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Regulations and Research on RC&S for Hydrogen Storage Relevant To Transport and Vehicle Issues with Special Focus on Composite Containments
Sep 2011
Publication
Developers interested in high pressure storage of hydrogen for mobile use increasingly rely on composite cylinders for onboard storage or transport of dangerous goods. Thus composite materials and systems deserve special consideration. History gives interesting background information important to the understanding of the current situation as to regulations codes and standards.Based on this review origins of different regulations for the storage o Read More
Spontaneous Ignition Processes Due To High-Pressure Hydrogen Release in Air
Sep 2011
Publication
Spontaneous ignition processes due to the high-pressure hydrogen releases into air were investigated both experimentally and theoretically. Such processes reproduce accident scenarios of sudden expansion of pressurized hydrogen into the ambient atmosphere in cases of tube or valve rupture. High-pressure hydrogen releases in the range of initial pressures from 20 to 275 bar and with nozzle diameters of 0.5 – 4 mm have been investigated. Glass tube Read More
Pressure Cycling Of Type 1 Pressure Vessels with Gaseous Hydrogen
Sep 2011
Publication
Type 1 steel pressure vessels are commonly used for the transport of pressurized gases including gaseous hydrogen. In the majority of cases these cylinders experience relatively few pressure cycles over their lifetime perhaps in the hundreds. In emerging markets such as hydrogen-powered industrial trucks hydrogen fuel systems are expected to experience thousands of cycles over just a few year period. This study investigates the fatigue life of Type Read More
Flammability Limits and Laminar Flame Speed of Hydrogen–air Mixtures at Sub-atmospheric Pressures
Sep 2011
Publication
Hydrogen behavior at elevated pressures and temperatures was intensively studied by numerous investigators. Nevertheless there is a lack of experimental data on hydrogen ignition and combustion at reduced sub-atmospheric pressures. Such conditions are related to the facilities operating under vacuum or sub-atmospheric conditions for instance like ITER vacuum vessel. Main goal of current work was an experimental evaluation of such fundamental Read More
Numerical Study on Fast Filling of 70 MPA Hydrogen Vehicle Cylinder
Sep 2011
Publication
There will be significant temperature rise within hydrogen vehicle cylinder during the fast filling process. The temperature rise should be controlled under the temperature limit (85 °C) of the structure material (set by ISO/TS 15869) because it may lead to the failure of the structure. In this paper a 2-dimensional axisymmetric computational fluid dynamics (CFD) model for fast filling of 70 MPa hydrogen vehicle cylinder is presented. The numerical simulation Read More
The Fifth Carbon Budget: The Next Step Towards a Low-carbon Economy
Nov 2015
Publication
This report sets out our advice on the fifth carbon budget covering the period 2028-2032 as required under Section 4 of the Climate Change Act; the Government will propose draft legislation for the fifth budget in summer 2016.
An Independent Assessment of the UK’s Clean Growth Strategy: From Ambition to Action
Nov 2018
Publication
This report provides the Committee on Climate Change’s response to the UK Government’s Clean Growth Strategy.The report finds that:The Government has made a strong commitment to achieving the UK’s climate change targets.Policies and proposals set out in the Clean Growth Strategy will need to be firmed up.Gaps to meeting the fourth and fifth carbon budgets remain. These gaps must be closed.Risks of under-delivery must be addressed and carbon Read More
Hydrogen in a Low-carbon Economy
Nov 2018
Publication
This report by the Committee on Climate Change (CCC) assesses the potential role of hydrogen in the UK’s low-carbon economy.It finds that hydrogen:is a credible option to help decarbonise the UK energy system but its role depends on early Government commitment and improved support to develop the UK’s industrial capabilitycan make an important contribution to long-term decarbonisation if combined with greater energy efficiency cheap low-carbon Read More
The Role of Charging and Refuelling Infrastructure in Supporting Zero-emission Vehicle Sales
Mar 2020
Publication
Widespread uptake of battery electric plug-in hybrid and hydrogen fuel-cell vehicles (collectively zero-emissions vehicles or ZEVs) could help many regions achieve deep greenhouse gas mitigation goals. Using the case of Canada this study investigates the extent to which increasing ZEV charging and refuelling availability may boost ZEV sales relative to other ZEV-supportive policies. We adapt a version of the Respondent-based Preferences and Constraint Read More
Public Acceptability of the Use of Hydrogen for Heating and Cooking in the Home: Results from Qualitative and Quantitative Research in UK<br/>Executive Summary
Nov 2018
Publication
This report for the CCC by Madano and Element Energy assesses the public acceptability of two alternative low-carbon technologies for heating the home: hydrogen heating and heat pumps.These technologies could potentially replace natural gas in many UK households as part of the government’s efforts to decrease carbon emissions in the UK.The report’s key findings are:carbon emissions reduction is viewed as an important issue but there is limited Read More
Hydrogen Onboard Storage: An Insertion of the Probabilistic Approach Into Standards & Regulations?
Sep 2005
Publication
The growing attention being paid by car manufacturers and the general public to hydrogen as a middle and long term energy carrier for automotive purpose is giving rise to lively discussions on the advantages and disadvantages of this technology – also with respect to safety. In this connection the focus is increasingly and justifiably so on the possibilities offered by a probabilistic approach to loads and component characteristics: a lower weight oblige Read More
Requirements for the Safety Assessment for the Approval of a Hydrogen Refueling Station
Sep 2007
Publication
The EC 6th framework research project HyApproval will draft a Handbook which will describe all relevant issues to get approval to construct and operate a Hydrogen Refuelling Station (HRS) for hydrogen vehicles. In WP3 of the HyApproval project it is under investigation which safety information competent authorities require to give a licence to construct an operate an HRS. The paper describes the applied methodology to collect the information from Read More
Safety Demands for Automotive Hydrogen Storage Systems
Sep 2005
Publication
Fuel storage systems for vehicles require a fail-safe design strategy. In case of system failures or accidents the control electronics have to switch the system into a safe operation mode. Failure Mode and Effect Analysis (FMEA) or Failure Tree Analysis (FTA) are performed already in the early design phase in order to minimize the risk of design failures in the fuel storage system. Currently the specifications of requirements for pressurized and liquid hydrogen fue Read More
Development of High-pressure Hydrogen Gas Barrier Materials
Oct 2015
Publication
We prepared several gas barrier resins based on amorphous PVA derivative that has the T1C (13C spin-lattice relaxation time) of a long time component in amorphous phase. We confirmed it was important to control state in amorphous phase of gas barrier resin in order to achieve both moldability and good gas barrier property. Polymer alloy was designed to improve flexibility. Polymer alloy made of amorphous PVA and elastomer resin showed good hydro Read More
Meeting Carbon Budgets – Ensuring a Low-carbon Recovery
Jun 2010
Publication
As part of its statutory role the Committee provides annual reports to Parliament on the progress that Government is making in meeting carbon budgets and in reducing emissions of greenhouse gases.Meeting Carbon Budgets – ensuring a low-carbon recovery is the Committee’s 2nd progress report. Within this report we assess the latest emissions data and determine whether emissions reductions have occurred as a result of the recession or as a result o Read More
Determination of Clearance Distances for Venting of Hydrogen Storage
Sep 2005
Publication
This paper discusses the results of computational fluid dynamics (CFD) modelling of hydrogen releases and dispersion outdoors during venting of hydrogen storage in real environment and geometry of a hydrogen refuelling or energy station for a given flow rate and dimensions of vent stack. The PHOENICS CFD software package was used to solve the continuity momentum and concentration equations with the appropriate boundary conditions buoyancy Read More
Reducing Emissions in Scotland – 2018 Progress Report
Sep 2019
Publication
This is the Committee’s seventh report on Scotland’s progress towards meetings emissions targets as requested by Scottish Ministers under the Climate Change (Scotland) Act 2009.Overall Scotland continues to outperform the rest of the UK in reducing its greenhouse gas emissions but successful strategies for energy and waste mask a lack of progress in other parts of the Scottish economy.The report shows that Scotland’s total emissions fell by 10% i Read More
Progress Report 2016: Meeting Carbon Budgets
Jun 2016
Publication
This is the CCC’s eighth annual report on the UK’s progress in meeting carbon budgets.The report shows that greenhouse gas emissions have fallen rapidly in the UK power sector but that progress has stalled in other sectors such as:heating in buildingstransportindustryagricultureThe report also outlines the Committee’s view of key criteria for the government’s ’emissions reduction plan’ published later in 2017
Massive H2 Production With Nuclear Heating, Safety Approach For Coupling A VHTR With An Iodine Sulfur Process Cycle
Sep 2005
Publication
In the frame of a sustainable development investigations dealing with massive Hydrogen production by means of nuclear heating are carried out at CEA. For nuclear safety thermodynamic efficiency and waste minimization purposes the technological solution privileged is the coupling of a gas cooled Very High Temperature Reactor (VHTR) with a plant producing Hydrogen from an Iodine/Sulfur (I/S) thermochemical cycle. Each of the aforementioned facili Read More
Dispersion Tests on Concentration and its Fluctuations for 40MPa Pressurized Hydrogen
Sep 2007
Publication
Hydrogen is one of the important alternative fuels for future transportation. At the present stage research into hydrogen safety and designing risk mitigation measures are significant task. For compact storage of hydrogen in fuel cell vehicles storage of hydrogen under high pressure up to 40 MPa at refuelling stations is planned and safety in handling such high-pressure hydrogen is essential. This paper describes our experimental investigation into disper Read More
Experimental Releases of Liquid Hydrogen
Sep 2011
Publication
If the hydrogen economy is to progress more hydrogen refuelling stations are required. In the short term in the absence of a hydrogen distribution network the most likely means of supplying the refuelling stations will be by liquid hydrogen road tanker. This development will clearly increase the number of tanker offloading operations significantly and these may need to be performed in more challenging environments with close proximity to the general publ Read More
Fundamental Safety Testing and Analysis of Solid State Hydrogen Storage Materials and Systems
Sep 2007
Publication
Hydrogen is seen as the future automobile energy storage media due to its inherent cleanliness upon oxidation and its ready utilization in fuel cell applications. Its physical storage in light weight low volume systems is a key technical requirement. In searching for ever higher gravimetric and volumetric density hydrogen storage materials and systems it is inevitable that higher energy density materials will be studied and used. To make safe and co Read More
Numerical Analysis for Hydrogen Flame Acceleration during a Severe Accident Initiated by SBLOCA in the APR1400 Containment
Jan 2022
Publication
We performed a hydrogen combustion analysis in the Advanced Power Reactor 1400 MWe (APR1400) containment during a severe accident initiated by a small break loss of coolant accident (SBLOCA) which occurred at a lower part of the cold leg using a multi-dimensional hydrogen analysis system (MHAS) to confirm the integrity of the APR1400 containment. The MHAS was developed by combining MAAP GASFLOW and COM3D to simulate hydrogen rele Read More
Compatibility of Metallic Materials with Hydrogen Review of the Present Knowledge
Sep 2007
Publication
In this document after a review of the accidents/incidents are described the different interactions between hydrogen gas and the most commonly used materials including the influence of "internal" and "external" hydrogen the phenomena occurring in all ranges of temperatures and pressures and Hydrogen Embrittlement (HE) created by gaseous hydrogen. The principle of all the test methods used to investigate this phenomenon are presented and di Read More
CFD Modelling of Accidental Hydrogen Release from Pipelines
Sep 2005
Publication
Although today hydrogen is distributed mainly by trailers in the long terms pipeline distribution will be more suitable if large amounts of hydrogen are produced on industrial scale. Therefore from the safety point of view it is essential to compare hydrogen pipelines to natural gas pipelines which are well established today. Within the paper we compare safety implications in accidental situations. We do not look into technological aspects such as com Read More
A Comparative Feasibility Study of the Use of Hydrogen Produced from Surplus Wind Power for a Gas Turbine Combined Cycle Power Plant
Dec 2021
Publication
Because of the increasing challenges raised by climate change power generation from renewable energy sources is steadily increasing to reduce greenhouse gas emissions especially CO2 . However this has escalated concerns about the instability of the power grid and surplus power generated because of the intermittent power output of renewable energy. To resolve these issues this study investigates two technical options that integrate a power-to-gas Read More
Life Cycle Environmental Analysis of a Hydrogen-based Energy Storage System for Remote Applications
Mar 2022
Publication
Energy storage systems are required to address the fluctuating behaviour of variable renewable energy sources. The environmental sustainability of energy storage technologies should be carefully assessed together with their techno-economic feasibility. In this work an environmental analysis of a renewable hydrogen-based energy storage system has been performed making use of input parameters made available in the framework of the European R Read More
The Safe Use of the Existing Natural Gas System for Hydrogen (Overview of the NATURALHY-Project)
Sep 2005
Publication
The transition period towards the situation in which hydrogen will become an important energy carrier will be lengthy (decades) costly and needs a significant R&D effort. It’s clear therefore that the development of a hydrogen system requires a practical strategy within the context of the existing assets. Examining the potential of the existing extensive natural gas chain (transmission - distribution - end user infrastructures and appliances) is a logical first step Read More
Assessment and Evaluation of 3rd Party Risk for Planned Hydrogen Demonstration Facility
Sep 2007
Publication
Potential risk exposure of 3rd parties i.e. people not involved in the actual operation of a plant is often a critical factor to gain authority approval and public acceptance for a development project. This is also highly relevant for development of demonstration facilities for hydrogen production and refuelling infrastructure. This paper presents and discusses results for risk exposure of 3rd parties based on risk assessment studies performed for the plan Read More
Compatibility of Materials with Hydrogen Particular Case- Hydrogen Assisted Stress Cracking of Titanium Alloys
Sep 2007
Publication
A review of the effect of hydrogen on materials is addressed in this paper. General aspects of the interaction of hydrogen and materials hydrogen embrittlement low temperature effects material suitability for hydrogen service and materials testing are the main subjects considered in the first part of the paper. As a particular case of the effect of hydrogen in materials the hydride formation of titanium alloys is considered. Alpha titanium alloys are c Read More
A Study of Barrier Walls for Mitigation of Unintended Releases of Hydrogen
Sep 2009
Publication
Hydrogen jet flames resulting from ignition of unintended releases can be extensive in length and pose significant radiation and impingement hazards. Depending on the leak diameter and source pressure the resulting consequence distances can be unacceptably large. One possible mitigation strategy to reduce exposure to jet flames is to incorporate barriers around hydrogen storage and delivery equipment. An experimental and modeling progra Read More
Complex Hydrides as Solid Storage Materials- First Safety Tests
Sep 2007
Publication
Hydrogen technology requires efficient and safe hydrogen storage systems. For this purpose storage in solid materials such as high capacity complex hydrides is studied intensely. Independent from the actual material to be used eventually any tank design will combine nanoscale powders of highly reactive material with pressurized hydrogen gas and so far little is known about the behaviour of these mixtures in case of incidents. For a first evaluation Read More
Hydrogen Storage: Thermodynamic Analysis of Alkyl-Quinolines and Alkyl-Pyridines as Potential Liquid Organic Hydrogen Carriers (LOHC)
Dec 2021
Publication
The liquid organic hydrogen carriers (LOHC) are aromatic molecules which can be considered as an attractive option for the storage and transport of hydrogen. A considerable amount of hydrogen up to 7–8% wt. can be loaded and unloaded with a reversible chemical reaction. Substituted quinolines and pyridines are available from petroleum coal processing and wood preservation or they can be synthesized from aniline. Quinolines and pyridines c Read More
Hydrogen Safety Aspects Related to High Pressure - PEM Water Electrolysis
Sep 2007
Publication
Polymer electrolyte membrane (PEM) water electrolysis has demonstrated its potentialities in terms of cell efficiency (energy consumption ≈ 4.0-4.2 kW/Nm3 H2) and gas purity (> 99.99% H2). Current research activities are aimed at increasing operating pressure up to several hundred bars for direct storage of hydrogen in pressurized vessels. Compared to atmospheric pressure electrolysis high-pressure operation yields additional problems especially wit Read More
Heat Radiation of Burning Hydrogen Air Mixtures Impurified by Organic Vapour and Particles
Sep 2007
Publication
Experiments were performed to investigate the radiative heat emission of small scale hydrogen/air explosions also impurified by minor amounts of inert particles and organic fuels. A volume of 1.5 dm3 hydrogen was injected into ambient air as free-jet and ignited. In further experiments simultaneously inert Aerosil and combustible fuels were injected into the blasting hydrogen/air gas cloud. Fuels were a spray of a solvent (Dipropyleneglycol-methyleth Read More
Modelling of Lean Uniform and Non-Uniform Hydrogen-Air Mixture Explosions in a Closed Vessel
Sep 2009
Publication
Simulation of hydrogen-air mixture explosions in a closed large-scale vessel with uniform and nonuniform mixture compositions was performed by the group of partners within the EC funded project “Hydrogen Safety as an Energy Carrier” (HySafe). Several experiments were conducted previously by Whitehouse et al. in a 10.7 m3 vertically oriented (5.7-m high) cylindrical facility with different hydrogen-air mixture compositions. Two particular experiments we Read More
Heat Networks 2020
Dec 2020
Publication
This publication by the Department for Business Energy and Industrial Strategy (BEIS) brings together heat networks investment opportunities in England and Wales. The opportunities present a wide range of projects supported through the development stages by the Heat Networks Delivery Unit (HNDU) and projects seeking capital support from the Heat Networks Investment Project (HNIP).The publication includes a list of one-page summaries for each Read More
Using Hydrogen Safety Best Practices and Learning From Safety Events
Sep 2009
Publication
A best practice is a technique or methodology that has reliably led to a desired result. A wealth of experience regarding the safe use and handling of hydrogen exists as a result of an extensive history in a wide variety of industrial and aerospace settings. Hydrogen Safety Best Practices (www.h2bestpractices.org) captures this vast knowledge base and makes it publicly available to those working with hydrogen and related systems Read More
Large-scale Hydrogen Release in an Isothermal Confined Area
Sep 2007
Publication
INERIS has set up large-scale fully instrumented experiments to study the formation of flammable clouds resulting from a finite duration spillage of hydrogen in a quiescent room (80 m3 chamber). Concentration temperature and mass flow measurements were monitored during the release period and several hours after. Experiments were carried out for mass flow rates ranging from 02 g/s to 1 g/s. The instrumentation allowed the observation and quan Read More
Materials Considerations in Hydrogen Production
Sep 2007
Publication
Correct selection and application of materials is essential to ensure safety and economy in production transportation and storage of hydrogen. There are several sources of materials challenges related to hydrogen. Established component producers may have limited experience in this specific field. Process developments may involve new process conditions with new demands on the materials. Further new materials will be added to the engineering to Read More
Recent Progress in the Steam Reforming of Bio-Oil for Hydrogen Production: A Review of Operating Parameters, Catalytic Systems and Technological Innovations
Dec 2021
Publication
The present review focuses on the production of renewable hydrogen through the catalytic steam reforming of bio-oil the liquid product of the fast pyrolysis of biomass. Although in theory the process is capable of producing high yields of hydrogen in practice certain technological issues require radical improvements before its commercialization. Herein we illustrate the fundamental knowledge behind the technology of the steam reforming of bio Read More
Predicting the Probability of Failure of Gas Pipelines Including Inspection and Repair Procedures
Sep 2007
Publication
This paper is concerned with predicting the impact on the probability of failure of adding hydrogen to the natural gas distribution network. Hydrogen has been demonstrated to change the behaviour of crack like defects which may affect the safety of pipeline or make it more expensive to operate. A tool has been developed based on a stochastic approach to assess the failure probability of the gas pipeline due to the existence of crack-lie defects includ Read More
Novel Wide-area Hydrogen Sensing Technology
Sep 2007
Publication
Element One Inc. is developing novel indicators for hydrogen gas for applications as a complement to conventional electronic hydrogen sensors or as a low-cost alternative in situations where an electronic signal is not needed. The indicator consists of a thin film coating or a pigment of a transition metal oxide such as tungsten oxide or molybdenum oxide with a catalyst such as platinum or palladium. The oxide is partially reduced in the presence of hydr Read More
Hydrogen Safety- New Challenges Based on BMW Hydrogen 7
Sep 2007
Publication
The BMW Hydrogen 7 is the world’s first premium sedan with a bi-fuelled internal combustion engine concept that has undergone the series development process. This car also displays the BMW typical driving pleasure. During development the features of the hydrogen energy source were emphasized. Engine tank system and vehicle electronics were especially developed as integral parts of the vehicle for use with hydrogen. The safety-oriented develop Read More
Measurement of Fatigue Crack Growth Rates for Steels in Hydrogen Containment Components
Sep 2009
Publication
The objective of this work was to enable the safe design of hydrogen pressure vessels by measuring the fatigue crack growth rates of ASME code-qualified steels in high-pressure hydrogen gas. While a design framework has recently been established for high-pressure hydrogen vessels a material property database does not exist to support the design calculations. This study addresses such voids in the database by measuring the fatigue crack growth Read More
Developing a Hydrogen Fuel Cell Vehicle (HFCV) Energy Consumption Model for Transportation Applications
Jan 2022
Publication
This paper presents a simple hydrogen fuel cell vehicle (HFCV) energy consumption model. Simple fuel/energy consumption models have been developed and employed to estimate the energy and environmental impacts of various transportation projects for internal combustion engine vehicles (ICEVs) battery electric vehicles (BEVs) and hybrid electric vehicles (HEVs). However there are few published results on HFCV energy models that can be simply i Read More
Simulation of the Fast Filling of Hydrogen Tanks
Sep 2009
Publication
High pressure storage of hydrogen in tanks is a promising option to provide the necessary fuel for transportation purposes. The fill process of a high-pressure tank should be reasonably short but must be designed to avoid too high temperatures in the tank. The shorter the fill should be the higher the maximum temperature in the tank climbs. For safety reasons an upper temperature limit is included in the requirements for refillable hydrogen tanks (ISO 1 Read More
Hydrogen Impact on Gas Engine CHP - Cadent Ltd
Feb 2019
Publication
The key project objectives include:Understand the range size type mode of operation and control system of installed gas engines in the UK. This will include equipment for CHP and for stand-by power operation.Produce data sets on the impact of hydrogen on gas engine operational performance.Develop knowledge on the impact of hydrogen content on the operation of the gas engine including overall efficiency changes to emissions profiles overall Read More
World Energy Issues Monitor 2019 Managing the Grand Energy Transition
Oct 2019
Publication
This is the tenth consecutive year of the World Energy Council’s (the Council) annual survey of key challenges and opportunities facing energy leaders in managing and shaping Energy Transitions. This year’s Issues Monitor report provides seven global maps six regional maps and fifty national maps.These maps have been developed by analysing the responses of nearly 2300 energy leaders drawn from across the Council’s diverse and truly global en Read More
Legal Regulation of Hydrogen in Germany and Ukraine as a Precondition for Energy Partnership and Energy Transition
Dec 2021
Publication
In August 2020 Germany and Ukraine launched an energy partnership that includes the development of a hydrogen economy. Ukraine has vast renewable energy resources for “green” hydrogen production and a gas transmission system for transportation instead of Russian natural gas. Based on estimates by Hydrogen Europe Ukraine can install 8000 MW of total electrolyser capacity by 2030. For these reasons Ukraine is among the EU’s priority partner Read More
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