Poland
The Cost Reduction Analysis of Green Hydrogen Production from Coal Mine Underground Water for Circular Economy
May 2024
Publication
The novelty of the paper is the analysis of the possibilities of reducing the operating costs of a mine water pumping station in an abandoned coal mine. To meet the energy needs of the pumping station and reduce the carbon footprint “green” energy from a photovoltaic farm was used. Surplus green energy generated during peak production is stored in the form of green hydrogen from the water electrolysis process. Rainwater and process water are still underutilized sources for increasing water resources and reducing water stress in the European Union. The article presents the possibilities of using these waters after purification in the production of green hydrogen by electrolysis. The article also presents three variants that ensure the energy self-sufficiency of the proposed concepts of operation of the pumping station.
Mapping the Future of Green Hydrogen: Integrated Analysis of Poland and the EU’s Development Pathways to 2050
Aug 2023
Publication
This article presents the results of a comparative scenario analysis of the “green hydrogen” development pathways in Poland and the EU in the 2050 perspective. We prepared the scenarios by linking three models: two sectoral models for the power and transport sectors and a Computable General Equilibrium model (d-Place). The basic precondition for the large-scale use of hydrogen in both Poland and in European Union countries is the pursuit of ambitious greenhouse gas reduction targets. The EU plans indicate that the main source of hydrogen will be renewable energy (RES). “Green hydrogen” is seen as one of the main methods with which to balance energy supply from intermittent RES such as solar and wind. The questions that arise concern the amount of hydrogen required to meet the energy needs in Poland and Europe in decarbonized sectors of the economy and to what extent can demand be covered by internal production. In the article we estimated the potential of the production of “green hydrogen” derived from electrolysis for different scenarios of the development of the electricity sector in Poland and the EU. For 2050 it ranges from 76 to 206 PJ/y (Poland) and from 4449 to 5985 PJ/y (EU+). The role of hydrogen as an energy storage was also emphasized highlighting its use in the process of stabilizing the electric power system. Hydrogen usage in the energy sector is projected to range from 67 to 76 PJ/y for Poland and from 1066 to 1601 PJ/y for EU+ by 2050. Depending on the scenario this implies that between 25% and 35% of green hydrogen will be used in the power sector as a long-term energy storage.
A Comparative Environmental Life Cycle Assessment Study of Hydrogen Fuel Electricity and Diesel Fuel for Public Buses
Aug 2023
Publication
Hydrogen fuel and electricity are energy carriers viewed as promising alternatives for the modernization and decarbonization of public bus transportation fleets. In order to choose development pathways that will lead transportation systems toward a sustainable future the authors developed an environmental model based on the Life Cycle Assessment approach. The model tested the impact of energy carrier consumption during driving as well as the electricity origin employed to power electric buses and produce hydrogen. Energy sources such as wind solar waste and grid electricity were investigated. The scope of the study included the life cycles of the energy carrier and the necessary infrastructure. The results were presented from two perspectives: the total environmental impact and global warming potential. In order to create a roadmap an original method for choosing sustainable development pathways was prepared. It was shown that the modernization of conventional bus fleets using hydrogen and electrical pathways can provide significant environmental benefits from both perspectives but especially in terms of global warming potential. It was emphasized that attention should be paid to the use of low- and zero-emission energy sources because their impact often strongly influenced the final environmental judgment. The energy carrier consumption also had a strong impact on the results obtained and that is why efforts should be made to reduce it. In addition it was confirmed that hydrogen and electricity production systems based on electricity generated by a waste-to-energy plant could be an environmentally reasonable dual solution for both sustainable waste management and meeting transport needs.
Hydrogen Embrittlement and Oxide Layer Effect in the Cathodically Charged Zircaloy-2
Apr 2020
Publication
Poland The present paper is aimed at determining the less investigated effects of hydrogen uptake on the microstructure and the mechanical behavior of the oxidized Zircaloy-2 alloy. The specimens were oxidized and charged with hydrogen. The different oxidation temperatures and cathodic current densities were applied. The scanning electron microscopy X-ray electron diffraction spectroscopy hydrogen absorption assessment tensile and nanoindentation tests were performed. At low oxidation temperatures an appearance of numerous hydrides and cracks and a slight change of mechanical properties were noticed. At high-temperature oxidation the oxide layer prevented the hydrogen deterioration of the alloy. For nonoxidized samples charged at different current density nanoindentation tests showed that both hardness and Young’s modulus revealed the minims at specific current value and the stepwise decrease in hardness during hydrogen desorption. The obtained results are explained by the barrier effect of the oxide layer against hydrogen uptake softening due to the interaction of hydrogen and dislocations nucleated by indentation test and hardening caused by the decomposition of hydrides. The last phenomena may appear together and result in hydrogen embrittlement in forms of simultaneous hydrogen-enhanced localized plasticity and delayed hydride cracking.
Economic Evaluation of Renewable Hydrogen Integration into Steelworks for the Production of Methanol and Methane
Jun 2022
Publication
This work investigates the cost-efficient integration of renewable hydrogen into steelworks for the production of methane and methanol as an efficient way to decarbonize the steel industry. Three case studies that utilize a mixture of steelworks off-gases (blast furnace gas coke oven gas and basic oxygen furnace gas) which differ on the amount of used off-gases as well as on the end product (methane and/or methanol) are analyzed and evaluated in terms of their economic performance. The most influential cost factors are identified and sensitivity analyses are conducted for different operating and economic parameters. Renewable hydrogen produced by PEM electrolysis is the most expensive component in this scheme and responsible for over 80% of the total costs. Progress in the hydrogen economy (lower electrolyzer capital costs improved electrolyzer efficiency and lower electricity prices) is necessary to establish this technology in the future.
Hydrogen Technology on the Polish Electromobility Market. Legal, Economic, and Social Aspects
Apr 2021
Publication
The aim of this study was to evaluate the motorization market of electric vehicles powered by hydrogen cells in Poland. European conditions of such technology were indicated as well as original proposals on amendments to the law to increase the development pace of electromobility based on hydrogen cells. There were also presented economic aspects of this economic phenomenon. Moreover survey research was conducted to examine the preferences of hydrogen and electric vehicle users in 5 primary Polish cities. In this way the level of social acceptance for the technological revolution based on hydrogen cells and taking place in the motorization sector was determined.
Hydrogen Stratification in Enclosures in Dependence of the Gas Release Momentum
Sep 2021
Publication
The hydrogen dispersion phenomenon in an enclosure depends on the ratio of the gas buoyancy induced momentum. Random diffusive motions of individual gas particles become dominative when the release momentum is low. Then a uniform hydrogen concentration appears in the enclosure instead of the gas stratification below the ceiling. The paper justifies this hypothesis by demonstrating fullscale experimental results of hydrogen dispersion within a confined space under six different release variations. During the experiments hydrogen was released into the test room of 60 m3 volume in two methods: through a nozzle and through 21 points evenly distributed on the emission box cover (multipoint release). Each release method was tested with three different hydrogen volume flow rates (3.17·10−3 m3/s 1.63·10−3 m3/s 3.34·10−4 m3/s). The tests confirm the increase of hydrogen convective upward flow and its stratification tendency relative to increased volume flow. A tendency of more uniform hydrogen cloud distribution when Mach Reynolds and Froud number values decreased was demonstrated. Because the hydrogen dispersion phenomena impact fire and explosive hazards the presented experimental results could help fire protection systems be in an enclosure designed allowing their effectiveness optimization.
Permeability Modeling and Estimation of Hydrogen Loss through Polymer Sealing Liners in Underground Hydrogen Storage
Apr 2022
Publication
Fluctuations in renewable energy production especially from solar and wind plants can be solved by large‐scale energy storage. One of the possibilities is storing energy in the form of hydrogen or methane–hydrogen blends. A viable alternative for storing hydrogen in salt caverns is Lined Rock Cavern (LRC) underground energy storage. One of the most significant challenges in LRC for hydrogen storage is sealing liners which need to have satisfactory sealing and mechanical properties. An experimental study of hydrogen permeability of different kinds of polymers was conducted followed by modeling of hydrogen permeability of these materials with different additives (graphite halloysite and fly ash). Fillers in polymers can have an impact on the hydrogen permeability ratio and reduce the amount of polymer required to make a sealing liner in the reservoir. Results of this study show that hydrogen permeability coefficients of polymers and estimated hydrogen leakage through these materials are similar to the results of salt rock after the salt creep process. During 60 days of hydrogen storage in a tank of 1000 m2 inner surface 1 cm thick sealing liner and gas pressure of 1.0 MPa only approx. 1 m3STP of hydrogen will diffuse from the reservoir. The study also carries out the modeling of the hydrogen permeability of materials using the Max‐ well model. The difference between experimental and model results is up to 17% compared to the differences exceeding 30% in some other studies.
The Influence of the First Filling Period Length and Reservoir Level Depth on the Operation of Underground Hydrogen Storage in a Deep Aquifer
Sep 2022
Publication
Underground storage is a method of storing large amounts of renewable energy that can be converted into hydrogen. One of the fundamental problems associated with this process concerns determining the timing and amount of injected gas in the first filling period for the operation of an underground storage facility. Ascertaining the hydrogen flow rate is essential to ensure that the capillary and fracturing pressures are not exceeded. The value of the flow rate was assessed by modelling the injection of hydrogen into a deep aquifer. The best initial H2 injection period was found to be five months. The volume of the cushion gas and the total storage capacity expanded with the extension of the first filling period length. The working capacity grew as the depth increased reaching maximum values at depths of approximately 1200e1400 m. This depth was considered optimal for storing hydrogen in the analysed structure.
Economic Conditions for Developing Hydrogen Production Based on Coal Gasification with Carbon Capture and Storage in Poland
Sep 2020
Publication
This study documents the results of economic assessment concerning four variants of coal gasification to hydrogen in a shell reactor. That assessment has been made using discounting methods (NPV: net present value IRR: internal rate of return) as well as indicators based on a free cash flow to firm (FCFF) approach. Additionally sensitivity analysis has been carried out along with scenario analysis in current market conditions concerning prices of hard coal lignite hydrogen and CO2 allowances as well as capital expenditures and costs related to carbon capture and storage (CCS) systems. Based on NPV results a negative economic assessment has been obtained for all the analyzed variants varying within the range of EUR −903 to −142 million although the variants based on hard coal achieved a positive IRR (5.1–5.7%) but lower than the assumed discount rates. In Polish conditions the gasification of lignite seems to be unprofitable in the assumed scale of total investment outlays and the current price of coal feedstock. The sensitivity analyses indicate that at least a 20% increase of hydrogen price would be required or a similar reduction of capital expenditures (CAPEX) and costs of operation for the best variant to make NPV positive. Analyses have also indicated that on the economic basis only the prices of CO2 allowances exceeding EUR 40/Mg (EUR 52/Mg for lignite) would generate savings due to the availability of CCS systems.
The New Model of Energy Cluster Management and Functioning
Sep 2022
Publication
This article was aimed to answer the question of whether local energy communities have a sufficient energy surplus for storage purposes including hydrogen production. The article presents an innovative approach to current research and a discussion of the concepts of the collective prosumer and virtual prosumer that have been implemented in the legal order and further amended in the law. From this perspective it was of utmost importance to analyze the model of functioning of an energy cluster consisting of energy consumers energy producers and hydrogen storage whose goal is to maximize the obtained benefits assuming the co-operative nature of the relationship. The announced and clear perspective of the planned benefits will provide the cluster members a measurable basis for participation in such an energy community. However the catalogue of benefits will be conditioned by the fulfillment of several requirements related to both the scale of covering energy demand from own sources and the need to store surplus energy. As part of the article the results of analyses together with a functional model based on real data of the local energy community are presented.
A Promising Cobalt Catalyst for Hydrogen Production
Mar 2022
Publication
In this work a metal cobalt catalyst was synthesized and its activity in the hydrogen production process was tested. The substrates were water and ethanol. Activity tests were conducted at a temperature range of 350–600 °C water to ethanol molar ratio of 3 to 5 and a feed flow of 0.4 to 1.2 mol/h. The catalyst had a specific surface area of 1.75 m2/g. The catalyst was most active at temperatures in the range of 500–600 °C. Under the most favorable conditions the ethanol conversion was 97% the hydrogen production efficiency was 4.9 mol (H2)/mol(ethanol) and coke production was very low (16 mg/h). Apart from hydrogen and coke CO2 CH4 CO and traces of C2H2 and C2H4 were formed.
Selection of Underground Hydrogen Storage Risk Assessment Techniques
Dec 2021
Publication
The article proposes the use of the analytic hierarchy process (AHP) method to select a risk assessment technique associated with underground hydrogen storage. The initial choosing and ranking of risk assessment techniques can be considered as a multi-criteria decision problem. The usage of a decision model based on six criteria is proposed. A ranking of methods for estimating the risks associated with underground hydrogen storage is presented. The obtained results show that the application of the AHP-based approach may be a useful tool for selecting the UHS risk assessment technique. The proposed method makes it possible to make an objective decision of the most satisfactory approach from the point of view of all the adopted decision criteria regarding the selection of the best risk assessment technique.
Fuel Cell Electric Vehicle (FCEV) Energy Flow Analysis in Real Driving Conditions (RDC)
Aug 2021
Publication
The search for fossil fuels substitutes forces the use of new propulsion technologies applied to means of transportation. Already widespread hybrid vehicles are beginning to share the market with hydrogen-powered propulsion systems. These systems are fuel cells or internal combustion engines powered by hydrogen fuel. In this context road tests of a hydrogen fuel cell drive were conducted under typical traffic conditions according to the requirements of the RDE test. As a result of the carried-out work energy flow conditions were presented for three driving phases (urban rural and motorway). The different contributions to the vehicle propulsion of the hydrogen system and the electric system in each phase of the driving route are indicated. The characteristic interaction of power train components during varying driving conditions was presented. A wide variation in the contribution of the fuel cell and the battery to the vehicle’s propulsion was identified. In urban conditions the share of the fuel cell in the vehicle’s propulsion is more than three times that contributed by the battery suburban—7 times highway—28 times. In the entire test the ratio of FC/BATT use was more than seven while the energy consumption was more than 22 kWh/100 km. The amounts of battery energy used and recovered were found to be very close to each other under RDE test conditions.
How Long Will Combustion Vehicles Be Used? Polish Transport Sector on the Pathway to Climate Neutrality
Nov 2021
Publication
Transformation of road transport sector through replacing of internal combustion vehicles with zero-emission technologies is among key challenges to achievement of climate neutrality by 2050. In a constantly developing economy the demand for transport services increases to ensure continuity in the supply chain and passenger mobility. Deployment of electric technologies in the road transport sector involves both businesses and households its pace depends on the technological development of zero-emission vehicles presence of necessary infrastructure and regulations on emission standards for new vehicles entering the market. Thus this study attempts to estimate how long combustion vehicles will be in use and what the state of the fleet will be in 2050. For obtainment of results the TR3E partial equilibrium model was used. The study simulates the future fleet structure in passenger and freight transport. The results obtained for Poland for the climate neutrality (NEU) scenario show that in 2050 the share of vehicles using fossil fuels will be ca. 30% in both road passenger and freight transport. The consequence of shifts in the structure of the fleet is the reduction of CO2 emissions ca. 80% by 2050 and increase of the transport demand for electricity and hydrogen.
Analysis of the Polish Hydrogen Strategy in the Context of the EU’s Strategic Documents on Hydrogen
Oct 2021
Publication
In December 2019 the European Commission unveiled an ambitious project the European Green Deal which aims to lead the European Union to climate neutrality by 2050. This is a significant challenge for all EU countries and especially for Poland. The role of hydrogen in the processes of decarbonization of the economy and transport is being discussed in many countries around the world to find rational solutions to this difficult and complex problem. There is an ongoing discussion about the hydrogen economy which covers the production of hydrogen its storage transport and conversion to the desired forms of energy primarily electricity mechanical energy and new fuels. The development of the hydrogen economy can significantly support the achievement of climate neutrality. The belief that hydrogen plays an important role in the transformation of the energy sector is widespread. There are many technical and economic challenges as well as legal and logistical barriers to deal with in the transition process. The development of hydrogen technologies and a global sustainable energy system that uses hydrogen offers a real opportunity to solve the challenges facing the global energy industry: meeting the need for clean fuels increasing the efficiency of fuel and energy production and significantly reducing greenhouse gas emissions. The paper provides an in-depth analysis of the Polish Hydrogen Strategy a document that sets out the directions for the development of hydrogen use (competences and technologies) in the energy transport and industrial sectors. This analysis is presented against the background of the European Commission’s document ‘A Hydrogen Strategy for a Climate-Neutral Europe’. The draft project presented is a good basis for further discussion on the directions of development of the Polish economy. The Polish Hydrogen Strategy although it was created later than the EU document does not fully follow its guidelines. The directions for further work on the hydrogen strategy are indicated so that its final version can become a driving force for the development of the country’s economy.
Study of the Effects of Changes in Gas Composition as Well as Ambient and Gas Temperature on Errors of Indications of Thermal Gas Meters
Oct 2020
Publication
Thermal gas meters represent a promising technology for billing customers for gaseous fuels however it is essential to ensure that measurement accuracy is maintained in the long term and in a broad range of operating conditions. The effect of hydrogen addition to natural gas will change the physicochemical properties of the mixture of natural gas and hydrogen. Such a mixture will be supplied through the gas system to consumers including households where the amounts of received gas will be metered. The physicochemical properties of hydrogen including the specific density or viscosity differ significantly from those of the natural gas components such as methane ethane propane nitrogen etc. Therefore it is of utmost importance to establish the impact of the changes in the gas composition caused by the addition of hydrogen to natural gas on the metrological properties of household gas meters including thermal gas meters. Furthermore since household gas meters can be installed outdoors and taking into account the fact that household gas meters are good heat exchangers the influence of ambient and gas temperature on the metrological properties of those meters should be investigated. This article reviews a test bench and a testing method concerning errors of thermal gas meter indicators using air and natural gas including the type containing hydrogen. The indication errors for thermal gas meters using air natural gas and natural gas with an addition of 2% 4% 5% 10% and 15% hydrogen were determined and then subjected to metrological analysis. Moreover the test method and test bench are discussed and the results of tests on the impact of ambient and gas temperatures (-25 ◦C and 55 ◦C respectively) on the errors of indications of thermal gas meters are presented. Conclusions for distribution system operators in terms of gas meter selection were drawn based on the test results.
Towards Sustainable Transport: Techno-Economic Analysis of Investing in Hydrogen Buses in Public Transport in the Selected City of Poland
Dec 2022
Publication
The production storage and use of hydrogen for energy purposes will become increasingly important during the energy transition. One way to use hydrogen is to apply it to power vehicles. This green technological solution affects low-emissions transport which is beneficial and important especially in cities. The authors of this article analyzed the use of hydrogen production infrastructure for bus propulsion in the city of Katowice (Poland). The methods used in the study included a greedy algorithm and cost methods which were applied for the selection of vehicles and identification of the infrastructure for the production storage and refueling of hydrogen as well as to conduct the economic analysis during this term. The article presented the complexity of the techno-economic analysis of the infrastructure and its installation. The key element was the selection of the number of vehicles to the hydrogen production possibilities of an electrolyser and capabilities of the storage and charging infrastructure.
Efficient Plasma Technology for the Production of Green Hydrogen from Ethanol and Water
Apr 2022
Publication
This study concerns the production of hydrogen from a mixture of ethanol and water. The process was conducted in plasma generated by a spark discharge. The substrates were introduced in the liquid phase into the reactor. The gaseous products formed in the spark reactor were hydrogen carbon monoxide carbon dioxide methane acetylene and ethylene. Coke was also produced. The energy efficiency of hydrogen production was 27 mol(H2 )/kWh and it was 36% of the theoretical energy efficiency. The high value of the energy efficiency of hydrogen production was obtained with relatively high ethanol conversion (63%). In the spark discharge it was possible to conduct the process under conditions in which the ethanol conversion reached 95%. However this entailed higher energy consumption and reduced the energy efficiency of hydrogen production to 8.8 mol(H2 )/kWh. Hydrogen production increased with increasing discharge power and feed stream. However the hydrogen concentration was very high under all tested conditions and ranged from 57.5 to 61.5%. This means that the spark reactor is a device that can feed fuel cells the power load of which can fluctuate.
Thermodynamic and Technical Issues of Hydrogen and Methane-Hydrogen Mixtures Pipeline Transmission
Feb 2019
Publication
The use of hydrogen as a non-emission energy carrier is important for the innovative development of the power-generation industry. Transmission pipelines are the most efficient and economic method of transporting large quantities of hydrogen in a number of variants. A comprehensive hydraulic analysis of hydrogen transmission at a mass flow rate of 0.3 to 3.0 kg/s (volume flow rates from 12000 Nm3/h to 120000 Nm3/h) was performed. The methodology was based on flow simulation in a pipeline for assumed boundary conditions as well as modeling of fluid thermodynamic parameters for pure hydrogen and its mixtures with methane. The assumed outlet pressure was 24 bar (g). The pipeline diameter and required inlet pressure were calculated for these parameters. The change in temperature was analyzed as a function of the pipeline length for a given real heat transfer model; the assumed temperatures were 5 and 25 ◦C. The impact of hydrogen on natural gas transmission is another important issue. The performed analysis revealed that the maximum participation of hydrogen in natural gas should not exceed 15%–20% or it has a negative impact on natural gas quality. In the case of a mixture of 85% methane and 15% hydrogen the required outlet pressure is 10% lower than for pure methane. The obtained results present various possibilities of pipeline transmission of hydrogen at large distances. Moreover the changes in basic thermodynamic parameters have been presented as a function of pipeline length for the adopted assumptions.
No more items...