Greece
Performance Analysis of a Zero-Energy Building Using Photovoltaics and Hydrogen Storage
Mar 2023
Publication
The exploitation of renewable energy sources in the building sector is a challenging aspect of achieving sustainability. The incorporation of a proper storage unit is a vital issue for managing properly renewable electricity production and so to avoid the use of grid electricity. The present investigation examines a zero-energy residential building that uses photovoltaics for covering all its energy needs (heating cooling domestic hot water and appliances-lighting needs). The building uses a reversible heat pump and an electrical heater so there is not any need for fuel. The novel aspect of the present analysis lies in the utilization of hydrogen as the storage technology in a power-to-hydrogen-to-power design. The residual electricity production from the photovoltaics feeds an electrolyzer for hydrogen production which is stored in the proper tank under high pressure. When there is a need for electricity and the photovoltaics are not enough the hydrogen is used in a fuel cell for producing the needed electricity. The present work examines a building of 400 m2 floor area in Athens with total yearly electrical demand of 23656 kWh. It was found that the use of 203 m2 of photovoltaics with a hydrogen storage capacity of 34 m3 can make the building autonomous for the year period.
The Evolution and Structure of Ignited High-pressure Cryogenic Hydrogen Jets
Jun 2022
Publication
The anticipated upscaling of hydrogen energy applications will involve the storage and transport of hydrogen at cryogenic conditions. Understanding the potential hazard arising from leaks in high-pressure cryogenic storage is needed to improve hydrogen safety. The manuscript reports a series of numerical simulations with detailed chemistry for the transient evolution of ignited high-pressure cryogenic hydrogen jets. The study aims to gain insight of the ignition processes flame structures and dynamics associated with the transient flame evolution. Numerical simulations were firstly conducted for an unignited jet released under the same cryogenic temperature of 80 K and pressure of 200 bar as the considered ignited jets. The predicted hydrogen concentrations were found to be in good agreement with the experimental measurements. The results informed the subsequent simulations of the ignited jets involving four different ignition locations. The predicted time series snapshots of temperature hydrogen mass fraction and the flame index are analyzed to study the transient evolution and structure of the flame. The results show that a diffusion combustion layer is developed along the outer boundary of the jet and a side diffusion flame is formed for the near-field ignition. For the far-field ignition an envelope flame is observed. The flame structure contains a diffusion flame on the outer edge and a premixed flame inside the jet. Due to the complex interactions between turbulence fuel-air mixing at cryogenic temperature and chemical reactions localized spontaneous ignition and transient flame extinguishment are observed. The predictions also captured the experimentally observed deflagration waves in the far-field ignited jets.
Cold Hydrogen Blowdown Release: An Inter-comparison Study
Sep 2021
Publication
Hydrogen dispersion in stagnant environment resulting from blowdown of a vessel storing the gas at cryogenic temperature is simulated using different CFD codes and modelling strategies. The simulations are based on the DISCHA experiments that were carried out by Karlsruhe Institute of Technology (KIT) and Pro-Science (PS). The selected test for the current study involves hydrogen release from a 2.815 dm3 volume tank with an initial pressure of 200 barg and temperature 80 K. During the release the hydrogen pressure in the tank gradually decreased. A total of about 139 gr hydrogen is released through a 4 mm diameter. The temperature time series and the temperature decay rate of the minimum value predicted by the different codes are compared with each other and with the experimentally measured ones. Recommendations for future experimental setup and for modeling approaches for similar releases are provided based on the present analysis. The work is carried out within the EU-funded project PRESLHY.
Hydrogen Role in the Valorization of Integrated Steelworks Process Off-gases through Methane and Methanol Syntheses
Jun 2021
Publication
The valorization of integrated steelworks process off-gases as feedstock for synthesizing methane and methanol is in line with European Green Deal challenges. However this target can be generally achieved only through process off-gases enrichment with hydrogen and use of cutting-edge syntheses reactors coupled to advanced control systems. These aspects are addressed in the RFCS project i3 upgrade and the central role of hydrogen was evident from the first stages of the project. First stationary scenario analyses showed that the required hydrogen amount is significant and existing renewable hydrogen production technologies are not ready to satisfy the demand in an economic perspective. The poor availability of low-cost green hydrogen as one of the main barriers for producing methane and methanol from process off-gases is further highlighted in the application of an ad-hoc developed dispatch controller for managing hydrogen intensified syntheses in integrated steelworks. The dispatch controller considers both economic and environmental impacts in the cost function and although significant environmental benefits are obtainable by exploiting process off-gases in the syntheses the current hydrogen costs highly affect the dispatch controller decisions. This underlines the need for big scale green hydrogen production processes and dedicated green markets for hydrogen-intensive industries which would ensure easy access to this fundamental gas paving the way for a C-lean and more sustainable steel production.
Integration of Renewable Hydrogen Production in Steelworks Off-Gases for the Synthesis of Methanol and Methane
May 2021
Publication
The steel industry is among the highest carbon-emitting industrial sectors. Since the steel production process is already exhaustively optimized alternative routes are sought in order to increase carbon efficiency and reduce these emissions. During steel production three main carbon-containing off-gases are generated: blast furnace gas coke oven gas and basic oxygen furnace gas. In the present work the addition of renewable hydrogen by electrolysis to those steelworks off-gases is studied for the production of methane and methanol. Different case scenarios are investigated using AspenPlusTM flowsheet simulations which differ on the end-product the feedstock flowrates and on the production of power. Each case study is evaluated in terms of hydrogen and electrolysis requirements carbon conversion hydrogen consumption and product yields. The findings of this study showed that the electrolysis requirements surpass the energy content of the steelwork’s feedstock. However for the methanol synthesis cases substantial improvements can be achieved if recycling a significant amount of the residual hydrogen.
A Review of Alternative Processes for Green Hydrogen Production Focused on Generating Hydrogen from Biomass
Apr 2024
Publication
Hydrogen plays a leading role in achieving a future with net zero greenhouse gas emissions. The present challenge is producing green hydrogen to cover the fuel demands of transportation and industry to gain independence from fossil fuels. This review’s goal is to critically demonstrate the existing methods of biomass treatment and assess their ability to scale up. Biomass is an excellent hydrogen carrier and biomass-derived processes are the main target for hydrogen production as they provide an innovative pathway to green hydrogen production. Comparing the existing processes thermochemical treatment is found to be far more evolved than biological or electrochemical treatment especially with regard to scaling prospects.
Techno-economic Evaluation of Medium Scale Power to Hydrogen to Combined Heat and Power Generation Systems
Jun 2022
Publication
The European Hydrogen Strategy and the new « Fit for 55 » package indicate the urgent need for the alignment of policy with the European Green Deal and European Union (EU) climate law for the decarbonization of the energy system and the use of hydrogen towards 2030 and 2050. The increasing carbon prices in EU Emission Trading System (ETS) as well as the lack of dispatchable thermal power generation as part of the Coal exit are expected to enhance the role of Combined Heat and Power (CHP) in the future energy system. In the present work the use of renewable hydrogen for the decarbonization of CHP plants is investigated for various fossil fuel substitution ratios and the impact of the overall efficiency the reduction of direct emissions and the carbon footprint of heat and power generation are reported. The analysis provides insights on efficient and decarbonized cogeneration linking the power with the heat sector via renewable hydrogen production and use. The levelized cost of hydrogen production as well as the levelized cost of electricity in the power to hydrogen to combined heat and power system are analyzed for various natural gas substitution scenarios as well as current and future projections of EU ETS carbon prices.
Two-Dimensional Photocatalysts for Energy and Environmental Applications
Jun 2022
Publication
The depletion of fossil fuels and onset of global warming dictate the achievement of efficient technologies for clean and renewable energy sources. The conversion of solar energy into chemical energy plays a vital role both in energy production and environmental protection. A photocatalytic approach for H2 production and CO2 reduction has been identified as a promising alternative for clean energy production and CO2 conversion. In this process the most critical parameter that controls efficiency is the development of a photocatalyst. Two-dimensional nanomaterials have gained considerable attention due to the unique properties that arise from their morphology. In this paper examples on the development of different 2D structures as photocatalysts in H2 production and CO2 reduction are discussed and a perspective on the challenges and required improvements is given.
Energy Transition on Sifnos: An Approach to Economic and Social Transition and Development
Mar 2022
Publication
This article aims to present the potential of energy transition in insular systems for social and economic transition and development when planned and implemented appropriately with the active involvement of local communities. To this end the example of Sifnos Energy Community is examined and presented as a pilot case. It proves that energy transition apart from its obvious energy conservation and climate necessity can provide a strong contribution to the development of remote areas and the remedying of crucial issues especially in insular communities such as unemployment low standards of living isolation and energy supply security. Energy transition on Sifnos has been undertaken by the Sifnos Energy Community (SEC) with the target to achieve 100% energy independency through effective and rational projects. The major project is a centralized hybrid power plant consisting of a wind park and a pumped hydro storage system. It was designed to fully cover the current electricity demand and the anticipated forthcoming load due to the overall transition to e-mobility for the transportation sector on the island. Through the exploitation of the excess electricity production with the production of potable water and hydrogen energy transition can facilitate the development of new professional activities on the island and reduce the local economy’s dependence on tourism. Additionally a daily link to the neighboring larger Cyclades islands can be established with a hydrogen powered-passenger vessel ensuring the secure and cheap overseas transportation connection of Sifnos throughout the whole year. The overall energy transition process is executed with the active involvement of the Sifnos citizens ensuring wide public acceptance and the minimization of the projects’ impacts on the natural and human environment. At the same time the anticipated benefits for the insular communities are maximized highlighting the energy transition process on Sifnos as a new sustainable development pattern. For all this effort and the already achieved results Sifnos has been declared as one of the six pilot islands of the European Community’s initiative “Clean Energy for EU Islands”.
Review on the Safe Use of Ammonia Fuel Cells in the Maritime Industry
May 2021
Publication
In April 2018 the International Maritime Organisation adopted an ambitious plan to contribute to the global efforts to reduce the Greenhouse Gas emissions as set by the Paris Agreement by targeting a 50% reduction in shipping’s Green House Gas emissions by 2050 benchmarked to 2008 levels. To meet these challenging goals the maritime industry must introduce environmentally friendly fuels with negligible or low SOX NOX and CO2 emissions. Ammonia use in maritime applications is considered promising due to its high energy density low flammability easy storage and low production cost. Moreover ammonia can be used as fuel in a variety of propulsors such as fuel cells and can be produced from renewable sources. As a result ammonia can be used as a versatile marine fuel exploiting the existing infrastructure and having zero SOX and CO2 emissions. However there are several challenges to overcome for ammonia to become a compelling fuel towards the decarbonisation of shipping. Such factors include the selection of the appropriate ammonia-fuelled power generator the selection of the appropriate system safety assessment tool and mitigating measures to address the hazards of ammonia. This paper discusses the state-of-the-art of ammonia fuelled fuel cells for marine applications and presents their potential and challenges.
The Interaction between Short- and Long-Term Energy Storage in an nZEB Office Building
Mar 2024
Publication
The establishment of near-autonomous micro-grids in commercial or public building complexes is gaining increasing popularity. Short-term storage capacity is provided by means of large battery installations or more often by the employees’ increasing use of electric vehicle batteries which are allowed to operate in bi-directional charging mode. In addition to the above short-term storage means a long-term storage medium is considered essential to the optimal operation of the building’s micro-grid. The most promising long-term energy storage carrier is hydrogen which is produced by standard electrolyzer units by exploiting the surplus electricity produced by photovoltaic installation due to the seasonal or weekly variation in a building’s electricity consumption. To this end a novel concept is studied in this paper. The details of the proposed concept are described in the context of a nearly Zero Energy Building (nZEB) and the associated micro-grid. The hydrogen produced is stored in a high-pressure tank to be used occasionally as fuel in an advanced technology hydrogen spark ignition engine which moves a synchronous generator. A size optimization study is carried out to determine the genset’s rating the electrolyzer units’ capacity and the tilt angle of the rooftop’s photovoltaic panels which minimize the building’s interaction with the external grid. The hydrogen-fueled genset engine is optimally sized to 40 kW (0.18 kW/kWp PV). The optimal tilt angle of the rooftop PV panels is 39◦ . The maximum capacity of the electrolyzer units is optimized to 72 kW (0.33 kWmax/kWp PV). The resulting system is tacitly assumed to integrate to an external hydrogen network to make up for the expected mismatches between hydrogen production and consumption. The significance of technology in addressing the current challenges in the field of energy storage and micro-grid optimization is discussed with an emphasis on its potential benefits. Moreover areas for further research are highlighted aiming to further advance sustainable energy solutions.
A Simulated Roadmap of Hydrogen Technology Contribution to Climate Change Mitigation Based on Representative Concentration Pathways Considerations
Apr 2018
Publication
Hydrogen as fuel has been a promising technology toward climate change mitigation efforts. To this end in this paper we analyze the contribution of hydrogen technology to our future environmental goals. It is assumed that hydrogen is being produced in higher efficiency across time and this is simulated on Global Change Assessment Model (GCAM). The environmental restrictions applied are the expected emissions representative concentration pathways (RCP) 2.6 4.5 and 6.0. Our results have shown increasing hydrogen production as the environmental constraints become stricter and hydrogen more efficient in being produced. This increase has been quantified and provided on open access as Supporting Information to this manuscript.
Results of the Pre-normative Research Project PRESLHY for the Safe Use of Liquid Hydrogen
Sep 2021
Publication
Liquid hydrogen (LH2) compared to compressed gaseous hydrogen offers advantages for large-scale transport and storage of hydrogen with higher densities. Although the gas industry has good experience with LH2 only little experience is available for the new applications of LH2 as an energy carrier. Therefore the European FCH JU funded project PRESLHY conducted pre-normative research for the safe use of cryogenic LH2 in non-industrial settings. The central research consisted of a broad experimental program combined with analytical work modelling and simulations belonging to the three key phenomena of the accident chain: release and mixing ignition and combustion. The presented results improve the general understanding of the behavior of LH2 in accidents and provide some design guidelines and engineering tools for safer use of LH2. Recommendations for improvement of current international standards are derived.
A Hot Syngas Purification System Integrated with Downdraft Gasification of Municipal Solid Waste
Jan 2019
Publication
Gasification of municipal solid waste (MSW) with subsequent utilization of syngas in gas engines/turbines and solid oxide fuel cells can substantially increase the power generation of waste-to-energy facilities and optimize the utilization of wastes as a sustainable energy resources. However purification of syngas to remove multiple impurities such as particulates tar HCl alkali chlorides and sulfur species is required. This study investigates the feasibility of high temperature purification of syngas from MSW gasification with the focus on catalytic tar reforming and desulfurization. Syngas produced from a downdraft fixed-bed gasifier is purified by a multi-stage system. The system comprises of a fluidized-bed catalytic tar reformer a filter for particulates and a fixed-bed reactor for dechlorination and then desulfurization with overall downward cascading of the operating temperatures throughout the system. Novel nano-structured nickel catalyst supported on alumina and regenerable Ni-Zn desulfurization sorbent loaded on honeycomb are synthesized. Complementary sampling and analysis methods are applied to quantify the impurities and determine their distribution at different stages. Experimental and thermodynamic modeling results are compared to determine the kinetic constraints in the integrated system. The hot purification system demonstrates up to 90% of tar and sulfur removal efficiency increased total syngas yield (14%) and improved cold gas efficiency (12%). The treated syngas is potentially applicable in gas engines/turbines and solid oxide fuel cells based on the dew points and concentration limits of the remaining tar compounds. Reforming of raw syngas by nickel catalyst for over 20 h on stream shows strong resistance to deactivation. Desulfurization of syngas from MSW gasification containing significantly higher proportion of carbonyl sulfide than hydrogen sulfide traces of tar and hydrogen chloride demonstrates high performance of Ni-Zn sorbents.
A CFD Analysis of Liquefied Gas Vessel Explosions
Dec 2021
Publication
Hydrogen is one of the most suitable candidates in replacing fossil fuels. However storage issues due to its very low density under ambient conditions are encountered in many applications. The liquefaction process can overcome such issues by increasing hydrogen’s density and thus enhancing its storage capacity. A boiling liquid expanding vapour explosion (BLEVE) is a phenomenon in liquefied gas storage systems. It is a physical explosion that might occur after the catastrophic rupture of a vessel containing a liquid with a temperature above its boiling point at atmospheric pressure. Even though it is an atypical accident scenario (low probability) it should be always considered due to its high yield consequences. For all the above-mentioned reasons the BLEVE phenomenon for liquid hydrogen (LH2) vessels was studied using the CFD methodology. Firstly the CFD model was validated against a well-documented CO2 BLEVE experiment. Secondly hydrogen BLEVE cases were simulated based on tests that were conducted in the 1990s on LH2 tanks designed for automotive purposes. The parametric CFD analysis examined different filling degrees initial pressures and temperatures of the tank content with the aim of comprehending to what extent the initial conditions influence the blast wave. Good agreement was shown between the simulation outcomes and the LH2 bursting scenario tests results.
Reduction in Greenhouse Gas and Other Emissions from Ship Engines: Current Trends and Future Options
Nov 2022
Publication
The impact of ship emission reductions can be maximised by considering climate health and environmental effects simultaneously and using solutions fitting into existing marine engines and infrastructure. Several options available enable selecting optimum solutions for different ships routes and regions. Carbon-neutral fuels including low-carbon and carbon-negative fuels from biogenic or non-biogenic origin (biomass waste renewable hydrogen) could resemble current marine fuels (diesel-type methane and methanol). The carbon-neutrality of fuels depends on their Well-to-Wake (WtW) emissions of greenhouse gases (GHG) including carbon dioxide (CO2) methane (CH4) and nitrous oxide emissions (N2O). Additionally non-gaseous black carbon (BC) emissions have high global warming potential (GWP). Exhaust emissions which are harmful to health or the environment need to be equally removed using emission control achieved by fuel engine or exhaust aftertreatment technologies. Harmful emission species include nitrogen oxides (NOx) sulphur oxides (SOx) ammonia (NH3) formaldehyde particle mass (PM) and number emissions (PN). Particles may carry polyaromatic hydrocarbons (PAHs) and heavy metals which cause serious adverse health issues. Carbon-neutral fuels are typically sulphur-free enabling negligible SOx emissions and efficient exhaust aftertreatment technologies such as particle filtration. The combinations of carbon-neutral drop-in fuels and efficient emission control technologies would enable (near-)zero-emission shipping and these could be adaptable in the short- to mid-term. Substantial savings in external costs on society caused by ship emissions give arguments for regulations policies and investments needed to support this development.
Optimizing the Installation of a Centralized Green Hydrogen Production Facility in the Island of Crete, Greece
Apr 2024
Publication
The European Union is committed to a 55% reduction in greenhouse gas emissions by 2030 as outlined in the Green Deal and Climate Law initiatives. In response to geopolitical events the RePowerEU initiative aims to enhance energy self-sufficiency reduce reliance on Russian natural gas and promote hydrogen utilization. Hydrogen valleys localized ecosystems integrating various hydrogen supply chain elements play a key role in this transition particularly benefiting isolated regions like islands. This manuscript focuses on optimizing a Centralized Green Hydrogen Production Facility (CGHPF) on the island of Crete. A mixed-integer linear programming framework is proposed to optimize the CGHPF considering factors such as land area wind and solar potential costs and efficiency. Additionally an in-depth sensitivity analysis is conducted to explore the impact of key factors on the economic feasibility of hydrogen investments. The findings suggest that hydrogen can be sold in Crete at prices as low as 3.5 EUR/kg. Specifically it was found in the base scenario that selling hydrogen at 3.5 EUR/kg the net profit of the investment could be as high as EUR 6.19 million while the capacity of the solar and wind installation supplying the grid hydrogen facility would be 23.51 MW and 52.97 MW respectively. It is noted that the high profitability is justified by the extraordinary renewable potential of Crete. Finally based on our study a policy recommendation to allow a maximum of 20% direct penetration of renewable sources of green hydrogen facilities into the grid is suggested to encourage and accelerate green hydrogen expansion.
On Green Hydrogen Generation Technologies: A Bibliometric Review
Mar 2024
Publication
Green hydrogen produced by water electrolysis with renewable energy plays a crucial role in the revolution towards energy sustainability and it is considered a key source of clean energy and efficient storage. Its ability to address the intermittency of renewable sources and its potential to decarbonize sectors that are difficult to electrify make it a strategic component in climate change mitigation. By using a method based on a bibliometric review of scientific publications this paper represents a significant contribution to the emerging field of research on green hydrogen and provides a detailed review of electrolyzer technologies identifying key areas for future research and technology development. The results reflect the immaturity of a technology which advances with different technical advancements waiting to find the optimal technical solution that allows for its massive implementation as a source of green hydrogen generation. According to the results found in this article alkaline (ALK) and proton exchange membrane (PEM) electrolyzers seem to be the ones that interest the scientific community the most. Similarly in terms of regional analysis Europe is clearly committed to green hydrogen in view of the analysis of its scientific results on materials and electrolyzer capacity forecasts for 2030.
Computational Analysis of Liquid Hydrogen Storage Tanks for Aircraft Applications
Mar 2023
Publication
During the last two decades the use of hydrogen (H2 ) as fuel for aircraft applications has been drawing attention; more specifically its storage in liquid state (LH2 ) which is performed in extreme cryogenic temperatures (−253 ◦C) is a matter of research. The motivation for this effort is enhanced by the predicted growth of the aviation sector; however it is estimated that this growth could be sustainable only if the strategies and objectives set by global organizations for the elimination of greenhouse gas emissions during the next decades such as the European Green Deal are taken into consideration and consequently technologies such as hydrogen fuel are promoted. Regarding LH2 in aircraft substantial effort is required to design analyze and manufacture suitable tanks for efficient storage. Important tools in this process are computational methods provided by advanced engineering software (CAD/CAE). In the present work a computational study with the finite element method is performed in order to parametrically analyze proper tanks examining the effect of the LH2 level stored as well as the tank geometric configuration. In the process the need for powerful numerical models is demonstrated owing to the highly non-linear dependence on temperature of the involved materials. The present numerical models’ efficiency could be further enhanced by integrating them as part of a total aircraft configuration design loop.
A Detailed Parametric Analysis of a Solar-Powered Cogeneration System for Electricity and Hydrogen Production
Dec 2022
Publication
Hydrogen has received increased attention in the last decades as a green energy carrier and a promising future fuel. The integration of hydrogen as well as the development of cogeneration plants makes the energy sector more eco-friendly and sustainable. The aim of this paper is the investigation of a solar-fed cogeneration system that can produce power and compressed green hydrogen. The examined unit contains a parabolic trough collector solar field a thermal energy storage tank an organic Rankine cycle and a proton exchange membrane water electrolyzer. The installation also includes a hydrogen storage tank and a hydrogen compressor. The unit is analyzed parametrically in terms of thermodynamic performance and economic viability in steady-state conditions with a developed and accurate model. Taking into account the final results the overall energy efficiency is calculated at 14.03% the exergy efficiency at 14.94% and the hydrogen production rate at 0.205 kg/h. Finally the payback period and the net present value are determined at 9 years and 122 k€ respectively.
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