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Centralized and Decentralized Electrolysis-based Hydrogen Supply Systems for Road Transportation - A Modeling Study of Current and Future Costs
Oct 2022
Publication
This work compares the costs of three electrolysis-based hydrogen supply systems for heavy road transportation: a decentralized off-grid system for hydrogen production from wind and solar power (Dec-Sa); a decentralized system connected to the electricity grid (Dec-Gc); and a centralized grid-connected electrolyzer with hydrogen transported to refueling stations (Cen-Gc). A cost-minimizing optimization model was developed in which the hydrogen production is designed to meet the demand at refueling stations at the lowest total cost for two timeframes: one with current electricity prices and one with estimated future prices. The results show that: For most of the studied geographical regions Dec-Gc gives the lowest costs of hydrogen delivery (2.2e3.3V/kgH2) while Dec-Sa entails higher hydrogen production costs (2.5e6.7V/kgH2). In addition the centralized system (Cen-Gc) involves lower costs for production and storage than the grid-connected decentralized system (Dec-Gc) although the additional costs for hydrogen transport increase the total cost (3.5e4.8V/kgH2).
Integration of a Multi-Stack Fuel Cell System in Microgrids: A Solution Based on Model Predictive Control
Sep 2020
Publication
This paper proposes a multi-objective model predictive control (MPC) designed for the power management of a multi-stack fuel cell (FC) system integrated into a renewable sources-based microgrid. The main advantage of MPC is the fact that it allows the current timeslot to be optimized while taking future timeslots into account. The multi-objective function solves the problem related to the power dispatch at time that includes criteria to reduce the multi-stack FC degradation operating and maintenance costs as well as hydrogen consumption. Regarding the scientific literature the novelty of this paper lies in the proposal of a generalized MPC controller for a multi-stack FC that can be used independently of the number of stacks that make it up. Although all the stacks that make up the modular FC system are identical their levels of degradation in general will not be. Thus over time each stack can present a different behavior. Therefore the power control strategy cannot be based on an equal distribution according to the nominal power of each stack. On the contrary the control algorithm should take advantage of the characteristics of the multi-stack FC concept distributing operation across all the stacks regarding their capacity to produce power/energy and optimizing the overall performance.
An Analysis of the Potential of Hydrogen Energy Technology on Demand Side Based on a Carbon Tax: A Case Study in Japan
Dec 2022
Publication
Hydrogen energy is considered one of the main measures of zero carbonization in energy systems but high equipment and hydrogen costs hinder the development of hydrogen energy technology. The objectives of this study are to quantify the environmental advantages of hydrogen energy through a carbon tax and study the application potential of hydrogen energy technology in a regional distributed energy system (RDES). In this study various building types in the smart community covered by Japan’s first hydrogen energy pipeline are used as an example. First ten buildings of five types are selected as the research objectives. Subsequently two comparative system models of a regional distributed hydrogen energy system (RDHES) and an RDES were established. Then by studying the optimal RDHES and RDES configuration and combining the prediction of future downward trends of fuel cell (FC) costs and energy carbon emissions the application effect of FC and hydrogen storage (HS) technologies on the demand side was analyzed. Finally the adaptability of the demand-side hydrogen energy system was studied by analyzing the load characteristics of different types of buildings. The results show that when the FC price is reduced to 1.5 times that of the internal combustion engine (ICE) the existing carbon tax system can sufficiently support the RDHES in gaining economic advantages in some regions. Notably when the carbon emissions of the urban energy system are reduced the RDHES demonstrates stronger anti-risk ability and has greater suitability for promotion in museums and shopping malls. The conclusions obtained in this study provide quantitative support for hydrogen energy promotion policies on the regional demand side and serve as a theoretical reference for the design and adaptability research of RDHESs.
The Origin and Occurrence of Natural Hydrogen
Mar 2023
Publication
Hydrogen is an attractive clean sustainable energy source primarily produced via industry. At present most reviews on hydrogen mainly focus on the preparation and storage of hydrogen while the development and utilization of natural hydrogen will greatly reduce its cost. Natural hydrogen has been discovered in many geological environments. Therefore based on extensive literature research in this study the distribution and sources of natural hydrogen were systematically sorted and the identification method and occurrence state of natural hydrogen were examined and summarized. The results of this research show that hydrogen has been discovered in oceanic spreading centers transform faults passive margins convergent margins and intraplate settings. The primary sources of the hydrogen include alterations in Fe(II)-containing rocks the radiolysis of water degassed magma and the reaction of water- and silica-containing rocks during the mechanical fracturing. Hydrogen can appear in free gas it can be adsorbed and trapped in inclusions. Currently natural hydrogen exploration is in its infancy. This systematic review helps to understand the origin distribution and occurrence pattern of natural hydrogen. In addition it facilitates the exploration and development of natural hydrogen deposits thus enabling the production of low-cost hydrogen.
Analysis of Hydrogen Gas Injection at Various Compositions in an Existing Natural Gas Pipeline
Jul 2021
Publication
The lack of hydrogen (H2) transportation infrastructure restricts the development of the H2 industry. Owing to the high investment of building specific facilities using existing natural gas (NG) pipelines to transport a blend of H2 and NG (H2NG) is a viable means of transportation and approach for large-scale long-time storage. However variation in the thermo-physical properties of an H2NG blend will impact the performance of pipeline appliances. To address the gaps in H2 transmission via an NG system in the context of energy consumption in the present paper a one-dimensional pipeline model is proposed to predict the blended flow in a real existing pipeline (Shan–Jing I China). The data of NG components were derived from real gas fields. Furthermore the influence of H2 fractions on pipeline energy coefficient and the layout of pressurization stations are comprehensively analyzed. In addition the case of intermediate gas injection is investigated and the effects of injection positions are studied. This study serves as a useful reference for the design of an H2NG pipeline system. The present study reveals that with the increasing in H2 fraction the distance between pressure stations increases. Furthermore when the arrangement of original pressure stations is maintained overpressure occur. Intermediate gas injection results in the inlet pressure of subsequent pressurization stations reducing. Using existing pipeline network to transport H2NG it is necessary to make appropriate adjustment.
Climate Action for the Shipping Industry: Some Perspectives on the Role of Nuclear Power in Maritime Decarbonization
Feb 2023
Publication
The shipping industry is a major enabler of globalization trade commerce and human welfare. But it is still heavily served by fossil fuels which make it one of the foremost greenhouse gas emitting sectors operational today. It is also one of the hardest to abate segments of the transport industry. As part of the economy-wide climate change mitigation and adaptation efforts it is necessary to consider a low carbon energy transition for this segment as well. This study examines the potential role of nuclear power and cogeneration towards greening this sector and identifies the associated techno-commercial and policy challenges associated with the transition. Quantitative estimates of the economics and investments associated with some of the possible routes are also presented. Alternatives such as nuclear-powered ships along commercial maritime trading routes ships working on nuclear derived green hydrogen ammonia or other sustainable power fuels will enable not only decarbonization of the shipping industry but also allow further diversification of the nuclear industry through non-electric applications of nuclear power and new sector coupling opportunities. In the run-up to the UNFCCC-COP28 meeting in 2023 in UAE nuclear equipped nations heavily engaged in and dependent on maritime trade and commerce should definitely consider nuclear driven decarbonization of shipping and some of the options presented here as part of their climate action strategies.
OIES Podcast – PolyGrid 2050: Integrating Hydrogen into the European Energy Transfer Infrastructure Landscape
Feb 2023
Publication
In this podcast David Ledesma talks with Rahmat Poudineh and Martin Palovic about their paper on integrating hydrogen into the European energy transfer infrastructure landscape. As hydrogen is expected to play an important role in European plans towards climate neutrality adequate hydrogen transport (and storage) infrastructure needs to be established. However hydrogen transport infrastructures are costly and have a long lead time. Furthermore hydrogen can be transported via a variety of means: it can be transported as a gas via pipelines or liquid via road rail and sea or even converted to derivatives such as ammonia or methanol for long distance transportation. It is also possible to transfer electrical energy instead of hydrogen and produce hydrogen in a decentralized way. From a system perspective all these infrastructures represent elements of a grand hydrogen ‘polygrid’ that will be the backbone of the future decarbonized energy system. This raises the fundamental question of how to prevent inefficiency and infrastructure redundancy across different modes of hydrogen transport. The task is made more challenging by technological uncertainty the unpredictability of future supply and demand for hydrogen network externality effects and investment irreversibility of grid-based infrastructures. In this podcast we discuss three possible coordination approaches to optimise future cross-sectoral investment into hydrogen transport infrastructure and highlight their strengths and shortcomings.
The podcast can be found on their website.
The podcast can be found on their website.
Achieving Net Zero Emissions in Italy by 2050: Challenges and Opportunities
Dec 2021
Publication
This paper contributes to the climate policy discussion by focusing on the challenges and opportunities of reaching net zero emissions by 2050 in Italy. To support Italian energy planning we developed energy roadmaps towards national climate neutrality consistent with the Paris Agreement objectives and the IPCC goal of limiting the increase in global surface temperature to 1.5 ◦C. Starting from the Italian framework these scenarios identify the correlations among the main pillars for the change of the energy paradigm towards net emissions by 2050. The energy scenarios were developed using TIMES-RSE a partial equilibrium and technology-rich optimization model of the entire Italian energy system. Subsequently an in-depth analysis was developed with the sMTISIM a long-term simulator of power system and electricity markets. The results show that to achieve climate neutrality by 2050 the Italian energy system will have to experience profound transformations on multiple and strongly related dimensions. A predominantly renewable-based energy mix (at least 80–90% by 2050) is essential to decarbonize most of the final energy consumption. However the strong increase of non-programmable renewable sources requires particular attention to new flexibility resources needed for the power system such as Power-to-X. The green fuels produced from renewables via Power-to-X will be a vital energy source for those sectors where electrification faces technical and economic barriers. The paper’s findings also confirm that the European “energy efficiency first” principle represents the very first step on the road to climate neutrality.
On Green Hydrogen Generation Technologies: A Bibliometric Review
Mar 2024
Publication
Green hydrogen produced by water electrolysis with renewable energy plays a crucial role in the revolution towards energy sustainability and it is considered a key source of clean energy and efficient storage. Its ability to address the intermittency of renewable sources and its potential to decarbonize sectors that are difficult to electrify make it a strategic component in climate change mitigation. By using a method based on a bibliometric review of scientific publications this paper represents a significant contribution to the emerging field of research on green hydrogen and provides a detailed review of electrolyzer technologies identifying key areas for future research and technology development. The results reflect the immaturity of a technology which advances with different technical advancements waiting to find the optimal technical solution that allows for its massive implementation as a source of green hydrogen generation. According to the results found in this article alkaline (ALK) and proton exchange membrane (PEM) electrolyzers seem to be the ones that interest the scientific community the most. Similarly in terms of regional analysis Europe is clearly committed to green hydrogen in view of the analysis of its scientific results on materials and electrolyzer capacity forecasts for 2030.
A Comprehensive Survey of Alkaline Electrolyzer Modeling: Electrical Domain and Specific Electrolyte Conductivity
May 2022
Publication
Alkaline electrolyzers are the most widespread technology due to their maturity low cost and large capacity in generating hydrogen. However compared to proton exchange membrane (PEM) electrolyzers they request the use of potassium hydroxide (KOH) or sodium hydroxide (NaOH) since the electrolyte relies on a liquid solution. For this reason the performances of alkaline electrolyzers are governed by the electrolyte concentration and operating temperature. Due to the growing development of the water electrolysis process based on alkaline electrolyzers to generate green hydrogen from renewable energy sources the main purpose of this paper is to carry out a comprehensive survey on alkaline electrolyzers and more specifically about their electrical domain and specific electrolytic conductivity. Besides this survey will allow emphasizing the remaining key issues from the modeling point of view.
Assessment of Wind Energy Potential for the Production of Renewable Hydrogen in Sindh Province of Pakistan
Apr 2019
Publication
In this study we developed a new hybrid mathematical model that combines wind-speed range with the log law to derive the wind energy potential for wind-generated hydrogen production in Pakistan. In addition we electrolyzed wind-generated power in order to assess the generation capacity of wind-generated renewable hydrogen. The advantage of the Weibull model is that it more accurately reflects power generation potential (i.e. the capacity factor). When applied to selected sites we have found commercially viable hydrogen production capacity in all locations. All sites considered had the potential to produce an excess amount of wind-generated renewable hydrogen. If the total national capacity of wind-generated was used Pakistan could conceivably produce 51917000.39 kg per day of renewable hydrogen. Based on our results we suggest that cars and other forms of transport could be fueled with hydrogen to conserve oil and gas resources which can reduce the energy shortfall and contribute to the fight against climate change and global warming. Also hydrogen could be used to supplement urban energy needs (e.g. for Sindh province Pakistan) again reducing energy shortage effects and supporting green city programs.
Research & Innovation to Support Net-zero Industrial Technologies
Mar 2023
Publication
The Green Deal Industrial Plan aims to boost the competitiveness of Europe’s net-zero industry and to accelerate the transition to climate neutrality. The Plan is based on four pillars: (1) a predictable and simplified regulatory environment; (2) faster access to funding; (3) developing skills for net-zero industry; and (4) open trade for resilient supply chains.
Future Energy Scenarios 2020
Jul 2020
Publication
Our Future Energy Scenarios (FES) outline four different credible pathways for the future of energy over the next 30 years. Based on input from over 600 experts the report looks at the energy needed in Britain across electricity and gas - examining where it could come from how it needs to change and what this means for consumers society and the energy system itself.
Sustainable Hydrogen Energy in Aviation - A Narrative Review
Feb 2023
Publication
In the modern world zero-carbon society has become a new buzzword of the era. Many projects have been initiated to develop alternatives not only to the environmental crisis but also to the shortage of fossil fuels. With successful projects in automobile technology hydrogen fuel is now being tested and utilized as a sustainable green fuel in the aviation sector which will lead to zero carbon emission in the future. From the mid-20th century to the early 21st numerous countries and companies have funded multimillion projects to develop hydrogen-fueled aircraft. Empirical data show positive results for various projects. Consequently large companies are investing in various innovations undertaken by researchers under their supervision. Over time the efficiency of hydrogen-fueled aircraft has improved but the lack of refueling stations large production cost and consolidated carbon market share have impeded the path of hydrogen fuel being commercialized. In addition the Unmanned Aerial Vehicle (UAV) is another important element of the Aviation industry Hydrogen started to be commonly used as an alternative fuel for heavy-duty drones using fuel cell technology. The purpose of this paper is to provide an overview of the chronological development of hydrogen-powered aircraft technology and potential aviation applications for hydrogen and fuel cell technology. Furthermore the major barriers to widespread adoption of hydrogen technology in aviation are identified as are future research opportunities.
Delivering a Reliable Decarbonised Power System
Mar 2023
Publication
This report illustrates what a reliable resilient decarbonised electricity supply system could look like in 2035 and the steps required to achieve it. It provides new insights and new advice on how such a system can be achieved by 2035 using real weather data and hourly analysis of Great Britain’s power system (Northern Ireland is part of the all-Ireland system). It also looks at the implications for hydrogen.
Large-scale Underground Hydrogen Storage: Integrated Modeling of a Reservoir-wellbore System
Jan 2023
Publication
Underground Hydrogen Storage (UHS) has received significant attention over the past few years as hydrogen seems well-suited for adjusting seasonal energy gaps. We present an integrated reservoir-well model for “Viking A00 the depleted gas field in the North Sea as a potential site for UHS. Our findings show that utilizing the integrated model results in more reasonable predictions as the gas composition changes over time. Sensitivity analyses show that the lighter the cushion gas the more production can be obtained. However the purity of the produced hydrogen will be affected to some extent which can be enhanced by increasing the fill-up period and the injection rate. The results also show that even though hydrogen diffuses into the reservoir and mixes up with the native fluids (mainly methane) the impact of hydrogen diffusion is marginal. All these factors will potentially influence the project's economics.
Comprehensive Analysis of the Operation of an Internal Combustion Engine Fueled by Hydrogen-containing Mixtures
Mar 2023
Publication
At present hydrogen is considered as one of the most promising motor fuels capable of replacing traditional hydrocarbons. This article presents the results of a comprehensive experimental study of the effect of hydrogen additives on the main parameters of a gasoline spark-ignition ICE. The thermophysical parameters of the processes of ignition and combustion inside the cylinder with the addition of hydrogen in the amount of 0%–20% of the air volume as well as the fuel and energy characteristics of the engine and its impact on the environment were studied. It has been established that hydrogen leads to significant changes in the engine operation. It increases some parameters and reduces others improving or worsening them compared to running on pure gasoline. So with a 20% H2 addition at an average engine load the following parameters increase: the maximum pressure in the cylinder by almost 20%; the rate of pressure increase in the combustion chamber by 2.8 times; the highest combustion temperature by 140 K. At the same time the following parameters decrease: average indicator pressure by 18%; ignition timing by 82% (6◦ to TDC versus 34◦ for gasoline); crank angle corresponding to the maximum pressure by 32% (9.4◦ versus 13.9◦ for gasoline); crank angle corresponding to maximum temperature by 54% (17.7◦ after TDC versus 38.3◦ for clean gasoline); ignition delay time (τind = 0.32 ms) and visible combustion time (τvis = 1.58 ms) by 4 and 2.3 times respectively.
Production of Hydrogen from Offshore Wind in China and Cost-competitive Supply to Japan
Nov 2021
Publication
The Japanese government has announced a commitment to net-zero greenhouse gas emissions by 2050. It envisages an important role for hydrogen in the nation’s future energy economy. This paper explores the possibility that a significant source for this hydrogen could be produced by electrolysis fueled by power generated from offshore wind in China. Hydrogen could be delivered to Japan either as liquid or bound to a chemical carrier such as toluene or as a component of ammonia. The paper presents an analysis of factors determining the ultimate cost for this hydrogen including expenses for production storage conversion transport and treatment at the destination. It concludes that the Chinese source could be delivered at a volume and cost consistent with Japan’s idealized future projections.
Modelling the Impacts of Hydrogen–Methane Blend Fuels on a Stationary Power Generation Engine
Mar 2023
Publication
To reduce greenhouse gas emissions from natural gas use utilities are investigating the potential of adding hydrogen to their distribution grids. This will reduce the carbon dioxide emissions from grid-connected engines used for stationary power generation and it may also impact their power output and efficiency. Promisingly hydrogen and natural gas mixtures have shown encouraging results regarding engine power output pollutant emissions and thermal efficiency in well-controlled on-road vehicle applications. This work investigates the effects of adding hydrogen to the natural gas fuel for a lean-burn spark-ignited four-stroke 8.9 liter eight-cylinder naturally aspirated engine used in a commercial stationary power generation application via an engine model developed in the GT-SUITETM modelling environment. The model was validated for fuel consumption air flow and exhaust temperature at two operating modes. The focus of the work was to assess the sensitivity of the engine’s power output brake thermal efficiency and pollutant emissions to blends of methane with 0–30% (by volume) hydrogen. Without adjusting for the change in fuel energy the engine power output dropped by approximately 23% when methane was mixed with 30% by volume hydrogen. It was found that increasing the fueling rate to maintain a constant equivalence ratio prevented this drop in power and reduced carbon dioxide emissions by almost 4.5%. In addition optimizing the spark timing could partially offset the increases in in-cylinder burned and unburned gas temperatures and in-cylinder pressures that resulted from the faster combustion rates when hydrogen was added to the natural gas. Understanding the effect of fuel change in existing systems can provide insight on utilizing hydrogen and natural gas mixtures as the primary fuel without the need for major changes in the engine.
A Simulated Roadmap of Hydrogen Technology Contribution to Climate Change Mitigation Based on Representative Concentration Pathways Considerations
Apr 2018
Publication
Hydrogen as fuel has been a promising technology toward climate change mitigation efforts. To this end in this paper we analyze the contribution of hydrogen technology to our future environmental goals. It is assumed that hydrogen is being produced in higher efficiency across time and this is simulated on Global Change Assessment Model (GCAM). The environmental restrictions applied are the expected emissions representative concentration pathways (RCP) 2.6 4.5 and 6.0. Our results have shown increasing hydrogen production as the environmental constraints become stricter and hydrogen more efficient in being produced. This increase has been quantified and provided on open access as Supporting Information to this manuscript.
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