrogen in Synthesis Gas Produced by a Fuel Reformer System
Jan 2022
Publication
Feeding IC engines with hydrogen‐rich syngas as an admixture to hydrocarbon fuels can decrease pollutant emissions particularly NOx. It offers a potential technique for low‐environmen‐ tal impact hydrocarbon fuel use in automotive applications. However hydrogen‐rich reformate gas (syngas) production via fuel reforming still needs more research and optimization. In this paper we describe the effect of a plasma torch assembly design on syngas yield and composition during plasma‐assisted reforming of gasoline. Additionally erosion resistance of the cathode‐emitting ma‐ terial under the conditions of gasoline reforming was studied using hafnium metal and lanthanated tungsten alloy. The gasoline reforming was performed with a noncatalytic nonthermal low‐current plasma system in the conditions of partial oxidation in an air and steam mixture. To find the most efficient plasma torch assembly configuration in terms of hydrogen production yield four types of anode design were tested i.e. two types of the swirl ring and two cathode materials while varying the inlet air and fuel flow rates. The experimental results showed that hydrogen was the highest proportion of the produced syngas. The smooth funnel shape anode design in Ring 1 at air/fuel flow rates of 24/4 27/4.5 and 30/5 g/min respectively was more effective than the edged funnel shape. Lanthanated tungsten alloy displayed higher erosion resistance than hafnium metal.
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