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Sequential Combustion in Steam Methane Reformers for Hydrogen and Power Production With CCUS in Decarbonized Industrial Clusters
Aug 2020
Publication
In future energy supply systems hydrogen and electricity may be generated in decarbonized industrial clusters using a common infrastructure for natural gas supply electricity grid and transport and geological storage of CO2. The novel contribution of this article consists of using sequential combustion in a steam methane reforming (SMR) hydrogen plant to allow for capital and operating cost reduction by using a single post-combustion carbon capture syste Read More
The Use of Hydrogen to Separate and Recycle Neodymium–iron–boron-type Magnets from Electronic Waste
May 2015
Publication
The rare earth metals have been identified by the European Union and the United States as being at greatest supply risk of all the materials for clean energy technologies. Of particular concern are neodymium and dysprosium both of which are employed in neodymium–iron–boron based magnets. Recycling of magnets based on these materials and contained within obsolete electronic equipment could provide an additional and secure supply. In the prese Read More
A Cost Estimation for CO2 Reduction and Reuse by Methanation from Cement Industry Sources in Switzerland
Feb 2018
Publication
The Swiss government has signed the Paris Climate Agreement and various measures need to be implemented in order to reach the target of a 50% reduction in CO2 emissions in Switzerland by 2030 compared with the value for 1990. Considering the fact that the production of cement in Switzerland accounts around 2.5 million ton for CO2 emissions of which corresponds to roughly 7% of the country's total CO2 emissions the following article ex Read More
A Review on Synthesis of Methane as a Pathway for Renewable Energy Storage With a Focus on Solid Oxide Electrolytic Cell-Based Processes
Sep 2020
Publication
Environmental issues related to global warming are constantly pushing the fossil fuel-based energy sector toward an efficient and economically viable utilization of renewable energy. However challenges related to renewable energy call for alternative routes of its conversion to fuels and chemicals by an emerging Power-to-X approach. Methane is one such high-valued fuel that can be produced through renewables-powered electrolytic routes. Such Read More
Radiation Damage of Reactor Pressure Vessel Steels Studied by Positron Annihilation Spectroscopy—A Review
Oct 2020
Publication
Safe and long term operation of nuclear reactors is one of the most discussed challenges in nuclear power engineering. The radiation degradation of nuclear design materials limits the operational lifetime of all nuclear installations or at least decreases its safety margin. This paper is a review of experimental PALS/PLEPS studies of different nuclear reactor pressure vessel (RPV) steels investigated over last twenty years in our laboratories. Positron annihil Read More
Fatigue Behavior of AA2198 in Liquid Hydrogen
Aug 2019
Publication
Tensile and fatigue tests were performed on an AA2198 aluminum alloy in the T851 condition in ambient air and liquid hydrogen (LH2). All fatigue tests were performed under load control at a frequency of 20 Hz and a stress ratio of R=0.1. The Gecks-Och-Function [1] was fitted on the measured cyclic lifetimes.The tensile strength in LH2 was measured to be 46 % higher compared to the value determined at ambient conditions and the fatigue limit was increa Read More
A Novel Self-Assembly Strategy for the Fabrication of Nano-Hybrid Satellite Materials with Plasmonically Enhanced Catalytic Activity
Jun 2021
Publication
The generation of hydrogen from water using light is currently one of the most promising alternative energy sources for humankind but faces significant barriers for large-scale applications due to the low efficiency of existing photo-catalysts. In this work we propose a new route to fabricate nano-hybrid materials able to deliver enhanced photo-catalytic hydrogen evolution combining within the same nanostructure a plasmonic antenna nanoparticl Read More
CFD Modelling of Underexpanded Hydrogen Jets Exiting Rectangular Shaped Openings
May 2020
Publication
Underexpanded jet releases from circular nozzles have been studied extensively both experimentally and numerically. However jet releases from rectangular openings have received much less attention and information on their dispersion behaviour is not as widely available. In this paper Computational Fluid Dynamics (CFD) is used to assess the suitability of using a pseudo-source approach to model jet releases from rectangular openings. A comparativ Read More
Rock Mass Response for Lined Rock Caverns Subjected to High Internal Gas Pressure
Mar 2022
Publication
The storage of hydrogen gas in underground lined rock caverns (LRCs) enables the implementation of the first fossil-free steelmaking process to meet the large demand for crude steel. Predicting the response of rock mass is important to ensure that gas leakage due to rupture of the steel lining does not occur. Analytical and numerical models can be used to estimate the rock mass response to high internal pressure; however the fitness of these models u Read More
Hydrogen Production from Natural Gas and Biomethane with Carbon Capture and Storage – A Techno-environmental Analysis
Mar 2020
Publication
This study presents an integrated techno-environmental assessment of hydrogen production from natural gas and biomethane combined with CO2 capture and storage (CCS). We have included steam methane reforming (SMR) and autothermal reforming (ATR) for syngas production. CO2 is captured from the syngas with a novel vacuum pressure swing adsorption (VPSA) process that combines hydrogen purification and CO2 separation in one cycle. As c Read More
Development of a Tangential Neutron Radiography System for Monitoring the Fatigue Cracks in Hydrogen Fuel Tanks
Jun 2016
Publication
Purpose- To present an overview of the research and development carried out in a European funded framework 7 (FP7) project called SafeHPower for the implementation of neutron radiography to inspect fatigue cracks in vehicle and storage hydrogen fuel tanks. Project background– Hydrogen (H2) is the most promising replacement fuel for road transport due to its abundance efficiency low carbon footprint and the absence of harmful emissions. For the Read More
Effect of Cementite on the Hydrogen Diffusion/Trap Characteristics of 2.25Cr-1Mo-0.25V Steel with and without Annealing
May 2018
Publication
Hydrogen embrittlement (HE) is a critical issue that affects the reliability of hydrogenation reactors. The hydrogen diffusivity/trap characteristics of 2.25Cr-1Mo-0.25V steel are important parameters mainly used to study the HE mechanism of steel alloys. In this work the hydrogen diffusivity/trap characteristics of heat-treated (annealed) and untreated 2.25Cr-1Mo-0.25V steel were studied using an electrochemical permeation method. The microstructures o Read More
Low-carbon Hydrogen Via Integration of Steam Methane Reforming with Molten Carbonate Fuel Cells at Low Fuel Utilization
Feb 2021
Publication
Hydrogen production is critical to many modern chemical processes – ammonia synthesis petroleum refining direct reduction of iron and more. Conventional approaches to hydrogen manufacture include steam methane reforming and autothermal reforming which today account for the lion's share of hydrogen generation. Without CO2 capture these processes emit about 8.7 kg of CO2 for each kg of H2 produced. In this study a molten carbonate fuel cell Read More
The Renewable Hydrogen–Methane (RHYME) Transportation Fuel: A Practical First Step in the Realization of the Hydrogen Economy
Feb 2022
Publication
The permanent introduction of green hydrogen into the energy economy would require that a discriminating selection be made of its use in the sectors where its value is optimal in terms of relative cost and life cycle reduction in carbon dioxide emissions. Consequently hydrogen can be used as an energy storage medium when intermittent wind and solar power exceed certain penetration in the grid likely above 40% and in road transportation right Read More
Analysis of Environmentally Assisted Cracking Processes in Notched Steels Using the Point Method
Sep 2019
Publication
This paper proposes the use of the Point Method (PM) to analyse Environmentally Assisted Cracking (EAC) processes in steels containing U-shaped notches. The PM a methodology included within the Theory of Critical Distances (TCD) has been extensively validated by many authors for the analysis of fracture and fatigue phenomena of different types of materials containing notches. However it has never been applied to other critical or subcritical cracking p Read More
Stress–Corrosion Cracking of AISI 316L Stainless Steel in Seawater Environments: Effect of Surface Machining
Oct 2020
Publication
To understand the effect of surface machining on the resistance of AISI 316L to SCC (stress–corrosion cracking) in marine environments we tested nuts surface-machined by different methods in a seawater-spraying chamber. Two forms of cracks were observed: on the machined surface and underneath it. On the surface cracks connected with the pitting sites were observed to propagate perpendicular to the hoop-stress direction identifying them as stre Read More
Research of Nanomaterials as Electrodes for Electrochemical Energy Storage
Jan 2022
Publication
This paper has experimentally proved that hydrogen accumulates in large quantities in metal-ceramic and pocket electrodes of alkaline batteries during their operation. Hydrogen accumulates in the electrodes in an atomic form. After the release of hydrogen from the electrodes a powerful exothermic reaction of atomic hydrogen recombination with a large energy release occurs. This exothermic reaction is the cause of thermal runaway in alkaline batteries Read More
Life Cycle Assessment of Hydrogen and Fuel Cell Technologies: Inventory of Work Performed by Projects Funded Under FCH JU
Apr 2020
Publication
This report is the public version of the deliverable B.3.7 'Life cycle assessment of Hydrogen and Fuel Cell Technologies - Inventory of work performed by projects funded under FCH JU'; it provides an overview of the progress achieved so far and a comprehensive analysis on Life Cycle Assessment (LCA) for various hydrogen technologies and processes. The review considers 73 Fuel Cells and Hydrogen 2 Joint Undertaking (FCH 2 JU) founded projects: f Read More
Materials for Hydrogen Storage
Aug 2003
Publication
Hydrogen storage is a materials science challenge because for all six storage methods currently being investigated materials with either a strong interaction with hydrogen or without any reaction are needed. Besides conventional storage methods i.e. high pressure gas cylinders and liquid hydrogen the physisorption of hydrogen on materials with a high specific surface area hydrogen intercalation in metals and complex hydrides and storage of hy Read More
Hydrogen Production by Electrochemical Reaction Using Ethylene Glycol with Terephthalic Acid
Jan 2021
Publication
In this study ethylene glycol (EG) and terephthalic acid (TPA) were used to generate hydrogen using copper electrodes in an alkaline aqueous solution and the corresponding reaction mechanism was experimentally investigated. Both EG and TPA produced hydrogen; however TPA consumed OH− inhibiting the production of intermediary compounds of EG and causing EG to actively react with H2O ultimately leading to enhanced hydrogen production. In a Read More
Effect of Vanadium-alloying on Hydrogen Embrittlement of Austenitic High-nitrogen Steels
Dec 2018
Publication
The effect of hydrogen on tensile behavior and fracture mechanisms of V-alloying and V-free high-nitrogen austenitic steels was evaluated. Two steels with the chemical compositions of Fe-23Cr–17Mn–0.1C–0.6N (0V-HNS) and Fe-19Cr–22Mn–1.5V–0.3C–0.9N (1.5V-HNS) were electrochemically hydrogen-charged in NaCl water-solution for 100 hours. According to X-ray diffraction analysis and TEM researches V-alloying promotes particle strengthening of the 1. Read More
Hydrogen: A Critical Part of Heat Decarbonisation
Feb 2021
Publication
The use of clean hydrogen is likely to form a key part of a net-zero emissions future and has the potential to replace natural gas for end use heating. As part of BDR Thermea Group Baxi Heating UK are at the forefront of hydrogen boiler development. Working with the Hy4Heat programme hydrogen fuelled boilers have been produced for inclusion in trial sites across the UK. This presentation will explore progress to date together with the hydrogen-ready boiler concept.
Hydrogen Europe 2020
Dec 2020
Publication
2020: a great year for hydrogen! Among other things 2020 has been exceptional for H2 technology deployment and policy development. The European Commission’s hydrogen strategy is just one of many crowning achievements! What does the future hold?
National Hydrogen Roadmap: Pathways to an Economically Sustainable Hydrogen Industry in Australia
Apr 2021
Publication
The National Hydrogen Roadmap provides a blueprint for the development of a hydrogen industry in Australia.Recently there has been a considerable amount of work undertaken (both globally and domestically) seeking to quantify the economic opportunities associated with hydrogen. The National Hydrogen Roadmap takes that analysis a step further by focusing on how those opportunities can be realised.National Hydrogen RoadmapThe Nati Read More
Renewable Energy Market Analysis: Africa and its Regions
Jan 2022
Publication
An energy system centred on renewable energy can help resolve many of Africa’s social economic health and environmental challenges. A profound energy transition is not only feasible it is essential for a climate-safe future in which sustainable development prerogatives are met. Renewables are key to overcoming energy poverty providing needed energy services without damaging human health or ecosystems and enabling a transformation of e Read More
Earth-Abundant Electrocatalysts for Water Splitting: Current and Future Directions
Mar 2021
Publication
Of all the available resources given to mankind the sunlight is perhaps the most abundant renewable energy resource providing more than enough energy on earth to satisfy all the needs of humanity for several hundred years. Therefore it is transient and sporadic that poses issues with how the energy can be harvested and processed when the sun does not shine. Scientists assume that electro/photoelectrochemical devices used for water splitting into h Read More
Effect of Anion Exchange Ionomer Content on Electrode Performance in AEM Water Electrolysis
Aug 2020
Publication
Anion exchange membrane water electrolysis (AEMWE) has acquired substantial consideration as a cost-effective hydrogen production technology. The anion ionomer content in the catalyst layers during hydrogen and oxygen evolution reaction (HER and OER) is of ultimate significance. Herein an in-situ half-cell analysis with reference electrodes was carried out for simultaneous potential measurements and identification of the influence of the anion excha Read More
Insight into Anomalous Hydrogen Adsorption on Rare Earth Metal Decorated on 2 Dimensional Hexagonal Boron Nitride a Density Functional Theory Study
Mar 2020
Publication
Hydrogen interaction with metal atoms is of prime focus for many energy related applications like hydrogen storage hydrogen evolution using catalysis etc. Although hydrogen binding with many main group alkaline and transition metals is quite well understood its binding properties with lanthanides are not well reported. In this article by density functional theory studies we show how a rare earth metal cerium binds with hydrogen when decorated over a h Read More
Techno-economic Feasibility of Road Transport of Hydrogen Using Liquid Organic Hydrogen Carriers
Sep 2020
Publication
The cost of storing and transporting hydrogen have been one of the main challenges for the realization of the hydrogen economy. Liquid organic hydrogen carriers (LOHC) are a promising novel solution to tackle these challenges. In this paper we compare the LOHC concept to compressed gas truck delivery and on-site production of hydrogen via water electrolysis. As a case study we consider transportation of by-product hydrogen from chlor-alkali and chl Read More
South Korea’s Big Move to Hydrogen Society
Nov 2020
Publication
Extensive energy consumption has become a major concern due to increase of greenhouse gas emissions and global warming. Hence hydrogen has attracted attention as a green fuel with zero carbon emission for green transportation through production of electric vehicles with hydrogen fuel cells. South Korea has launched a hydrogen society policy with the objective of expanding production of hydrogen from renewable energy sources. The hydro Read More
A Critical Review of Renewable Hydrogen Production Methods: Factors Affecting Their Scale-Up and Its Role in Future Energy Generation
Feb 2022
Publication
An increase in human activities and population growth have significantly increased the world’s energy demands. The major source of energy for the world today is from fossil fuels which are polluting and degrading the environment due to the emission of greenhouse gases. Hydrogen is an identified efficient energy carrier and can be obtained through renewable and non-renewable sources. An overview of renewable sources of hydrogen production w Read More
A Study on the Characteristics of Academic Topics Related to Renewable Energy Using the Structural Topic Modelling and the Weak Signal Concept
Mar 2021
Publication
It is important to examine in detail how the distribution of academic research topics related to renewable energy is structured and which topics are likely to receive new attention in the future in order for scientists to contribute to the development of renewable energy. This study uses an advanced probabilistic topic modeling to statistically examine the temporal changes of renewable energy topics by using academic abstracts from 2010–2019 and explor Read More
TM-doped Mg12O12 Nano-cages for Hydrogen Storage Applications: Theoretical Study
Feb 2022
Publication
DFT calculations at B3LYP/6-31g(dp) with the D3 version of Grimme’s dispersion are performed to investigate the application of TM-encapsulated Mg12O12 nano-cages (TM= Mn Fe and Co) as a hydrogen storage material. The molecular dynamic (MD) calculations are utilized to examine the stability of the considered structures. TD-DFT method reveals that the TM-encapsulation converts the Mg12O12 from an ultraviolet into a visible optical active m Read More
Comarine Derivatives Designed as Carbon Dioxide and Hydrogen Storage
Feb 2022
Publication
The growing of fossil fuel burning leads to increase CO2 and H2 emissions which cause increasing of global warming that has brought big attention. As a result enormous researches have been made to reduce CO2 and H2 build up in the environment. One of the most promising approaches for managing CO2 and H2 gases percentage in the atmosphere is capturing and storage them inside proper materials. Therefore the design of new materials for car Read More
A Probabilistic Framework for the Techno-economic Assessment of Smart Energy Hubs for Electric Vehicle Charging
Apr 2022
Publication
Smart energy hubs (Smart Hubs) equipped with Vehicle-to-Grid (V2G) charging photovoltaic (PV) energy generation and hydrogen storage capabilities are an emerging technology with potential to alleviate the impact of electric vehicles (EV) on the electricity grid. Their operation however is characterised by intermittent PV energy generation as well as uncertainties in EV traffic and driver preference. These uncertainties when combined with the need t Read More
Multi-Criteria Optimization of a Biomass-Based Hydrogen Production System Integrated With Organic Rankine Cycle
Oct 2020
Publication
Biomass-based gasification is an attractive and promising pathway for hydrogen production. In this work a biomass-based hydrogen production system integrated with organic Rankine cycle was designed and investigated to predict the performance of hydrogen production yield and electricity generation under various operating conditions. The modified equilibrium model presented desirable results for the produced syngas compositions compared Read More
Hydrogen Embrittlement and Improved Resistance of Al Addition in Twinning-Induced Plasticity Steel: First-Principles Study
Apr 2019
Publication
Understanding the mechanism of hydrogen embrittlement (HE) of austenitic steels and developing an effective strategy to improve resistance to HE are of great concern but challenging. In this work first-principles studies were performed to investigate the HE mechanism and the improved resistance of Al-containing austenite to HE. Our results demonstrate that interstitial hydrogen atoms have different site preferences in Al-free and Al-containing au Read More
An Innovative and Comprehensive Approach for the Consequence Analysis of Liquid Hydrogen Vessel Explosions
Oct 2020
Publication
Hydrogen is one of the most suitable solutions to replace hydrocarbons in the future. Hydrogen consumption is expected to grow in the next years. Hydrogen liquefaction is one of the processes that allows for increase of hydrogen density and it is suggested when a large amount of substance must be stored or transported. Despite being a clean fuel its chemical and physical properties often arise concerns about the safety of the hydrogen technologies. A Read More
The Role of Hydrogen in Hydrogen Embrittlement of Metals: The Case of Stainless Steel
Apr 2019
Publication
Hydrogen embrittlement (HE) of metals has remained a mystery in materials science for more than a century. To try to clarify this mystery tensile tests were conducted at room temperature (RT) on a 316 stainless steel (SS) in air and hydrogen of 70 MPa. With an aim to directly observe the effect of hydrogen on ordering of 316 SS during deformation electron diffraction patterns and images were obtained from thin foils made by a focused ion beam from t Read More
Aldehyde Replacement Advances Efficient Hydrogen Production in Electrolyser
Mar 2022
Publication
The high energy consumption and production of undesired oxygen greatly restrict the wide adoption of water electrolysis for hydrogen production. In a paper recently published in Nature Catalysis Wang and coworkers rationally introduce aldehydes for oxidation at anode to replace oxygen evolution reaction which can produce hydrogen and value-added products at low potential realizing efficient bipolar hydrogen production with high-purity. Moreover these Read More
Economic Analysis of Improved Alkaline Water Electrolysis
Feb 2017
Publication
Alkaline water electrolysis (AWE) is a mature hydrogen production technology and there exists a range of economic assessments for available technologies. For advanced AWEs which may be based on novel polymer-based membrane concepts it is of prime importance that development comes along with new configurations and technical and economic key process parameters for AWE that might be of interest for further economic assessments. This pap Read More
The Impact of Hydrogen on Mechanical Properties; A New In Situ Nanoindentation Testing Method
Feb 2019
Publication
We have designed a new method for electrochemical hydrogen charging which allows us to charge very thin coarse-grained specimens from the bottom and perform nanomechanical testing on the top. As the average grain diameter is larger than the thickness of the sample this setup allows us to efficiently evaluate the mechanical properties of multiple single crystals with similar electrochemical conditions. Another important advantage is that the top Read More
Review of the Current Status of Ammonia-Blended Hydrogen Fuel Engine Development
Jan 2022
Publication
As fossil fuels continue to be extracted and used issues such as environmental pollution and energy scarcity are surfacing. For the transportation industry the best way to achieve the goal of “carbon neutrality” is to research efficient power systems and develop new alternative fuels. As the world’s largest product of chemicals ammonia is a new renewable fuel with good combustion energy. It can be used as an alternative fuel to reduce carbon emissions becau Read More
Future Fuels Strategy: Discussion Paper Powering Choice
Feb 2021
Publication
New vehicle technologies and fuels will drive the future of road transport in Australia. Increased availability of battery electric vehicles hydrogen fuel cell vehicles biofuels and associated recharging and refuelling infrastructure will:give consumers more choiceprovide productivity emissions reduction fuel security and air quality benefitsOur Future Fuels Strategy: Discussion Paper sets out the direction and practical actions to enable the private sector Read More
Results of the Pre-normative Research Project PRESLHY for the Safe Use of Liquid Hydrogen
Sep 2021
Publication
Liquid hydrogen (LH2) compared to compressed gaseous hydrogen offers advantages for large-scale transport and storage of hydrogen with higher densities. Although the gas industry has good experience with LH2 only little experience is available for the new applications of LH2 as an energy carrier. Therefore the European FCH JU funded project PRESLHY conducted pre-normative research for the safe use of cryogenic LH2 in non-industrial set Read More
Numerical Simulation of Tensile Behavior of Corroded Aluminum Alloy 2024 T3 Considering the Hydrogen Embrittlement
Jan 2018
Publication
A multi-scale modeling approach for simulating the tensile behavior of the corroded aluminum alloy 2024 T3 was developed accounting for both the geometrical features of corrosion damage and the effect of corrosion-induced hydrogen embrittlement (HE). The approach combines two Finite Element (FE) models: a model of a three-dimensional Representative Unit Cell (RUC) representing an exfoliated area and its correspondent hydrogen embrittled Read More
The Impact of Climate Targets on Future Steel Production – An Analysis Based on a Global Energy System Model
Apr 2020
Publication
This paper addresses how a global climate target may influence iron and steel production technology deployment and scrap use. A global energy system model ETSAP-TIAM was used and a Scrap Availability Assessment Model (SAAM) was developed to analyse the relation between steel demand recycling and the availability of scrap and their implications for steel production technology choices. Steel production using recycled materials has a continuous Read More
AC-DC Converters for Electrolyzer Applications: State of the Art and Future Challenges
May 2020
Publication
The main objective of the article is to provide a thorough review of currently used AC-DC converters for alkaline and proton exchange membrane (PEM) electrolyzers in power grid or wind energy conversion systems. Based on the current literature this article aims at emphasizing the advantages and drawbacks of AC-DC converters mainly based on thyristor rectifier bridges and chopper-rectifiers. The analysis is mainly focused on the current iss Read More
Multi-Period Planning of Hydrogen Supply Network for Refuelling Hydrogen Fuel Cell Vehicles in Urban Areas
May 2020
Publication
The hydrogen economy refers to an economic and industrial structure that uses hydrogen as its main energy source replacing traditional fossil-fuel-based energy systems. In particular the widespread adoption of hydrogen fuel cell vehicles (HFCVs) is one of the key factors enabling a hydrogen economy and aggressive investment in hydrogen refuelling infrastructure is essential to make large-scale adoption of HFCVs possible. In this study we address t Read More
Unusual Hydrogen Implanted Gold with Lattice Contraction at Increased Hydrogen Content
Mar 2021
Publication
The experimental evidence for the contraction of volume of gold implanted with hydrogen at low doses is presented. The contraction of lattice upon the addition of other elements is very rare and extraordinary in the solid-state not only for gold but also for many other solids. To explain the underlying physics the pure kinetic theory of absorption is not adequate and the detailed interaction of hydrogen in the lattice needs to be clarified. Our analysis poin Read More
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