Italy
Comparative Life Cycle Assessment of Hydrogen-fuelled Passenger Cars
Feb 2021
Publication
In order to achieve gradual but timely decarbonisation of the transport sector it is essential to evaluate which types of vehicles provide a suitable environmental performance while allowing the use of hydrogen as a fuel. This work compares the environmental life-cycle performance of three different passenger cars fuelled by hydrogen: a fuel cell electric vehicle an internal combustion engine car and a hybrid electric vehicle. Besides two vehicle Read More
Control of Electrons’ Spin Eliminates Hydrogen Peroxide Formation During Water Splitting
Jul 2017
Publication
The production of hydrogen through water splitting in a photoelectrochemical cell suffers from an overpotential that limits the efficiencies. In addition hydrogen-peroxide formation is identified as a competing process affecting the oxidative stability of photoelectrodes. We impose spin-selectivity by coating the anode with chiral organic semiconductors from helically aggregated dyes as sensitizers; Zn-porphyrins and triarylamines. Hydrogen peroxide f Read More
Hydrogen Embrittlement in Advanced High Strength Steels and Ultra High Strength Steels: A New Investigation Approach
Dec 2018
Publication
In order to reduce CO2 emissions and fuel consumption and to respect current environmental norms the reduction of vehicles weight is a primary target of the automotive industry. Advanced High Strength Steels (AHSS) and Ultra High Strength Steel (UHSS) which present excellent mechanical properties are consequently increasingly used in vehicle manufacturing. The increased strength to mass ratio compensates the higher cost per kg and AHSS and Read More
Engineering Thoughts on Hydrogen Embrittlement
Jul 2018
Publication
Hydrogen Embrittlement (HE) is a topical issue for pipelines transporting sour products. Engineers need a simple and effective approach in materials selection at design stage. In other words they must know if a material is susceptible to cracking to be able of:selecting the right material and apply correct operational measures during the service life.Following ASTM F2078 HE is “a permanent loss of ductility in a metal or alloy caused by hydrogen in combination Read More
The Deltah Lab, a New Multidisciplinary European Facility to Support the H2 Distribution & Storage Economy
Apr 2021
Publication
The target for European decarburization encourages the use of renewable energy sources and H2 is considered the link in the global energy system transformation. So research studies are numerous but only few facilities can test materials and components for H2 storage. This work offers a brief review of H2 storage methods and presents the preliminary results obtained in a new facility. Slow strain rate and fatigue life tests were performed in H2 at Read More
Hydrogen Embrittlement in a 2101 Lean Duplex Stainless Steel
Sep 2019
Publication
Duplex Stainless Steels (DSSs) are an attractive class of materials characterized by a strong corrosion resistance in many aggressive environments. Thanks to the high mechanical performances DSSs are widely used for many applications in petrochemical industry chemical and nuclear plants marine environment desalination etc.Among the DSSs critical aspects concerning the embrittlement process it is possible to remember the steel sensitization and the h Read More
Detection, Characterization and Sizing of Hydrogen Induced Cracking in Pressure Vessels Using Phased Array Ultrasonic Data Processing
Jul 2016
Publication
Pressure vessels operating in sour service conditions in refinery environments can be subject to the risk of H₂S cracking resulting from the hydrogen entering into the material. This risk which is related to the specific working conditions and to the quality of the steel used shall be properly managed in order to maintain the highest safety at a cost-effective level.Nowadays the typical management strategy is based on a risk based inspection (RBI) evaluatio Read More
Towards a Climate-neutral Energy System in the Netherlands
Jan 2022
Publication
This paper presents two different scenarios for the energy system of the Netherlands that achieve the Dutch government’s national target of near net-zero greenhouse gas emissions in 2050. Using the system optimisation model OPERA the authors have analysed the technology sector and cost implications of the assumptions underlying these scenarios. While the roles of a number of key energy technology and emission mitigation options are strongly depen Read More
Experimental Study of Hydrogen Embrittlement in Maraging Steels
Feb 2018
Publication
This research activity aims at investigating the hydrogen embrittlement of Maraging steels in connection to real sudden failures of some of the suspension blades of the Virgo Project experimental apparatus. Some of them failed after 15 years of service in working conditions. Typically in the Virgo detector blades are loaded up to 50-60% of the material yield strength. For a deeper understanding of the failure the relationship between hydrogen concentratio Read More
Optimisation-based System Designs for Deep Offshore Wind Farms including Power to Gas Technologies
Feb 2022
Publication
A large deployment of energy storage solutions will be required by the stochastic and non-controllable nature of most renewable energy sources when planning for higher penetration of renewable electricity into the energy mix. Various solutions have been suggested for dealing with medium- and long-term energy storage. Hydrogen and ammonia are two of the most frequently discussed as they are both carbon-free fuels. In this paper the authors an Read More
A Preliminary Assessment of the Potential of Low Percentage Green Hydrogen Blending in the Italian Natural Gas Network
Oct 2020
Publication
The growing rate of electricity generation from renewables is leading to new operational and management issues on the power grid because the electricity generated exceeds local requirements and the transportation or storage capacities are inadequate. An interesting option that is under investigation by several years is the opportunity to use the renewable electricity surplus to power electrolyzers that split water into its component parts with the hy Read More
Performance Assessment of an Integrated Environmental Control System of Civil Hypersonic Vehicles
Apr 2022
Publication
This paper discloses the architecture and related performance of an environment control system designed to be integrated within a complex multi-functional thermal and energy management system that manages the heat loads and generation of electric power in a hypersonic vehicle by benefitting from the presence of cryogenic liquid hydrogen onboard. A bleed-less architecture implementing an open-loop cycle with a boot-strap sub-freezing air cycl Read More
Numerical Evaluation of the Effect of Fuel Blending with CO2 and H2 on the Very Early Corona‐Discharge Behavior in Spark Ignited Engines
Feb 2022
Publication
Reducing green‐house gases emission from light‐duty vehicles is compulsory in order to slow down the climate change. The application of High Frequency Ignition systems based on the Corona discharge effect has shown the potential to extend the dilution limit of engine operating conditions promoting lower temperatures and faster combustion events thus higher thermal and indicating efficiency. Furthermore predicting the behavior of Corona ignition Read More
Macroeconomic Factors Influencing Public Policy Strategies for Blue and Green Hydrogen
Nov 2021
Publication
The aim of this paper is to analyze the factors affecting hydrogen and Carbon Capture and Storage Technologies (“CCS”) policies taking into consideration Fossil Fuel Consumption Oil Reserves the Debt/GDP Ratio the Trilemma Index and other variables with respect to OECD countries. STATA 17 was used for the analysis. The results confirm the hypothesis that countries with high fossil fuel consumption and oil reserves are investing in blue hydrogen and CC Read More
Solid-State Hydrogen Storage Systems and the Relevance of a Gender Perspective
Sep 2021
Publication
This paper aims at addressing the exploitation of solid-state carriers for hydrogen storage with attention paid both to the technical aspects through a wide review of the available integrated systems and to the social aspects through a preliminary overview of the connected impacts from a gender perspective. As for the technical perspective carriers to be used for solid-state hydrogen storage for various applications can be classified into two classes: metal Read More
Finding Synergy Between Renewables and Coal: Flexible Power and Hydrogen Production from Advanced IGCC Plants with Integrated CO2 Capture
Feb 2021
Publication
Variable renewable energy (VRE) has seen rapid growth in recent years. However VRE deployment requires a fleet of dispatchable power plants to supply electricity during periods with limited wind and sunlight. These plants will operate at reduced utilization rates that pose serious economic challenges. To address this challenge this paper presents the techno-economic assessment of flexible power and hydrogen production from integrated gasificati Read More
Dynamic Emulation of a PEM Electrolyzer by Time Constant Based Exponential Model
Feb 2019
Publication
The main objective of this paper is to develop a dynamic emulator of a proton exchange membrane (PEM) electrolyzer (EL) through an equivalent electrical model. Experimental investigations have highlighted the capacitive effect of EL when subjecting to dynamic current profiles which so far has not been reported in the literature. Thanks to a thorough experimental study the electrical domain of a PEM EL composed of 3 cells has been modeled und Read More
Analysis of Standard and Innovative Methods for Allocating Upstream and Refinery GHG Emissions to Oil Products
Sep 2017
Publication
Alternative fuel policies need accurate and transparent methods to find the embedded carbon intensity of individual refinery products. This study investigates different ways of allocating greenhouse gases emissions deriving from refining and upstream crude oil supply. Allocation methods based on mass energy content economic value and innovatively added-value are compared with the marginal refining emissions calculated by CONCAWE’s linear-progra Read More
Electric Mobility in Portugal: Current Situation and Forecasts for Fuel Cell Vehicles
Nov 2021
Publication
In recent years the growing concern for air quality has led to the development of sustainable vehicles to replace conventional internal combustion engine (ICE) vehicles. Currently the most widespread technology in Europe and Portugal is that of Battery Electric Vehicles (BEV) or plug‐in HEV (PHEV) electric cars but hydrogen‐based transport has also shown significant growth in the commercialization of Fuel Cell Electric Vehicles (FCEV) and in the developm Read More
Numerical Investigation of Dual Fuel Combustion on a Compression Ignition Engine Fueled with Hydrogen/Natural Gas Blends
Mar 2022
Publication
The present work aims to assess the influence of the composition of blends of hydrogen (H2 ) and Natural Gas (NG) on Dual Fuel (DF) combustion characteristics including gaseous emissions. The 3D-CFD study is carried out by means of a customized version of the KIVA-3V code. An automotive 2.8 L 4-cylinder turbocharged diesel engine was previously modified in order to operate in DF NG–diesel mode and tested at the dynamometer bench. Aft Read More
The Route from Green H2 Production through Bioethanol Reforming to CO2 Catalytic Conversion: A Review
Mar 2022
Publication
Currently a progressively different approach to the generation of power and the production of fuels for the automotive sector as well as for domestic applications is being taken. As a result research on the feasibility of applying renewable energy sources to the present energy scenario has been progressively growing aiming to reduce greenhouse gas emissions. Following more than one approach the integration of renewables mainly involv Read More
Heat Recovery from a PtSNG Plant Coupled with Wind Energy
Nov 2021
Publication
Power to substitute natural gas (PtSNG) is a promising technology to store intermittent renewable electricity as synthetic fuel. Power surplus on the electric grid is converted to hydrogen via water electrolysis and then to SNG via CO2 methanation. The SNG produced can be directly injected into the natural gas infrastructure for long-term and large-scale energy storage. Because of the fluctuating behaviour of the input energy source the overall annual pl Read More
How to Give a renewed Chance to Natural Gas as Feed for the Production of Hydrogen: Electric MSR Coupled with CO2 Mineralization
Sep 2021
Publication
Recent years have seen a growing interest in water electrolysis as a way to store renewable electric energy into chemical energy through hydrogen production. However today the share of renewable energy is still limited and there is the need to have a continuous use of H2 for industrial chemicals applications. Firstly the paper discusses the use of electrolysis - connected to a conventional grid - for a continuous H2 production in terms of asso Read More
Life Cycle Assessment and Water Footprint of Hydrogen Production Methods: From Conventional to Emerging Technologies
Oct 2020
Publication
A common sustainability issue arising in production systems is the efficient use of resources for providing goods or services. With the increased interest in a hydrogen (H2) economy the life-cycle environmental performance of H2 production has special significance for assisting in identifying opportunities to improve environmental performance and to guide challenging decisions and select between technology paths. Life cycle impact assessment meth Read More
Water Electrolysis for the Production of Hydrogen to Be Employed in the Ironmaking and Steelmaking Industry
Nov 2021
Publication
The way to decarbonization will be characterized by the huge production of hydrogen through sustainable routes. Thus the basic production way is water electrolysis sustained by renewable energy sources allowing for obtaining “green hydrogen”. The present paper reviews the main available technologies for the water electrolysis finalized to the hydrogen production. We describe the fundamental of water electrolysis and the problems related to purifica Read More
Investigating Hydrogen-Based Non-Conventional Storage for PV Power in Eco-Energetic Optimization of a Multi-Energy System
Dec 2021
Publication
Through the integration of multiple energy carriers with related technologies multi-energy systems (MES) can exploit the synergies coming from their interplay for several benefits towards decarbonization. In such a context inclusion of Power-to-X technologies in periods of excess renewable electricity supply removes the need for curtailment of renewable electricity generation. In order to achieve the environmental benefits of MES without neglecting th Read More
Flexible Power & Biomass-to-Methanol Plants: Design Optimization and Economic Viability of the Electrolysis Integration
Nov 2021
Publication
This paper assesses the optimal design criteria of a flexible power and biomass to methanol (PBtM) plant conceived to operate both without green hydrogen addition (baseline mode) and with hydrogen addition (enhanced mode) following an intermittent use of the electrolysis system which is turned on when the electricity price allows an economically viable hydrogen production. The assessed plant includes a gasification section syngas cleaning and compr Read More
Main Hydrogen Production Processes: An Overview
May 2021
Publication
Due to its characteristics hydrogen is considered the energy carrier of the future. Its use as a fuel generates reduced pollution as if burned it almost exclusively produces water vapor. Hydrogen can be produced from numerous sources both of fossil and renewable origin and with as many production processes which can use renewable or non-renewable energy sources. To achieve carbon neutrality the sources must necessarily be renewable a Read More
Technical and Commercial Challenges of Proton-Exchange Membrane (PEM) Fuel Cells
Dec 2020
Publication
This review critically evaluates the latest trends in fuel cell development for portable and stationary fuel cell applications and their integration into the automotive industry. Fast start-up high efficiency no toxic emissions into the atmosphere and good modularity are the key advantages of fuel cell applications. Despite the merits associated with fuel cells the high cost of the technology remains a key factor impeding its widespread commercialization. Ther Read More
Operation of a Solid Oxide Fuel Cell Based Power System with Ammonia as a Fuel: Experimental Test and System Design
Nov 2020
Publication
Ammonia has strong potentialities as sustainable fuel for energy applications. NH3 is carbon free and can be synthetized from renewable energy sources (RES). In Solid Oxide Fuel Cells NH3 reacts electrochemically thereby avoiding the production of typical combustion pollutants such as NOx. In this study an ammonia-fueled solid oxide fuel cells (SOFC) system design is proposed and a thermodynamic model is developed to evaluate its performance. A Read More
An Extensive Review of Liquid Hydrogen in Transportation with Focus on the Maritime Sector
Sep 2022
Publication
The European Green Deal aims to transform the EU into a modern resource-efficient and competitive economy. The REPowerEU plan launched in May 2022 as part of the Green Deal reveals the willingness of several countries to become energy independent and tackle the climate crisis. Therefore the decarbonization of different sectors such as maritime shipping is crucial and may be achieved through sustainable energy. Hydrogen is potentially Read More
Hydrogen-Fuel Cell Hybrid Powertrain: Conceptual Layouts and Current Applications
Nov 2022
Publication
Transportation is one of the largest sources of CO2 emissions accounting for more than 20% of worldwide emissions. However it is one of the areas where decarbonization presents the greatest hurdles owing to its capillarity and the benefits that are associated with the use of fossil fuels in terms of energy density storage and transportation. In order to accomplish comprehensive decarbonization in the transport sector it will be required to encourage Read More
An Insight into Underground Hydrogen Storage in Italy
Apr 2023
Publication
Hydrogen is a key energy carrier that could play a crucial role in the transition to a low-carbon economy. Hydrogen-related technologies are considered flexible solutions to support the large-scale implementation of intermittent energy supply from renewable sources by using renewable energy to generate green hydrogen during periods of low demand. Therefore a short-term increase in demand for hydrogen as an energy carrier and an increase in Read More
The Role of Direct Air Capture in EU’s Decarbonisation and Associated Carbon Intensity for Synthetic Fuels Production
May 2023
Publication
Direct air capture (DAC) is considered one of the mitigation strategies in most of the future scenarios trying to limit global temperature to 1.5 ◦C. Given the high expectations placed on DAC for future decarbonisation this study presents an extensive review of DAC technologies exploring a number of techno-economic aspects including an updated collection of the current and planned DAC projects around the world. A dedicated analysis focused on the Read More
Modelling and Experimental Analysis of a Polymer Electrolyte Membrane Water Electrolysis Cell at Different Operating Temperatures
Nov 2018
Publication
In this paper a simplified model of a Polymer Electrolyte Membrane (PEM) water electrolysis cell is presented and compared with experimental data at 60 ◦C and 80 ◦C. The model utilizes the same modelling approach used in previous work where the electrolyzer cell is divided in four subsections: cathode anode membrane and voltage. The model of the electrodes includes key electrochemical reactions and gas transport mechanism (i.e. H2 O2 and H2O) w Read More
Dynamic Simulation and Thermoeconomic Analysis of a Hybrid Renewable System Based on PV and Fuel Cell Coupled with Hydrogen Storage
Nov 2021
Publication
The production of “green hydrogen” is currently one of the hottest topics in the field of renewable energy systems research. Hydrogen storage is also becoming more and more attractive as a flexible solution to mitigate the power fluctuations of solar energy systems. The most promising technology for electricity-to-hydrogen conversion and vice versa is the reversible solid-oxide cell (SOC). This device is still very expensive but it exhibits excellent Read More
Greenhouse Gas Implications of Extending the Service Life of PEM Fuel Cells for Automotive Applications: A Life Cycle Assessment
Feb 2022
Publication
A larger adoption of hydrogen fuel-cell electric vehicles (FCEVs) is typically included in the strategies to decarbonize the transportation sector. This inclusion is supported by life-cycle assessments (LCAs) which show the potential greenhouse gas (GHG) emission benefit of replacing internal combustion engine vehicles with their fuel cell counterpart. However the literature review performed in this study shows that the effects of durability and performance losses Read More
Optimal Design of a Hydrogen-powered Fuel Cell System for Aircraft Applications
Mar 2024
Publication
Recently hydrogen and fuel cells have gained interest as an emerging technology to mitigate the effects of climate change caused by the aviation sector. The aim of this work is to evaluate the applicability of this technology to an existing regional aircraft in order to assess its electrification with the aim of reducing greenhouse gas emissions and achieving sustainability goals. The design of a proton-exchange membrane fuel cell system (PEMFC) with the inclus Read More
Thermoacoustic Combustion Stability Analysis of a Bluff Body-Stabilized Burner Fueled by Methane–Air and Hydrogen–Air Mixtures
Apr 2023
Publication
Hydrogen can play a key role in the gradual transition towards a full decarbonization of the combustion sector e.g. in power generation. Despite the advantages related to the use of this carbon-free fuel there are still several challenging technical issues that must be addressed such as the thermoacoustic instability triggered by hydrogen. Given that burners are usually designed to work with methane or other fossil fuels it is important to investigate t Read More
A Critical Review of Polymer Electrolyte Membrane Fuel Cell Systems for Automotive Applications: Components, Materials, and Comparative Assessment
Mar 2023
Publication
The development of innovative technologies based on employing green energy carriers such as hydrogen is becoming high in demand especially in the automotive sector as a result of the challenges associated with sustainable mobility. In the present review a detailed overview of the entire hydrogen supply chain is proposed spanning from its production to storage and final use in cars. Notably the main focus is on Polymer Electrolyte Membrane Fuel C Read More
On the Technology of Solid Oxide Fuel Cell (SOFC) Energy Systems for Stationary Power Generation: A Review
Nov 2022
Publication
This paper presents a comprehensive overview on the current status of solid oxide fuel cell (SOFC) energy systems technology with a deep insight into the techno-energy performance. In recent years SOFCs have received growing attention in the scientific landscape of high efficiency energy technologies. They are fuel flexible highly efficient and environmentally sustainable. The high working temperature makes it possible to work in cogeneration and driv Read More
An On-Board Pure H2 Supply System Based on A Membrane Reactor for A Fuel Cell Vehicle: A Theoretical Study
Jul 2020
Publication
In this novel conceptual fuel cell vehicle (FCV) an on-board CH4 steam reforming (MSR) membrane reformer (MR) is considered to generate pure H2 for supplying a Fuel Cell (FC) system as an alternative to the conventional automobile engines. Two on-board tanks are forecast to store CH4 and water useful for feeding both a combustion chamber (designed to provide the heat required by the system) and a multi tubes Pd-Ag MR useful to generate pure H Read More
A Multi-Criteria Decision-Making Framework for Zero Emission Vehicle Fleet Renewal Considering Lifecycle and Scenario Uncertainty
Mar 2024
Publication
: In the last decade with the increased concerns about the global environment attempts have been made to promote the replacement of fossil fuels with sustainable sources. For transport which accounts for around a quarter of total greenhouse gas emissions meeting climate neutrality goals will require replacing existing fleets with electric or hydrogen-propelled vehicles. However the lack of adequate decision support approach makes the introduc Read More
Renewable Methanol Production from Green Hydrogen and Captured CO2: A Techno-economic Assessment
Nov 2022
Publication
This paper aims to present a pre-feasibility study of a power-to-fuel plant configuration designed for the production of 500 kg/h of renewable methanol (e-methanol) from green hydrogen and captured carbon dioxide. Hydrogen is obtained by water electrolysis employing the overproduction of renewable electricity. Carbon dioxide is assumed to be separated from the flue gas of a conventional power station by means of an amine-based CO2 absorp Read More
Redrawing the EU’s Energy Relations: Getting it Right with African Renewable Hydrogen
Oct 2022
Publication
In this paper we will explore the state of play with renewable hydrogen development in Africa through some case studies from AGHA members and the scope for growth moving forward. In so doing we will address some of the prevailing challenges to build out of a clean hydrogen economy that could be foreseen already at this early stage and look for potential solutions building on what is already in place in other sectors. We make the case that there should Read More
Hydrogen Refueling Process: Theory, Modeling, and In-Force Applications
Mar 2023
Publication
Among the alternative fuels enabling the energy transition hydrogen-based transportation is a sustainable and efficient choice. It finds application both in light-duty and heavy-duty mobility. However hydrogen gas has unique qualities that must be taken into account when employed in such vehicles: high-pressure levels up to 900 bar storage in composite tanks with a temperature limit of 85 ◦C and a negative Joule–Thomson coefficient throughout a Read More
Assessment of Hydrogen Based Long Term Electrical Storage in Residential Energy Systems
Oct 2022
Publication
Among the numerous envisioned applications for hydrogen in the decarbonization of the energy system seasonal energy storage is usually regarded as one of the most likely options. Although long-term energy storage is usually considered at grid-scale level given the increasing diffusion of distributed energy systems and the expected cost reduction in hydrogen related components some companies are starting to offer residential systems with PV modu Read More
Performance and Stability of a Critical Raw Materials-free Anion Exchange Membrane Electrolysis Cell
Feb 2023
Publication
A water electrolysis cell based on anion exchange membrane (AEM) and critical raw materials-free (CRM-free) electrocatalysts was developed. A NiFe-oxide electrocatalyst was used at the anode whereas a series of metallic electrocatalysts were investigated for the cathode such as Ni NiCu NiMo NiMo/KB. These were compared to a benchmark Pt/C cathode. CRMs-free anode and cathode catalysts were synthetized with a crystallite size of about 10 nm. The Read More
A Novel Optimal Power Control for a City Transit Hybrid Bus Equipped with a Partitioned Hydrogen Fuel Cell Stack
May 2020
Publication
The development of more sustainable and zero-emissions collective transport solutions could play a very important measure in the near future within smart city policies. This paper tries to give a contribution to this aim proposing a novel approach to fuel cell vehicle design and operation. Traditional difficulties experienced in fuel cell transient operation are in fact normally solved in conventional vehicle prototypes through the hybridization of the propulsi Read More
Renewable Hydrogen Supply Chains: A Planning Matrix and an Agenda for Future Research
Oct 2022
Publication
Worldwide energy systems are experiencing a transition to more sustainable systems. According to the Hydrogen Roadmap Europe (FCH EU 2019) hydrogen will play an important role in future energy systems due to its ability to support sustainability goals and will account for approximately 13% of the total energy mix in the coming future. Correct hydrogen supply chain (HSC) planning is therefore vital to enable a sustainable transition. However due to the o Read More
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