India

NiCu alloy catalysts with varying composition for electrolysis in alkaline water have been prepared by DC magnetron co-sputtering under Ar gas environment at substrate bias of  60 V. Nanocrystallinity lattice parameters and grain size of the NiCu alloys have been measured by grazing incidence X-ray diffraction (GIXRD). Elemental and microstructural analysis of the NiCu alloy have been done by field emission scanning electron microscopy (FESEM) as well as transmission electron microscopy (TEM). To analyze the NiCu alloys activity towards hydrogen evolution reaction (HER) cyclic voltammetry measurements have been done in a 6 M KOH at room temperature and further HER activities have been correlated with the varying Cu concentration in NiCu alloy catalysts.

Bilayer Mg/Ti (200 nm) thin films were successfully prepared by using D.C. magnetron sputtering unit. These films were vacuum annealed at 573 K temperature for one hour to obtain homogeneous and intermixed structure of bilayer. Hydrogenation of these thin film structures was made at different hydrogen pressure (15 30 & 45 psi) for 30 min to visualize the effect of hydrogen on film structure. The UV–Vis absorption spectra I-V characteristics and Raman spectroscopy were carried out to study the effect of hydrogen on optical electrical and structural properties of Mg/Ti bilayer thin films. The annealed thin film represents the semiconductor nature with the conductivity of the order of 10-5 Ώ⁻¹-m⁻¹ and it decreases as hydrogen pressure increases. The nonlinear dependence of resistivity on hydrogen pressure reveals inhomogeneous distribution of hydrogen in the thin film. Raman spectroscopy confirmed the presence of hydrogen in thin film where the intensity of peaks was found to be decreased with hydrogen pressure.

Considering energy crises and pollution problems today much work has been done for alternative fuels for fossil fuels and lowering the toxic components in the combustion products. Expert studies proved that hydrogen one of the prominent alternative energy source which has many excellent combustion properties that can be used for improving combustion and emissions performance of gasoline-fuelled spark ignition (SI) engines. This article experimentally investigated the performance and emission characteristics of a high speed single cylinder SI engine operating with different hydrogen gasoline blends. For this purpose the conventional carburetted high speed SI engine was modified into an electronically controllable engine with help of electronic control unit (ECU) which dedicatedly used to control the injection timings and injection durations of gasoline. Various hydrogen enrichment levels were selected to investigate the effect of hydrogen addition on engine brake mean effective pressure (Bmep) brake thermal efficiency volumetric efficiency and emission characteristics. The test results demonstrated that combustion performances fuel consumption and brake mean effective pressure were eased with hydrogen enrichment. The experimental results also showed that the brake thermal efficiency was higher than that for the pure gasoline operation. Moreover HC and CO emissions were all reduced after hydrogen enrichment.

In the climate change mitigation context based on the blue hydrogen concept a narrative frame is presented in this paper to build the argument for solving the energy trilemma which is the possibility of job loss and stranded asset accumulation with a sustainable energy solution in gas- and oil-rich regions especially for the Persian Gulf region. To this aim scientific evidence and multidimensional feasibility analysis have been employed for making the narrative around hydrogen clear in public and policy discourse so that choices towards acceleration of efforts can begin for paving the way for the future hydrogen economy and society. This can come from natural gas and petroleum-related skills technologies experience and infrastructure. In this way we present results using multidimensional feasibility analysis through STEEP and give examples of oil- and gas-producing countries to lead the transition action along the line of hydrogen-based economy in order to make quick moves towards cost effectiveness and sustainability through international cooperation. Lastly this article presents a viewpoint for some regional geopolitical cooperation building but needs a more full-scale assessment.

Fully decarbonizing global industry is essential to achieving climate stabilization and reaching net zero greenhouse gas emissions by 2050–2070 is necessary to limit global warming to 2 °C. This paper assembles and evaluates technical and policy interventions both on the supply side and on the demand side. It identifies measures that employed together can achieve net zero industrial emissions in the required timeframe. Key supply-side technologies include energy efficiency (especially at the system level) carbon capture electrification and zero-carbon hydrogen as a heat source and chemical feedstock. There are also promising technologies specific to each of the three top-emitting industries: cement iron & steel and chemicals & plastics. These include cement admixtures and alternative chemistries several technological routes for zero-carbon steelmaking and novel chemical catalysts and separation technologies. Crucial demand-side approaches include material-efficient design reductions in material waste substituting low-carbon for high-carbon materials and circular economy interventions (such as improving product longevity reusability ease of refurbishment and recyclability). Strategic well-designed policy can accelerate innovation and provide incentives for technology deployment. High-value policies include carbon pricing with border adjustments or other price signals; robust government support for research development and deployment; and energy efficiency or emissions standards. These core policies should be supported by labeling and government procurement of low-carbon products data collection and disclosure requirements and recycling incentives. In implementing these policies care must be taken to ensure a just transition for displaced workers and affected communities. Similarly decarbonization must complement the human and economic development of low- and middle-income countries.

Noble metals are added to boiling water reactors (BWRs) to mitigate stress corrosion cracking of structural components made from steels and Ni-based alloys and this technology is referred to as Noble Metal Chemical Addition (NMCA) or NobleChemTM. There is a growing concern that NMCA can cause unwanted harmful effects on the corrosion and hydrogen uptake properties of Zircaloy-2 fuel cladding. To investigate this we have subjected Zircaloy-2 fuel claddings to out-of-pile BWR conditions in a custom-built autoclave. These claddings are oxidized in pressurized hot water (280 °C 9 MPa) for 25 60 and 150 days wherein Pt nanoparticles (~10 nm) were simultaneously injected. Cross-sectional focused ion beam cuts made at the oxide-metal interface reveal that the oxide growth is not significantly influenced by the local Pt loadings (≤ 1 µg·cm^-2). Surprisingly an inverse correlation was observed between oxide thicknesses and metal's hydrogen contents. Interestingly Pt catalysts have led to diminished hydrogen absorption in specimens with liner exposed to the hot water. Overall Pt catalysts exhibited no detrimental effects on the corrosion rate and hydrogen absorption in Zircaloy-2.

Apart from many limitations the usage of hydrogen in different day-to-day applications have been increasing drastically in recent years. However numerous techniques available to produce hydrogen electrolysis of water is one of the simplest and cost-effective hydrogen production techniques. In this method water is split into hydrogen and oxygen by using external electric current. In this research a novel hydrogen production system incorporated with Photovoltaic – Thermal (PVT) solar collector is developed. The influence of different parameters like solar collector tilt angle thermal collector design and type of heat transfer fluid on the performance of PVT system and hydrogen production system are also discussed. Finally thermal efficiency electrical efficiency and hydrogen production rate have been predicted by using the Adaptive Neuro-Fuzzy Inference System (ANFIS) technique. Based on this study results it can be inferred that the solar collector tilt angle plays a significant role to improve the performance of the electrical and thermal performance of PVT solar system and Hydrogen yield rate. On the other side the spiral-shaped thermal collector with water exhibited better end result than the other hydrogen production systems. The predicted results ANFIS techniques represent an excellent agreement with the experimental results. In consequence it is suggested that the developed ANFIS model can be adopted for further studies to predict the performance of the hydrogen production system.

Hydrogen is a clean fuel and an abundant renewable energy resource. In recent years huge scientific attention has been invested to invent suitable materials for its safe storage. Conducting polymers has been extensively investigated as a potential hydrogen storage and fuel cell membrane due to the low cost ease of synthesis and processability to achieve the desired morphological and microstructural architecture ease of doping and composite formation chemical stability and functional properties. The review presents the recent progress in the direction of material selection modification to achieve appropriate morphology and adsorbent properties chemical and thermal stabilities. Polyaniline is the most explored material for hydrogen storage. Polypyrrole and polythiophene has also been explored to some extent. Activated carbons derived from conducting polymers have shown the highest specific surface area and significant storage. This review also covers recent advances in the field of proton conducting solid polymer electrolyte membranes in fuel cells application. This review focuses on the basic structure synthesis and working mechanisms of the polymer materials and critically discusses their relative merits.

A district heating system is an eco-friendly power generation facility with high energy efficiency. The boiler water wall tube used in the district heating system is exposed to extremely harsh conditions and unexpected fractures often occur during operation. In this study a corrosion failure analysis of the boiler water wall tube was performed to elucidate the failure mechanisms. The study revealed that overheating by flames was the cause of the failure of the boiler water wall tube. With an increase in temperature in a localized region the microstructure not only changed from ferrite/pearlite to martensite/bainite which made it more susceptible to brittleness but it also developed tensile residual stresses in the water-facing side by generating cavities or microcracks along the grain boundaries inside the tube. High-temperature hydrogen embrittlement combined with stress corrosion cracking initiated many microcracks inside the tube and created an intergranular fracture.

In response to the global challenge of climate change 136 countries accounting for 90% of global GDP and 85% of the population have now set net-zero targets. A transition to net-zero will require the decarbonization of all sectors of the economy. Green-hydrogen produced from renewable energy sources poses little to no threat to the environment and increasing its production will support net-zero targets Our study examined the evolution of green-hydrogen research themes since the UN Sustainable Development Goals were adopted in 2015 by utilizing bibliographic couplings keyword co-occurrence and keyphrase analysis of 642 articles from 2016 to 2021 in the Scopus database. We studied bibliometrics indicators and temporal evolution of publications and citations patterns of open access the effect of author collaboration influential publications and top contributing countries. We also consider new indicators like publication views keyphrases topics with prominence and field weighted citation impact and Altmetrics to understand the research direction further. We find four major thematic distributions of green-hydrogen research based on keyword co-occurrence networks: hydrogen storage hydrogen production electrolysis and the hydrogen economy. We also find networks of four research clusters that provide new information on the journal’s contributions to green-hydrogen research. These are materials chemistry hydrogen energy and cleaner production applied energy and fuel cells. Most green-hydrogen research aligns with Affordable and Clean Energy (SDG 7) and Climate Action (SDG 13). The outcomes of policy decisions in the United States Europe India and China will profoundly impact green-hydrogen production and storage over the next five years. If these policies are implemented these countries will account for two-thirds of this growth. Asia will account for the most significant part and become the second-largest producer globally.