United States
Hydrogen Compatability of Structural Materials in Natural Gas Networks
Sep 2021
Publication
There is growing interest in utilizing existing infrastructure for storage and distribution of hydrogen. Gaseous hydrogen for example could be added to natural gas in the short-term whereas entire systems can be converted to transmission and distribution networks for hydrogen. Many active programs around the world are exploring the safety and feasibility of adding hydrogen to these networks. Concerns have been raised about the structural integrity of materials in these systems when exposed to hydrogen. In general the effects of hydrogen on these materials are grossly misunderstood. Hydrogen unequivocally degrades fatigue and fracture resistance of structural steels in these systems even for low hydrogen partial pressure (-l bar). In most systems however hydrogen effects will not be apparent because the stresses in these systems remain very low. Another misunderstanding results from the kinetics of the hydrogen effects: hydrogen degrades fatigue and fracture properties immediately upon exposure to gaseous hydrogen and those effects disappear when the hydrogen environment is removed even after prolonged exposure. There is also a misperception that materials selection can mitigate hydrogen effects. While some classes of materials perform better in hydrogen environments than other classes for most practical circumstances the range of response for a given class of material in gaseous hydrogen environments is rather narrow. These observations can be systematically characterized by considering the intersection of materials environmental and mechanical variables associated with the service application. Indeed any safety assessment of a hydrogen pressure system must quantitatively consider these aspects. In this report we quantitatively evaluate the importance of the materials environmental and mechanical variables in the context of hydrogen additions to natural gas piping and pipeline systems with the aim of providing an informed perspective on parameters relevant for assessing structural integrity of natural gas systems in the presence of gaseous hydrogen.
Analysis of a Large Balloon Explosion Incident
Sep 2021
Publication
On December 19 2017 a large balloon containing about 22 thousand cubic meters of hydrogen was deliberately torn open to initiate deflation at the completion of a filling test. An inadvertent ignition occurred after about two seconds and caused an explosion that produced extensive light damage to a large building near the balloon test pad. The analysis described here includes an estimate of the buoyancy induced mixing into the torn balloon and the blast wave produced by assumed constant flame speed combustion of the 55% to 65% hydrogen-in-air mixture. Comparisons of calculated blast wave pressures are consistent with estimates of the pressure needed to cause the observed building damage for flame speeds in the range 85 m/s to about 100 m/s.
Time-phased Geospatial Siting Analysis for Renewable Hydrogen Production Facilities under a Billion-kilogram-scale Build-out using California as an Example
Jun 2022
Publication
For renewable hydrogen to be a significant part of the future decarbonized energy and transportation sectors a rapid and massive build-out of hydrogen production facilities will be needed. This paper describes a geospatial modeling approach to identifying the optimal locations for renewable hydrogen fuel production throughout the state of California based on least-cost generation and transport. This is accomplished by (1) estimating and projecting California renewable hydrogen demand scenarios through the year 2050 (2) identifying feedstock locations (3) excluding areas not suitable for development and (4) selecting optimal site locations using commercial geospatial modeling software. The findings indicate that there is a need for hundreds of new renewable hydrogen production facilities in the decades preceding the year 2050. In selecting sites for development feedstock availability by technology type is the driving factor."
Everything About Hydrogen Podcast: Hydrogen 101
Aug 2019
Publication
A 10-minute tour of hydrogen industry technology and terminology for those who are new to the sector or who would simply like a quick review of the basics behind this burgeoning energy source.
Podcast can be found on their website
Podcast can be found on their website
“Bigger than Government”: Exploring the Social Construction and Contestation of Net-zero Industrial Megaprojects in England
Jan 2023
Publication
Industry is frequently framed as hard-to-decarbonize given its diversity of requirements technologies and supply chains many of which are unique to particular sectors. Net zero commitments since 2019 have begun to challenge the carbon intensity of these various industries but progress has been slow globally. Against this backdrop the United Kingdom has emerged as a leader in industrial decarbonization efforts. Their approach is based on industrial clusters which cut across engineering spatial and socio-political dimensions. Two of the largest of these clusters in England in terms of industrial emissions are the Humber and Merseyside. In this paper drawn from a rich mixed methods original dataset involving expert interviews (N = 46 respondents) site visits (N = 20) a review of project documents and the academic literature we explore ongoing efforts to decarbonize both the Humber and Merseyside through the lens of spatially expansive and technically complex megaprojects. Both have aggressive implementation plans in place for the deployment of net-zero infrastructure with Zero Carbon Humber seeking billions in investment to build the country’s first large-scale bioenergy with carbon capture and storage (BECCS) plant alongside a carbon transport network and hydrogen production infrastructure and HyNet seeking billions in investment to build green and blue hydrogen facilities along with a carbon storage network near Manchester and Liverpool. We draw from the social construction of technology (SCOT) literature to examine the relevant social groups interpretive flexibility and patterns of closure associated with Zero Carbon Humber and HyNet. We connect our findings to eight interpretive frames surrounding the collective projects and make connections to problems contestation and closure.
The Role of Natural Gas and its Infrastructure in Mitigating Greenhouse Gas Emissions, Improving Regional Air Quality, and Renewable Resource Integration
Nov 2017
Publication
The pursuit of future energy systems that can meet electricity demands while supporting the attainment of societal environment goals including mitigating climate change and reducing pollution in the air has led to questions regarding the viability of continued use of natural gas. Natural gas use particularly for electricity generation has increased in recent years due to enhanced resource availability from non-traditional reserves and pressure to reduce greenhouse gasses (GHG) from higher-emitting sources including coal generation. While lower than coal emissions current natural gas power generation strategies primarily utilize combustion with higher emissions of GHG and criteria pollutants than other low-carbon generation options including renewable resources. Furthermore emissions from life cycle stages of natural gas production and distribution can have additional detrimental GHG and air quality (AQ) impacts. On the other hand natural gas power generation can play an important role in supporting renewable resource integration by (1) providing essential load balancing services and (2) supporting the use of gaseous renewable fuels through the existing infrastructure of the natural gas system. Additionally advanced technologies and strategies including fuel cells and combined cooling heating and power (CCHP) systems can facilitate natural gas generation with low emissions and high efficiencies. Thus the role of natural gas generation in the context of GHG mitigation and AQ improvement is complex and multi-faceted requiring consideration of more than simple quantification of total or net emissions. If appropriately constructed and managed natural gas generation could support and advance sustainable and renewable energy. In this paper a review of the literature regarding emissions from natural gas with a focus on power generation is conducted and discussed in the context of GHG and AQ impacts. In addition a pathway forward is proposed for natural gas generation and infrastructure to maximize environmental benefits and support renewable resources in the attainment of emission reductions.
Everything About Hydrogen Podcast: Global Energy Majors in the Hydrogen Space
Jul 2022
Publication
On today’s episode of Everything About Hydrogen we are speaking with Paul Bogers Vice President for Hydrogen at Shell. As a company Shell needs no introduction but the company’s work and investments in the hydrogen space make it a global leader in the energy transition especially when it comes to the hydrogen component. Paul is amongst the executives at Shell that are working to bring their hydrogen vision to fruition and it is great to have him with us on the show today.
The podcast can be found on their website
The podcast can be found on their website
Hydrogen Storage in Pure and Boron-Substituted Nanoporous Carbons—Numerical and Experimental Perspective
Aug 2021
Publication
Nanoporous carbons remain the most promising candidates for effective hydrogen storage by physisorption in currently foreseen hydrogen-based scenarios of the world’s energy future. An optimal sorbent meeting the current technological requirement has not been developed yet. Here we first review the storage limitations of currently available nanoporous carbons then we discuss possible ways to improve their storage performance. We focus on two fundamental parameters determining the storage (the surface accessible for adsorption and hydrogen adsorption energy). We define numerically the values nanoporous carbons have to show to satisfy mobile application requirements at pressures lower than 120 bar. Possible necessary modifications of the topology and chemical compositions of carbon nanostructures are proposed and discussed. We indicate that pore wall fragmentation (nano-size graphene scaffolds) is a partial solution only and chemical modifications of the carbon pore walls are required. The positive effects (and their limits) of the carbon substitutions by B and Be atoms are described. The experimental ‘proof of concept’ of the proposed strategies is also presented. We show that boron substituted nanoporous carbons prepared by a simple arc-discharge technique show a hydrogen adsorption energy twice as high as their pure carbon analogs. These preliminary results justify the continuation of the joint experimental and numerical research effort in this field.
Pore-scale Study of Microbial Hydrogen Consumption and Wettability Alteration During Underground Hydrogen Storage
Feb 2023
Publication
Hydrogen can be a renewable energy carrier and is suggested to store renewable energy and mitigate carbon dioxide emissions. Subsurface storage of hydrogen in salt caverns deep saline formations and depleted oil/gas reservoirs would help to overcome imbalances between supply and demand of renewable energy. Hydrogen however is one of the most important electron donors for many subsurface microbial processes including methanogenesis sulfate reduction and acetogenesis. These processes cause hydrogen loss and changes of reservoir properties during geological hydrogen storage operations. Here we report the results of a typical halophilic sulfate-reducing bacterium growing in a microfluidic pore network saturated with hydrogen gas at 35 bar and 37°C. Test duration is 9 days. We observed a significant loss of H2 from microbial consumption after 2 days following injection into a microfluidic device. The consumption rate decreased over time as the microbial activity declined in the pore network. The consumption rate is influenced profoundly by the surface area of H2 bubbles and microbial activity. Microbial growth in the silicon pore network was observed to change the surface wettability from a water-wet to a neutral-wet state. Due to the coupling effect of H2 consumption by microbes and wettability alteration the number of disconnected H2 bubbles in the pore network increased sharply over time. These results may have significant implications for hydrogen recovery and gas injectivity. First pore-scale experimental results reveal the impacts of subsurface microbial growth on H2 in storage which are useful to estimate rapidly the risk of microbial growth during subsurface H2 storage. Second microvisual experiments provide critical observations of bubble-liquid interfacial area and reaction rate that are essential to the modeling that is needed to make long-term predictions. Third results help us to improve the selection criteria for future storage sites.
Comparative Levelized Cost Analysis of Transmitting Renewable Solar Energy
Feb 2023
Publication
A bottom-up cost analysis for delivering utility-scale PV-generated electricity as hydrogen through pipelines and as electricity through power is undertaken. Techno-economic generation and demand data for California are used to calculate the levelized cost of transmitting (LCOT) energy and the levelized cost of electricity (LCOE) prior to distribution. High-voltage levels of 230 kV and 500 kV and 24-inch and 36-inch pipelines for 100 to 700 miles of transmission are considered. At 100 miles of transmission the cost of transmission between each medium is comparable. At longer distances the pipeline scenarios become increasingly cheaper at low utilization levels. The all-electric pathways utilizing battery energy storage systems can meet 95% of the load for as low as 356 USD/MWh whereas when meeting 100% of load with the hydrogen gas turbine and fuel cell pathways the costs are 278 and 322 USD/MWh respectively.
Everything About Hydrogen Podcast: Where Does Hydrogen Fit in the Global Energy Transition?
Apr 2022
Publication
On this episode the EAH team discusses the role of hydrogen in the energy transition with Michael Liebreich Chairman and CEO of Liebreich Associates. Michael is an acknowledged thought leader on clean energy mobility technology climate sustainability and finance. He is the founder and senior contributor to Bloomberg New Energy Finance a member of numerous industry governmental and multilateral advisory boards an angel investor a former member of the board of Transport for London and an Advisor to the UK Board of Trade.
The podcast can be found on their website
The podcast can be found on their website
Influences on Hydrogen Production at a Wind Farm
Dec 2022
Publication
If an affordable infrastructure for low-carbon-intensity hydrogen can be developed then hydrogen is expected to become a key factor in decarbonizing the atmosphere. This research focuses on factors an existing wind farm operator would consider when weighing participating in the electricity market the hydrogen market or both. The solutions depend on the state of technology which is changing rapidly the local market structures the local natural resources and the local pre-existing infrastructure. Consequently this investigation used an assessment approach that examined the variation of net present value. The investigation identified profitability conditions under three different scenarios: 1) Make and sell what makes economic sense at the time of production 2) Use electrolyzer and fuel cell to consume power from the grid at times of low net demand and to produce electricity at times of high net demand 3) Same as #2 but also market hydrogen directly when profitable.
Fundamentals, Materials, and Machine Learning of Polymer Electrolyte Membrane Fuel Cell Technology
Jun 2020
Publication
Polymer electrolyte membrane (PEM) fuel cells are electrochemical devices that directly convert the chemical energy stored in fuel into electrical energy with a practical conversion efficiency as high as 65%. In the past years significant progress has been made in PEM fuel cell commercialization. By 2019 there were over 19000 fuel cell electric vehicles (FCEV) and 340 hydrogen refueling stations (HRF) in the U.S. (~8000 and 44 respectively) Japan (~3600 and 112 respectively) South Korea (~5000 and 34 respectively) Europe (~2500 and 140 respectively) and China (~110 and 12 respectively). Japan South Korea and China plan to build approximately 3000 HRF stations by 2030. In 2019 Hyundai Nexo and Toyota Mirai accounted for approximately 63% and 32% of the total sales with a driving range of 380 and 312 miles and a mile per gallon (MPGe) of 65 and 67 respectively. Fundamentals of PEM fuel cells play a crucial role in the technological advancement to improve fuel cell performance/durability and reduce cost. Several key aspects for fuel cell design operational control and material development such as durability electrocatalyst materials water and thermal management dynamic operation and cold start are briefly explained in this work. Machine learning and artificial intelligence (AI) have received increasing attention in material/energy development. This review also discusses their applications and potential in the development of fundamental knowledge and correlations material selection and improvement cell design and optimization system control power management and monitoring of operation health for PEM fuel cells along with main physics in PEM fuel cells for physics-informed machine learning. The objective of this review is three fold: (1) to present the most recent status of PEM fuel cell applications in the portable stationary and transportation sectors; (2) to describe the important fundamentals for the further advancement of fuel cell technology in terms of design and control optimization cost reduction and durability improvement; and (3) to explain machine learning physics-informed deep learning and AI methods and describe their significant potentials in PEM fuel cell research and development (R&D).
Magnesium-Based Hydrogen Storage Alloys: Advances, Strategies, and Future Outlook for Clean Energy Applications
May 2024
Publication
Magnesium-based hydrogen storage alloys have attracted significant attention as promising materials for solid-state hydrogen storage due to their high hydrogen storage capacity abundant reserves low cost and reversibility. However the widespread application of these alloys is hindered by several challenges including slow hydrogen absorption/desorption kinetics high thermodynamic stability of magnesium hydride and limited cycle life. This comprehensive review provides an in-depth overview of the recent advances in magnesium-based hydrogen storage alloys covering their fundamental properties synthesis methods modification strategies hydrogen storage performance and potential applications. The review discusses the thermodynamic and kinetic properties of magnesium-based alloys as well as the effects of alloying nanostructuring and surface modification on their hydrogen storage performance. The hydrogen absorption/desorption properties of different magnesium-based alloy systems are compared and the influence of various modification strategies on these properties is examined. The review also explores the potential applications of magnesium-based hydrogen storage alloys including mobile and stationary hydrogen storage rechargeable batteries and thermal energy storage. Finally the current challenges and future research directions in this field are discussed highlighting the need for fundamental understanding of hydrogen storage mechanisms development of novel alloy compositions optimization of modification strategies integration of magnesium-based alloys into hydrogen storage systems and collaboration between academia and industry.
Review on Ammonia as a Potential Fuel: From Synthesis to Economics
Feb 2021
Publication
Ammonia a molecule that is gaining more interest as a fueling vector has been considered as a candidate to power transport produce energy and support heating applications for decades. However the particular characteristics of the molecule always made it a chemical with low if any benefit once compared to conventional fossil fuels. Still the current need to decarbonize our economy makes the search of new methods crucial to use chemicals such as ammonia that can be produced and employed without incurring in the emission of carbon oxides. Therefore current efforts in this field are leading scientists industries and governments to seriously invest efforts in the development of holistic solutions capable of making ammonia a viable fuel for the transition toward a clean future. On that basis this review has approached the subject gathering inputs from scientists actively working on the topic. The review starts from the importance of ammonia as an energy vector moving through all of the steps in the production distribution utilization safety legal considerations and economic aspects of the use of such a molecule to support the future energy mix. Fundamentals of combustion and practical cases for the recovery of energy of ammonia are also addressed thus providing a complete view of what potentially could become a vector of crucial importance to the mitigation of carbon emissions. Different from other works this review seeks to provide a holistic perspective of ammonia as a chemical that presents benefits and constraints for storing energy from sustainable sources. State-of-the-art knowledge provided by academics actively engaged with the topic at various fronts also enables a clear vision of the progress in each of the branches of ammonia as an energy carrier. Further the fundamental boundaries of the use of the molecule are expanded to real technical issues for all potential technologies capable of using it for energy purposes legal barriers that will be faced to achieve its deployment safety and environmental considerations that impose a critical aspect for acceptance and wellbeing and economic implications for the use of ammonia across all aspects approached for the production and implementation of this chemical as a fueling source. Herein this work sets the principles research practicalities and future views of a transition toward a future where ammonia will be a major energy player.
Linking Cost Decline and Demand Surge in the Hydrogen Market: A Case Study in China
Jun 2023
Publication
Hydrogen is crucial in achieving global energy transition and carbon neutrality goals. Existing market estimates typically presume linear or exponential growth but fail to consider how market demand responds to the declining cost of underlying technologies. To address this this study utilizes a learning curve model to project the cost of electrolyzers and its subsequent impact on hydrogen market aligning with a premise that the market demand is proportional to the cost of hydrogen. In a case study of China’s hydrogen market projecting from 2020 to 2060 we observed substantial differences in market evolution compared to exponential growth scenarios. Contrary to exponential growth scenarios China’s hydrogen market experiences faster growth during the 2020–2040 period rather than later. Such differences underscore the necessity for proactive strategic planning in emerging technology markets particularly for those experiencing rapid cost decline such as hydrogen. The framework can also be extended to other markets by using local data providing valuable insights to investors policymakers and developers engaged in the hydrogen market.
Numerical Simulation of Hydrogen Diffusion in Cement Sheath of Wells Used for Underground Hydrogen Storage
Jul 2023
Publication
The negative environmental impact of carbon emissions from fossil fuels has promoted hydrogen utilization and storage in underground structures. Hydrogen leakage from storage structures through wells is a major concern due to the small hydrogen molecules that diffuse fast in the porous well cement sheath. The second-order parabolic partial differential equation describing the hydrogen diffusion in well cement was solved numerically using the finite difference method (FDM). The numerical model was verified with an analytical solution for an ideal case where the matrix and fluid have invariant properties. Sensitivity analyses with the model revealed several possibilities. Based on simulation studies and underlying assumptions such as non-dissolvable hydrogen gas in water present in the cement pore spaces constant hydrogen diffusion coefficient cement properties such as porosity and saturation etc. hydrogen should take about 7.5 days to fully penetrate a 35 cm cement sheath under expected well conditions. The relatively short duration for hydrogen breakthrough in the cement sheath is mainly due to the small molecule size and high hydrogen diffusivity. If the hydrogen reaches a vertical channel behind the casing a hydrogen leak from the well is soon expected. Also the simulation result reveals that hydrogen migration along the axial direction of the cement column from a storage reservoir to the top of a 50 m caprock is likely to occur in 500 years. Hydrogen diffusion into cement sheaths increases with increased cement porosity and diffusion coefficient and decreases with water saturation (and increases with hydrogen saturation). Hence cement with a low water-to-cement ratio to reduce water content and low cement porosity is desirable for completing hydrogen storage wells.
Investigation of the Suitability of Viper: Blast CFD Software for Hydrogen and Vapor Cloud Explosions
Sep 2023
Publication
Many simplified methods for estimating blast loads from a hydrogen or vapor cloud explosion are unable to take into account the accurate geometry of confining spaces obstacles or landscape that may significantly interact with the blast wave and influence the strength of blast loads. Computation fluid dynamics (CFD) software Viper::Blast which was originally developed for the simulation of the detonation of high explosives is able to quickly and easily model geometry for blast analyses however its use for vapor cloud explosions and deflagrations is not well established. This paper describes the results of an investigation into the suitability of Viper::Blast for use in modeling hydrogen deflagration and detonation events from various experiments in literature. Detonation events have been captured with a high degree of detail and relatively little uncertainty in inputs while deflagration events are significantly more complex. An approach is proposed that may allow for a reasonable bounding of uncertainty potentially leading to an approach to CFD-based Monte Carlo analyses that are able to address a problem’s true geometry while remaining reasonably pragmatic in terms of run-time and computational investment. This will allow further exploration of practical CFD application to inform hydrogen safety in the engineering design assessment and management of energy mobility and transport systems infrastructure and operations.
Engineering Models for Refueling Protocol Development: Validation and Recommendations
Sep 2023
Publication
Fouad Ammouri,
Nicola Benvenuti,
Elena Vyazmina,
Vincent Ren,
Guillaume Lodier,
Quentin Nouvelot,
Thomas Guewouo,
Dorine Crouslé,
Rony Tawk,
Nicholas Hart,
Steve Mathison,
Taichi Kuroki,
Spencer Quong,
Antonio Ruiz,
Alexander Grab,
Alexander Kvasnicka,
Benoit Poulet,
Christopher Kutz and
Martin Zerta
The PRHYDE project (PRotocol for heavy duty HYDrogEn refueling) funded by the Clean Hydrogen partnership aims at developing recommendations for heavy-duty refueling protocols used for future standardization activities for trucks and other heavy duty transport systems applying hydrogen technologies. Development of a protocol requires a validated approach. Due to the limited time and budget the experimental data cannot cover the whole possible ranges of protocol parameters such as initial vehicle pressure and temperature ambient and precooling temperatures pressure ramp refueling time hardware specifications etc. Hence a validated numerical tool is essential for a safe and efficient protocol development. For this purpose engineering tools are used. They give good results in a very reasonable computation time of several seconds or minutes. These tools provide the heat parameters estimation in the gas (volume average temperature) and 1D temperature distribution in the tank wall. The following models were used SOFIL (Air Liquide tool) HyFill (by ENGIE) and H2Fills (open access code by NREL). The comparison of modelling results and experimental data demonstrated a good capability of codes to predict the evolution of average gas temperature in function of time. Some recommendations on model validation for the future protocol development are given.
Thermodynamic and Emission Analysis of a Hydrogen/Methane Fueled Gas Turbine
May 2023
Publication
The importance of hydrogen in the effort to decarbonize the power sector has grown immensely in recent years. Previous studies have investigated the effects of mixing hydrogen into natural gas for gas turbine combustors but limited studies have examined the resulting effects hydrogen addition has on the entire system. In this work a thermodynamic model of a gas turbine with combustion chemical kinetics integrated is created and the effects hydrogen addition (0-100 volume percent addition) has on the system performance emissions and combustion kinetics are analyzed. The maximum system performance is achieved when the maximum turbine inlet temperature is reached and the resulting optimal fuel/air equivalence ratio is determined. As hydrogen is added to the fuel mixture the optimal equivalence ratio shifts leaner causing non-linearity in emissions and system performance at optimal conditions. An analysis of variance is conducted and it is shown that isentropic efficiencies of the turbine and compressor influences the system performance the most out of any system parameter. While isentropic efficiencies of the turbine and compressor increase towards 100% an operating regime where the optimal system efficiency cannot be achieved is discovered due to the lower flammability limit of the fuel being reached. This can be overcome by mixing hydrogen into the fuel.
A Comprehensive Resilience Assessment Framework for Hydrogen Energy Infrastructure Development
Jun 2023
Publication
In recent years sustainable development has become a challenge for many societies due to natural or other disruptive events which have disrupted economic environmental and energy infrastructure growth. Developing hydrogen energy infrastructure is crucial for sustainable development because of its numerous benefits over conventional energy sources. However the complexity of hydrogen energy infrastructure including production utilization and storage stages requires accounting for potential vulnerabilities. Therefore resilience needs to be considered along with sustainable development. This paper proposes a decision-making framework to evaluate the resilience of hydrogen energy infrastructure by integrating resilience indicators and sustainability contributing factors. A holistic taxonomy of resilience performance is first developed followed by a qualitative resilience assessment framework using a novel Intuitionistic fuzzy Weighted Influence Nonlinear Gauge System (IFWINGS). The results highlighted that Regulation and legislation Government preparation and Crisis response budget are the most critical resilience indicators in the understudy hydrogen energy infrastructure. A comparative case study demonstrates the practicality capability and effectiveness of the proposed approach. The results suggest that the proposed model can be used for resilience assessment in other areas.
Accelerating the Green Hydrogen Revolution: A Comprehensive Analysis of Technological Advancements and Policy Interventions
Apr 2024
Publication
Promoting green hydrogen has emerged as a pivotal discourse in the contemporary energy landscape driven by pressing environmental concerns and the quest for sustainable energy solutions. This paper delves into the multifaceted domain of C-Suite issues about green hydrogen encompassing both technological advancements and policy considerations. The question of whether green hydrogen is poised to become the focal point of the upcoming energy race is explored through an extensive analysis of its potential as a clean and versatile energy carrier. The transition from conventional fossil fuels to green hydrogen is considered a fundamental shift in energy paradigms with far-reaching implications for global energy markets. The paper provides a comprehensive overview of state-of-the-art green hydrogen technologies including fuel cells photocatalysts photo electrocatalysts and hydrogen panels. In tandem with technological advancements the role of policy and strategy in fostering the development of green hydrogen energy assumes paramount significance. The paper elucidates the critical interplay between government policies market dynamics and corporate strategies in shaping the green hydrogen landscape. It delves into policy mechanisms such as subsidies carbon pricing and renewable energy mandates shedding light on their potential to incentivize the production and adoption of green hydrogen. This paper offers a nuanced exploration of C-Suite issues surrounding green hydrogen painting a comprehensive picture of the technological and policy considerations that underpin its emergence as a transformative energy source. As the global community grapples with the imperatives of climate change mitigation and the pursuit of sustainable energy solutions understanding these issues becomes imperative for executives policymakers and stakeholders alike.
Experimental Investigation of Stress Corrosion on Supercritical CO2 Transportation Pipelines Against Leakage for CCUS Applications
Nov 2022
Publication
Carbon Capture Utilization and Storage (CCUS) is one of the key technologies that will determine how humans address global climate change. For captured CO2 in order to avoid the complications associated with two-phase flow most carbon steel pipelines are operated in the supercritical state on a large scale. A pipeline has clear Stress Corrosion Cracking (SCC) sensitivity under the action of stress and corrosion medium which will generally cause serious consequences. In this study X70 steel was selected to simulate an environment in the process of supercritical CO2 transportation by using high-temperature high-pressure Slow Strain Rate Tensile (SSRT) tests and high-temperature high-pressure electrochemical test devices with different O2 and SO2 contents. Studies have shown that 200 ppm SO2 shows a clear SCC sensitivity tendency which is obvious when the SO2 content reaches 600 ppm. The SCC sensitivity increases with the increase of SO2 concentration but the increase amplitude decreases. With the help of advanced microscopic characterization techniques such as scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) through the analysis of fracture and side morphology the stress corrosion mechanism of a supercritical CO2 pipeline containing SO2 and O2 impurities was obtained by hydrogen embrittlement fracture characteristics. With the increase of SO2 content the content of Fe element decreases and the corrosion increases demonstrating that SO2 plays a leading role in electrochemical corrosion. This study further strengthens the theoretical basis of stress corrosion of supercritical CO2 pipelines plays an important role in preventing leakage of supercritical CO2 pipelines and will provide guidance for the industrial application of CCUS.
The Transition to a Renewable Energy Electric Grid in the Caribbean Island Nation of Antigua and Barbuda
Aug 2023
Publication
The present study describes the development and application of a model of the national electricity system for the Caribbean dual-island nation of Antigua and Barbuda to investigate the cost optimal mix of solar photovoltaics (PVs) wind and in the most novel contribution concentrating solar power (CSP). These technologies together with battery and hydrogen energy storage can enable the aim of achieving 100% renewable electricity and zero carbon emissions. The motivation for this study was that while most nations in the Caribbean rely largely on diesel fuel or heavy fuel oil for grid electricity generation many countries have renewable resources beyond wind and solar energy. Antigua and Barbuda generates 93% of its electricity from diesel-fueled generators and has set the target of becoming a net-zero nation by 2040 as well as having 86% renewable energy generation in the electricity sector by 2030 but the nation has no hydroelectric or geothermal resources. Thus this study aims to demonstrate that CSP is a renewable energy technology that can help assist Antigua and Barbuda in its transition to a renewable energy electric grid while also decreasing electricity generation costs. The modeled optimal mix of renewable energy technologies presented here was found for Antigua and Barbuda by assessing the levelized cost of electricity (LCOE) for systems comprising various combinations of energy technologies and storage. Other factors were also considered such as land use and job creation. It was found that 100% renewable electricity systems are viable and significantly less costly than current power systems and that there is no single defined pathway towards a 100% renewable energy grid but several options are available.
Dispersion of Under-expanded Hydrogen-methane Blended Jets through a Circular Orifice
Sep 2023
Publication
Blending hydrogen into natural gas and using existing natural gas infrastructure provides energy storage greenhouse gas emission reduction from combustion and other benefits as the world transitions to a hydrogen economy. Though this seems to be a simple and attractive technique there is a dearth of existing safety codes and standards and understanding the safety implications is warranted before implementation. In this paper we present some preliminary findings on the dispersion characteristics of hydrogen-methane blends performed under controlled conditions inside a laboratory. Experiments were performed at two different upstream pressures of 5 and 10 bar as the blends dispersed into air through a 1 mm diameter orifice. Blends of 25 50 and 75 vol-% hydrogen in methane were tested. Spatially resolved Raman signals from hydrogen methane and nitrogen were acquired simultaneously at 10 Hz using separate ICCD cameras from which the individual concentrations and jet boundaries could be determined. Finally a comparison between dispersion characteristics of blended fuel jets with pure hydrogen and pure methane jets was made.
Renewable Hydrogen and Synthetic Fuels Versus Fossil Fuels for Trucking, Shipping and Aviation: A Holistic Cost Model
Aug 2023
Publication
Potential carbon neutrality of the global trucking shipping and aviation sectors by 2050 could be achieved by substituting fossil fuels with renewable hydrogen and synthetic fuels. To investigate the economic impact of fuel substitution over time a holistic cost model is developed and applied to three case studies in Norway an early adopter of carbon-neutral freight transport. The model covers the value chains from local electricity and fuel production (hydrogen ammonia Fischer–Tropsch e-fuel) to fuel consumption for long-haul trucking short-sea shipping and mid-haul aviation. The estimates are internally consistent and allow cross-mode and cross-fuel comparisons that set this work apart from previous studies more narrowly focused on a given transport mode or fuel. The model contains 150 techno-economic parameters to identify which components along the value chains drive levelized costs. This paper finds a cost reduction potential for renewable fuels of 41% to 68% until 2050 but carbon-neutral transport will suffer asymmetric cost disadvantages. Fuel substitution is most expensive in short-sea shipping followed by mid-haul aviation and long-haul trucking. Cost developments of electricity direct air capture of carbon vehicle expenses and fuel-related payload losses are significant drivers.
Route-to-Market Strategy for Low-carbon Hydrogen from Natural Gas in the Permian Basin
Aug 2023
Publication
This paper investigates the untapped potential of the Permian Basin a multifaceted energy axis in Texas and adjoining states in the emerging era of decarbonization. Aligned with current policy directives on regional hydrogen hubs this study explores the viability of developing a hydrogen energy hub in the Permian Basin thereby producing low-carbon intensity hydrogen from natural gas in the Basin and transporting it to the Greater Houston area. Diverging from existing literature this study provides an integrated techno-economic evaluation of the entire hydrogen value chain in the Permian Basin encompassing production storage and transportation. Furthermore it comparatively analyzes the scenario of interest against an optimized base scenario thereby underlining comparative advantages and disadvantages. The paper concludes that the delivered cost of Permian based low-carbon intensity hydrogen to the Greater Houston area is $1.85/kg benchmarked to the scenario with hydrogen produced close to the Greater Houston area and delivered at $1.42/kg. Our findings reveal that Permian-based low-carbon intensity hydrogen production can achieve cost savings in feedstock ($0.25/kg) and potentially accrue a higher production tax credit due to a shorter gas supply chain to production ($0.33/kg). Nevertheless a significant cost barrier is the expense of long-haul pipeline transport ($0.90/kg) from the Permian Basin to Houston as opposed to local production. Despite the obstacles the study identifies a potential breakeven solution where increasing the production scale to at least 412000 metric ton per year (about 3 steam reforming plants) in the Permian Basin can effectively lower costs in the transport sector. Hence a scaled-up production can mitigate the cost difference and establish the Permian Basin as a competitive player in the hydrogen market. In conclusion a SWOT analysis presents Strengths Weaknesses Opportunities and Threats associated with Permian-based hydrogen production.
Fuel Cell Electric Vehicles (FCEV): Policy Advances to Enhance Commercial Success
May 2021
Publication
Many initiatives and policies attempt to make our air cleaner by reducing the carbon foot imprint on our planet. Most of the existing and planned initiatives have as their objectives the reduction of carbon dependency and the enhancement of newer or better technologies in the near future. However numerous policies exist for electric vehicles (EVs) and only some policies address specific issues related to fuel cell electric vehicles (FCEV). The lack of a distinction between the policies for EVs and FCEVs provides obstacles for the advancement of FCEV-related technologies that may otherwise be successful and competitive in the attempt to create a cleaner planet. Unfortunately the lack of this distinction is not always based on intellectual or scientific evidence. Therefore governments may need to introduce clearer policy distinctions in order to directly address FCEV-related challenges that may not pertain to other EVs. Unfortunately lobbyism continues to exist that supports the maintenance of the status quo as new technologies may threaten traditional less sustainable approaches to provide opportunities for a better environment. This lobbyism has partially succeeded in hindering the advancement of new technologies partially because the development of new technologies may reduce profit and business opportunities for traditionalists. However these challenges are slowly overcome as the demand for cleaner air and lower carbon emissions has increased and a stronger movement toward newer and cleaner technologies has gained momentum. This paper will look at policies that have been either implemented or are in the process of being implemented to address the challenge of overcoming traditional obstacles with respect to the automobile industry. The paper reviewed synthesized and discussed policies in the USA Japan and the European Union that helped implement new technologies with a focus on FCEVs for larger mass markets. These regions were the focus of this paper because of their particular challenges. South Korea and China were not included in this discussion as these countries already have equal or even more advanced policies and initiatives in place.
Water Consumption from Electrolytic Hydrogen in a Carbon-neutral US Energy System
Feb 2023
Publication
Hydrogen is an energy carrier with potential applications in decarbonizing difficult-to-electrify energy and industrial systems. The environmental profile of hydrogen varies substantially with its inputs. Water consumption is a particular issue of interest as decisions are made about capital and other investments that will affect the scale and scope of hydrogen use. This study focuses on electrolytic hydrogen due to its path to greenhouse gas neutrality and irreducible water demand (though other pathways might be more water intensive). Specifically it evaluates life cycle consumptive freshwater intensity of electrolytic hydrogen in the United States at volumes associated with 12 scenarios for a deeply decarbonized 2050 US energy system from two modeling efforts for which both electricity fuel mix and electrolytic hydrogen production were projected (America’s Zero Carbon Action Plan and Net Zero America) in addition to volumes for a stylized energy storage project (500 MW hydrogen-fired turbine). Freshwater requirements for hydrogen could be large. Under a central estimate for 2050 US electrolytic hydrogen production electrolytic freshwater demand for process and feedstock inputs alone (i.e. excluding water for electricity) would be about 7.5% of total 2014 US freshwater consumption for energy (1 billion cubic meters/year 109 m3 /y; [0.2% 15%] across scenarios for 2050 electrolytic hydrogen production of [0.3 18] exajoules EJ). Including water associated with production of input electricity doubles this central estimate to 15% (2 × 109 m3 /y; [1% 23%] across scenarios). Turbines using electrolytic hydrogen are estimated to be about as freshwater intensive as a coal or nuclear plant assuming decarbonized low-water electricity inputs. Although a decarbonized energy system is projected to require less water for resource capture and electricity conversion than the current fossil-dominated energy system additional conversion processes supporting decarbonization like electrolysis could offset water savings.
Technological Pathways for Decarbonizing Petroleum Refining
Sep 2021
Publication
This paper discusses the technical specifications of how U.S. petroleum refineries can reduce facility emissions and shift to produce low-carbon fuels for hard to abate sectors by utilizing existing innovative technologies.
A Compilation of Operability and Emissions Performance of Residential Water Heaters Operated on Blends of Natural Gas and Hydrogen Including Consideration for Reporting Bases
Feb 2023
Publication
The impact of hydrogen added to natural gas on the performance of commercial domestic water heating devices has been discussed in several recent papers in the literature. Much of the work focuses on performance at specific hydrogen levels (by volume) up to 20–30% as a near term blend target. In the current work new data on several commercial devices have been obtained to help quantify upper limits based on flashback limits. In addition results from 39 individual devices are compiled to help generalize observations regarding performance. The emphasis of this work is on emissions performance and especially NOx emissions. It is important to consider the reporting bases of the emissions numbers to avoid any unitended bias. For water heaters the trends associated with both mass per fuel energy input and concentration-based representation are similar For carbon free fuels bases such as 12% CO2 should be avoided. In general the compiled data shows that NOx NO UHC and CO levels decrease with increasing hydrogen percentage. The % decrease in NOx and NO is greater for low NOx devices (meaning certified to NOx <10 ng/J using premixing with excess air) compared to conventional devices (“pancake burners” partial premixing). Further low NOx devices appear to be able to accept greater amounts of hydrogen above 70% hydrogen in some cases without modification while conventional water heaters appear limited to 40–50% hydrogen. Reporting emissions on a mass basis per unit fuel energy input is preferred to the typical dry concentration basis as the greater amount of water produced by hydrogen results in a perceived increase in NOx when hydrogen is used. While this effort summarizes emissions performance with added hydrogen additional work is needed on transient operation higher levels of hydrogen system durability/reliability and heating efficiency.
Thermodynamics, Energy Dissipation, and Figures of Merit of Energy Storage Systems—A Critical Review
Sep 2021
Publication
The path to the mitigation of global climate change and global carbon dioxide emissions avoidance leads to the large-scale substitution of fossil fuels for the generation of electricity with renewable energy sources. The transition to renewables necessitates the development of large-scale energy storage systems that will satisfy the hourly demand of the consumers. This paper offers an overview of the energy storage systems that are available to assist with the transition to renewable energy. The systems are classified as mechanical (PHS CAES flywheels springs) electromagnetic (capacitors electric and magnetic fields) electrochemical (batteries including flow batteries) hydrogen and thermal energy storage systems. Emphasis is placed on the magnitude of energy storage each system is able to achieve the thermodynamic characteristics the particular applications the systems are suitable for the pertinent figures of merit and the energy dissipation during the charging and discharging of the systems.
Solar Hydrogen for High Capacity, Dispatchable, Long-distance Energy transmission – A Case Study for Injection in the Greenstream Natural Gas Pipeline
Nov 2022
Publication
This paper presents the results of techno-economic modelling for hydrogen production from a photovoltaic battery electrolyser system (PBES) for injection into a natural gas transmission line. Mellitah in Libya connected to Gela in Italy by the Greenstream subsea gas transmission line is selected as the location for a case study. The PBES includes photovoltaic (PV) arrays battery electrolyser hydrogen compressor and large-scale hydrogen storage to maintain constant hydrogen volume fraction in the pipeline. Two PBES configurations with different large-scale storage methods are evaluated: PBESC with compressed hydrogen stored in buried pipes and PBESL with liquefied hydrogen stored in spherical tanks. Simulated hourly PV electricity generation is used to calculate the specific hourly capacity factor of a hypothetical PV array in Mellitah. This capacity factor is then used with different PV sizes for sizing the PBES. The levelised cost of delivered hydrogen (LCOHD) is used as the key techno-economic parameter to optimise the size of the PBES by equipment sizing. The costs of all equipment except the PV array and batteries are made to be a function of electrolyser size. The equipment sizes are deemed optimal if PBES meets hydrogen demand at the minimum LCOHD. The techno-economic performance of the PBES is evaluated for four scenarios of fixed and constant hydrogen volume fraction targets in the pipeline: 5% 10% 15% and 20%. The PBES can produce up to 106 kilotonnes of hydrogen per year to meet the 20% target at an LCOHD of 3.69 €/kg for compressed hydrogen storage (PBESC) and 2.81 €/kg for liquid hydrogen storage (PBESL). Storing liquid hydrogen at large-scale is significantly cheaper than gaseous hydrogen even with the inclusion of a significantly larger PV array that is required to supply additional electrcitiy for liquefaction.
Production of Hydrogen from Offshore Wind in China and Cost-competitive Supply to Japan
Nov 2021
Publication
The Japanese government has announced a commitment to net-zero greenhouse gas emissions by 2050. It envisages an important role for hydrogen in the nation’s future energy economy. This paper explores the possibility that a significant source for this hydrogen could be produced by electrolysis fueled by power generated from offshore wind in China. Hydrogen could be delivered to Japan either as liquid or bound to a chemical carrier such as toluene or as a component of ammonia. The paper presents an analysis of factors determining the ultimate cost for this hydrogen including expenses for production storage conversion transport and treatment at the destination. It concludes that the Chinese source could be delivered at a volume and cost consistent with Japan’s idealized future projections.
Solar Water Splitting by Photovoltaic-electrolysis with a Solar-to-hydrogen Efficiency over 30%
Oct 2016
Publication
Hydrogen production via electrochemical water splitting is a promising approach for storing solar energy. For this technology to be economically competitive it is critical to develop water splitting systems with high solar-to-hydrogen (STH) efficiencies. Here we report a photovoltaic-electrolysis system with the highest STH efficiency for any water splitting technology to date to the best of our knowledge. Our system consists of two polymer electrolyte membrane electrolysers in series with one InGaP/GaAs/GaInNAsSb triple-junction solar cell which produces a large-enough voltage to drive both electrolysers with no additional energy input. The solar concentration is adjusted such that the maximum power point of the photovoltaic is well matched to the operating capacity of the electrolysers to optimize the system efficiency. The system achieves a 48-h average STH efficiency of 30%. These results demonstrate the potential of photovoltaic-electrolysis systems for cost-effective solar energy storage.
Sufficiency, Sustainability, and Circularity of Critical Materials for Clean Hydrogen
Jan 2022
Publication
Effective global decarbonization will require an array of solutions across a portfolio of low-carbon resources. One such solution is developing clean hydrogen. This unique fuel has the potential to minimize climate change impacts helping decarbonize hard-to-abate sectors such as heavy industry and global transport while also promoting energy security sustainable growth and job creation. The authors estimate suggest that hydrogen needs to grow seven-fold to support the global energy transition eventually accounting for ten percent of total energy consumption by 2050. A scaleup of this magnitude will increase demand for materials such as aluminum copper iridium nickel platinum vanadium and zinc to support hydrogen technologies - renewable electricity technologies and the electrolyzers for renewable hydrogen carbon storage for low-carbon hydrogen or fuel cells using hydrogen to power transport. This report a joint product of the World Bank and the Hydrogen Council examines these three critical areas. Using new data on the material intensities of key technologies the report estimates the amount of critical minerals needed to scale clean hydrogen. In addition it shows how incorporating sustainable practices and policies for mining and processing materials can help minimize environmental impacts. Key among these approaches is the use of recycled materials innovations in design in order to reduce material intensities and adoption of policies from the Climate Smart Mining (CSM) Framework to reduce impacts to greenhouse gas emissions and water footprint.
Process of Transformation to Net Zero Steelmaking: Decarbonisation Scenarios Based on the Analysis of the Polish Steel Industry
Apr 2023
Publication
The European steel industry is experiencing new challenges related to the market situation and climate policy. Experience from the period of pandemic restrictions and the effects of Russia’s armed invasion of Ukraine has given many countries a basis for including steel along with raw materials (coke iron ore electricity) in economic security products (CRMA). Steel is needed for economic infrastructure and construction development as well as a material for other industries (without steel factories will not produce cars machinery ships washing machines etc.). In 2022 steelmakers faced a deepening energy crisis and economic slowdown. The market situation prompted steelmakers to impose restrictions on production volumes (worldwide production fell by 4% compared to the previous year). Despite the difficult economic situation of the steel industry (production in EU countries fell by 11% in 2022 compared to the previous year) the EU is strengthening its industrial decarbonisation policy (“Fit for 55”). The decarbonisation of steel production is set to accelerate by 2050. To sharply reduce carbon emissions steel mills need new steelmaking technologies. The largest global steelmakers are already investing in new technologies that will use green hydrogen (produced from renewable energy sources). Reducing iron ore with hydrogen plasma will drastically reduce CO2 emissions (steel production using hydrogen could emit up to 95% less CO2 than the current BF + BOF blast furnace + basic oxygen furnace integrated method). Investments in new technologies must be tailored to the steel industry. A net zero strategy (deep decarbonisation goal) may have different scenarios in different EU countries. The purpose of this paper was to introduce the conditions for investing in low-carbon steelmaking technologies in the Polish steel market and to develop (based on expert opinion) scenarios for the decarbonisation of the Polish steel industry.
Preliminary Study for the Commercialization of a Electrochemical Hydrogen Compressor
Mar 2023
Publication
A global energy shift to a carbon‐neutral society requires clean energy. Hydrogen can accelerate the process of expanding clean and renewable energy sources. However conventional hydrogen compression and storage technology still suffers from inefficiencies high costs and safety concerns. An electrochemical hydrogen compressor (EHC) is a device similar in structure to a water electrolyzer. Its most significant advantage is that it can accomplish hydrogen separation and compression at the same time. With no mechanical motion and low energy consumption the EHC is the key to future hydrogen compression and purification technology breakthroughs. In this study the compression performance efficiency and other related parameters of EHC are investigated through experiments and simulation calculations. The experimental results show that under the same experimental conditions increasing the supply voltage and the pressure in the anode chamber can improve the reaction rate of EHC and balance the pressure difference between the cathode and anode. The presence of residual air in the anode can impede the interaction between hydrogen and the catalyst as well as the proton exchange membrane (PEM) resulting in a decrease in performance. In addition it was found that a single EHC has a better compression ratio and reaction rate than a double EHC. The experimental results were compatible with the theoretical calculations within less than a 7% deviation. Finally the conditions required to reach commercialization were evaluated using the theoretical model.
Energy and Economic Advantages of Using Solar Stills for Renewable Energy-Based Multi-Generation of Power and Hydrogen for Residential Buildings
Apr 2024
Publication
The multi-generation systems with simultaneous production of power by renewable energy in addition to polymer electrolyte membrane electrolyzer and fuel cell (PEMFC-PEMEC) energy storage have become more and more popular over the past few years. The fresh water provision for PEMECs in such systems is taken into account as one of the main challenges for them where conventional desalination technologies such as reverse osmosis (RO) and mechanical vapor compression (MVC) impose high electricity consumption and costs. Taking this point into consideration as a novelty solar still (ST) desalination is applied as an alternative to RO and MVC for better techno-economic justifiability. The comparison made for a residential building complex in Hawaii in the US as the case study demonstrated much higher technical and economic benefits when using ST compared with both MVC and RO. The photovoltaic (PV) installed capacity decreased by 11.6 and 7.3 kW compared with MVC and RO while the size of the electrolyzer declined by 9.44 and 6.13% and the hydrogen storage tank became 522.1 and 319.3 m3 smaller respectively. Thanks to the considerable drop in the purchase price of components the payback period (PBP) dropped by 3.109 years compared with MVC and 2.801 years compared with RO which is significant. Moreover the conducted parametric study implied the high technical and economic viability of the system with ST for a wide range of building loads including high values.
Reduction in Greenhouse Gas and Other Emissions from Ship Engines: Current Trends and Future Options
Nov 2022
Publication
The impact of ship emission reductions can be maximised by considering climate health and environmental effects simultaneously and using solutions fitting into existing marine engines and infrastructure. Several options available enable selecting optimum solutions for different ships routes and regions. Carbon-neutral fuels including low-carbon and carbon-negative fuels from biogenic or non-biogenic origin (biomass waste renewable hydrogen) could resemble current marine fuels (diesel-type methane and methanol). The carbon-neutrality of fuels depends on their Well-to-Wake (WtW) emissions of greenhouse gases (GHG) including carbon dioxide (CO2) methane (CH4) and nitrous oxide emissions (N2O). Additionally non-gaseous black carbon (BC) emissions have high global warming potential (GWP). Exhaust emissions which are harmful to health or the environment need to be equally removed using emission control achieved by fuel engine or exhaust aftertreatment technologies. Harmful emission species include nitrogen oxides (NOx) sulphur oxides (SOx) ammonia (NH3) formaldehyde particle mass (PM) and number emissions (PN). Particles may carry polyaromatic hydrocarbons (PAHs) and heavy metals which cause serious adverse health issues. Carbon-neutral fuels are typically sulphur-free enabling negligible SOx emissions and efficient exhaust aftertreatment technologies such as particle filtration. The combinations of carbon-neutral drop-in fuels and efficient emission control technologies would enable (near-)zero-emission shipping and these could be adaptable in the short- to mid-term. Substantial savings in external costs on society caused by ship emissions give arguments for regulations policies and investments needed to support this development.
A Multi-period Sustainable Hydrogen Supply Chain Model Considering Pipeline Routing and Carbon Emissions: The Case Study of Oman
Nov 2022
Publication
This paper presents a mathematical model for a multi-period hydrogen supply chain design problem considering several design features not addressed in other studies. The model is formulated as a mixed-integer program allowing the production and storage facilities to be extended over time. Pipeline and tube trailer transport modes are considered for carrying hydrogen. The model also allows finding the optimal pipeline routes and the number of transport units. The objective is to obtain an efficient supply chain design within a given time frame in a way that the demand and carbon dioxide emissions constraints are satisfied and the total cost is minimized. A computer program is developed to ease the problem-solving process. The computer program extracts the geographical information from Google Maps and solves the problem using an optimization solver. Finally the applicability of the proposed model is demonstrated in a case study from Oman.
Feasibility of Hydrogen Fuel Cell Technology for Railway Intercity Services: A Case Study for the Piedmont in North Carolina
Jul 2021
Publication
Diesel fuel combustion results in exhaust containing air pollutants and greenhouse gas emissions. Many railway vehicles use diesel fuel as their energy source. Exhaust emissions as well as concerns about economical alternative power supply have driven efforts to move to hydrogen motive power. Hydrogen fuel cell technology applied to railways offers the opportunity to eliminate harmful exhaust emissions and the potential for a low- or zero-emission energy supply chain. Currently only multiple-unit trains with hydrail technology operate commercially. Development of an Integrated Hybrid Train Simulator for intercity railway is presented. The proposed tool incorporates the effect of powertrain components during the wheel-to-tank process. Compared to its predecessors the proposed reconfigurable tool provides high fidelity with medium requirements and minimum computation time. Single train simulation and the federal government’s Greenhouse gases Regulated Emissions and Energy use in Transportation (GREET) model are used in combination to evaluate the feasibility of various train and powertrain configurations. The Piedmont intercity service operating in North Carolina is used as a case study. The study includes six train configurations and powertrain options as well as nine hydrogen supply options in addition to the diesel supply. The results show that a hydrail option is not only feasible but a low- or zero-carbon hydrogen supply chain could be possible.
The Socio-technical Dynamics of Net-zero Industrial Megaprojects: Outside-in and Inside-out Analyses of the Humber Industrial Cluster
Feb 2023
Publication
Although energy-intensive industries are often seen as ‘hard-to-decarbonise’ net-zero megaprojects for industrial clusters promise to improve the technical and economic feasibility of hydrogen fuel switching and carbon capture and storage (CCS). Mobilising insights from the megaproject literature this paper analyses the dynamics of an ambitious first-of-kind net-zero megaproject in the Humber industrial cluster in the United Kingdom which includes CCS and hydrogen infrastructure systems industrial fuel switching CO2 capture green and blue hydrogen production and hydrogen storage. To analyse the dynamics of this emerging megaproject the article uses a socio-technical system lens to focus on developments in technology actors and institutions. Synthesising multiple megaproject literature insights the paper develops a comprehensive framework that addresses both aggregate (‘outside-in’) developments and the endogenous (‘inside-out’) experiences and activities regarding three specific challenges: technical system integration actor coordination and institutional alignment. Drawing on an original dataset involving expert interviews (N = 46) site visits (N = 7) and document analysis the ‘outside-in’ analysis finds that the Humber megaproject has progressed rapidly from outline visions to specific technical designs enacted by new coalitions and driven by strengthening policy targets and financial support schemes. The complementary ‘inside-out’ analysis however also finds 12 alignment challenges that can delay or derail materialisation of the plans. While policies are essential aggregate drivers institutional misalignments presently also prevent project-actors from finalising design and investment decisions. Our analysis also finds important tensions between the project's high-pace delivery focus (to meet government targets) and allowing sufficient time for pilot projects learning-by-doing and design iterations.
Evaluation of Hydrogen Blend Stability in Low-Pressure Gas Distribution
Apr 2023
Publication
Natural gas distribution companies are developing ambitious plans to decarbonize the services that they provide in an affordable manner and are accelerating plans for the strategic integration of renewable natural gas and the blending of green hydrogen produced by electrolysis powered with renewable electricity being developed from large new commitments by states such as New York and Massachusetts. The demonstration and deployment of hydrogen blending have been proposed broadly at 20% of hydrogen by volume. The safe distribution of hydrogen blends in existing networks requires hydrogen blends to exhibit similar behavior as current supplies which are also mixtures of several hydrocarbons and inert gases. There has been limited research on the properties of blended hydrogen in low-pressure natural gas distribution systems. Current natural gas mixtures are known to be sufficiently stable in terms of a lack of chemical reaction between constituents and to remain homogeneous through compression and distribution. Homogeneous mixtures are required both to ensure safe operation of customer-owned equipment and for safety operations such as leak detection. To evaluate the stability of mixtures of hydrogen and natural gas National Grid experimentally tested a simulated distribution natural gas pipeline with blends containing hydrogen at up to 50% by volume. The pipeline was outfitted with ports to extract samples from the top and bottom of the pipe at intervals of 20 feet. Samples were analyzed for composition and the effectiveness of odorant was also evaluated. The new results conclusively demonstrate that hydrogen gas mixtures do not significantly separate or react under typical distribution pipeline conditions and gas velocity profiles. In addition the odorant retained its integrity in the blended gas during the experiments and demonstrated that it remains an effective method of leak detection.
Design for Reliability and Safety: Challenges and Opportunities in Hydrogen Mobility Assets
Sep 2023
Publication
Safety and reliability are important performance attributes of any engineered system where humanmachine interactions are present. However they are usually approached as afterthoughts or in some cases unintended consequences of the system design and development process that must be addressed and verified in subsequent design stages. In plain words safety and reliability are often seen as constraints that add layers of complexity and extra costs to the minimum functional system of interest. No longer. Shell Hydrogen is embedding the Design for Reliability and Safety approach to engineer our products and assets in such a way that safety and reliability are at the core of a concurrent engineering process throughout the system lifecycle. This has been achieved in practice by leveraging systems reliability and safety engineering methods along with the experience and expertise of Shell Hydrogen original equipment manufacturers and system integrators in designing building and operating hydrogen assets for mobility applications.<br/>The challenges in implementing this approach are many ranging from access to historical data on equipment and component safety and reliability performance to lack of standardization in the industry when dealing with hydrogen related hazards. In this paper we will describe the approach in more detail some of our early successes and failures during deployment and the continual improvement journey that lies ahead.
Everything About Hydrogen Podcast: Improving PEM Efficiency
Jan 2023
Publication
On this episode of EAH we sat down with Alejandro Oyarce Barnett Chief Technology Officer and Co-Founder at Hystar. Hystar is a technology-focused company specializing in PEM electrolysers for hydrogen production using renewable energy. The company got its start as a spin-off from SINTEF one of Europe’s largest independent research organizations and has raised private funding so the company can focus on production of its high-efficiency PEM units and keep pace with demand for hydrogen generation capacity. Hystar announced on January 11 2023 that the company has closed a Series B funding round of USD 26mn to rapidly scale-up to full commercial operations with an automated GW-capacity production line by 2025. Alejandro joined us to discuss in more detail the origins of Hystar its technology and the mission at the core of the company.
The podcast can be found on their website.
The podcast can be found on their website.
Everything About Hydrogen Podcast: A Green Future for Oman
Feb 2023
Publication
On this episode of Everything About Hydrogen we are speaking with Nashwa Al Rawahy Director of HMR Environmental Consultants based in Muscat Oman with regional offices in the United Arab Emirates.
We are excited to have an expert like Nashwa join us to discuss environmental and social impact studies their value to the communities and projects and the importance of building long term In Country Value (ICV).
The podcast can be found on their website.
We are excited to have an expert like Nashwa join us to discuss environmental and social impact studies their value to the communities and projects and the importance of building long term In Country Value (ICV).
The podcast can be found on their website.
Green Hydrogen Supply Chain Risk Analysis: A European Hard-to-abate Sectors Perspective
May 2023
Publication
Green hydrogen is a tentative solution for the decarbonisation of hard-to-abate sectors such as steel chemical cement and refinery industries. Green hydrogen is a form of hydrogen gas that is produced using renewable energy sources such as wind or solar power through a process called electrolysis. The green hydrogen supply chain includes several interconnected entities such as renewable energy providers electrolysers distribution facilities and consumers. Although there have been many studies about green hydrogen little attention has been devoted to green hydrogen supply chain risk identification and analysis especially for hard-to-abate sectors in Europe. This research contributes to existing knowledge by identifying and analysing the European region’s green hydrogen supply chain risk factors. Using a Delphi method 7 categories and 43 risk factors are identified based on the green hydrogen supply chain experts’ opinions. The best-worst method is utilised to determine the importance weights of the risk categories and risk factors. High investment of capital for hydrogen production and delivery technology was the highest-ranked risk factor followed by the lack of enough capacity for electrolyser and policy & regulation development. Several mitigation strategies and policy recommendations are proposed for high-importance risk factors. This study provides novelty in the form of an integrated approach resulting in a scientific ranking of the risk factors for the green hydrogen supply chain. The results of this study provide empirical evidence which corroborates with previous studies that European countries should endeavour to create comprehensive and supportive standards and regulations for green hydrogen supply chain implementation.
Everything About Hydrogen Podcast: Policy Simplicity & Certainty
Mar 2023
Publication
On this episode of Everything About Hydrogen we have Daria Nochevnik the Director of Policy and Partnerships for Hydrogen Council.
The podcast can be found on their website.
The podcast can be found on their website.
Challenges Toward Achieving a Successful Hydrogen Economy in the US: Potential End-use and Infrastructure Analysis to the Year 2100
Jul 2022
Publication
Fossil fuels continue to exacerbate climate change due to large carbon emissions resulting from their use across a number of sectors. An energy transition away from fossil fuels seems inevitable and energy sources such as renewables and hydrogen may provide a low carbon alternative for the future energy system particularly in large emitting nations such as the United States. This research quantifies and maps potential hydrogen fuel distribution pathways for the continental US reflecting technological changes barriers to deployment and end-use-cases from 2020 to 2100 clarifying the potential role of hydrogen in the US energy transition. The methodology consists of two parts a linear optimization of the global energy system constrained by carbon reduction targets and system cost followed by a projection of hydrogen infrastructure development. Key findings include the emergence of trade pattern diversification with a greater variety of end-uses associated with imported fuels and greater annual hydrogen consumption over time. Further sensitivity analysis identified the influence of complementary technologies including nuclear power and carbon capture and storage technologies. We conclude that hydrogen penetration into the US energy system is economically viable and can contribute toward achieving Paris Agreement and more aggressive carbon reduction targets in the future.
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