Malaysia

Adoption of hydrogen energy as an alternative to fossil fuels could be a major step towards decarbonising and fulfilling the needs of the energy sector. Hydrogen can be an ideal alternative for many fields compared with other alternatives. However there are many potential environmental challenges that are not limited to production and distribution systems but they also focus on how hydrogen is used through fuel cells and combustion pathways. The use of hydrogen has received little attention in research and policy which may explain the widely claimed belief that nothing but water is released as a by-product when hydrogen energy is used. We adopt systems thinking and system dynamics approaches to construct a conceptual model for hydrogen energy with a special focus on the pathways of hydrogen use to assess the potential unintended consequences and possible interventions; to highlight the possible growth of hydrogen energy by 2050. The results indicate that the combustion pathway may increase the risk of the adoption of hydrogen as a combustion fuel as it produces NOx which is a key air pollutant that causes environmental deterioration which may limit the application of a combustion pathway if no intervention is made. The results indicate that the potential range of global hydrogen demand is rising ranging from 73 to 158 Mt in 2030 73 to 300 Mt in 2040 and 73 to 568 Mt in 2050 depending on the scenario presented.

There have been many indices available in the process industries to describe rank or quantify hazards to people properties and environments. Most of the developed methods were meant to be applied to large scale and complex systems of process industries. Development of a swift and simple inherent safety index method which is relevant to small scale less complex membrane fuel cell system particularly the one in which to be applied during an early design stage is essential as an alternative to current comprehensive and yet time-consuming indices. In this work a modified version of PIIS modified prototype index for inherent safety (m-PIIS) was developed with the objectives of identifying indicating and estimating inherent safety of fuel cell system at an early design stage. The developed index was tested at four proton exchange membrane (PEM) fuel cell systems namely high pressure PEMFC system low pressure PEMFC system LH2 PEMFC system and on-board Me-OH PEMFC system. The developed index was also benchmarked against the original PIIS and ISI using the published results for the selection of process routes in MMA production. Results have indicated that m-PIIS has strong positive relationship with PIIS and ISI on most of the reaction step in MMA with the most significant are the C4 TBA and C3 reaction steps. Other reaction steps such as C2/MP C2/PA and ACH showed a strong positive relationship as well.

Due to energy and environmental issues hydrogen has become a more attractive clean fuel. Furthermore there is high interest in producing hydrogen from biomass with a view to sustainability. The thermochemical process for hydrogen production i.e. gasification is the focus of this work. This paper discusses the mathematical modeling of hydrogen production process via biomass steam gasification with calcium oxide as sorbent in a gasifier. A modelling framework consisting of kinetics models for char gasification methanation Boudouard methane reforming water gas shift and carbonation reactions to represent the gasification and CO2 adsorption in the gasifier is developed and implemented in MATLAB. The scope of the work includes an investigation of the influence of the temperature steam/biomass ratio and sorbent/biomass ratio on the amount of hydrogen produced product gas compositions and carbon conversion. The importance of different reactions involved in the process is also discussed. It is observed that hydrogen production and carbon conversion increase with increasing temperature and steam/biomass ratio. The model predicts a maximum hydrogen mole fraction in the product gas of 0.81 occurring at 950 K steam/biomass ratio of 3.0 and sorbent/biomass ratio of 1.0. In addition at sorbent/biomass ratio of 1.52 purity of H2 can be increased to 0.98 mole fraction with all CO2 present in the system adsorbed.

Hydrogen is a zero-carbon footprint energy source with high energy density that could be the basis of future energy systems. Membrane-based water electrolysis is one means by which to produce high-purity and sustainable hydrogen. It is important that the scientific community focus on developing electrolytic hydrogen systems which match available energy sources. In this review various types of water splitting technologies and membrane selection for electrolyzers are discussed. We highlight the basic principles recent studies and achievements in membrane-based electrolysis for hydrogen production. Previously the NafionTM membrane was the gold standard for PEM electrolyzers but today cheaper and more effective membranes are favored. In this paper CuCl–HCl electrolysis and its operating parameters are summarized. Additionally a summary is presented of hydrogen production by water splitting including a discussion of the advantages disadvantages and efficiencies of the relevant technologies. Nonetheless the development of cost-effective and efficient hydrogen production technologies requires a significant amount of study especially in terms of optimizing the operation parameters affecting the hydrogen output. Therefore herein we address the challenges prospects and future trends in this field of research and make critical suggestions regarding the implementation of comprehensive membrane-based electrolytic systems.

A solid-state storage system is the most practical option for hydrogen because it is more convenient and safer. Metal hydrides especially MgH₂ are the most promising materials that offer high gravimetric capacity and good reversibility. However the practical application of MgH₂ is restricted by slow sorption kinetics and high stability of thermodynamic properties. Hydrogen storage performance of MgH₂ was enhanced by introducing the Mg–Na–Al system that destabilises MgH₂ with NaAlH₄. The Mg–Na–Al system has superior performance compared to that of unary MgH₂ and NaAlH₄. To boost the performance of the Mg–Na–Al system the ball milling method and the addition of a catalyst were introduced. The Mg–Na–Al system resulted in a low onset decomposition temperature superior cyclability and enhanced kinetics performances. The Al12Mg17 and NaMgH₃ that formed in situ during the dehydrogenation process modify the reaction pathway of the Mg–Na–Al system and alter the thermodynamic properties. In this paper the overview of the recent progress in hydrogen storage of the Mg–Na–Al system is detailed. The remaining challenges and future development of Mg–Na–Al system are also discussed. This paper is the first review report on hydrogen storage properties of the Mg–Na–Al system.

The maritime shipping sector is a major contributor to CO₂ emissions and this figure is expected to rise in coming decades. With the intent of reducing emissions from this sector this research proposes the utilization of the jet stream to transport a combination of cargo and hydrogen using airships or balloons at altitudes of 10–20 km. The jet streams flow in the mid-latitudes predominantly in a west–east direction reaching an average wind speed of 165 km/h. Using this combination of high wind speeds and reliable direction hydrogen-filled airships or balloons could carry hydrogen with a lower fuel requirement and shorter travel time compared to conventional shipping. Jet streams at different altitudes in the atmosphere were used to identify the most appropriate circular routes for global airship travel. Round-the-world trips would take 16 days in the Northern Hemisphere and 14 in the Southern Hemisphere. Hydrogen transport via the jet stream due to its lower energy consumption and shorter cargo delivery time access to cities far from the coast could be a competitive alternative to maritime shipping and liquefied hydrogen tankers in the development of a sustainable future hydrogen economy.

Recently hydrogen (H2) has emerged as a superior energy carrier that has the potential to replace fossil fuel. However storing H2 under safe and operable conditions is still a challenging process due to the current commercial method i.e. H2 storage in a pressurised and liquified state which requires extremely high pressure and extremely low temperature. To solve this problem re‐ search on solid‐state H2 storage materials is being actively conducted. Among the solid‐state H2 storage materials borohydride is a potential candidate for H2 storage owing to its high gravimetric capacity (majority borohydride materials release >10 wt% of H2). Mg(BH4)2 which is included in the borohydride family shows promise as a good H2 storage material owing to its high gravimetric capacity (14.9 wt%). However its practical application is hindered by high thermal decomposition temperature (above 300 °C) slow sorption kinetics and poor reversibility. Currently the general research on the use of additives to enhance the H2 storage performance of Mg(BH4)2 is still under investigation. This article reviews the latest research on additive‐enhanced Mg(BH4)2 and its impact on the H2 storage performance. The future prospect and challenges in the development of additive‐ enhanced Mg(BH4)2 are also discussed in this review paper. To the best of our knowledge this is the first systematic review paper that focuses on the additive‐enhanced Mg(BH4)2 for solid‐state H2 storage.

Gasification of municipal solid waste (MSW) with subsequent utilization of syngas in gas engines/turbines and solid oxide fuel cells can substantially increase the power generation of waste-to-energy facilities and optimize the utilization of wastes as a sustainable energy resources. However purification of syngas to remove multiple impurities such as particulates tar HCl alkali chlorides and sulfur species is required. This study investigates the feasibility of high temperature purification of syngas from MSW gasification with the focus on catalytic tar reforming and desulfurization. Syngas produced from a downdraft fixed-bed gasifier is purified by a multi-stage system. The system comprises of a fluidized-bed catalytic tar reformer a filter for particulates and a fixed-bed reactor for dechlorination and then desulfurization with overall downward cascading of the operating temperatures throughout the system. Novel nano-structured nickel catalyst supported on alumina and regenerable Ni-Zn desulfurization sorbent loaded on honeycomb are synthesized. Complementary sampling and analysis methods are applied to quantify the impurities and determine their distribution at different stages. Experimental and thermodynamic modeling results are compared to determine the kinetic constraints in the integrated system. The hot purification system demonstrates up to 90% of tar and sulfur removal efficiency increased total syngas yield (14%) and improved cold gas efficiency (12%). The treated syngas is potentially applicable in gas engines/turbines and solid oxide fuel cells based on the dew points and concentration limits of the remaining tar compounds. Reforming of raw syngas by nickel catalyst for over 20 h on stream shows strong resistance to deactivation. Desulfurization of syngas from MSW gasification containing significantly higher proportion of carbonyl sulfide than hydrogen sulfide traces of tar and hydrogen chloride demonstrates high performance of Ni-Zn sorbents.

This study presents an overview of the economic analysis and environmental impact of natural gas conversion technologies. Published articles related to economic analysis and environmental impact of natural gas conversion technologies were reviewed and discussed. The economic analysis revealed that the capital and the operating expenditure of each of the conversion process is strongly dependent on the sophistication of the technical designs. The emerging technologies are yet to be economically viable compared to the well-established steam reforming process. However appropriate design modifications could significantly reduce the operating expenditure and enhance the economic feasibility of the process. The environmental analysis revealed that emerging technologies such as carbon dioxide (CO2) reforming and the thermal decomposition of natural gas offer advantages of lower CO2 emissions and total environmental impact compared to the well-established steam reforming process. Appropriate design modifications such as steam reforming with carbon capture storage and utilization the use of an optimized catalyst in thermal decomposition and the use of solar concentrators for heating instead of fossil fuel were found to significantly reduced the CO2 emissions of the processes. There was a dearth of literature on the economic analysis and environmental impact of photocatalytic and biochemical conversion processes which calls for increased research attention that could facilitate a comparative analysis with the thermochemical processes.

Hydrogen fuel cells are electrochemical power generators of high conversion efficiency and incredibly clean operation. Throughout the world the growth of fuel cell research and application has been very rapid in the last ten years where successful pilot projects on many areas have been implemented. In Malaysia approximately RM40 million has been granted to academic research institutions for fuel cell study and development. Recently Malaysia saw the emergence of its first hydrogen fuel cell developer signaling the readiness of the industrial sector to be involved in marketing the potential of fuel cells. Focusing mainly on Polymer Electrolyte Membrane fuel cell technology this paper demonstrates the efforts by Malaysian institutions both industrial and academic to promote hydrogen fuel cell education training application R&D as well as technology transfer. Emphasis is given to the existing collaboration between G-Energy Technologies and UniversitiTeknologi MARA that culminates with the successful application of a locally developed fuel cell system for a single-seated vehicle. Briefs on the potential of realizing a large-scale utilization of this clean technology into Malaysia’s mainstream power industry domestic consumers and energy consuming industries is also discussed. Key challenges are also identified where pilot projects government policy and infrastructural development is central to strengthen the prospect of hydrogen fuel cell implementation in Malaysia.