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Advanced Optimal Planning for Microgrid Technologies Including Hydrogen and Mobility at a Real Microgrid Testbed
Apr 2021
Publication
This paper investigates the optimal planning of microgrids including the hydrogen energy system through mixed-integer linear programming model. A real case study is analyzed by extending the only microgrid lab facility in Austria. The case study considers the hydrogen production via electrolysis seasonal storage and fuelling station for meeting the hydrogen fuel demand of fuel cell vehicles busses and trucks. The optimization is performed relative to two different reference cases which satisfy the mobility demand by diesel fuel and utility electricity based hydrogen fuel production respectively. The key results indicate that the low emission hydrogen mobility framework is achieved by high share of renewable energy sources and seasonal hydrogen storage in the microgrid. The investment optimization scenarios provide at least 66% and at most 99% carbon emission savings at increased costs of 30% and 100% respectively relative to the costs of the diesel reference case (current situation)
Decrease in Hydrogen Embrittlement Susceptibility of 10B21 Screws by Bake Aging
Aug 2016
Publication
The effects of baking on the mechanical properties and fracture characteristics of low-carbon boron (10B21) steel screws were investigated. Fracture torque tests and hydrogen content analysis were performed on baked screws to evaluate hydrogen embrittlement (HE) susceptibility. The diffusible hydrogen content within 10B21 steel dominated the fracture behavior of the screws. The fracture torque of 10B21 screws baked for a long duration was affected by released hydrogen. Secondary ion mass spectroscopy (SIMS) result showed that hydrogen content decreased with increasing baking duration and thus the HE susceptibility of 10B21 screws improved. Diffusible hydrogen promoted crack propagation in high-stress region. The HE of 10B21 screws can be prevented by long-duration baking.
A Comparative Review of Alternative Fuels for the Maritime Sector: Economic, Technology, and Policy Challenges for Clean Energy Implementation
Oct 2021
Publication
Global maritime transportation is responsible for around 3% of total anthropogenic green‐ house gas emissions and significant proportions of SOx NOx and PM emissions. Considering the predicted growth in shipping volumes to 2050 greenhouse gas emissions from ships must be cut by 75–85% per ton‐mile to meet Paris Agreement goals. This study reviews the potential of a range of alternative fuels for decarbonisation in maritime. A systematic literature review and information synthesis method was applied to evaluate fuel characteristics production pathways utilization technologies energy efficiency lifecycle environmental performance economic viability and cur‐ rent applicable policies. Alternative fuels are essential to decarbonisation in international shipping. However findings suggest there is no single route to deliver the required greenhouse gas emissions reductions. Emissions reductions vary widely depending on the production pathways of the fuel. Alternative fuels utilising a carbon‐intensive production pathway will not provide decarbonisation instead shifting emissions elsewhere in the supply chain. Ultimately a system‐wide perspective to creating an effective policy framework is required in order to promote the adoption of alternative propulsion technologies.
Utilization and Recycling of End of Life Plastics for Sustainable and Clean Industrial Processes Including the Iron and Steel Industry
Aug 2019
Publication
About 400 million tonnes of plastics are produced per annum worldwide. End-of-life of plastics disposal contaminates the waterways aquifers and limits the landfill areas. Options for recycling plastic wastes include feedstock recycling mechanical /material recycling industrial energy recovery municipal solid waste incineration. Incineration of plastics containing E-Wastes releases noxious odours harmful gases dioxins HBr polybrominated diphenylethers and other hydrocarbons. This study focusses on recycling options in particular feedstock recycling of plastics in high-temperature materials processing for a sustainable solution to the plastic wastes not suitable for recycling. Of the 7% CO2 emissions attributed to the iron and steel industry worldwide ∼30% of the carbon footprint is reduced using the waste plastics compared to other carbon sources in addition to energy savings. Plastics have higher H2 content than the coal. Hydrogen evolved from the plastics acts as the reductant alongside the carbon monoxide. Hydrogen reduction of iron ore in presence of plastics increases the reaction rates due to higher diffusion of H2 compared to CO. Plastic replacement reduces the process temperature by at least 100–200 °C due to the reducing gases (hydrogen) which enhance the energy efficiency of the process. Similarly plastics greatly reduce the emissions in other high carbon footprint process such as magnesia production while contributing to energy.
Analysis of Stress Corrosion Cracking in X80 Pipeline Steel: An Approach from the Theory of Critical Distances
Dec 2018
Publication
This paper presents an analysis of Stress Corrosion Cracking (SCC) based on the Theory of Critical Distances (TCD). The research is based on an experimental program composed of fracture specimens with notch radius varying from 0 mm (crack-like defect) up to 1 mm and tensile specimens. A pipeline steel was used in this work (X80). It has been analysed in one hydrogen embrittlement situation. The study has been completed with Finite Elements Simulation analysis. The capacity of the TCD to analyse SCC processes has been proven.
Hydrogen Production as a Clean Energy Carrier through Heterojunction Semiconductors for Environmental Remediation
Apr 2022
Publication
Today as a result of the advancement of technology and increasing environmental problems the need for clean energy has considerably increased. In this regard hydrogen which is a clean and sustainable energy carrier with high energy density is among the well-regarded and effective means to deliver and store energy and can also be used for environmental remediation purposes. Renewable hydrogen energy carriers can successfully substitute fossil fuels and decrease carbon dioxide (CO2 ) emissions and reduce the rate of global warming. Hydrogen generation from sustainable solar energy and water sources is an environmentally friendly resolution for growing global energy demands. Among various solar hydrogen production routes semiconductor-based photocatalysis seems a promising scheme that is mainly performed using two kinds of homogeneous and heterogeneous methods of which the latter is more advantageous. During semiconductor-based heterogeneous photocatalysis a solid material is stimulated by exposure to light and generates an electron–hole pair that subsequently takes part in redox reactions leading to hydrogen production. This review paper tries to thoroughly introduce and discuss various semiconductor-based photocatalysis processes for environmental remediation with a specific focus on heterojunction semiconductors with the hope that it will pave the way for new designs with higher performance to protect the environment.
Advanced Sizing Methodology for a Multi-Mode eVTOL UAV Powered by a Hydrogen Fuel Cell and Battery
Jan 2022
Publication
A critical drawback of battery-powered eVTOL UAVs is their limited range and endurance and this drawback could be solved by using a combination of hydrogen fuel cells and batteries. The objective of this paper is to develop a sizing methodology for the lift+cruise-type eVTOL UAV powered by a hydrogen fuel cell and battery. This paper presents the constraints analysis method for forward flight/VTOL multi-mode UAV the regression model for electric propulsion system sizing a sizing method for an electric propulsion system and hydrogen fuel cell system and a transition analysis method. The total mass of the UAV is iteratively calculated until convergence and the optimization method is used to ensure that the sizing results satisfy the design requirements. The sizing results are the UAV’s geometry mass and power data. To verify the accuracy of the proposed sizing methodology the sizing and the conceptual design phase results of a 25 kg hydrogen fuel-cell-powered UAV are compared. All parameters had an error within 10% and satisfied the design requirements.
Investing in Hydrogen: Ready, Set, Net Zero
Sep 2020
Publication
Achieving the UK's net zero target by 2050 will be a challenge. Hydrogen can make a substantial contribution but it needs investment and policy support to establish demand increase the scale of deployment and reduce costs. The Ten Point Plan for a Green Industrial Revolution confirms the government’s commitment to drive the growth of low carbon hydrogen in the UK through a range of measures. This includes publishing its hydrogen strategy and setting out revenue mechanisms to attract private investment as well as allocating further support for hydrogen production and hydrogen applications in heating.
We have created a bespoke model to help understand the cost of hydrogen in the UK across the value chain under different pathways. Our analysis highlights areas for cost reduction and identifies factors that could make hydrogen more attractive to investors.
You can read the full report on the Deloitte website at this link
We have created a bespoke model to help understand the cost of hydrogen in the UK across the value chain under different pathways. Our analysis highlights areas for cost reduction and identifies factors that could make hydrogen more attractive to investors.
You can read the full report on the Deloitte website at this link
Using Additives to Control the Decomposition Temperature of Sodium Borohydride
May 2020
Publication
Hydrogen (H2) shows great promise as zero-carbon emission fuel but there are several challenges to overcome in regards to storage and transportation to make it a more universal energy solution. Gaseous hydrogen requires high pressures and large volume tanks while storage of liquid hydrogen requires cryogenic temperatures; neither option is ideal due to cost and the hazards involved. Storage in the solid state presents an attractive alternative and can meet the U.S. Department of Energy (DOE) constraints to find materials containing > 7 % H2 (gravimetric weight) with a maximum H2 release under 125 °C.
While there are many candidate hydrogen storage materials the vast majority are metal hydrides. Of the hydrides this review focuses solely on sodium borohydride (NaBH4) which is often not covered in other hydride reviews. However as it contains 10.6% (by weight) H2 that can release at 133 ± 3 JK−1mol−1 this inexpensive material has received renewed attention. NaBH4 should decompose to H2g) Na(s) and B(s) and could be recycled into its original form. Unfortunately metal to ligand charge transfer in NaBH4 induces high thermodynamic stability creating a high decomposition temperature of 530 °C. In an effort make H2 more accessible at lower temperatures researchers have incorporated additives to destabilize the structure.
This review highlights metal additives that have successfully reduced the decomposition temperature of NaBH4 with temperatures ranging from 522 °C (titanium (IV) fluoride) to 379 °C (niobium (V) fluoride). We describe synthetic methods employed chemical pathways taken and the challenges of boron derivative formation on H2 cycling. Though no trends can be found across all additives it is our hope that compiling the data here will enable researchers to gain a better understanding of the additives’ influence and to determine how a new system might be designed to make NaBH4 a more viable H2 fuel source.
While there are many candidate hydrogen storage materials the vast majority are metal hydrides. Of the hydrides this review focuses solely on sodium borohydride (NaBH4) which is often not covered in other hydride reviews. However as it contains 10.6% (by weight) H2 that can release at 133 ± 3 JK−1mol−1 this inexpensive material has received renewed attention. NaBH4 should decompose to H2g) Na(s) and B(s) and could be recycled into its original form. Unfortunately metal to ligand charge transfer in NaBH4 induces high thermodynamic stability creating a high decomposition temperature of 530 °C. In an effort make H2 more accessible at lower temperatures researchers have incorporated additives to destabilize the structure.
This review highlights metal additives that have successfully reduced the decomposition temperature of NaBH4 with temperatures ranging from 522 °C (titanium (IV) fluoride) to 379 °C (niobium (V) fluoride). We describe synthetic methods employed chemical pathways taken and the challenges of boron derivative formation on H2 cycling. Though no trends can be found across all additives it is our hope that compiling the data here will enable researchers to gain a better understanding of the additives’ influence and to determine how a new system might be designed to make NaBH4 a more viable H2 fuel source.
High-Purity and Clean Syngas and Hydrogen Production From Two-Step CH4 Reforming and H2O Splitting Through Isothermal Ceria Redox Cycle Using Concentrated Sunlight
Jul 2020
Publication
The thermochemical conversion of methane (CH4) and water (H2O) to syngas and hydrogen via chemical looping using concentrated sunlight as a sustainable source of process heat attracts considerable attention. It is likewise a means of storing intermittent solar energy into chemical fuels. In this study solar chemical looping reforming of CH4 and H2O splitting over non-stoichiometric ceria (CeO2/CeO2−δ) redox cycle were experimentally investigated in a volumetric solar reactor prototype. The cycle consists of (i) the endothermic partial oxidation of CH4 and the simultaneous reduction of ceria and (ii) the subsequent exothermic splitting of H2O and the simultaneous oxidation of the reduced ceria under isothermal operation at ~1000°C enabling the elimination of sensible heat losses as compared to non-isothermal thermochemical cycles. Ceria-based reticulated porous ceramics with different sintering temperatures (1000 and 1400°C) were employed as oxygen carriers and tested with different methane flow rates (0.1–0.4 NL/min) and methane concentrations (50 and 100%). The impacts of operating conditions on the foam-averaged oxygen non-stoichiometry (reduction extent δ) syngas yield methane conversion solar-to-fuel energy conversion efficiency as well as the effects of transient solar conditions were demonstrated and emphasized. As a result clean syngas was successfully produced with H2/CO ratios approaching 2 during the first reduction step while high-purity H2 was subsequently generated during the oxidation step. Increasing methane flow rate and CH4 concentration promoted syngas yields up to 8.51 mmol/gCeO2 and δ up to 0.38 at the expense of enhanced methane cracking reaction and reduced CH4 conversion. Solar-to-fuel energy conversion efficiency namely the ratio of the calorific value of produced syngas to the total energy input (solar power and calorific value of converted methane) and CH4 conversion were achieved in the range of 2.9–5.6% and 40.1–68.5% respectively.
Complex Methods of Estimation Technological Strength of Welded Joints in Welding at Low Temperatures
Feb 2021
Publication
A comprehensive methodology for estimating the technological strength of welded joints are developed based on parameters reflecting the welding technology weldability hydrogen force and deformation conditions for welding and other informative parameters that correlate with the characteristics of the welded joint as well as improving existing methods for estimating the technological strength of welded joints connections through the introduction of modern equipment and non-destructive testing systems. It has been established that the proposed comprehensive estimation methodology will allow reaching a new qualitative level in assessing the technological strength of a welded joint using modern equipment and measuring instruments. According to the results of the experimental work it was found that when welding at low temperatures the increase in the probability of the formation and development of cold cracks is mainly determined by the critical content of diffusible hydrogen in the weld metal depending on the structural and force parameters of the welded joints.
Hydrogen Production by Fluidized Bed Reactors: A Quantitative Perspective Using the Supervised Machine Learning Approach
Jul 2021
Publication
The current hydrogen generation technologies especially biomass gasification using fluidized bed reactors (FBRs) were rigorously reviewed. There are involute operational parameters in a fluidized bed gasifier that determine the anticipated outcomes for hydrogen production purposes. However limited reviews are present that link these parametric conditions with the corresponding performances based on experimental data collection. Using the constructed artificial neural networks (ANNs) as the supervised machine learning algorithm for data training the operational parameters from 52 literature reports were utilized to perform both the qualitative and quantitative assessments of the performance such as the hydrogen yield (HY) hydrogen content (HC) and carbon conversion efficiency (CCE). Seven types of operational parameters including the steam-to-biomass ratio (SBR) equivalent ratio (ER) temperature particle size of the feedstock residence time lower heating value (LHV) and carbon content (CC) were closely investigated. Six binary parameters have been identified to be statistically significant to the performance parameters (hydrogen yield (HY)) hydrogen content (HC) and carbon conversion efficiency (CCE) by analysis of variance (ANOVA). The optimal operational conditions derived from the machine leaning were recommended according to the needs of the outcomes. This review may provide helpful insights for researchers to comprehensively consider the operational conditions in order to achieve high hydrogen production using fluidized bed reactors during biomass gasification.
High Purity, Self-sustained, Pressurized Hydrogen Production from Ammonia in a Catalytic Membrane Reactor
Dec 2021
Publication
The combination of catalytic decomposition of ammonia and in situ separation of hydrogen holds great promise for the use of ammonia as a clean energy carrier. However finding the optimal catalyst – membrane pair and operation conditions have proved challenging. Here we demonstrate that cobalt-based catalysts for ammonia decomposition can be efficiently 2 used together with a Pd-Au based membrane to produce high purity hydrogen at elevated pressure. Compared to a conventional packed bed reactor the membrane reactor offers several operational advantages that result in energetic and economic benefits. The robustness and durability of the combined system has been demonstrated for more than 1000 h on stream yielding a very pure hydrogen stream (>99.97 % H2) and recovery (>90 %). When considering the required hydrogen compression for storage/utilization and environmental issues the combined system offers the additional advantage of production of hydrogen at moderate pressures along with full ammonia conversion. Altogether our results demonstrate the possibility of deploying high pressure (350 bar) hydrogen generators from ammonia with H2 efficiencies of circa 75% without any external energy input and/or derived CO2 emissions.
HyDeploy2: Materials Summary and Interpretation
May 2021
Publication
During the exemption application process the original report was evaluated as part of a regulatory review and responses to questions submitted for further consideration. These have been addressed in this revised version (revision 1) in the form of an addendum. The addendum includes the question raised its number and the response to it. The area of the main body of the report to which each question and response refers is indicated by square brackets and the addendum number e.g. [A1].<br/>Through analysis of the literature and results of the practical testing the susceptibility of materials present in the Winlaton trial site to hydrogen degradation has been assessed with consideration of the Winlaton operating conditions (up to 20% H2 at total blend pressures of 20 mbar – 2 bar). The aim of this report has been to determine whether there are any components which have been identified at the Winlaton trial site which could have a significantly increased risk of failure due to their exposure to hydrogen during the one year trial. Where possible direct supporting data has been used to make assessments on the likelihood of failure; in other cases the assessment was aided by collaborative expert opinion in the fields of mechanical engineering materials science and the domestic gas industry.<br/>Click on the supplements tab to view the other documents from this report
HyDeploy2: Summary of Procedures for the Trial Network
Jun 2021
Publication
The assessment of appropriate operational procedures to govern the injection of a hydrogen/natural gas blend into Northern Gas Networks’ (NGN) Winlaton gas distribution network was a key requirement of the HyDeploy2 project. To perform this assessment the review was broken down into two areas procedures upstream of the emergency control valve (owned by NGN) and procedures downstream of the Emergency Control Valve (procedures which would be performed by Gas Safe registered individuals). Assessment of the upstream procedures was led by NGN (own and carry out all upstream procedures on NGN’s gas network) and assessment of the downstream procedures was led by Blue Flame Associates (an industry expert on downstream gas procedures).<br/>Methodologies were adopted to be able to highlight procedures that could potentially be used on the Winlaton trial network during the hydrogen blended gas injection period and if they were impacted by the changing of the gas within the network from natural gas to hydrogen blended gas. This method determined that for downstream gas procedures a total of 56 gas procedures required expert review resulting in 80 technical questions to be assessed and for the upstream gas procedures a total of 80 gas procedures required expert review resulting in 266 technical questions to be assessed.<br/>The operational procedures assessment has led to a determination as to whether a change is or is not required for relevant operational procedures where a basis of concern existed with respect to the injection of hydrogen blended gas. Any requirements to modify an existing procedure has been given in this report referencing the source as to where the detailed analysis for the change/no change recommendation has been given.<br/>The assessment took into account the associated experimental and research carried out as part of the HyDeploy and HyDeploy2 projects such as the assessment of gas characteristics materials impact appliance survey of assets on the Winlaton network and impact of hydrogen blended gas on gas detection equipment references to these studies have been given accordingly to associated impacted operational procedures.<br/>The conclusion of the assessment is that for upstream gas procedures there are some operational procedures that are unchanged some that require an increase in the frequency as to how often they are performed and some procedures which require a technical modification. For downstream domestic gas procedures all procedures applicable to a domestic gas installation were deemed to not be detrimentally affected by the introduction of a 20 mol% hydrogen blend.<br/>For upstream gas procedures an appropriate training package will be built off the back of the results presented in this report and disseminated accordingly to all relevant Operatives that will be responsible for the safety operation and maintenance of the Winlaton network during the hydrogen blend injection period. For downstream gas procedures the Gas Safe community have been fully engaged and informed about the trial.<br/>Click on the supplements tab to view the other documents from this report
Hydrogen Storage Behavior of Mg-based Alloy Catalyzed by Carbon-cobalt Composites
Feb 2021
Publication
The composites comprised of Co nanoparticle and C nanosheet were prepared though a high-temperature carbonization reaction. The catalysis of Co@C composites on the hydrogen storage behavior of Mg90Ce5Y5 alloy was investigated in detail by XRD SEM TEM PCI and DSC method. Because of the synergistic catalytic function of C and Co in C@Co nanocomposites the Mg90Ce5Y5 alloy with 10 wt.% C@Co shows the excellent hydrogen absorption and desorption performances. Time for releasing hydrogen reduces from 150 min to 11 min with the addition of the C@Co composites at the temperature of 300 °C. Meanwhile the dehydrogenation activation energy also declines from 130.3 to 81.9 kJ mol−1 H2 after the addition of the C@Co composites. This positive effect attributes to the C layer with the high defect density and the Co nanoparticles which reduces the energy barriers for the nucleation of Mg/MgH2 phase and the recombination of hydrogen molecule. Besides the C@Co composites also improve the activation property of the Mg90Ce5Y5 alloy which was fully activated in the first cycle. Moreover the temperature for initial dehydrogenation and the endothermic peak of the alloy hydride were also decreased. Although the addition of the C@Co composites increases the plateau pressures and decreases the value of the decomposition enthalpy these differences are so small that the improvement on thermodynamics can hardly be seen.
Investment Frameworks for Development of CCUS in the UK
Jul 2019
Publication
The CCUS Advisory Group (CAG) established in March 2019 is an industry-led group considering the critical challenges facing the development of CCUS market frameworks and providing insight into potential solutions. The CAG brings together experts from across the CCUS industry finance and legal sectors.<br/>The CAG has examined a range of business models focusing on industrial CCUS power production CO? transport and storage and hydrogen production. It has considered how the proposed business models interact in order to minimise issues such as cross-chain risk and has considered issues such as delivery capability. The conclusions of the CAG can be found in this report.
Hydrogen Projects Database – Analysis
Jun 2020
Publication
The IEA produced this dataset as part of efforts to track advances in low-carbon hydrogen technology. It covers all projects commissioned worldwide since 2000 to produce hydrogen for energy or climate-change-mitigation purposes. It includes projects which their objective is either to reduce emissions associated with producing hydrogen for existing applications or to use hydrogen as an energy carrier or industrial feedstock in new applications that have the potential to be a low-carbon technology. Projects in planning or construction are also covered.
Link to Download Database from IEA Website
Link to Download Database from IEA Website
A Novel Remaining Useful Life Prediction Method for Hydrogen Fuel Cells Based on the Gated Recurrent Unit Neural Network
Jan 2022
Publication
The remaining useful life (RUL) prediction for hydrogen fuel cells is an important part of its prognostics and health management (PHM). Artificial neural networks (ANNs) are proven to be very effective in RUL prediction as they do not need to understand the failure mechanisms behind hydrogen fuel cells. A novel RUL prediction method for hydrogen fuel cells based on the gated recurrent unit ANN is proposed in this paper. Firstly the data were preprocessed to remove outliers and noises. Secondly the performance of different neural networks is compared including the back propagation neural network (BPNN) the long short-term memory (LSTM) network and the gated recurrent unit (GRU) network. According to our proposed method based on GRU the root mean square error was 0.0026 the mean absolute percentage error was 0.0038 and the coefficient of determination was 0.9891 for the data from the challenge datasets provided by FCLAB Research Federation when the prediction starting point was 650 h. Compared with the other RUL prediction methods based on the BPNN and the LSTM our prediction method is better in both prediction accuracy and convergence rate.
Reversible Hydrogenation of AB2-type Zr–Mg–Ni–V Based Hydrogen Storage Alloys
Feb 2021
Publication
The development of hydrogen energy is hindered by the lack of high-efficiency hydrogen storage materials. To explore new high-capacity hydrogen storage alloys reversible hydrogen storage in AB2-type alloy is realized by using A or B-side elemental substitution. The substitution of small atomic-radius element Zr and Mg on A-side of YNi2 and partial substitution of large atomic-radius element V on B-side of YNi2 alloy was investigated in this study. The obtained ZrMgNi4 ZrMgNi3V and ZrMgNi2V2 alloys remained single Laves phase structure at as-annealed hydrogenated and dehydrogenated states indicating that the hydrogen-induced amorphization and disproportionation was eliminated. From ZrMgNi4 to ZrMgNi2V2 with the increase of the degree of vanadium substitution the reversible hydrogen storage capacity increased from 0.6 wt% (0.35H/M) to 1.8 wt% (1.0H/M) meanwhile the lattice stability gradually increased. The ZrMgNi2V2 alloy could absorb 1.8 wt% hydrogen in about 2 h at 300 K under 4 MPa H2 pressure and reversibly desorb the absorbed hydrogen in approximately 30 min at 473 K without complicated activation process. The prominent properties of ZrMgNi2V22 elucidate its high potential for hydrogen storage application.
Overview of Power Electronic Converter Topologies Enabling Large-Scale Hydrogen Production via Water Electrolysis
Feb 2022
Publication
Renewable power-to-hydrogen (P2H) technology is one of the most promising solutions for fulfilling the increasing global demand for hydrogen and to buffer large-scale fluctuating renewable energies. The high-power high-current ac/dc converter plays a crucial role in P2H facilities transforming medium-voltage (MV) ac power to a large dc current to supply hydrogen electrolyzers. This work introduces the general requirements and overviews several power converter topologies for P2H systems. The performances of different topologies are evaluated and compared from multiple perspectives. Moreover the future trend of eliminating the line frequency transformer (LFT) is discussed. This work can provide guidance for future designing and implementing of power-electronics-based P2H systems.
The Hydrogen Grand Challenge
Apr 2016
Publication
More than 90% of the world’s growing energy demand is satisfied by fossil fuels (BP Statistical Review … 2015)1. One consequence of the unrestrained use of this technology is the continuous increase of the CO2 level of the atmosphere2. There are also the challenges associated with the limitations of the corresponding resources (Hubbert 1956; BP Statistical Review … 2015). Climate change as a consequence of the growing CO2 level (see text footnote 2 ESRL Global Monitoring Division 2015) has been identified as one of the most critical challenges facing mankind and requires immediate action: “The Paris Agreement aims to strengthen the global response to the threat of climate change ( … ) by low greenhouse gas emissions development in a manner that does not threaten food production” (United Nations Framework … 2015). How to reach the corresponding significant reduction of CO2 emission by 2050 is not defined in this document but it implies that mankind must transform its energy technology from a fossil to a renewable basis. Numerous studies and publications have indicated that the sun’s energy and its derivatives (wind water) are by far sufficient to supply world’s energy demand (see e.g. Smalley 2005; Züttel et al. 2010); but the large daily and seasonal power variation of renewable energy is an additional complication for a wide spread replacement of fossil energy by renewable energy.
Ignition of Hydrogen-air Mixtures Under Volumetric Expansion Conditions
Sep 2017
Publication
A better understanding of chemical kinetics under volumetric expansion is important for a number of situations relevant to industrial safety including detonation diffraction and direct initiation reflected shock-ignition at obstacles ignition behind a decaying shock among others. The ignition of stoichiometric hydrogen-air mixtures was studied using 0D numerical simulations with time-dependent specific volume variations. The competition between chemical energy release and expansion-induced cooling was characterized for different cooling rates and mathematical forms describing the shock decay rate. The critical conditions for reaction quenching were systematically determined and the thermo-chemistry dynamics were analyzed near the critical conditions.
Photocatalytic Hydrogen Production by Photo-Reforming of Methanol with One-pot Synthesized Pt-containing TiO2 Photocatalysts
Jul 2019
Publication
Functionalization of semiconductors by metallic nanoparticle is considered to be one of the most effective procedure to improve photocatalytic hydrogen production. Photodeposition is frequently used for functionalization but particle sizes and dispersions are still difficult to control. Here Pt functionalization is achieved in a one-pot synthesis. The as-prepared samples are compared to reference materials prepared by conventional photodeposition and our results confirm that small and well-dispersed nanoparticles with superior stability are obtained by one-pot synthesis. The enhanced stability is attributed to a limited leaching of Pt nanoparticles during illumination likely caused by the preferable interaction of small well dispersed Pt nanoparticles with the TiO2 support material. In addition our results demonstrate that Na-residues are detrimental for the photocatalytic performance and washing in acidic solution is mandatory to effectively reduce the sodium contamination.
Gaseous Fueling of an Adapted Commercial Automotive Spark-ignition Engine: Simplified Thermodynamic Modeling and Experimental Study Running on Hydrogen, Methane, Carbon Monoxide and their Mixtures
Dec 2022
Publication
In the present work methane carbon monoxide hydrogen and the binary mixtures 20 % CH4–80 % H2 80 % CH4–20 % H2 25 % CO–75 % H2 (by volume) were considered as fuels of a naturally aspirated port-fuel injection four-cylinder Volkswagen 1.4 L spark-ignition (SI) engine. The interest in these fuels lies in the fact that they can be obtained from renewable resources such as the fermentation or gasification of residual biomasses as well as the electrolysis of water with electricity of renewable origin in the case of hydrogen. In addition they can be used upon relatively easy modifications of the engines including the retrofitting of existing internal combustion engines. It has been found that the engine gives similar performance regardless the gaseous fuel nature if the air–fuel equivalence ratio (λ) is the same. Maximum brake torque and mean effective pressure values within 45–89 N⋅m and 4.0–8.0 bar respectively have been obtained at values of λ between 1 and 2 at full load engine speed of 2000 rpm and optimum spark-advance. In contrast the nature of the gaseous fuel had great influence upon the range of λ values at which a fuel (either pure or blend) could be used. Methane and methane-rich mixtures with hydrogen or carbon monoxide allowed operating the engine at close to stoichiometric conditions (i.e. 1 < λ < 1.5) yielding the highest brake torque and mean effective pressure values. On the contrary hydrogen and hydrogen-rich mixtures with methane or carbon monoxide could be employed only in the very fuel-lean region (i.e. 1.5 < λ < 2). The behavior of carbon monoxide was intermediate between that of methane and hydrogen. The present study extends and complements previous works in which the aforementioned fuels were compared only under stoichiometric conditions in air (λ = 1). In addition a simple zero-dimensional thermodynamic combustion model has been developed that allows describing qualitatively the trends set by the several fuels. Although the model is useful to understand the influence of the fuels properties on the engine performance its predictive capability is limited by the simplifications made.
Prediction of Hydrogen Concentration in Containment During Severe Accidents Using Fuzzy Neural Network
Jan 2015
Publication
Recently severe accidents in nuclear power plants (NPPs) have become a global concern. The aim of this paper is to predict the hydrogen buildup within containment resulting from severe accidents. The prediction was based on NPPs of an optimized power reactor 1000. The increase in the hydrogen concentration in severe accidents is one of the major factors that threaten the integrity of the containment. A method using a fuzzy neural network (FNN) was applied to predict the hydrogen concentration in the containment. The FNN model was developed and verified based on simulation data acquired by simulating MAAP4 code for optimized power reactor 1000. The FNN model is expected to assist operators to prevent a hydrogen explosion in severe accident situations and manage the accident properly because they are able to predict the changes in the trend of hydrogen concentration at the beginning of real accidents by using the developed FNN model.
Two-dimensional Vanadium Carbide for Simultaneously Tailoring the Hydrogen Sorption Thermodynamics and Kinetics of Magnesium Hydride
May 2021
Publication
Magnesium hydride (MgH2) is a potential material for solid-state hydrogen storage. However the thermodynamic and kinetic properties are far from practical application in the current stage. In this work two-dimensional vanadium carbide (V2C) MXene with layer thickness of 50−100 nm was fist synthesized by selectively HF-etching the Al layers from V2AlC MAX phase and then introduced into MgH2 to improve the hydrogen sorption performances of MgH2. The onset hydrogen desorption temperature of MgH2 with V2C addition is significantly reduced from 318 °C for pure MgH2 to 190 °C with a 128 °C reduction of the onset temperature. The MgH2+ 10 wt% V2C composite can release 6.4 wt% of H2 within 10 min at 300 °C and does not loss any capacity for up to 10 cycles. The activation energy for the hydrogen desorption reaction of MgH2 with V2C addition was calculated to be 112 kJ mol−1 H2 by Arrhenius's equation and 87.6 kJ mol−1 H2 by Kissinger's equation. The hydrogen desorption reaction enthalpy of MgH2 + 10 wt% V2C was estimated by van't Hoff equation to be 73.6 kJ mol−1 H2 which is slightly lower than that of the pure MgH2 (77.9 kJ mol−1 H2). Microstructure studies by XPS TEM and SEM showed that V2C acts as an efficient catalyst for the hydrogen desorption reaction of MgH2. The first-principles density functional theory (DFT) calculations demonstrated that the bond length of Mg−H can be reduced from 1.71 Å for pure MgH2 to 2.14 Å for MgH2 with V2C addition which contributes to the destabilization of MgH2. This work provides a method to significantly and simultaneously tailor the hydrogen sorption thermodynamics and kinetics of MgH2 by two-dimensional MXene materials.
HyDeploy2 : Trial Management
May 2021
Publication
The trial management philosophy of the Winlaton trial within HyDeploy2 has been developed to enable the overall objectives of the project to be achieved; the safe demonstration of operating a Gas Distribution Network (GDN) on a blend of natural gas and hydrogen. The approach taken to develop the management philosophy of the Winlaton trial has been to continue the trial management strategies deployed for the Keele trial under HyDeploy albeit with site specific modifications where necessary. This document provides an overview of the management and governance processes associated with the trial itself.<br/>Click on the supplement tab to view the other documents from this report
North East Network & Industrial Cluster Development – Summary Report A Consolidated Summary Report by SGN & Wood
Nov 2021
Publication
In response to the global climate emergency governments across the world are aiming to lower greenhouse gas emissions to slow the damaging effects of climate change.<br/>The Scottish Government has set a target of net zero emissions by 2045. Already a global leader in renewable energy and low-carbon technology deployment Scotland’s energy landscape is set to undergo more change as it moves toward becoming carbon-neutral. Key to that change will be the transition from natural gas to zero-carbon gases like hydrogen and biomethane.<br/>Scotland’s north-east and central belt are home to some of its largest industrial carbon emitters. The sector’s reliance on natural gas means that it emits 11.9Mt of CO2 emissions per year says NECCUS: the equivalent of 2.6 million cars or roughly all the cars in Scotland. Most homes and businesses across Scotland also use natural gas for heating.<br/>Our North-East Network and Industrial Cluster project is laying the foundations for the rapid decarbonisation of this high-emitting sector. We’ve published a report outlining the practical steps needed to rapidly decarbonise a significant part of Scotland’s homes and industry. It demonstrates how hydrogen can play a leading role in delivering the Scottish Government’s target of one million homes with low carbon heat by 2030.<br/>The research published with global consulting and engineering advisor Wood sets out a transformational and accelerated pathway to 100% hydrogen for Scotland’s gas networks which you can see on the map below. It also details the feasibility of a CO2 collection network to securely capture transport and store carbon dioxide emissions deep underground.
Integrated Electricity, Hydrogen and Methane System Modelling Framework: Application to the Dutch Infrastructure Outlook 2050
Mar 2021
Publication
The future energy system is widely expected to show increasing levels of integration across differing energy carriers. Electricity hydrogen methane and heat systems may become increasingly interdependent due to coupling through conversion and hybrid energy technologies. Market parties network operators policy makers and regulators require tools to capture implications of possible techno-economic and institutional developments in one system for the operation of others. In this article we provide an integrated electricity hydrogen and methane systems modelling framework focusing on interdependencies between them. The proposed integrated electricity and (renewable) gas system model is a market equilibrium model with hourly price and volume interactions considering ramp rates of conventional units variability of intermittent renewables conversion transport as well as storage of electricity hydrogen and methane. The integrated model is formulated as a linear program under the assumption of perfect competition. As proof-of-concept the model has been applied to a test case consisting of 34 electricity nodes 19 hydrogen nodes and 22 methane nodes reflecting the regional governance scenario in the Dutch Infrastructure Outlook 2050 study. The case study also includes different sensitivity analyses with regard to variable renewable capacity energy demand and biomass prices to illustrate model response to perturbations of its main drivers. This article demonstrates that the interweaving of electricity hydrogen and methane systems can provide the required flexibility in the future energy system.
Research on Hydrogen Consumption and Driving Range of Hydrogen Fuel Cell Vehicle under the CLTC-P Condition
Dec 2021
Publication
Hydrogen consumption and mileage are important economic indicators of fuel cell vehicles. Hydrogen consumption is the fundamental reason that restricts mileage. Since there are few quantitative studies on hydrogen consumption during actual vehicle operation the high cost of hydrogen consumption in outdoor testing makes it impossible to guarantee the accuracy of the test. Therefore this study puts forward a test method based on the hydrogen consumption of fuel cell vehicles under CLTC-P operating conditions to test the hydrogen consumption of fuel cell vehicles per 100 km. Finally the experiment shows that the mileage calculated by hydrogen consumption has a higher consistency with the actual mileage. Based on this hydrogen consumption test method the hydrogen consumption can be accurately measured and the test time and cost can be effectively reduced.
Ranking Locations for Hydrogen Production Using Hybrid Wind-Solar: A Case Study
Apr 2021
Publication
Observing the growing energy demand of modern societies many countries have recognized energy security as a looming problem and renewable energies as a solution to this issue. Renewable hydrogen production is an excellent method for the storage and transfer of energy generated by intermittent renewable sources such as wind and solar so that they can be used at a place and time of our choosing. In this study the suitability of 15 cities in Fars province Iran for renewable hydrogen production was investigated and compared by the use of multiple multi-criteria decision-making methods including ARAS SAW CODAS and TOPSIS. The obtained rankings were aggregated by rank averaging Borda method and Copeland method. Finally the partially ordered set ranking technique was used to reach a general consensus about the ranking. The criteria that affect hydrogen production were found to be solar energy potential wind energy potential population air temperature natural disasters altitude relative humidity land cost skilled labor infrastructure topographic condition and distance from main roads. These criteria were weighted using the best–worst method (BWM) based on the data collected by a questionnaire. Solar energy potential was estimated using the Angstrom model. Wind energy potential was estimated by using the Weibull distribution function for each month independently. The results of the multi-criteria decision-making methods showed Izadkhast to be the most suitable location for renewable hydrogen production in the studied area.
An Integrated Hydrogen Fuel Cell to Distribution Network System: Challenging and Opportunity for D-STATCOM
Oct 2021
Publication
The electric power industry sector has become increasingly aware of how counterproductive voltage sag affects distribution network systems (DNS). The voltage sag backfires disastrously at the demand load side and affects equipment in DNS. To settle the voltage sag issue this paper achieved its primary purpose to mitigate the voltage sag based on integrating a hydrogen fuel cell (HFC) with the DNS using a distribution static synchronous compensator (D-STATCOM) system. Besides this paper discusses the challenges and opportunities of D-STATCOM in DNS. In this paper using HFC is well-designed modeled and simulated to mitigate the voltage sag in DNS with a positive impact on the environment and an immediate response to the issue of the injection of voltage. Furthermore this modeling and controller are particularly suitable in terms of cost-effectiveness as well as reliability based on the adaptive network fuzzy inference system (ANFIS) fuzzy logic system (FLC) and proportional–integral (P-I). The effectiveness of the MATLAB simulation is confirmed by implementing the system and carrying out a DNS connection obtaining efficiencies over 94.5% at three-phase fault for values of injection voltage in HFC D-STATCOM using a P-I controller. Moreover the HFC D-STATCOM using FLC proved capable of supporting the network by 97.00%. The HFC D-STATCOM based ANFIS proved capable of supporting the network by 98.00% in the DNS.
H2ero Net Zero: Hydrogen Europe Position Paper on the Fit for 55 Package
Jun 2021
Publication
Hydrogen has seen unprecedented development in the year 2020. From innovative niche technology it is fast becoming a systemic element in the European Union’s (EU) efforts to transition to a climate-neutral society in 2050. It will become a crucial energy vector and the other leg of the energy transition – alongside renewable electricity – by replacing coal oil and gas across different segments of the economy. The rapid development of hydrogen is important for meeting the EU’s climate objectives and preserving and enhancing the EU’s industrial and economic competitiveness securing jobs and value creation in this high-tech sector.
Europe is currently leading in hydrogen technology and European companies and knowledge institutions can be instrumental in advancing technological developments and industrial scale-up. It is imperative that Europe maintains this leadership position and seizes the current momentum for hydrogen technologies. The EU is well placed to become the birthplace of a global hydrogen economy denominated in Euro currency.
It is time that hydrogen moves from an afterthought to a central pillar of the energy system. The “Fit for 55 Package” presents a unique opportunity to begin putting into place a concrete and fit for purpose framework for the development of a clean hydrogen economy. In this paper you will find Hydrogen Europe’s recommendations on how hydrogen can:
Europe is currently leading in hydrogen technology and European companies and knowledge institutions can be instrumental in advancing technological developments and industrial scale-up. It is imperative that Europe maintains this leadership position and seizes the current momentum for hydrogen technologies. The EU is well placed to become the birthplace of a global hydrogen economy denominated in Euro currency.
It is time that hydrogen moves from an afterthought to a central pillar of the energy system. The “Fit for 55 Package” presents a unique opportunity to begin putting into place a concrete and fit for purpose framework for the development of a clean hydrogen economy. In this paper you will find Hydrogen Europe’s recommendations on how hydrogen can:
- Unleash the potential of renewables.
- Bring “efficiency” to the energy “system” of the future.
- Enable a carbon-neutral transport system.
Tautomeric Equilibrium of an Asymmetric β-Diketone in Halogen-Bonded Cocrystals with Perfluorinated Iodobenzenes
Jun 2021
Publication
In order to study the effect of halogen bond on tautomerism in β-diketones in the solid-state we have prepared a series of cocrystals derived from an asymmetric β-diketone benzoyl-4-pyridoylmethane (b4pm) as halogen bond acceptor and perfluorinated iodobenzenes: iodopentaflourobenzene (ipfb) 12- 13- and 14-diiodotetraflorobenzene (12tfib 13tfib and 14tfib) and 135-triiodo-246-trifluorobenzene (135titfb). All five cocrystals are assembled by I···N halogen bonds involving pyridyl nitrogen and iodoperfluorobenzene iodine resulting in 1:1 (four compounds) or 1:2 (one compound) cocrystal stoichiometry. Tautomer of b4pm in which hydrogen atom is adjacent to the pyridyl fragment was found to be more stable in vacuo than tautomer with a benzoyl hydroxyl group. This tautomer is also found to be dominant in the majority of crystal structures somewhat more abundantly in crystal structures of cocrystals in which additional I···O halogen bond with the benzoyl oxygen has been established. Attempts have also been made to prepare an equivalent series of cocrystals using a closely related asymmetric β-diketone benzoyl-3-pyridoylmethane (b3pm); however all attempts were unsuccessful which is attributed to more effective crystal packing of b3pm isomer compared to b4pm which reduced the probability of cocrystal formation.
Empowering Hydrogen Storage Properties of Haeckelite Monolayers via Metal Atom Functionalization
Mar 2021
Publication
Using hydrogen as an energy carrier requires new technological solutions for its onboard storage. The exploration of two-dimensional (2D) materials for hydrogen storage technologies has been motivated by their open structures which facilitates fast hydrogen kinetics. Herein the hydrogen storage properties of lightweight metal functionalized r57 haeckelite sheets are studied using density functional theory (DFT) calculations. H2 molecules are adsorbed on pristine r57 via physisorption. The hydrogen storage capacity of r57 is improved by decorating it with alkali and alkaline-earth metals. In addition the in-plane substitution of r57 carbons with boron atoms (B@r57) both prevents the clustering of metals on the surface of 2D material and increases the hydrogen storage capacity by improving the adsorption thermodynamics of hydrogen molecules. Among the studied compounds B@r57-Li4 with its 10.0 wt% H2 content and 0.16 eV/H2 hydrogen binding energy is a promising candidate for hydrogen storage applications. A further investigation as based on the calculated electron localization functions atomic charges and electronic density of states confirm the electrostatic nature of interactions between the H2 molecules and the protruding metal atoms on 2D haeckelite sheets. All in all this work contributes to a better understanding of pure carbon and B-doped haeckelites for hydrogen storage.
A Historical Analysis of Hydrogen Economy Research, Development, and Expectations, 1972 to 2020
Jan 2023
Publication
Global climate change concerns have pushed international governmental actions to reduce greenhouse gas emissions by adopting cleaner technologies hoping to transition to a more sustainable society. The hydrogen economy is one potential long-term option for enabling deep decarbonization for the future energy landscape. Progress towards an operating hydrogen economy is discouragingly slow despite global efforts to accelerate it. There are major mismatches between the present situation surrounding the hydrogen economy and previous proposed milestones that are far from being reached. The overall aim of this study is to understand whether there has been significant real progress in the achievement of a hydrogen economy or whether the current interest is overly exaggerated (hype). This study uses bibliometric analysis and content analysis to historically map the hydrogen economy’s development from 1972 to 2020 by quantifying and analyzing three sets of interconnected data. Findings indicate that interest in the hydrogen economy has significantly progressed over the past five decades based on the growing numbers of academic publications media coverage and projects. However various endogenous and exogenous factors have influenced the development of the hydrogen economy and created hype at different points in time. The consolidated results explore the changing trends and how specific events or actors have influenced the development of the hydrogen economy with their agendas the emergence of hype cycles and the expectations of a future hydrogen economy.
HyDeploy2: Network Information and Maps
Jun 2021
Publication
Winlaton site was chosen as the site for the HyDeploy 2 North East trial as it was seen as the site that offered a high degree of variability with regards materials on the network size of network and statistical representation of housing. The Winlaton trial network is an estate of the wider Winlaton gas network situated in Blaydon near Gateshead. The Winlaton trial network has been isolated from the wider Winlaton gas network where it was previously supplied from and will be supplied with the blended gas from NGN’s Low Thornley gas depot with the installation of a brand-new pressure regulating district governor.<br/>The data contained within this report outlines the expected seasonal gas demand on the Winlaton trial network and the associated leakage and repair history for the network. No unusual repairs or leakage behaviour has been observed on this network. A DSEAR assessment has been conducted on the governor station ensuring ATEX compliance. The network isolation and reinforcement requirements are also given in this report highlighting the necessary actions to isolate the trial network from the wider Winlaton gas network. The NGN Safety Case outlines the risks associated with the operation of a gas grid and the ALARP mitigations developed to minimise them and what response is necessary in case such risks are realised. The existing safety case will be amended to account for the infrastructural operational and commercial changes associated with the HyDeploy 2 project. The report also contains a detailed register of all the assets on the Winlaton trial network this data set was used to inform the scientific research programme and specifically to allow an assessment to be carried out with regards to the operability of the existing and newly installed assets on the Winlaton trial network with respect to the blended gas.<br/>Click on supplement tab to view the other documents from this report
Risk Assessment Method Combining Independent Protection Layers (IPL) of Layer of Protection Analysis (LOPA) and RISKCURVES Software: Case Study of Hydrogen Refueling Stations in Urban Areas
Jul 2021
Publication
The commercialization of eco-friendly hydrogen vehicles has elicited attempts to expand hydrogen refueling stations in urban areas; however safety measures to reduce the risk of jet fires have not been established. The RISKCURVES software was used to evaluate the individual and societal risks of hydrogen refueling stations in urban areas and the F–N (Frequency–Number of fatalities) curve was used to compare whether the safety measures satisfied international standards. From the results of the analysis it was found that there is a risk of explosion in the expansion of hydrogen refueling stations in urban areas and safety measures should be considered. To lower the risk of hydrogen refueling stations this study applied the passive and active independent protection layers (IPLs) of LOPA (Layer of Protection Analysis) and confirmed that these measures significantly reduced societal risk as well as individual risk and met international standards. In particular such measures could effectively reduce the impact of jet fire in dispensers and tube trailers that had a high risk. Measures employing both IPL types were efficient in meeting international standard criteria; however passive IPLs were found to have a greater risk reduction effect than active IPLs. The combination of RISKCURVES and LOPA is an appropriate risk assessment method that can reduce work time and mitigate risks through protective measures compared to existing risk assessment methods. This method can be applied to risk assessment and risk mitigation not only for hydrogen facilities but also for hazardous materials with high fire or explosion risk.
Materials for End to End Hydrogen Roadmap
Jun 2021
Publication
This report is commissioned by the Henry Royce Institute for advanced materials as part of its role around convening and supporting the UK advanced materials community to help promote and develop new research activity. The overriding objective is to bring together the advanced materials community to discuss analyse and assimilate opportunities for emerging materials research for economic and societal benefit. Such research is ultimately linked to both national and global drivers namely Transition to Zero Carbon Sustainable Manufacture Digital & Communications Circular Economy as well as Health & Wellbeing.
This paper can be download from their website
This paper can be download from their website
Homes of the Future: Unpacking Public Perceptions to Power the Domestic Hydrogen Transition
Apr 2022
Publication
Decarbonization in several countries is now linked to the prospect of implementing a national hydrogen economy. In countries with extensive natural gas infrastructure hydrogen may provide a real opportunity to decarbonize space heating. While this approach may prove technically and economically feasible in the longterm it is unclear whether consumers will be willing to adopt hydrogen-fueled appliances for heating and cooking should techno-economic feasibility be achieved. In response this paper develops an analytical framework for examining hydrogen acceptance which links together socio-technical barriers and social acceptance factors. Applying this framework the study synthesizes the existing knowledge on public perceptions of hydrogen and identifies critical knowledge gaps which should be addressed to support domestic hydrogen acceptance. The paper demonstrates that a future research agenda should account for the interactions between acceptance factors at the attitudinal socio-political market community and behavioral level. The analysis concludes that hydrogen is yet to permeate the public consciousness due to a lack of knowledge and awareness owing to an absence of information dissemination. In response consumer engagement in energy markets and stronger public trust in key stakeholders will help support social acceptance as the hydrogen transition unfolds. Affordability may prove the most critical barrier to the large-scale adoption of hydrogen homes while the disruptive impacts of the switchover and distributional injustice represent key concerns. As a starting point the promise of economic environmental and community benefits must be communicated and fulfilled to endorse the value of hydrogen homes.
Evaluation Techniques of Hydrogen Permeation in Sealing Rubber Materials
Dec 2020
Publication
Three techniques for determining the hydrogen permeation properties of rubber samples were developed based on the volumetric and gravimetric measurements of released H2 gas after sample decompression. These methods include gas chromatography (GC) by thermal desorption analysis (TDA) volumetric collection (VC) measurement of hydrogen by graduated cylinder and gravimetric (GM) measurement by electronic balance. By measuring the released hydrogen against elapsed time after the decompression of pressure the charging amount (C0) and diffusivity (D) were obtained with the developed diffusion analysis program. From these values the solubility (S) and permeability (P) of polymers were evaluated through the relations of Henry's law and P=SD respectively. The developed techniques were applied to three kinds of spherically shaped sealing rubber materials. D S and P were analyzed as a function of pressure. The transport behaviors obtained in the three methods are discussed and compared with the characteristics of each measuring technique. The correlations between transport parameters and carbon black filler or density are discussed.
Safety Criteria for the Transport of Hydrogen in Permanently Mounted Composite Pressure Vessels
Sep 2019
Publication
The recent growth of the net of hydrogen fuelling stations increases the demands to transport compressed hydrogen on road by battery vehicles or tube-trailers both in composite pressure vessels. As a transport regulation the ADR is applicable in Europe and adjoined regions and is used for national transport in the EU. This regulation provides requirements based on the behaviour of each individual pressure vessel regardless of the pressure of the transported hydrogen and relevant consequences resulting from generally possible worst case scenarios such as sudden rupture. In 2012 the BAM (German Federal Institute for Materials Research and Testing) introduced consequence-dependent requirements and established them in national transport requirements concerning the “UN service life checks” etc. to consider the transported volume and pressure of gases. This results in a requirement that becomes more restrictive as the product of pressure and volume increases. In the studies presented here the safety measures for hydrogen road transport are identified and reviewed through a number of safety measures from countries including Japan the USA and China. Subsequently the failure consequences of using trailer vehicles the related risk and the chance are evaluated. A benefit-related risk criterion is suggested to add to regulations and to be defined as a safety goal in standards for hydrogen transport vehicles and for mounted pressure vessels. Finally an idea is given for generating probabilistic safety data and for highly efficient evaluation without a significant increase of effort.
Horizon 2020 Impact Assessment Report
Nov 2011
Publication
Horizon 2020 is the biggest EU Research and Innovation programme ever with nearly €80 billion of funding available over 7 years (2014 to 2020) – in addition to the private investment that this money will attract. It promises more breakthroughs discoveries and world-firsts by taking great ideas from the lab to the market.<br/>Horizon 2020 is the financial instrument implementing the Innovation Union a Europe 2020 flagship initiative aimed at securing Europe's global competitiveness.<br/><br/>Seen as a means to drive economic growth and create jobs Horizon 2020 has the political backing of Europe’s leaders and the Members of the European Parliament. They agreed that research is an investment in our future and so put it at the heart of the EU’s blueprint for smart sustainable and inclusive growth and jobs.<br/><br/>By coupling research and innovation Horizon 2020 is helping to achieve this with its emphasis on excellent science industrial leadership and tackling societal challenges. The goal is to ensure Europe produces world-class science removes barriers to innovation and makes it easier for the public and private sectors to work together in delivering innovation.<br/><br/>Horizon 2020 is open to everyone with a simple structure that reduces red tape and time so participants can focus on what is really important. This approach makes sure new projects get off the ground quickly – and achieve results faster.<br/><br/>The EU Framework Programme for Research and Innovation will be complemented by further measures to complete and further develop the European Research Area. These measures will aim at breaking down barriers to create a genuine single market for knowledge research and innovation.
Hy4Heat Progress Report
Jan 2021
Publication
Hy4Heat’s mission is to establish if it is technically possible safe and convenient to replace natural gas (methane) with hydrogen in residential and commercial buildings and gas appliances. This will enable the government to determine whether to proceed to a community trial.
There is growing international consensus that hydrogen will be essential to successfully tackling climate change. So BEIS is working to develop hydrogen as a strategic decarbonised energy carrier for the UK which will be an essential element of the UK’s efforts to transform and decarbonise our energy system in line with our legally binding 2050 net zero commitment. Hydrogen can be used across multiple end-use sectors including industry transport heat and power. BEIS is looking to support and develop low carbon hydrogen production methods which will position hydrogen as a highly effective decarbonisation option particularly in hard-to electrify sectors and processes.
At the end of 2017 BEIS appointed Arup to be the programme manager for the Hy4Heat programme. Arup partnered with technical and industry specialists: Kiwa Gastec Progressive Energy Embers and Yo Energy and together the team oversees the programme and technical management of all the work packages. For the past three years Hy4Heat has been exploring whether replacing natural gas (methane) with hydrogen for domestic heating and cooking is feasible and could be part of a plausible potential pathway to help meet heat decarbonisation targets. To do this the programme has been seeking to provide the technical performance usability and safety evidence to demonstrate whether hydrogen can be used for heat in buildings.
This report and any attachment is freely available on the Hy4Heat website here. The report can also be downloaded directly by clicking on the pdf icon above.
There is growing international consensus that hydrogen will be essential to successfully tackling climate change. So BEIS is working to develop hydrogen as a strategic decarbonised energy carrier for the UK which will be an essential element of the UK’s efforts to transform and decarbonise our energy system in line with our legally binding 2050 net zero commitment. Hydrogen can be used across multiple end-use sectors including industry transport heat and power. BEIS is looking to support and develop low carbon hydrogen production methods which will position hydrogen as a highly effective decarbonisation option particularly in hard-to electrify sectors and processes.
At the end of 2017 BEIS appointed Arup to be the programme manager for the Hy4Heat programme. Arup partnered with technical and industry specialists: Kiwa Gastec Progressive Energy Embers and Yo Energy and together the team oversees the programme and technical management of all the work packages. For the past three years Hy4Heat has been exploring whether replacing natural gas (methane) with hydrogen for domestic heating and cooking is feasible and could be part of a plausible potential pathway to help meet heat decarbonisation targets. To do this the programme has been seeking to provide the technical performance usability and safety evidence to demonstrate whether hydrogen can be used for heat in buildings.
This report and any attachment is freely available on the Hy4Heat website here. The report can also be downloaded directly by clicking on the pdf icon above.
Partitioning of Interstitial Segregants during Decohesion: A DFT Case Study of the Σ3 Symmetric Tilt Grain Boundary in Ferritic Steel
Sep 2019
Publication
The effect of hydrogen atoms at grain boundaries in metals is usually detrimental to the cohesion of the interface. This effect can be quantified in terms of the strengthening energy which is obtained following the thermodynamic model of Rice and Wang. A critical component of this model is the bonding or solution energy of the atoms to the free surfaces that are created during decohesion. At a grain boundary in a multicomponent system it is not immediately clear how the different species would partition and distribute on the cleaved free surfaces. In this work it is demonstrated that the choice of partitioning pattern has a significant effect on the predicted influence of H and C on grain boundary cohesion. To this end the Σ3(112)[11¯0] symmetric tilt grain boundary in bcc Fe with different contents of interstitial C and H was studied taking into account all possible distributions of the elements as well as surface diffusion effects. H as a single element has a negative influence on grain boundary cohesion independent of the details of the H distribution. C on the other hand can act both ways enhancing or reducing the cohesion of the interface. The effect of mixed H and C compositions depends on the partition pattern. However the general trend is that the number of detrimental cases increases with increasing H content. A decomposition of the strengthening energy into chemical and mechanical contributions shows that the elastic contribution dominates at high C contents while the chemical contribution sets the trend for high H contents.
FCH Programme Review Report 2014
Apr 2015
Publication
The 2014 Review is the fourth review of the FCH JU project portfolio. The reviews began in 2011 following a recommendation arising from the interim evaluation of the FCH JU which identified the need to ensure that the FCH JU project portfolio as a whole fulfilled the objectives of the Multi-Annual Implementation or Work Plan.<br/><br/>An international team of leading experts in the FCH field undertakes each review based on (1) The achievements of the portfolio against the strategic objectives and content of the FCH JU’s MAIP/MAWP and the AIP/AWPs as set out for the transportation and energy innovation pillars and the cross-cutting category; (2) The extent to which the portfolio meets the FCH JU’s remit for promoting the horizontal activities of RCS PNR safety life-cycle and socio-economic analysis education and training and public awareness; (3) The portfolio’s effectiveness in promoting linkages and co-operation between projects and between FCH JU-supported projects and those supported by other European instruments the Member States and internationally. Review panels The 2014 review comprised six panels covering a total of 114 projects. Each panel covered between 10 and 24 projects as shown in Table 1 below. The objective was to assess projects within each panel as a sub-portfolio (within the FCH JU portfolio) and not as individual projects although examples of individual projects representing good practice were highlighted.
Fuel Cells and Hydrogen: Joint Undertaking Programme Review 2011 Final Report
Apr 2012
Publication
The Fuel Cells and Hydrogen Joint Undertaking (FCH JU) has the ambitious objective to place Europe at the forefront of the development commercialization and deployment of fuel cells and hydrogen technologies as of 2015. About €470 million over a six year period have been granted by the European Union to achieve this and private funds are being attracted to support the same ambition as part of the global European effort embedded in the multi-annual implementation plan MAIP (2008-2013).
Simulation-based Safety Investigation of a Hydrogen Fueling Station with an On-site Hydrogen Production System Involving Methylcyclohexane
Jan 2017
Publication
Adequate safety measures are crucial for preventing major accidents at hydrogen fuelling stations. In particular risk analysis of the domino effect at hydrogen fuelling stations is essential because knock-on accidents are likely to intensify the consequences of a relatively small incident. Several risk assessment studies have focused on hydrogen fuelling stations but none have investigated accidental scenarios related to the domino effect at such stations. Therefore the purpose of this study is to identify a domino effect scenario analyze the scenario by using simulations and propose safety measures for preventing and mitigating of the scenario. In this hazard identification study we identified the domino effect scenario of a hydrogen fuelling station with an on-site hydrogen production system involving methylcyclohexane and investigated through simulations of the scenario. The simulations revealed that a pool fire of methylcyclohexane or toluene can damage the process equipment and that thermal radiation may cause the pressurized hydrogen tanks to rupture. The rupture-type vent system can serve as a critical safety measure for preventing and mitigating the examined scenario.
Ignition of Hydrogen-air Mixtures by Moving Heated Particles
Oct 2015
Publication
Studying thermal ignition mechanisms is a key step for evaluating many ignition hazards. In the present work two-dimensional simulations with detailed chemistry are used to study the reaction pathways of the transient flow and ignition of a stoichiometric hydrogen-air mixture by moving hot spheres. For temperatures above the ignition threshold ignition takes place after a short time between the front stagnation point and separation location depending upon the sphere's surface temperature. Closer to the threshold the volume of gas adjacent to the separation region ignites homogeneously after a longer time. These results demonstrate the importance of boundary layer development and flow separation in the ignition process.
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