United Kingdom

One of the most attractive routes for the production of hydrogen or syngas for use in fuel cell applications is the reforming and partial oxidation of hydrocarbons. The use of hydrocarbons in high temperature fuel cells is achieved through either external or internal reforming. Reforming and partial oxidation catalysis to convert hydrocarbons to hydrogen rich syngas plays an important role in fuel processing technology. The current research in the area of reforming and partial oxidation of methane methanol and ethanol includes catalysts for reforming and oxidation methods of catalyst synthesis and the effective utilization of fuel for both external and internal reforming processes. In this paper the recent progress in these areas of research is reviewed along with the reforming of liquid hydrocarbons from this an overview of the current best performing catalysts for the reforming and partial oxidizing of hydrocarbons for hydrogen production is summarized.

As the world’s largest integrated energy and chemicals company Saudi Aramco continues to invest in technologies and innovative business models to enable the sustainable use of hydrocarbon resources across the value chain.  In this podcast David Ledesma discusses with Yasser Mufti Vice President Strategy & Market Analysis Saudi Aramco about Saudi Aramco’s perspectives on hydrogen its opportunities and challenges. This wide-ranging interview discusses Saudi Aramco’s investment in new technologies and the sustainable use of its hydrocarbon resources before addressing the role of hydrogen in achieving a low emissions economy possible business models and the barriers to achieving hydrogen’s growth. The podcast then moves on to discuss ammonia carbon capture utilisation and storage finishing up with a forward-looking perspective on the vision for Saudi Aramco asking how will the company look in 2050 and specifically whether it will still be a hydrocarbon company?

The podcast can be found on their website

Objectives

The aim of this review is to establish which available literature may be of use as part of the HSE funded project which will investigate spontaneous ignition of accidental hydrogen releases (JR02071). It will identify  phenomena that have the potential to cause spontaneous ignition of releases of pressured hydrogen and identify literature that may be of use when formulating the experimental program.

Main Findings

The identification of important work that shows conclusive evidence of spontaneous ignition of hydrogen due to the failure of a boundary layer.

The Government’s recently published ‘Road to Zero’ strategy sets out objectives to electrify cars and reduce emissions from heavy goods vehicles (HGVs) through policies such as ending the sale of diesel and petrol cars and subsidising electric charging infrastructure. The CCC response to the strategy however stated that the proposed measures do not go far enough. New Government policies combined with action from industry will be required for mobility related carbon reduction targets to be met.<br/>Hydrogen has been identified by the Government and CCC as one potential solution. The CCC report on a possible future hydrogen economy recognises that in particular hydrogen may have an important role to play for long distance journeys and heavy goods transport. This view was echoed further in the recent CCC ‘Net Zero’ report.<br/>Cadent’s HyNet project will produce low carbon hydrogen through reformation of natural gas combined with carbon capture utilisation and storage (CCUS). HyNet has primarily been designed to supply low carbon heat to industry and a blend of hydrogen to Cadent’s existing natural gas network but also provides the opportunity to supply low cost hydrogen for mobility. The HyMotion project has considered the relative merits of such an approach modelled potential demand scenarios and sought to determine technical and commercial solutions to enable deployment.<br/>Hydrogen fuel cell electric vehicles (FCEVs) share powertrain technologies with battery electric vehicles (BEVs) but the roll-out of BEVs is currently ahead of FCEVs. This is largely due to a lack of low cost low carbon bulk hydrogen production and refuelling infrastructure both of which HyNet seeks to address.

The objective of the analysis is to provide a robust assessment of the economic impact of HyNet NW over the period to 2050 across both the North West of England and the UK as a whole. Impact is assessed through modelling of direct indirect and induced effect frameworks:

• Direct effects – activities that directly accrue due to the construction and operation of the facilities;
• Indirect effects – the purchase of goods and services to facilitate construction/operation; and
• Induced effects – spending of wages and salaries generated directly and indirectly through construction and operation.

The approach taken is to define the capital and operating expenditure (CAPEX and OPEX) profiles of the Project investment as the basis of analysis distinguishing where feasible between design construction and equipment costs and establishing the likely sourcing of these activities from within the North West UK and overseas.

Consideration is also given to the potential impacts of inward investment attracted to the North West/UK in the wake of the Project.

Hydrogen solutions have a critical role to play in the UK not only in helping the nation meet its net-zero target but in creating the economic growth and jobs that will kickstart the green recovery.

The Government must act now to ensure that the UK capitalises on the opportunity presented by hydrogen and builds a world-leading industry.

COVID-19 has caused significant economic upheaval across the country with unemployment expected to reach up to 14.8 per cent by the end of 20201. The UK must identify those areas of the economy which have significant economic growth potential and can deliver long-term and sustainable increases in GVA and jobs. It will be important to consider regional factors and ensure that investment is targeted in those areas that have been hardest hit by the crisis.

Many major economies have identified hydrogen as a key part of both decarbonisation and economic recovery. As part of its stimulus package Germany announced a €9billion investment in green hydrogen solutions aiming to deploy 5GW by 2030. The Hydrogen Council estimates a future hydrogen and equipment market worth $2.5 trillion globally by 2050 supporting 30 million new jobs.

Hydrogen offers the UK a pathway to deep cost-effective decarbonisation while delivering economic growth and job creation. It should therefore be at the heart of the Government’s green recovery programme ensuring that the UK builds back better and greener.

• Economic Impact Assessment Summary 
• Economic impact Assessment Methodology
• Economic impact Assessment of the Hydrogen Value Chain of the UK infographic
• Imperial College Consultants Review of the EIA.

A solid-state hydrogen storage material comprising ammonia borane (AB) and polyethylene oxide (PEO) has been produced by freeze-drying from aqueous solutions from 0% to 100% AB by mass. The phase mixing behaviour of AB and PEO has been investigated using X-ray diffraction which shows that a new ‘intermediate’ crystalline phase exists different from both AB and PEO as observed in our previous work (Nathanson et al. 2015). It is suggested that hydrogen bonding interactions between the ethereal oxygen atom (–O–) in the PEO backbone and the protic hydrogen atoms attached to the nitrogen atom (N–H) of AB molecules promote the formation of a reaction intermediate leading to lowered hydrogen release temperatures in the composites compared to neat AB. PEO also acts to significantly reduce the foaming of AB during hydrogen release. A temperature-composition phase diagram has been produced for the AB-PEO system to show the relationship between phase mixing and hydrogen release.

This paper presents a study undertaken on a naturally aspirated direct injection diesel engine investigating the combustion and emission characteristics of CH₄-CO₂  and CH₄-CO₂ -H₂ mixtures. These aspirated gas mixtures were pilot-ignited by diesel fuel while the engine load was varied between 0 and 7 bar IMEP by only adjusting the flow rate of the aspirated mixtures. The in-cylinder gas composition was also investigated when combusting CH₄-CO₂ and CH₄-CO₂-H₂ mixtures at different engine loads with in cylinder samples collected using two different sampling arrangements. The results showed a longer ignition delay period and lower peak heat release rates when the proportion of CO₂ was increased in the aspirated mixture. Exhaust CO₂ emissions were observed to be higher for 60 CH₄:40CO₂ mixture but lower for the 80CH₄:20CO₂ mixture as compared to diesel fuel only combustion at all engine loads. Both exhaust and in-cylinder NO_x levels were observed to decrease when the proportion of CO₂ was increased; NO_x levels increased when the proportion of H₂ was increased in the aspirated mixture. In-cylinder NO_x levels were observed to be higher in the region between the sprays as compared to within the spray core attributable to higher gas temperatures reached post ignition in that region.

Biomimetic sulfur-deficient indium sulfide (In_2.77S₄) was synthesized by a template-assisted hydrothermal method using leaves of Mimosa pudica as a template for the first time. The effect of this template in modifying the morphology of the semiconductor particles was determined by physicochemical characterization revealing an increase in surface area decrease in microsphere size and pore size and an increase in pore volume density in samples synthesized with the template. X-ray photoelectron spectroscopy (XPS) analysis showed the presence of organic sulfur (Ssingle bondO/Ssingle bondC/Ssingle bondH) and sulfur oxide species (single bondSO₂ SO₃²− SO₄²−) at the surface of the indium sulfide in samples synthesized with the template. Biomimetic indium sulfide also showed significant amounts of Fe introduced as a contaminant present on the Mimosa pudica leaves. The presence of these sulfur and iron species favors the photocatalytic activity for hydrogen production by their acting as a sacrificial reagent and promoting water oxidation on the surface of the templated particles respectively. The photocatalytic hydrogen production rates over optimally-prepared biomimetic indium sulfide and indium sulfide synthesized without the organic template were 73 and 22 μmol g⁻¹ respectively indicating an improvement by a factor of three in the templated sample.

Minimising tailpipe emissions and the decarbonisation of transport in a cost effective way remains a major objective for policymakers and vehicle manufacturers. Current trends are rapidly evolving but appear to be moving towards solutions in which vehicles which are increasingly electrified. As a result we will see a greater linkage between the wider energy system and the transportation sector resulting in a more complex and mutual dependency. At the same time major investments into technological innovation across both sectors are yielding rapid advancements into on-board energy storage and more compact/lightweight on-board electricity generators. In the absence of sufficient technical data on such technology holistic evaluations of the future transportation sector and its energy sources have not considered the impact of a new generation of innovation in propulsion technologies. In this paper the potential impact of a number of novel powertrain technologies are evaluated and presented. The analysis considers heavy duty vehicles with conventional reciprocating engines powered by diesel and hydrogen hybrid and battery electric vehicles and vehicles powered by hydrogen fuel cells and freepiston engine generators (FPEGs). The benefits are compared for each technology to meet the expectations of representative medium and heavy-duty vehicle drivers. Analysis is presented in terms of vehicle type vehicle duty cycle fuel economy greenhouse gas (GHG) emissions impact on the vehicle etc.. The work shows that the underpinning energy vector and its primary energy source are the most significant factor for reducing primary energy consumption and net CO₂ emissions. Indeed while an HGV with a BEV powertrain offers no direct tailpipe emissions it produces significantly worse lifecycle CO2 emissions than a conventional diesel powertrain. Even with a de-carbonised electricity system (100 g CO2/kWh) CO₂ emissions are similar to a conventional Diesel fuelled HGV. For the HGV sector range is key to operator acceptability of new powertrain technologies. This analysis has shown that cumulative benefits of improved electrical powertrains on-board storage efficiency improvements and vehicle design in 2025 and 2035 mean that hydrogen and electric fuelled vehicles can be competitive on gravimetric and volumetric density. Overall the work demonstrates that presently there is no common powertrain solution appropriate for all vehicle types but how subtle improvements at a vehicle component level can have significant impact on the design choices for the wider energy system.