Norway
Carbon-negative Hydrogen from Biomass Using Gas Switching Integrated Gasification: Techno-economic Assessment
Sep 2022
Publication
Ambitious decarbonization pathways to limit the global temperature rise to well below 2 ◦C will require largescale CO2 removal from the atmosphere. One promising avenue for achieving this goal is hydrogen production from biomass with CO2 capture. The present study investigates the techno-economic prospects of a novel biomass-to-hydrogen process configuration based on the gas switching integrated gasification (GSIG) concept. GSIG applies the gas switching combustion principle to indirectly combust off-gas fuel from the pressure swing adsorption unit in tubular reactors integrated into the gasifier to improve efficiency and CO2 capture. In this study these efficiency gains facilitated a 5% reduction in the levelized cost of hydrogen (LCOH) relative to conventional O2-blown fluidized bed gasification with pre-combustion CO2 capture even though the larger and more complex gasifier cancelled out the capital cost savings from avoiding the air separation and CO2 capture units. The economic assessment also demonstrated that advanced gas treatment using a tar cracker instead of a direct water wash can further reduce the LCOH by 12% and that the CO2 prices in excess of 100 €/ton consistent with ambitious decarbonization pathways will make this negative-emission technology economically highly attractive. Based on these results further research into the GSIG concept to facilitate more efficient utilization of limited biomass resources can be recommended.
An Extensive Review of Liquid Hydrogen in Transportation with Focus on the Maritime Sector
Sep 2022
Publication
The European Green Deal aims to transform the EU into a modern resource-efficient and competitive economy. The REPowerEU plan launched in May 2022 as part of the Green Deal reveals the willingness of several countries to become energy independent and tackle the climate crisis. Therefore the decarbonization of different sectors such as maritime shipping is crucial and may be achieved through sustainable energy. Hydrogen is potentially clean and renewable and might be chosen as fuel to power ships and boats. Hydrogen technologies (e.g. fuel cells for propulsion) have already been implemented on board ships in the last 20 years mainly during demonstration projects. Pressurized tanks filled with gaseous hydrogen were installed on most of these vessels. However this type of storage would require enormous volumes for large long-range ships with high energy demands. One of the best options is to store this fuel in the cryogenic liquid phase. This paper initially introduces the hydrogen color codes and the carbon footprints of the different production techniques to effectively estimate the environmental impact when employing hydrogen technologies in any application. Afterward a review of the implementation of liquid hydrogen (LH2 ) in the transportation sector including aerospace and aviation industries automotive and railways is provided. Then the focus is placed on the maritime sector. The aim is to highlight the challenges for the adoption of LH2 technologies on board ships. Different aspects were investigated in this study from LH2 bunkering onboard utilization regulations codes and standards and safety. Finally this study offers a broad overview of the bottlenecks that might hamper the adoption of LH2 technologies in the maritime sector and discusses potential solutions.
Integration Assessment of Turquoise Hydrogen in the European Energy System
Mar 2024
Publication
Turquoise hydrogen from natural gas pyrolysis has recently emerged as a promising alternative for low-carbon hydrogen production with a high-value pure carbon by-product. However the implications of this technology on the broader energy system are not well understood at present. To close this literature gap this study presents an assessment of the integration of natural gas pyrolysis into a simplified European energy system. The energy system model minimizes the cost by optimizing investment and hourly dispatch of a broad range of electricity and fuel production transmission and storage technologies as well as imports/exports on the global market. Norway is included as a major natural gas producer and Germany as a major energy importer. Results reveal that pyrolysis is economically attractive at modest market shares where the carbon by-product can be sold into highvalue markets for 400 €/ton. However pyrolysis-dominated scenarios that employ methane as a hydrogen carrier also hold promise as they facilitate deep decarbonization without the need for vast expansions of international electricity hydrogen and CO2 transmission networks. The simplicity and security benefits of such pyrolysis-led decarbonization pathways justify the modest 11 % cost premium involved for an energy system where natural gas is the only energy trade vector. In conclusion there is a strong case for turquoise hydrogen in future energy systems and further efforts for commercialization of natural gas pyrolysis are recommended.
Simulating Offshore Hydrogen Production via PEM Electrolysis using Real Power Production Data from a 2.3 MW Floating Offshore Wind Turbine
Mar 2023
Publication
This work presents simulation results from a system where offshore wind power is used to produce hydrogen via electrolysis. Real-world data from a 2.3 MW floating offshore wind turbine and electricity price data from Nord Pool were used as input to a novel electrolyzer model. Data from five 31-day periods were combined with six system designs and hydrogen production system efficiency and production cost were estimated. A comparison of the overall system performance shows that the hydrogen production and cost can vary by up to a factor of three between the cases. This illustrates the uncertainty related to the hydrogen production and profitability of these systems. The highest hydrogen production achieved in a 31-day period was 17 242 kg using a 1.852 MW electrolyzer (i.e. utilization factor of approximately 68%) the lowest hydrogen production cost was 4.53 $/kg H2 and the system efficiency was in the range 56.1e56.9% in all cases.
Techno-economic Modelling of Zero-emission Marine Transport with Hydrogen Fuel and Superconducting Propulsion System: Case Study of a Passenger Ferry
Mar 2023
Publication
This paper proposes a techno-economic model for a high-speed hydrogen ferry. The model can describe the system properties i.e. energy demand weight and daily operating expenses of the ferry. A novel aspect is the consideration of superconductivity as a measure for cost saving in the setting where liquid hydrogen (LH2) can be both coolant and fuel. We survey different scenarios for a high-speed ferry that could carry 300 passengers. The results show that despite higher energy demand compressed hydrogen gas is more economical compared with LH2 for now; however constructing large-scale hydrogen liquefaction plants make it competitive in the future. Moreover compressed hydrogen gas is restricted to a shorter distance while LH2 makes longer distances possible and whenever LH2 is accessible using a superconducting propulsion system has a beneficial impact on both energy and cost savings. These effects strengthen if the operational time or the weight of the ferry increases.
Experimental Study of Hydrogen Production Using Electrolyte Nanofluids with a Simulated Light Source
Dec 2021
Publication
In this research we conducted water electrolysis experiments of a carbon black (CB) based sodium sulfate electrolyte using a Hoffman voltameter. The main objective was to investigate hydrogen production in such systems as well as analyse the electrical properties and thermal properties of nanofluids. A halogen lamp mimicking solar energy was used as a radiation source and a group of comparative tests were also conducted with different irradiation areas. The results showed that by using CB and light it was possible to increase the hydrogen production rate. The optimal CB concentration was 0.1 wt %. At this concentration the hydrogen production rate increased by 30.37% after 20 min of electrolysis. Hence we show that using CB in electrolytes irradiated by solar energy could save the electrical energy necessary for electrolysis processes.
Blue, Green, and Turquoise Pathways for Minimizing Hydrogen Production Costs from Steam Methane Reforming with CO2 Capture
Nov 2022
Publication
Rising climate change ambitions require large-scale clean hydrogen production in the near term. “Blue” hydrogen from conventional steam methane reforming (SMR) with pre-combustion CO2 capture can fulfil this role. This study therefore presents techno-economic assessments of a range of SMR process configurations to minimize hydrogen production costs. Results showed that pre-combustion capture can avoid up to 80% of CO2 emissions cheaply at 35 €/ton but the final 20% of CO2 capture is much more expensive at a marginal CO2 avoidance cost around 150 €/ton. Thus post-combustion CO2 capture should be a better solution for avoiding the final 20% of CO2. Furthermore an advanced heat integration scheme that recovers most of the steam condensation enthalpy before the CO2 capture unit can reduce hydrogen production costs by about 6%. Two hybrid hydrogen production options were also assessed. First a “blue-green” hydrogen plant that uses clean electricity to heat the reformer achieved similar hydrogen production costs to the pure blue configuration. Second a “blue turquoise” configuration that replaces the pre-reformer with molten salt pyrolysis for converting higher hydrocarbons to a pure carbon product can significantly reduce costs if carbon has a similar value to hydrogen. In conclusion conventional pre-combustion CO2 capture from SMR is confirmed as a good solution for kickstarting the hydrogen economy and it can be tailored to various market conditions with respect to CO2 electricity and pure carbon prices.
Identifying and Analysing Important Model Assumptions: Combining Techno-economic and Political Feasibility of Deep Decarbonisation Pathways in Norway
Mar 2024
Publication
Understanding the political feasibility of transition pathways is a key issue in energy transitions. Policy changes are a significant source of uncertainty in energy system optimisation modelling. Energy system models are nevertheless continuously being updated to reflect policy signals as realistically as possible. Using the concept of transition pathways as a starting point this cross-disciplinary study combines energy system optimization modelling with political feasibility of different transition pathways. This combination generates insights into key political decision points in the ongoing energy transition. Resting on actor support structure and political feasibility of four main pathway categories (electrification hydrogen biomass and energy efficiency) we identify critical model assumptions that are politically significant and impact model outcome. Then by replacing the critical assumptions with technical limitations we model a scenario that is unrestrained by assumptions about policy we identify areas where political choices are key to model outcomes. The combination of actor preferences and modelled energy system consequences enables the identification of future key decision points. We find that there is considerable support for electrification as the main pathway to net-zero. The implications of widespread electrification in terms of energy production and grid capacity lead us to identify challenging policy decisions with implications for the energy transition.
In the Green? Perceptions of Hydrogen Production Methods Among the Norwegian Public
Feb 2023
Publication
This article presents findings from a representative survey fielded through the Norwegian Citizen Panel examining public perceptions of hydrogen fuel and its different production methods. Although several countries including Norway have strategies to increase the production of hydrogen fuel our results indicate that hydrogen as an energy carrier and its different production methods are still unknown to a large part of the public. A common misunderstanding seems to be confusing ‘hydrogen fuel’ in general with environmentally friendly ‘green hydrogen’. Results from a survey experiment (N = 1906) show that production method is important for public acceptance. On a five-point acceptance scale respondents score on average 3.9 for ‘green’ hydrogen which is produced from renewable energy sources. The level of acceptance is significantly lower for ‘blue’ (3.2) and ‘grey’ (2.3) hydrogen when respondents are informed that these are produced from coal oil or natural gas. Public support for hydrogen fuel in general as well as the different production methods is also related to their level of worry about climate change gender and political affiliation. Widespread misunderstandings regarding ‘green’ hydrogen production could potentially fuel public resistance as new ‘blue’ or ‘grey’ projects develop. Our results indicate a need for clearer communication from the government and developers regarding production methods to avoid distrust and potential public backfire.
Renewable Hydrogen Supply Chains: A Planning Matrix and an Agenda for Future Research
Oct 2022
Publication
Worldwide energy systems are experiencing a transition to more sustainable systems. According to the Hydrogen Roadmap Europe (FCH EU 2019) hydrogen will play an important role in future energy systems due to its ability to support sustainability goals and will account for approximately 13% of the total energy mix in the coming future. Correct hydrogen supply chain (HSC) planning is therefore vital to enable a sustainable transition. However due to the operational characteristics of the HSC its planning is complicated. Renewable hydrogen supply can be diverse: Hydrogen can be produced de-centrally with renewables such as wind and solar energy or centrally by using electricity generated from a hydro power plant with a large volume. Similarly demand for hydrogen can also be diverse with many new applications such as fuels for fuel cell electrical vehicles and electricity generation feedstocks in industrial processes and heating for buildings. The HSC consists of various stages (production storage distribution and applications) in different forms with strong interdependencies which further increase HSC complexity. Finally planning of an HSC depends on the status of hydrogen adoption and market development and on how mature technologies are and both factors are characterised by high uncertainties. Directly adapting the traditional approaches of supply chain planning for HSCs is insufficient. Therefore in this study we develop a planning matrix with related planning tasks leveraging a systematic literature review to cope with the characteristics of HSCs. We focus only on renewable hydrogen due to its relevance to the future low-carbon economy. Furthermore we outline an agenda for future research from the supply chain management perspective in order to support HSC development considering the different phases of HSCs adoption and market development.
Transitioning Remote Arctic Settlements to Renewable Energy Systems – A Modelling Study of Longyearbyen, Svalbard
Nov 2019
Publication
As transitioning away from fossil fuels to renewable energy sources comes on the agenda for a range of energy systems energy modelling tools can provide useful insights. If large parts of the energy system turns out to be based on variable renewables an accurate representation of their short-term variability in such models is crucial. In this paper we have developed a stochastic long-term energy model and applied it to an isolated Arctic settlement as a challenging and realistic test case. Our findings suggest that the stochastic modelling approach is critical in particular for studies of remote Arctic energy systems. Furthermore the results from a case study of the Norwegian settlement of Longyearbyen suggest that transitioning to a system based on renewable energy sources is feasible. We recommend that a solution based mainly on renewable power generation but also including energy storage import of hydrogen and adequate back-up capacity is taken into consideration when planning the future of remote Arctic settlements.
Hydrogen Informed Gurson Model for Hydrogen Embrittlement Simulation
Jul 2019
Publication
Hydrogen-microvoid interactions were studied via unit cell analyses with different hydrogen concentrations. The absolute failure strain decreases with hydrogen concentration but the failure loci were found to follow the same trend dependent only on stress triaxiality in other words the effects of geometric constraint and hydrogen on failure are decoupled. Guided by the decoupling principle a hydrogen informed Gurson model is proposed. This model is the first practical hydrogen embrittlement simulation tool based on the hydrogen enhanced localized plasticity (HELP) mechanism. It introduces only one additional hydrogen related parameter into the Gurson model and is able to capture hydrogen enhanced internal necking failure of microvoids with accuracy; its parameter calibration procedure is straightforward and cost efficient for engineering purpose
Projecting the Future Cost of PEM and Alkaline Water Electrolysers; a CAPEX Model Including Electrolyser Plant Size and Technology Department
Oct 2022
Publication
The investment costs of water electrolysis represent one key challenge for the realisation of renewable hydrogen-based energy systems. This work presents a technology cost assessment and outlook towards 2030 for alkaline electrolysers (AEL) and PEM electrolysers (PEMEL) in the MW to GW range taking into consideration the effects of plant size and expected technology developments. Critical selected data was fitted to a modified power law to describe the cost of an electrolyser plant based on the overall capacity and a learning/technology development rate to derive cost estimations for different PEMEL and AEL plant capacities towards 2030. The analysis predicts that the CAPEX gap between AEL and PEMEL technologies will decrease significantly towards 2030 with plant size until 1 e10 MW range. Beyond this only marginal cost reductions can be expected with CAPEX values approaching 320e400 $/kW for large scale (greater than 100 MW) plants by 2030 with subsequent cost reductions possible. Learning rates for electrolysers were estimated at 25 e30% for both AEL and PEMEL which are significantly higher than the learning rates reported in previous literature.
Optimal Renewable Energy Distribution Between Gasifier and Electrolyzer for Syngas Generation in a Power and Biomass-to-Liquid Fuel Process
Jan 2022
Publication
By adding energy as hydrogen to the biomass-to-liquid (BtL) process several published studies have shown that carbon efficiency can be increased substantially. Hydrogen can be produced from renewable electrical energy through the electrolysis of water or steam. Adding high-temperature thermal energy to the gasifier will also increase the overall carbon efficiency. Here an economic criterion is applied to find the optimal distribution of adding electrical energy directly to the gasifier as opposed to the electrolysis unit. Three different technologies for electrolysis are applied: solid oxide steam electrolysis (SOEC) alkaline water electrolysis (AEL) and proton exchange membrane (PEM). It is shown that the addition of part of the renewable energy to the gasifier using electric heaters is always beneficial and that the electrolysis unit operating costs are a significant portion of the costs. With renewable electricity supplied at a cost of 50 USD/MWh and a capital cost of 1500 USD/kW installed SOEC the operating costs of electric heaters and SOEC account for more than 70% of the total costs. The energy efficiency of the electrolyzer is found to be more important than the capital cost. The optimal amount of energy added to the gasifier is about 37–39% of the energy in the biomass feed. A BtL process using renewable hydrogen imports at 2.5 USD/kg H2 or SOEC for hydrogen production at reduced electricity prices gives the best values for the economic objective.
Water Electrolysis: From Textbook Knowledge to the Latest Scientific Strategies and Industrial Developments
May 2022
Publication
Replacing fossil fuels with energy sources and carriers that are sustainable environmentally benign and affordable is amongst the most pressing challenges for future socio-economic development. To that goal hydrogen is presumed to be the most promising energy carrier. Electrocatalytic water splitting if driven by green electricity would provide hydrogen with minimal CO2 footprint. The viability of water electrolysis still hinges on the availability of durable earth-abundant electrocatalyst materials and the overall process efficiency. This review spans from the fundamentals of electrocatalytically initiated water splitting to the very latest scientific findings from university and institutional research also covering specifications and special features of the current industrial processes and those processes currently being tested in large-scale applications. Recently developed strategies are described for the optimisation and discovery of active and durable materials for electrodes that ever-increasingly harness first principles calculations and machine learning. In addition a technoeconomic analysis of water electrolysis is included that allows an assessment of the extent to which a large-scale implementation of water splitting can help to combat climate change. This review article is intended to cross-pollinate and strengthen efforts from fundamental understanding to technical implementation and to improve the ‘junctions’ between the field’s physical chemists materials scientists and engineers as well as stimulate much-needed exchange among these groups on challenges encountered in the different domains.
Operating Hydrogen-Based Energy Storage Systems in Wind Farms for Smooth Power Injection: A Penalty Fees Aware Model Predictive Control
Aug 2022
Publication
Smooth power injection is one of the possible services that modern wind farms could provide in the not-so-far future for which energy storage is required. Indeed this is one among the three possible operations identified by the International Energy Agency (IEA)-Hydrogen Implementing Agreement (HIA) within the Task 24 final report that may promote their integration into the main grid in particular when paired to hydrogen-based energy storages. In general energy storage can mitigate the inherent unpredictability of wind generation providing that they are deployed with appropriate control algorithms. On the contrary in the case of no storage wind farm operations would be strongly affected as well as their economic performances since the penalty fees wind farm owners/operators incur in case of mismatches between the contracted power and that actually delivered. This paper proposes a Model Predictive Control (MPC) algorithm that operates a Hydrogen-based Energy Storage System (HESS) consisting of one electrolyzer one fuel cell and one tank paired to a wind farm committed to smooth power injection into the grid. The MPC relies on Mixed-Logic Dynamic (MLD) models of the electrolyzer and the fuel cell in order to leverage their advanced features and handles appropriate cost functions in order to account for the operating costs the potential value of hydrogen as a fuel and the penalty fee mechanism that may negatively affect the expected profits generated by the injection of smooth power. Numerical simulations are conducted by considering wind generation profiles from a real wind farm in the center-south of Italy and spot prices according to the corresponding market zone. The results show the impact of each cost term on the performances of the controller and how they can be effectively combined in order to achieve some reasonable trade-off. In particular it is highlighted that a static choice of the corresponding weights can lead to not very effective handling of the effects given by the combination of the system conditions with the various exogenous’ while a dynamic choice may suit the purpose instead. Moreover the simulations show that the developed models and the set-up mathematical program can be fruitfully leveraged for inferring indications on the devices’ sizing.
Strategies for the Sampling of Hydrogen at Refuelling Stations for Purity Assessment
Aug 2021
Publication
Hydrogen delivered at hydrogen refuelling station must be compliant with requirements stated in different standards which require specialized sampling device and personnel to operate it. Currently different strategies are implemented in different parts of the world and these strategies have already been used to perform 100s of hydrogen fuel sampling in USA EU and Japan. However these strategies have never been compared on a large systematic study. The purpose of this paper is to describe and compare the different strategies for sampling hydrogen at the nozzle and summarize the key aspects of all the existing hydrogen fuel sampling including discussion on material compatibility with the impurities that must be assessed. This review highlights the fact it is currently difficult to evaluate the impact or the difference these strategies would have on the hydrogen fuel quality assessment. Therefore comparative sampling studies are required to evaluate the equivalence between the different sampling strategies. This is the first step to support the standardization of hydrogen fuel sampling and to identify future research and development area for hydrogen fuel sampling.
Explosive Phase Transition in LH2
Sep 2021
Publication
This paper describes two models for analysing and simulating the physical effects of explosive phase transition of liquid hydrogen (LH2) also known as cold BLEVE. The present work is based on theoretical and experimental work for liquefied CO2. A Rankine Hugoniot analysis for evaporation waves that was previously developed for CO2 is now extended to LH2. A CFD-method for simulating two-phase flow with mass transfer between the phases is presented and compared with the Rankine Hugoniot analysis results. The Rankine Hugoniot method uses real fluid equations of state suited for LH2 while the CFD method uses linear equations of state suited for shock capturing methods. The results show that there will be a blast from a catastrophic rupture of an LH2 vessel and that the blast waves will experience a slow decay due to the large positive pressure phase.
Overview of First Outcomes of PNR Project HYTUNNEL-CS
Sep 2021
Publication
Dmitry Makarov,
Donatella Cirrone,
Volodymyr V. Shentsov,
Sergii Kashkarov,
Vladimir V. Molkov,
Z. Xu,
Mike Kuznetsov,
Alexandros G. Venetsanos,
Stella G. Giannissi,
Ilias C. Tolias,
Knut Vaagsaether,
André Vagner Gaathaug,
Mark R. Pursell,
Wayne M. Rattigan,
Frank Markert,
Luisa Giuliani,
L.S. Sørensen,
A. Bernad,
Mercedes Sanz Millán,
U. Kummer,
Christian Brauner,
Paola Russo,
J. van den Berg,
F. de Jong,
Tom Van Esbroeck,
M. Van De Veire,
Didier Bouix,
Gilles Bernard-Michel,
Sergey Kudriakov,
Etienne Studer,
Domenico Ferrero,
Joachim Grüne and
G. Stern
The paper presents the first outcomes of the experimental numerical and theoretical studies performed in the funded by Fuel Cell and Hydrogen Joint Undertaking (FCH2 JU) project HyTunnel-CS. The project aims to conduct pre-normative research (PNR) to close relevant knowledge gaps and technological bottlenecks in the provision of safety of hydrogen vehicles in underground transportation systems. Pre normative research performed in the project will ultimately result in three main outputs: harmonised recommendations on response to hydrogen accidents recommendations for inherently safer use of hydrogen vehicles in underground traffic systems and recommendations for RCS. The overall concept behind this project is to use inter-disciplinary and inter-sectoral prenormative research by bringing together theoretical modelling and experimental studies to maximise the impact. The originality of the overall project concept is the consideration of hydrogen vehicle and underground traffic structure as a single system with integrated safety approach. The project strives to develop and offer safety strategies reducing or completely excluding hydrogen-specific risks to drivers passengers public and first responders in case of hydrogen vehicle accidents within the currently available infrastructure.
Value of Green Hydrogen When Curtailed to Provide Grid Balancing Services
Aug 2022
Publication
This paper evaluates the potential of grid services in France Italy Norway and Spain to provide an alternative income for electrolysers producing hydrogen from wind power. Grid services are simulated with each country's data for 2017 for energy prices grid services and wind power profiles from relevant wind parks. A novel metric is presented the value of curtailed hydrogen which is independent from several highly uncertain parameters such as electrolyser cost or hydrogen market price. Results indicate that grid services can monetise the unused spare capacity of electrolyser plants improving their economy in the critical deployment phase. For most countries up-regulation yields a value of curtailed hydrogen above 6 V/kg over 3 times higher than the EU's 2030 price target (without incentives). However countries with large hydro power resources such as Norway yield far lower results below 2 V/kg. The value of curtailed hydrogen also decreases with hydrogen production corresponding to the cases of symmetric and down-regulation.
Systems-Based Safety Analysis for Hydrogen-Driven Autonomous Ships
Jun 2024
Publication
In the maritime domain hydrogen fuel cell propulsion and autonomous vessels are two important issues that are yet to be implemented together because of a few challenges. It is obvious that there are several individual safety studies on Maritime Autonomous Surface Ships and hydrogen storage as well as fuel cells based on various risk assessment tools but the combined safety studies that include hydrogen fuel cells on autonomous vessels with recent risk analysis methods are extremely limited. This research chooses the “System-Theoretic Process Analysis” (STPA) method which is a recent method for potential risk identification and mitigation. Both hydrogen and autonomous vessels are analyzed and assessed together with the STPA method. Results are not speculative but rather flexible compared to conventional systems. The study finds a total of 44 unsafe control actions (UCAs) evolved from human and central control unit controllers through STPA. Further the loss scenarios (LS) are identified that lead to those UCAs so that loss scenarios can be assessed and UCAs can be mitigated for safe operation. The objective of this study is to ensure adequate safety for hydrogen fuel cell propulsion on autonomous vessels.
Blue Hydrogen and Industrial Base Products: The Future of Fossil Fuel Exporters in a Net-zero World
May 2022
Publication
Is there a place for today’s fossil fuel exporters in a low-carbon future? This study explores trade channels between energy exporters and importers using a novel electricity-hydrogen-steel energy systems model calibrated to Norway a major natural gas producer and Germany a major energy consumer. Under tight emission constraints Norway can supply Germany with electricity (blue) hydrogen or natural gas with re-import of captured CO2. Alternatively it can use hydrogen to produce steel through direct reduction and supply it to the world market an export route not available to other energy carriers due to high transport costs. Although results show that natural gas imports with CO2 capture in Germany is the least-cost solution avoiding local CO2 handling via imports of blue hydrogen (direct or embodied in steel) involves only moderately higher costs. A robust hydrogen demand would allow Norway to profitably export all its natural gas production as blue hydrogen. However diversification into local steel production as one example of easy-to-export industrial base products offers an effective hedge against the possibility of lower European blue hydrogen demand. Looking beyond Europe the findings of this study are also relevant for the world’s largest energy exporters (e.g. OPEC+) and importers (e.g. developing Asia). Thus it is recommended that large hydrocarbon exporters consider a strategic energy export transition to a diversified mix of blue hydrogen and climate-neutral industrial base products.
European Hydrogen Train the Trainer Framework for Responders: Outcomes of the Hyresponder Project
Sep 2023
Publication
Síle Brennan,
Didier Bouix,
Christian Brauner,
Dominic Davis,
Natalie DeBacker,
Alexander Dyck,
André Vagner Gaathaug,
César García Hernández,
Laurence Grand-Clement,
Etienne Havret,
Deborah Houssin-Agbomson,
Petr Kupka,
Laurent Lecomte,
Eric Maranne,
Vladimir V. Molkov,
Pippa Steele,
Adolfo Pinilla,
Paola Russo and
Gerhard Schoepf
HyResponder is a European Hydrogen Train the Trainer programme for responders. This paper describes the key outputs of the project and the steps taken to develop and implement a long-term sustainable train the trainer programme in hydrogen safety for responders across Europe and beyond. This FCH2 JU (now Clean Hydrogen Joint Undertaking) funded project has built on the successful outcomes of the previous HyResponse project. HyResponder has developed further and updated educational operational and virtual reality training for trainers of responders to reflect the state-of-the-art in hydrogen safety including liquid hydrogen and expand the programme across Europe and specifically within the 10 countries represented directly within the project consortium: Austria Belgium the Czech Republic France Germany Italy Norway Spain Switzerland and the United Kingdom. For the first time four levels of educational materials from fire fighter through to specialist have been developed. The digital training resources are available on the e-Platform (https://hyresponder.eu/e-platform/). The revised European Emergency Response Guide is now available to all stakeholders. The resources are intended to be used to support national training programs. They are available in 8 languages: Czech Dutch English French German Italian Norwegian and Spanish. Through the HyResponder activities trainers from across Europe have undertaken joint actions which are in turn being used to inform the delivery of regional and national training both within and beyond the project. The established pan-European network of trainers is shaping the future in the important for inherently safer deployment of hydrogen systems and infrastructure across Europe and enhancing the reach and impact of the programme.
Hydrogen for Harvesting the Potential of Offshore Wind: A North Sea Case Study
Dec 2023
Publication
Economical offshore wind developments depend on alternatives for cost-efficient transmission of the generated energy to connecting markets. Distance to shore availability of an offshore power grid and scale of the wind farm may impede export through power cables. Conversion to H2 through offshore electrolysis may for certain offshore wind assets be a future option to enable energy export. Here we analyse the cost sensitivity of offshore electrolysis for harvesting offshore wind in the North Sea using a technology-detailed multi-carrier energy system modelling framework for analysis of energy export. We include multiple investment options for electric power and hydrogen export including HVDC cables new hydrogen pipelines tie-in to existing pipelines and pipelines with linepacking. Existing hydropower is included in the modelling and the effect on offshore electrolysis from increased pumping capacity in the hydropower system is analysed. Considering the lack of empirical cost data on offshore electrolysis as well as the high uncertainty in future electricity and H2 prices we analyse the cost sensitivity of offshore electrolysis in the North Sea by comparing costs relative to onshore electrolysis and energy prices relative to a nominal scenario. Offshore electrolysis is shown to be particularly sensitive to the electricity price and an electricity price of 1.5 times the baseline assumption was needed to provide sufficient offshore energy for any significant offshore electrolysis investments. On the other hand too high electricity prices would have a negative impact on offshore electrolysis because the energy is more valuable as electricity even at the cost of increased wind power curtailment. This shows that there is a window-of-opportunity in terms of onshore electricity where offshore electrolysis can play a significant role in the production of H2 . Pumped hydropower increases the maximum installed offshore electrolysis at the optimal electricity and H2 prices and makes offshore electrolysis more competitive at low electricity prices. Linepacking can make offshore electrolysis investments more robust against low H2 and high electricity prices as it allow for more variable H2 production through storing excess energy from offshore. The increased electrolysis capacity needed for variable electrolyser operation and linepacking is installed onshore due to its lower CAPEX compared to offshore installations.
Hydrogen Safety Strategies and Risk Management in Equinor
Sep 2021
Publication
Equinor has in recent years focused on low carbon technologies in addition to conventional oil & gas technologies. Clear strategic directions have been set to demonstrate Equinor’s commitment to longterm value creation that supports the Paris Agreement. This includes acceleration of decarbonization by establishing a well-functioning market for carbon capture transport and storage (CCS) as well as development of competitive hydrogen-based value chains and solutions. The specific properties of hydrogen must be taken into account in order to ensure safe design and operation of hydrogen systems as these properties differ substantially from those of natural gas and other conventional oil & gas products. Development projects need to consider and mitigate the increased possibility of high explosion pressures or detonation if hydrogen releases accumulate in enclosed or congested areas. On the other hand hydrogen’s buoyant properties can be exploited by locating potential leak points in the open to avoid gas accumulation thereby reducing the explosion risk. The purpose of this paper is to introduce Equinor’s hydrogen-based value chain projects and present our approach to ensure safe and effective designs. Safety strategies constitute the basis for Equinor’s safety and risk management. The safety strategies describe the connection between the hazards and risk profiles on one hand and the safety barrier elements and their needed performance on the other as input to safe design. The safety strategies also form the basis for safe operation. Measures to control the risk through practical designs follow from these strategies.
Chemical Inhibition of Premixed Hydrogen-air Flames: Experimental Investigation using a 20-litre Vessel
Sep 2021
Publication
Throughout the history of the mining petroleum process and nuclear industries continuous efforts have been made to develop and improve measures to prevent and mitigate accidental explosions. Over the coming decades energy systems are expected to undergo a transition towards sustainable use of conventional hydrocarbons and an increasing share of renewable energy sources in the global energy mix. The variable and intermittent supply of energy from solar and wind points to energy systems based on hydrogen or hydrogen-based fuels as the primary energy carriers. However the safety-related properties of hydrogen imply that it is not straightforward to achieve and document the same level of safety for hydrogen systems compared to similar systems based on established fuels such as petrol diesel and natural gas. Compared to the conventional fuels hydrogen-air mixtures have lower ignition energy higher combustion reactivity and a propensity to undergo deflagration-to-detonation-transition (DDT) under certain conditions. To achieve an acceptable level of safety it is essential to develop effective measures for mitigating the consequences of hydrogen explosions in systems with certain degree of congestion and confinement. Extensive research over the last decade have demonstrated that chemical inhibition or partial suppression can be used for mitigating the consequences of vapour cloud explosions (VCEs) in congested process plants. Total and cooperation partners have demonstrated that solid flame inhibitors injected into flammable hydrocarbon-air clouds represent an effective means of mitigating the consequences of VCEs involving hydrocarbons. For hydrogen-air explosions these same chemicals inhibitors have not proved effective. It is however well-known that hydrocarbons can affect the burning velocity of hydrogen-air mixtures greatly. This paper gives an overview over previous work on chemical inhibitors. In addition experiments in a 20-litre vessel have been performed to investigate the effect of combinations of hydrocarbons and alkali salts on hydrogen/air mixtures.
A CFD Analysis of Liquefied Gas Vessel Explosions
Dec 2021
Publication
Hydrogen is one of the most suitable candidates in replacing fossil fuels. However storage issues due to its very low density under ambient conditions are encountered in many applications. The liquefaction process can overcome such issues by increasing hydrogen’s density and thus enhancing its storage capacity. A boiling liquid expanding vapour explosion (BLEVE) is a phenomenon in liquefied gas storage systems. It is a physical explosion that might occur after the catastrophic rupture of a vessel containing a liquid with a temperature above its boiling point at atmospheric pressure. Even though it is an atypical accident scenario (low probability) it should be always considered due to its high yield consequences. For all the above-mentioned reasons the BLEVE phenomenon for liquid hydrogen (LH2) vessels was studied using the CFD methodology. Firstly the CFD model was validated against a well-documented CO2 BLEVE experiment. Secondly hydrogen BLEVE cases were simulated based on tests that were conducted in the 1990s on LH2 tanks designed for automotive purposes. The parametric CFD analysis examined different filling degrees initial pressures and temperatures of the tank content with the aim of comprehending to what extent the initial conditions influence the blast wave. Good agreement was shown between the simulation outcomes and the LH2 bursting scenario tests results.
Discharge Modeling of Large Scale LH2 Experiments with an Engineering Tool
Sep 2021
Publication
Accurate estimation of mass flow rate and release conditions is important for the design of dispersion and combustion experiments for the subsequent validation of CFD codes/models for consequence assessment analysis within related risk assessment studies and for associated Regulation Codes and Standards development. This work focuses on the modelling of the discharge phase of the recent large scale LH2 release and dispersion experiments performed by HSE within the framework of PRESLHY project. The experimental conditions covered sub-cooled liquid stagnation conditions at two pressures (2 and 6 bara) and 3 release nozzle diameters (1 ½ and ¼ inches). The simulations were performed using a 1d engineering tool which accounts for discharge line effects due to friction extra resistance due to fittings and area change. The engineering tool uses the Possible Impossible Flow (PIF) algorithm for choked flow calculations and the Helmholtz Free Energy (HFE) EoS formulation. Three different phase distribution models were applied. The predictions are compared against measured and derived data from the experiments and recommendations are given both regarding engineering tool applicability and future experimental design.
Energy Management Strategies for a Zero-emission Hybrid Domestic Ferry
Oct 2021
Publication
The paper presents three approaches for the sizing and control of a maritime hybrid power-plant equipped with proton exchange membrane fuel cells and batteries. The study focuses on three different power-plant configurations including the energy management strategy and the power-plant component sizing. The components sizing is performed following the definition of the energy management strategy using the sequential optimization approach. These configurations are tested using a dynamic model developed in Simulink. The simulations are carried out to validate the technical feasibility of each configuration for maritime use. Each energy management strategy is developed to allow for the optimization of a chosen set of parameters such as hydrogen consumption and fuel cell degradation. It is observed that in the hybrid power-plant optimization there are always trade-offs and the optimization should be carried out by prioritizing primary factors the ship owner considers most important for day-to-day operations.
Improving Carbon Efficiency and Profitability of the Biomass to Liquid Process with Hydrogen from Renewable Power
Aug 2018
Publication
A process where power and biomass are converted to Fischer-Tropsch liquid fuels (PBtL) is compared to a conventional Biomass-to-Liquid (BtL) process concept. Based on detailed process models it is demonstrated that the carbon efficiency of a conventional Biomass to Liquid process can be increased from 38 to more than 90% by adding hydrogen from renewable energy sources. This means that the amount of fuel can be increased by a factor of 2.4 with the same amount of biomass. Electrical power is applied to split water/steam at high temperature over solid oxide electrolysis cells (SOEC). This technology is selected because part of the required energy can be replaced by available heat. The required electrical power for the extra production is estimated to be 11.6 kWh per liter syncrude (C ) 5+ . By operating the SOEC iso-thermally close to 850 °C the electric energy may be reduced to 9.5 kWh per liter which is close to the energy density of jet fuel. A techno-economic analysis is performed where the total investments and operating costs are compared for the BtL and PBtL. With an electrical power price of 0.05 $/kWh and with SOEC investment cost of the 1000 $/kW(el) the levelized cost of producing advanced biofuel with the PBtL concept is 1.7 $/liter which is approximately 30% lower than for the conventional BtL. Converting excess renewable electric power to advanced biofuel in a PBtL plant is a sensible way of storing energy as a fuel with a relatively high energy density.
Reduction of Maritime GHG Emissions and the Potential Role of E-fuels
Nov 2021
Publication
Maritime transport accounts for around 3% of global anthropogenic Greenhouse gas (GHG) emissions (Well-to-Wake) and these emissions must be reduced with at least 50% in absolute values by 2050 to contribute to the ambitions of the Paris agreement (2015). Zero carbon fuels made from renewable sources (hydro wind or solar) are by many seen as the most promising option to deliver the desired GHG reductions. For the maritime sector these fuels come in two forms: First as E-Hydrogen or E-Ammonia; Second as Hydrocarbon E-fuels in the form of E-Diesel E-LNG or E-Methanol. We evaluate emissions energy use and cost for E-fuels and find that the most robust path to these fuels is through dual-fuel engines and systems to ensure flexibility in fuel selection to prepare for growing supplies and lower risks. The GHG reduction potential of E-fuels depends entirely on abundant renewable electricity.
Climate Change Impacts of E-fuels for Aviation in Europe Under Present-day Conditions and Future Policy Scenarios
Jan 2023
Publication
‘E-fuels’ or ‘synthetic fuels’ are hydrocarbon fuels synthesized from hydrogen (H2) and carbon dioxide (CO2) where H2 can be produced via electrolysis of water or steam reforming of natural gas and CO2 is captured from the combustion of a fossil or biogenic source or directly from the atmosphere. E-fuels are drop-in substitutes for fossil fuels but their climate change mitigation benefits are largely unclear. This study evaluates the climate change impacts of e-fuels for aviation by combining different sources of CO2 and H2 up to 2050 under two contrasting policy scenarios. The analysis includes different climate metrics and the effects of near-term climate forcers which are particularly relevant for the aviation sector. Results are produced for European average conditions and for Poland and Norway two countries with high and low emission intensity from their electricity production mix. E-fuels can either have higher or lower climate change impacts than fossil fuels depending on multiple factors such as in order of importance the electricity mix the origin of CO2 the technology for H2 production and the electrolyzer efficiency. The climate benefits are generally higher for e-fuels produced from CO2 of biogenic origin while e-fuels produced from CO2 from direct air capture or fossil fuel combustion require countries with clean electricity to outperform fossil fuels. Synthetic fuels produced from H2 derived from natural gas have higher impacts than fossil fuels even when coupled with carbon capture and storage if CO2 is sourced from fossil fuels or the atmosphere. Climate change impacts of e-fuels improve in the future and they can all achieve considerable climate change mitigation in 2050 relative to fossil jet fuel provided that strict climate policy measures are implemented to decarbonize the electricity sector. Under reduced policy efforts future climate impacts in 2050 of e-fuels from atmospheric or fossil CO2 are still higher than those of fossil jet fuels with an average European electricity mix. This study shows the conditions to maximize the climate change mitigation benefits of e-fuels which essentially depend on progressive decarbonization of the electricity sector and on reduced use of CO2 sourced from fossil fuels.
Quantitative Risk Analysis of Scaled-up Hydrogen Facilities
Sep 2021
Publication
Development of hydrogen facilities such as hydrogen refuelling stations (HRS) at scale is a fine balance between economy and safety where an optimal solution would both prevent showstoppers due to cost of increased safety measures and prevent showstoppers due to hydrogen accidents. A detailed Quantitative Risk Analysis (QRA) methodology is presented where the aim is to establish the total risk of the facility and use it to find the right level of safety features such as blast walls and layout. With upscaled hydrogen facilities comes larger area footprints and more potential leak points. These effects will cause increased possible consequence in terms of vapour cloud explosions and increased leak frequencies. Both effects contributing negative to the total risk of the hydrogen facility. At the same time as the number of such facilities is increasing rapidly the frequency of incidents can also increase. A risk-based approach is employed where inherently safe solutions is investigated and cost efficient and acceptable solutions can be established. The present QRA uses well established tools such as SAFETI FLACS and Express which are fitted for hydrogen risks. By using the established Explosion Risk Analysis tool Express the explosion risk inside the station can be found. By using CFD tools actively one can point at physical risk drivers such as equipment layout that can minimize gas cloud build-up on the station. The explosion simulations are further used to find the effects of e.g. blast wall on the pressures affecting on people on the other side of the wall. This is used together with the results from the SAFETI analysis to develop risk contours around the facility. Current standardized safety distances are discussed by considering the effects of scaling and risk drivers on the safety distances. The methodology can be used to develop certain requirement for how hydrogen facilities should be built inherently safe and in cost-efficient ways.
Examining the Role of Safety in Communication Concerning Emerging Hydrogen Technologies by Selected Groups of Stakeholders
Sep 2021
Publication
Governments and other stakeholders actively promote and facilitate the development and deployment of hydrogen and fuel cell technologies. Various strategy documents and energy forecasts outline the environmental and societal benefits of the prospective hydrogen economy. At the same time the safety related properties of hydrogen imply that it is not straightforward to achieve and document the same level of safety for hydrogen systems compared to conventional fuels. Severe accidents can have major impact on the development of energy technologies. The stakes will increase significantly as the use of hydrogen shifts from controlled environments in industrial facilities to the public domain and as the transport-related consumption extends from passenger cars and buses to trains ships and airplanes. Widespread deployment of hydrogen as an energy carrier in society will require massive investments. This implies commercial and political commitment involvement and influence on research priorities and decision-making. The legacy from accidents and the messages communicated by influential stakeholders impact not only how the public perceives hydrogen technologies but also governmental policies the development of regulations codes and standards (RCS) and ultimately the measures adopted for preventing and mitigating accidents. This paper explores whether and how selected aspects of safety are considered when distinct groups of stakeholders frame the hydrogen economy. We assess to what extent the communication is consistent with the current state-of-the-art in hydrogen safety and the contemporary strength of knowledge in risk assessments for hydrogen systems. The approach adopted entails semi-quantitative text analysis and close reading to highlight variations between diverse groups of stakeholders. The results indicate a bias in the framing of the safety-related aspects of the hydrogen economy towards procedural organisational and societal measures of risk reduction at the expense of well-known challenges and knowledge gaps associated with the implications of fundamental safety-related properties of hydrogen.
A Hydrogen-Fueled Micro Gas Turbine Unit for Carbon-Free Heat and Power Generation
Oct 2022
Publication
The energy transition with transformation into predominantly renewable sources requires technology development to secure power production at all times despite the intermittent nature of the renewables. Micro gas turbines (MGTs) are small heat and power generation units with fast startup and load-following capability and are thereby suitable backup for the future’s decentralized power generation systems. Due to MGTs’ fuel flexibility a range of fuels from high-heat to lowheat content could be utilized with different greenhouse gas generation. Developing micro gas turbines that can operate with carbon-free fuels will guarantee carbon-free power production with zero CO2 emission and will contribute to the alleviation of the global warming problem. In this paper the redevelopment of a standard 100-kW micro gas turbine to run with methane/hydrogen blended fuel is presented. Enabling micro gas turbines to run with hydrogen blended fuels has been pursued by researchers for decades. The first micro gas turbine running with pure hydrogen was developed in Stavanger Norway and launched in May 2022. This was achieved through a collaboration between the University of Stavanger (UiS) and the German Aerospace Centre (DLR). This paper provides an overview of the project and reports the experimental results from the engine operating with methane/hydrogen blended fuel with various hydrogen content up to 100%. During the development process the MGT’s original combustor was replaced with an innovative design to deal with the challenges of burning hydrogen. The fuel train was replaced with a mixing unit new fuel valves and an additional controller that enables the required energy input to maintain the maximum power output independent of the fuel blend specification. This paper presents the test rig setup and the preliminary results of the test campaign which verifies the capability of the MGT unit to support intermittent renewable generation with minimum greenhouse gas production. Results from the MGT operating with blended methane/hydrogen fuel are provided in the paper. The hydrogen content varied from 50% to 100% (volume-based) and power outputs between 35 kW to 100kW were tested. The modifications of the engine mainly the new combustor fuel train valve settings and controller resulted in a stable operation of the MGT with NOx emissions below the allowed limits. Running the engine with pure hydrogen at full load has resulted in less than 25 ppm of NOx emissions with zero carbon-based greenhouse gas production.
Effect of Mechanical Ventilation on Accidental Hydrogen Releases - Large Scale Experiments
Sep 2021
Publication
This paper presents a series of experiments on the effectiveness of existing mechanical ventilation systems during accidental hydrogen releases in confined spaces like underground garages. The purpose was to find the mass flow rate limit hence the TPRD diameter limit that will not require a change in the ventilation system. The experiments were performed in a 40 ft ISO container in Norway and hydrogen gas was used in all experiments. The forced ventilation system was installed with a standard outlet 315 mm diameter. The ventilation parameters during the investigation were British Standard with 10 ACH and British Standard with 6 ACH. The hydrogen releases were obtained through 0.5 mm and 1 mm nozzle from different hydrogen reservoir pressures. Both types of mass flow: constant and blowdown were included in the experimental matrix. The analysis of hydrogen concentration of created hydrogen cloud in the container shows the influence of the forced ventilation on hydrogen releases together with TPRD diameter and reservoir pressure. The generated experimental data will be used to validate a CFD model in the next step.
Ultra-Cheap Renewable Energy as an Enabling Technology for Deep Industrial Decarbonization via Capture and Utilization of Process CO2 Emissions
Jul 2022
Publication
Rapidly declining costs of renewable energy technologies have made solar and wind the cheapest sources of energy in many parts of the world. This has been seen primarily as enabling the rapid decarbonization of the electricity sector but low-cost low-carbon energy can have a great secondary impact by reducing the costs of energy-intensive decarbonization efforts in other areas. In this study we consider by way of an exemplary carbon capture and utilization cycle based on mature technologies the energy requirements of the “industrial carbon cycle” an emerging paradigm in which industrial CO2 emissions are captured and reprocessed into chemicals and fuels and we assess the impact of declining renewable energy costs on overall economics of these processes. In our exemplary process CO2 is captured from a cement production facility via an amine scrubbing process and combined with hydrogen produced by a solar-powered polymer electrolyte membrane using electrolysis to produce methanol. We show that solar heat and electricity generation costs currently realized in the Middle East lead to a large reduction in the cost of this process relative to baseline assumptions found in published literature and extrapolation of current energy price trends into the near future would bring costs down to the level of current fossil-fuel-based processes.
Pore-scale Study of Microbial Hydrogen Consumption and Wettability Alteration During Underground Hydrogen Storage
Feb 2023
Publication
Hydrogen can be a renewable energy carrier and is suggested to store renewable energy and mitigate carbon dioxide emissions. Subsurface storage of hydrogen in salt caverns deep saline formations and depleted oil/gas reservoirs would help to overcome imbalances between supply and demand of renewable energy. Hydrogen however is one of the most important electron donors for many subsurface microbial processes including methanogenesis sulfate reduction and acetogenesis. These processes cause hydrogen loss and changes of reservoir properties during geological hydrogen storage operations. Here we report the results of a typical halophilic sulfate-reducing bacterium growing in a microfluidic pore network saturated with hydrogen gas at 35 bar and 37°C. Test duration is 9 days. We observed a significant loss of H2 from microbial consumption after 2 days following injection into a microfluidic device. The consumption rate decreased over time as the microbial activity declined in the pore network. The consumption rate is influenced profoundly by the surface area of H2 bubbles and microbial activity. Microbial growth in the silicon pore network was observed to change the surface wettability from a water-wet to a neutral-wet state. Due to the coupling effect of H2 consumption by microbes and wettability alteration the number of disconnected H2 bubbles in the pore network increased sharply over time. These results may have significant implications for hydrogen recovery and gas injectivity. First pore-scale experimental results reveal the impacts of subsurface microbial growth on H2 in storage which are useful to estimate rapidly the risk of microbial growth during subsurface H2 storage. Second microvisual experiments provide critical observations of bubble-liquid interfacial area and reaction rate that are essential to the modeling that is needed to make long-term predictions. Third results help us to improve the selection criteria for future storage sites.
Comparison of Alternative Marine Fuels
Sep 2019
Publication
The overall ambition of the study has been to assess the commercial and operational viability of alternative marine fuels based on review existing academic and industry literature. The approach assesses how well six alternative fuels perform compared to LNG fuel on a set of 11 key parameters. Conventional fuels are not covered in this study however 2020 compliant fuels (HFO+scrubber and low sulphur fuels are included in the conclusion for comparative purposes.
Computational Fluid Dynamics Simulations of Hydrogen Releases and Vented Deflagrations in Large Enclosures
Nov 2019
Publication
This paper presents model predictions obtained with the CFD tool FLACS for hydrogen releases and vented deflagrations in containers and larger enclosures. The paper consists of two parts. The first part compares experimental results and model predictions for two test cases: experiments performed by Gexcon in 20-foot ISO containers (volume 33 m3 ) as part of the HySEA project and experiments conducted by SRI International and Sandia National Laboratories in a scaled warehouse geometry (volume 45.4 m3 ). The second part explores the use of the model system validated in the first part to accidental releases of hydrogen from forklift trucks inside a full-scale warehouse geometry (32 400 m3 ). The results demonstrate the importance of using realistic and reasonably accurate geometry models of the systems under consideration when performing CFD-based risk assessment studies. The discussion highlights the significant inherent uncertainty associated with quantitative risk assessments for vented hydrogen deflagrations in complex geometries. The suggestions for further work include a pragmatic approach for developing empirical correlations for pressure loads from vented hydrogen deflagrations in industrial warehouses with hydrogen-powered forklift trucks.
Exploring the Complexity of Hydrogen Perception and Acceptance Among Key Stakeholders in Norway
Nov 2022
Publication
This article explores the complexity of factors or mechanisms that can influence hydrogen stakeholder perception and acceptance in Norway. We systematically analyze 16 semi-structured in-depth interviews with industry stakeholders at local municipal regional and national levels of interest and authority in Norway. Four empirical dimensions are identified that highlight the need for whole system approaches in hydrogen technology research: (1) several challenges incentives and synergy effects influence the hydrogen transition; (2) transport preferences are influenced by combined needs and limitations; (3) levels of knowledge and societal trust determinant to perceptions of risk and acceptance; and (4) national and international hydrogen stakeholders are crucial to building incentives and securing commitment among key actors. Our findings imply that project management planners engineers and policymakers need to apply a whole system perspective and work across local regional and national levels before proceeding with large-scale development and implementation of the hydrogen supply chain.
Earth-Abundant Electrocatalysts in Proton Exchange Membrane Electrolyzers
Dec 2018
Publication
In order to adopt water electrolyzers as a main hydrogen production system it is critical to develop inexpensive and earth-abundant catalysts. Currently both half-reactions in water splitting depend heavily on noble metal catalysts. This review discusses the proton exchange membrane (PEM) water electrolysis (WE) and the progress in replacing the noble-metal catalysts with earth-abundant ones. The efforts within this field for the discovery of efficient and stable earth-abundant catalysts (EACs) have increased exponentially the last few years. The development of EACs for the oxygen evolution reaction (OER) in acidic media is particularly important as the only stable and efficient catalysts until now are noble-metal oxides such as IrOx and RuOx. On the hydrogen evolution reaction (HER) side there is significant progress on EACs under acidic conditions but there are very few reports of these EACs employed in full PEM WE cells. These two main issues are reviewed and we conclude with prospects for innovation in EACs for the OER in acidic environments as well as with a critical assessment of the few full PEM WE cells assembled with EACs.
Enhancing Safety of Liquid and Vaporised Hydrogen Transfer Technologies in Public Areas for Mobile Applications
Sep 2023
Publication
Federico Ustolin,
Donatella Cirrone,
Vladimir V. Molkov,
Dmitry Makarov,
Alexandros G. Venetsanos,
Stella G. Giannissi,
Giordano Emrys Scarponi,
Alessandro Tugnoli,
Ernesto Salzano,
Valerio Cozzani,
Daniela Lindner,
Birgit Gobereit,
Bernhard Linseisen,
Stuart J. Hawksworth,
Thomas Jordan,
Mike Kuznetsov,
Simon Jallais and
Olga Aneziris
International standards related to cryogenic hydrogen transferring technologies for mobile applications (filling of trucks ships stationary tanks) are missing and there is lack of experience. The European project ELVHYS (Enhancing safety of liquid and vaporized hydrogen transfer technologies in public areas for mobile applications) aims to provide indications on inherently safer and efficient cryogenic hydrogen technologies and protocols in mobile applications by proposing innovative safety strategies which are the results of a detailed risk analysis. This is carried out by applying an inter-disciplinary approach to study both the cryogenic hydrogen transferring procedures and the phenomena that may arise from the loss of containment of a piece of equipment containing hydrogen. ELVHYS will provide critical inputs for the development of international standards by creating inherently safer and optimized procedures and guidelines for cryogenic hydrogen transferring technologies thus increasing their safety level and efficiency. The aim of this paper is twofold: present the state of the art of liquid hydrogen transfer technologies by focusing on previous research projects such as PRESLHY and introduce the objectives and methods planned in the new EU project ELVHYS.
Microfluidic Storage Capacity and Residual Trapping During Cyclic Injections: Implications for Underground Storage
Apr 2023
Publication
Long-term and large-scale H2 storage is vital for a sustainable H2 economy. Research in underground H2 storage (UHS) in porous media is emerging but the understanding of H2 reconnection and recovery mechanisms under cyclic loading is not yet adequate. This paper reports a qualitative and quantitative investigation of H2 reconnection and recovery mechanisms in repeated injection-withdrawal cycles. Here we use microfluidics to experimentally investigate up to 5 cycles of H2 injection and withdrawal under a range of injection rates at shallow reservoir storage conditions. We find that H2 storage capacities increase with increasing injection rate and range between ~10% and 60%. The residual H2 saturation is in the same range between cycles (30e40%) but its distribution in the pore space visually appears to be hysteretic. In most cases the residually trapped H2 reconnects in the subsequent injection cycle predominantly in proximity to the large pore clusters. Our results provide valuable experimental data to advance the understanding of multiple H2 injection cycles in UHS schemes.
A Review on Hydrogen Embrittlement and Risk-based Inspection of Hydrogen Technologies
May 2023
Publication
Hydrogen could gradually replace fossil fuels mitigating the human impact on the environment. However equipment exposed to hydrogen is subjected to damaging effects due to H2 absorption and permeation through metals. Hence inspection activities are necessary to preserve the physical integrity of the containment systems and the risk-based (RBI) methodology is considered the most beneficial approach. This review aims to provide relevant information regarding hydrogen embrittlement its effect on materials’ properties and the synergistic interplay of the factors influencing its occurrence. Moreover an overview of predictive maintenance strategies is presented focusing on the RBI methodology. A systematic review was carried out to identify examples of the application of RBI to equipment exposed to hydrogenated environments and to identify the most active research groups. In conclusion a significant lack of knowledge has been highlighted along with difficulties in applying the RBI methodology for equipment operating in a pure hydrogen environment.
Renewable Hydrogen and Synthetic Fuels Versus Fossil Fuels for Trucking, Shipping and Aviation: A Holistic Cost Model
Aug 2023
Publication
Potential carbon neutrality of the global trucking shipping and aviation sectors by 2050 could be achieved by substituting fossil fuels with renewable hydrogen and synthetic fuels. To investigate the economic impact of fuel substitution over time a holistic cost model is developed and applied to three case studies in Norway an early adopter of carbon-neutral freight transport. The model covers the value chains from local electricity and fuel production (hydrogen ammonia Fischer–Tropsch e-fuel) to fuel consumption for long-haul trucking short-sea shipping and mid-haul aviation. The estimates are internally consistent and allow cross-mode and cross-fuel comparisons that set this work apart from previous studies more narrowly focused on a given transport mode or fuel. The model contains 150 techno-economic parameters to identify which components along the value chains drive levelized costs. This paper finds a cost reduction potential for renewable fuels of 41% to 68% until 2050 but carbon-neutral transport will suffer asymmetric cost disadvantages. Fuel substitution is most expensive in short-sea shipping followed by mid-haul aviation and long-haul trucking. Cost developments of electricity direct air capture of carbon vehicle expenses and fuel-related payload losses are significant drivers.
Modelling of Fast Fueling of Pressurized Hydrogen Tanks for Maritime Applications
Apr 2023
Publication
This paper studies fast fueling of gaseous hydrogen into large hydrogen (H2) tanks suitable for maritime applications. Three modeling methods have been developed and evaluated: (1) Two-dimensional computational fluid dynamic (CFD) modeling (2) One-dimensional wall discretized modeling and (3) Zero-dimensional modeling. A detailed 2D CFD simulation of a small H2-tank was performed and validated with data from literature and then used to simulate a large H2-tank. Results from the 2D-model show non-uniform temperature distribution inside the large tank but not in the small H2-tank. The 1D-model can predict the mean temperature in small H2-tanks but not the inhomogeneous temperature field in large H2-tanks. The 0D-model is suitable as a screening tool to obtain rough estimates. Results from the modeling of the large H2-tank show that the heat transfer to the wall during fast filling is inhibited by heat conduction in the wall which leads to an unacceptably high mean hydrogen temperature.
Design of Gravimetric Primary Standards for Field-testing of Hydrogen Refuelling Stations
Apr 2020
Publication
The Federal Institute of Metrology METAS developed a Hydrogen Field Test Standard (HFTS) that can be used for field verification and calibration of hydrogen refuelling stations. The testing method is based on the gravimetric principle. The experimental design of the HFTS as well as the description of the method are presented here.
Does Time Matter? A Multi-level Assessment of Delayed Energy Transitions and Hydrogen Pathways in Norway
Mar 2023
Publication
The Russian invasion of Ukraine has undeniably disrupted the EU's energy system and created a window of opportunity for an acceleration of the low-carbon energy transition in Europe. As the trading bloc's biggest gas supplier Norway faces the imminent threat of fast-depleting gas reserves and declining value for its exports. Norway is trying to beat the clock by aggressively exploring more petroleum therefore delaying its energy transition. In anticipation of the future drop in gas prices Norway is counting on blue hydrogen to valorise its gas resources before gradually shifting to green hydrogen export. Against this background this article seeks to understand how changes in the EU's energy landscape have affected the energy export sector and low-carbon hydrogen export developments in Norway from a multi-level perspective. Using the exploratory scenario approach the article assesses the implications of the different petroleum exploration outcomes on the development of the low-carbon hydrogen export market in Norway. The findings show that despite gas discoveries there is an urgent need for a phase-out plan for the Norwegian petroleum sector. For low-carbon hydrogen to play an important role in Norway's energy transition time is of the essence and action needs to be taken during this window of opportunity. An industrial sector and its value chain could take 25 years to transform which means that actions and policies for a full transformation pathway need to take place in Norway by 2025 to be ready for a climate-neutral Europe in 2050.
Towards Accident Prevention on Liquid Hydrogen: A Data-driven Approach for Releases Prediction
Mar 2023
Publication
Hydrogen is a clean substitute for hydrocarbon fuels in the marine sector. Liquid hydrogen (2 ) can be used to move and store large amounts of hydrogen. This novel application needs further study to assess the potential risk and safety operation. A recent study of 2 large-scale release tests was conducted to replicate spills of 2 inside the ship’s tank connection space and during bunkering operations. The tests were performed in a closed and outdoor facility. The 2 spills can lead to detonation representing a safety concern. This study analyzed the aforementioned 2 experiments and proposed a novel application of the random forests algorithm to predict the oxygen phase change and to estimate whether the hydrogen concentration is above the lower flammability limit (LFL). The models show accurate predictions in different experimental conditions. The findings can be used to select reliable safety barriers and effective risk reduction measures in 2 spills.
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