United Kingdom
Are Scenarios of Hydrogen Vehicle Adoption Optimistic? A Comparison with Historical Analogies
Nov 2015
Publication
There is a large literature exploring possible hydrogen futures using various modelling and scenario approaches. This paper compares the rates of transition depicted in that literature with a set of historical analogies. These analogies are cases in which alternative-fuelled vehicles have penetrated vehicle markets. The paper suggests that the literature has tended to be optimistic about the possible rate at which hydrogen vehicles might replace oil-based transportation. The paper compares 11 historical adoptions of alternative fuel vehicles with 24 scenarios from 20 studies that depict possible hydrogen futures. All but one of the hydrogen scenarios show vehicle adoption faster than has occurred for hybrid electric vehicles in Japan the most successful market for hybrids. Several scenarios depict hydrogen transitions occurring at a rate faster than has occurred in any of the historic examples. The paper concludes that scenarios of alternative vehicle adoption should include more pessimistic scenarios alongside optimistic ones.
Performance Analysis of a Flexi-Fuel Turbine-Combined Free-Piston Engine Generator
Jul 2019
Publication
The turbine-combined free-piston engine generator (TCFPEG) is a hybrid machine generating both mechanical work from the gas turbine and electricity from the linear electric generator for battery charging. In the present study the system performance of the designed TCFPEG system is predicted using a validated numerical model. A parametric analysis is undertaken based on the influence of the engine load valve timing the number of linear generators adopted and different fuels on the system performance. It is found that when linear electric generators are connected with the free-piston gas turbine the bottom dead centre the peak piston velocity and engine operation frequency are all reduced. Very minimal difference on the in-cylinder pressure and the compressor pressure is observed while the peak pressure in the bounce chamber is reduced. When coupled with a linear electric generator the system efficiency can be improved to nearly 50% by optimising engine load and the number of the linear generators adopted in the TCFPEG system. The system is able to be operated with different fuels as the piston is not limited by a mechanical system; the output power and system efficiency are highest when hydrogen is used as the fuel.
Feasibility of Hydrogen Production from Steam Reforming of Biodiesel (FAME) Feedstock on Ni-supported Catalysts
Jan 2015
Publication
The catalytic steam reforming of biodiesel was examined over Ni-alumina and Ni–ceria–zirconia catalysts at atmospheric pressure. Effects of temperatures of biodiesel preheating/vaporising (190–365 ◦C) and reforming (600–800 ◦C) molar steam to carbon ratio (S/C = 2–3) and residence time in the reformer represented by the weight hourly space velocity ‘WHSV’ of around 3 were examined for 2 h. Ni supported on calcium aluminate and on ceria–zirconia supports achieved steady state hydrogen product stream within 90% of the equilibrium yields although 4% and 1% of the carbon feed had deposited on the catalysts respectively during the combined conditions of start-up and steady state. Addition of dopants to ceria–zirconia supported catalyst decreased the performance of the catalyst. Increase in S/C ratio had the expected positive effects of higher H2 yield and lower carbon deposition.
Cold Hydrogen Blowdown Release: An Inter-comparison Study
Sep 2021
Publication
Hydrogen dispersion in stagnant environment resulting from blowdown of a vessel storing the gas at cryogenic temperature is simulated using different CFD codes and modelling strategies. The simulations are based on the DISCHA experiments that were carried out by Karlsruhe Institute of Technology (KIT) and Pro-Science (PS). The selected test for the current study involves hydrogen release from a 2.815 dm3 volume tank with an initial pressure of 200 barg and temperature 80 K. During the release the hydrogen pressure in the tank gradually decreased. A total of about 139 gr hydrogen is released through a 4 mm diameter. The temperature time series and the temperature decay rate of the minimum value predicted by the different codes are compared with each other and with the experimentally measured ones. Recommendations for future experimental setup and for modeling approaches for similar releases are provided based on the present analysis. The work is carried out within the EU-funded project PRESLHY.
Producing Low Carbon Gas- Future Gas Series part 2
Jul 2018
Publication
Of all the sectors in the UK decarbonising heat remains one of the most challenging. Heat used for industrial domestic and commercial purposes generates around a third of all UK carbon emissions 70% of which is due to burning natural gas. In order to meet our legally binding national climate change targets unabated natural gas use for heat must be phased out. Low carbon gas - including hydrogen and biogases - is one option to replace it. The Future Gas Series examines the opportunities and challenges associated with using low carbon gas to help decarbonise the UK economy.<br/><br/>This is the second report in the three-part Future Gas Series. Part 1: Next Steps for the Gas Grid explored the potential to decarbonise the existing gas grid. The report Part 2: the Production of Low Carbon Gas focuses on the issues related to the production of low carbon gas. It considers the different production technologies the potential scale of deployment of each method and the potential feedstocks. It also discusses issues related to bulk transport and storage of gas. Put together from expert evidence from across industry and academia it provides a balanced guide for policy makers in this area. It was a co-chaired by James Heappey MP (Conservative) Alan Whitehead MP (Labour) and Alistair Carmichael MP (SNP).<br/><br/>Carbon Connect suggests that biogases- such as biomethane and bioSNG- provide low regrets opportunities in the near term to provide low carbon heat and could also potentially make use of waste that would otherwise go to landfill. However they require further support to allow them to continue contributing to decarbonising the UK economy. Hydrogen could provide huge decarbonisation opportunities and has applications across the energy system from putting hydrogen in the gas grid to be burnt for heat in homes to hydrogen buses and trains. However to realise this potential a market for hydrogen must be built up. This should incentivise business to invest in hydrogen technologies reward those who use hydrogen and build up hydrogen infrastructure.<br/><br/>
Financing Efficiency Evaluation and Influencing Factors of Hydrogen Energy Listed Enterprises in China
Jan 2022
Publication
Existing studies of financing efficiency concentrate on capital structure and a single external environment or internal management characteristic. Few of the studies include the internal and external financing environments at the same time for hydrogen energy industry financing efficiency. This paper used the data envelopment analysis (DEA) model and the Malmquist index to measure the financing efficiency of 70 hydrogen energy listed enterprises in China from 2014 to 2020 from both static and dynamic perspectives. Then a tobit model was constructed to explore the influence of external environment and internal factors on the financing efficiency. The contributions of this paper are studying the internal and external financing environments and integrating financing cost efficiency and capital allocation efficiency into the financing efficiency of hydrogen energy enterprises. The results show that firstly the financing efficiency of China’s hydrogen energy listed enterprises showed an upward trend during the years 2014–2020. Secondly China’s hydrogen energy enterprises mainly gather in the eastern coastal areas and their financing efficiency is more than that in western areas. Thirdly the regional economic development level enterprise scale financing structure capital utilization efficiency and profitability have significant effects on the financing efficiency. These results can promote the achievement of “carbon neutrality” in China.
Incorporating Homeowners' Preferences of Heating Technologies in the UK TIMES Model
Feb 2018
Publication
Hot water and space heating account for about 80% of total energy consumption in the residential sector in the UK. It is thus crucial to decarbonise residential heating to achieve UK's 2050 greenhouse gas reduction targets. However the decarbonisation transitions determined by most techno-economic energy system models might be too optimistic or misleading for relying on cost minimisation alone and not considering households' preferences for different heating technologies. This study thus proposes a novel framework to incorporate heterogeneous households' (HHs) preferences into the modelling process of the UK TIMES model. The incorporated preferences for HHs are based on a nationwide survey on homeowners' choices of heating technologies. Preference constraints are then applied to regulate the HHs' choices of heating technologies to reflect the survey results. Consequently compared to the least cost transition pathway the preference-driven pathway adopts heating technologies gradually without abrupt increases of market shares. Heat pumps and electric heaters are deployed much less than in the cost optimal result. Extensive district heating using low-carbon fuels and conservation measures should thus be deployed to provide flexibility for decarbonisation. The proposed framework can also incorporate preferences for other energy consumption technologies and be applied to other linear programming based energy system models.
China Progress on Renewable Energy Vehicles: Fuel Cells, Hydrogen and Battery Hybrid Vehicles
Dec 2018
Publication
Clean renewable energy for Chinese cities is a priority in air quality improvement. This paper describes the recent Chinese advances in Polymer Electrolyte Membrane (PEM) hydrogen-fuel-cell-battery vehicles including buses and trucks. Following the 2016 Chinese government plan for new energy vehicles bus production in Foshan has now overtaken that in the EU USA and Japan combined. Hydrogen infrastructure requires much advance to catch up but numbers of filling stations are now increasing rapidly in the large cities. A particular benefit in China is the large number of battery manufacturing companies which fit well into the energy storage plan for hybrid fuel cell buses. The first city to manufacture thousands of PEM-battery hybrid buses is Foshan where the Feichi (Allenbus) company has built a new factory next to a novel fuel cell production line capable of producing 500 MW of fuel cell units per year. Hundreds of these buses are running on local Foshan routes this year while production of city delivery trucks has also been substantial. Results for energy consumption of these vehicles are presented and fitted to the Coulomb theory previously delineated.
Net Zero Strategy: Build Back Greener
Oct 2021
Publication
Last year the Prime Minister set out his 10 point plan for a green industrial revolution laying the foundations for a green economic recovery from the impact of COVID-19 with the UK at the forefront of the growing global green economy.
This strategy builds on that approach to keep us on track for UK carbon budgets our 2030 Nationally Determined Contribution and net zero by 2050. It includes:
This strategy builds on that approach to keep us on track for UK carbon budgets our 2030 Nationally Determined Contribution and net zero by 2050. It includes:
- our decarbonisation pathways to net zero by 2050 including illustrative scenarios
- policies and proposals to reduce emissions for each sector
- cross-cutting action to support the transition.
Thermal Management System Architecture for Hydrogen-Powered Propulsion Technologies: Practices, Thematic Clusters, System Architectures, Future Challenges, and Opportunities
Jan 2022
Publication
The thermal management system architectures proposed for hydrogen-powered propulsion technologies are critically reviewed and assessed. The objectives of this paper are to determine the system-level shortcomings and to recognise the remaining challenges and research questions that need to be sorted out in order to enable this disruptive technology to be utilised by propulsion system manufacturers. Initially a scientometrics based co-word analysis is conducted to identify the milestones for the literature review as well as to illustrate the connections between relevant ideas by considering the patterns of co-occurrence of words. Then a historical review of the proposed embodiments and concepts dating back to 1995 is followed. Next feasible thermal management system architectures are classified into three distinct classes and its components are discussed. These architectures are further extended and adapted for the application of hydrogen-powered fuel cells in aviation. This climaxes with the assessment of the available evidence to verify the reasons why no hydrogen-powered propulsion thermal management system architecture has yet been approved for commercial production. Finally the remaining research challenges are identified through a systematic examination of the critical areas in thermal management systems for application to hydrogen-powered air vehicles’ engine cooling. The proposed solutions are discussed from weight cost complexity and impact points of view by a system-level assessment of the critical areas in the field.
A Critique on the UK's Net Zero Strategy
Dec 2022
Publication
Before the Covid-19 pandemic UK passed net-zero emission law legislation to become the first major economy in the world to end its contribution to global warming by 2050. Following the UK’s legislation to reach net-zero emissions a long-term strategy for transition to a net-zero target was published in 2021. The strategy is a technology-led and with a top-down approach. The intention is to reach the target over the next three decades. The document targets seven sectors to reduce emissions and include a wide range of policies and innovations for decarbonization. This paper aims to accomplish a much needed review of the strategy in heat and buildings part and cover the key related areas in future buildings standard heat pumps and use of hydrogen as elaborated in the strategy. For that purpose this research reviews key themes in the policy challenges recent advancement and future possibilities. It provides an insight on the overall development toward sustainability and decarbonization of built environment in the UK by 2050. A foresight model Future Wheels is also used to visualize the findings from the review and provide a clear picture of the potential impact of the policy.
A Review on Recent Progress in the Integrated Green Hydrogen Production Processes
Feb 2022
Publication
The thermochemical water‐splitting method is a promising technology for efficiently con verting renewable thermal energy sources into green hydrogen. This technique is primarily based on recirculating an active material capable of experiencing multiple reduction‐oxidation (redox) steps through an integrated cycle to convert water into separate streams of hydrogen and oxygen. The thermochemical cycles are divided into two main categories according to their operating temperatures namely low‐temperature cycles (<1100 °C) and high‐temperature cycles (<1100 °C). The copper chlorine cycle offers relatively higher efficiency and lower costs for hydrogen production among the low‐temperature processes. In contrast the zinc oxide and ferrite cycles show great potential for developing large‐scale high‐temperature cycles. Although several challenges such as energy storage capacity durability cost‐effectiveness etc. should be addressed before scaling up these technologies into commercial plants for hydrogen production. This review critically examines various aspects of the most promising thermochemical water‐splitting cycles with a particular focus on their capabilities to produce green hydrogen with high performance redox pairs stability and the technology maturity and readiness for commercial use.
Transitioning to Hydrogen
Jan 2020
Publication
The UK is investigating supplying hydrogen to homes and businesses instead of natural gas by “repurposing” the gas network. It presents a major engineering challenge which has never been done anywhere else in the world.
In a new report titled ‘Transitioning to hydrogen’ experts from a cross-professional engineering institution (PEI) working group including the IET have assessed the engineering risks and uncertainties and concluded there is no reason why repurposing the gas network to hydrogen cannot be achieved. But there are several engineering risks and uncertainties which need to be addressed.
In a new report titled ‘Transitioning to hydrogen’ experts from a cross-professional engineering institution (PEI) working group including the IET have assessed the engineering risks and uncertainties and concluded there is no reason why repurposing the gas network to hydrogen cannot be achieved. But there are several engineering risks and uncertainties which need to be addressed.
Governing the UK’s Transition to Decarbonised Heating: Lessons from a Systematic Review of Past and Ongoing Heat Transitions
May 2020
Publication
According to the UK’s Committee on Climate Change the economically efficient achievement of Government’s legally-binding carbon-reduction target will require full decarbonisation of all heat in buildings and the decarbonisation of most industrial heat over the next 20 to 30 years (BEIS 2018). This goliath task is not unprecedented. Indeed the scale of this transition is similar to the UK’s former transition from coal to natural gas heating. Albeit the rate of transition away from natural gas will certainly need to be greater than the rate of the transition toward natural gas to achieve net zero greenhouse gas emissions by 2050.<br/><br/>At present Government’s commitment stands in sharp contrast with its inaction on heat decarbonisation to date. Under pressure to progress this agenda Government has charged the Clean Heat Directorate with the task of outlining the process for determining the UK’s long-term heat policy framework to be published in the ‘Roadmap for policy on heat decarbonisation’ in the summer of 2020 (BEIS 2017). This report resulting from one of six EPSRC-funded secondments is designed to support early thinking on the roadmap by answering the research question: How can ‘Transitions’ research informs the roadmap for governing the UK’s heating transition?<br/><br/>‘Transitions’ research is an interdisciplinary field of study within the Social Sciences and Humanities that investigates the co-evolution of social and technological systems (such as the UK heating system) and the dynamics by which fundamental change in these systems occur. To investigate what insights this area of research may hold for the governance of the UK’s heat transition a systematic literature review was conducted focusing specifically on past and ongoing heat transitions across Europe.<br/><br/>The review uncovered learnings about the role of path dependency; power and politics; complexity; cross-sector interactions; multi-level governance; and intermediaries in shaping non-linear transitions toward renewable heat. This report illustrates each learning with real-world examples from case studies undertaken by Transitions researchers and concludes with a long list of policy and process-oriented governance recommendations for the UK Government.
Conceptual Propulsion System Design for a Hydrogen-powered Regional Train
Apr 2015
Publication
Many railway vehicles use diesel as their energy source but exhaust emissions and concerns about economical fuel supply demand alternatives. Railway electrification is not cost effective for some routes particularly low-traffic density regional lines. The journey of a regional diesel–electric train is simulated over the British route Birmingham Moor Street to Stratford-upon-Avon and return to establish a benchmark for the conceptual design of a hydrogen-powered and hydrogen-hybrid vehicle. A fuel cell power plant compressed hydrogen at 350 and 700 bar and metal-hydride storage are evaluated. All equipment required for the propulsion can be accommodated within the space of the original diesel– electric train while not compromising passenger-carrying capacity if 700 bar hydrogen tanks are employed. The hydrogen trains are designed to meet the benchmark journey time of 94 min and the operating range of a day without refuelling. An energy consumption reduction of 34% with the hydrogen-powered vehicle and a decrease of 55% with the hydrogen-hybrid train are achieved compared with the original diesel–electric. The well-to-wheel carbon dioxide emissions are lower for the conceptual trains: 55% decrease for the hydrogen-powered and 72% reduction for the hydrogen-hybrid assuming that the hydrogen is produced from natural gas.
Concepts for Improving Hydrogen Storage in Nanoporous Materials
Feb 2019
Publication
Hydrogen storage in nanoporous materials has been attracting a great deal of attention in recent years as high gravimetric H2 capacities exceeding 10 wt% in some cases can be achieved at 77 K using materials with particularly high surface areas. However volumetric capacities at low temperatures and both gravimetric and volumetric capacities at ambient temperature need to be improved before such adsorbents become practically viable. This article therefore discusses approaches to increasing the gravimetric and volumetric hydrogen storage capacities of nanoporous materials and maximizing the usable capacity of a material between the upper storage and delivery pressures. In addition recent advances in machine learning and data science provide an opportunity to apply this technology to the search for new materials for hydrogen storage. The large number of possible component combinations and substitutions in various porous materials including Metal-Organic Frameworks (MOFs) is ideally suited to a machine learning approach; so this is also discussed together with some new material types that could prove useful in the future for hydrogen storage applications.
On the Response of a Lean-premixed Hydrogen Combustor to Acoustic and Dissipative-dispersive Entropy Waves
May 2019
Publication
Combustion of hydrogen or hydrogen containing blends in gas turbines and industrial combustors can activate thermoacoustic combustion instabilities. Convective instabilities are an important and yet less investigated class of combustion instability that are caused by the so called “entropy waves”. As a major shortcoming the partial decay of these convective-diffusive waves in the post-flame region of combustors is still largely unexplored. This paper therefore presents an investigation of the annihilating effects due to hydrodynamics heat transfer and flow stretch upon the nozzle response. The classical compact analysis is first extended to include the decay of entropy waves and heat transfer from the nozzle. Amplitudes and phase shifts of the responding acoustical waves are then calculated for subcritical and supercritical nozzles subject to acoustic and entropic forcing. A relation for the stretch of entropy wave in the nozzle is subsequently developed. It is shown that heat transfer and hydrodynamic decay can impart considerable effects on the entropic response of the nozzle. It is further shown that the flow stretching effects are strongly frequency dependent. The results indicate that dissipation and dispersion of entropy waves can significantly influence their conversion to sound and therefore should be included in the entropy wave models.
Evaluation of Performance Characteristics of a Novel Hydrogen-fuelled Free-piston Engine Generator
Mar 2020
Publication
In this work we present the experimental results obtained from hydrogen fuelled spark-ignited dual piston free-piston engine generator (FPEG) prototype operated in two-stroke and four-stroke mode. The FPEG testing was successfully conducted at 3.7 compression ratio engine speed between 5 Hz and 11 Hz and with different equivalence ratios. The FPEG technical details experimental set-up and operational control are explained in detail. Performance indicators show that both equivalence ratio and engine speed affect the engine operation characteristics. For every set of specified FPEG parameters appropriate range of equivalence ratio is recommended to prevent unwanted disturbance to electric generator operation. Both two-stroke and four-stroke cycle mode were tested and the results showed different combustion characteristics with the two thermodynamic cycles. Four-stroke cycle mode could operate with indicated thermal efficiency gain up to 13.2% compared with the two-stroke cycle.
Hydrogen Effects in Non-ferrous Alloys: Discussion
Jun 2017
Publication
This is a transcript of the discussion session on the effects of hydrogen in the non-ferrous alloys of zirconium and titanium which are anisotropic hydride-forming metals. The four talks focus on the hydrogen embrittlement mechanisms that affect zirconium and titanium components which are respectively used in the nuclear and aerospace industries. Two specific mechanisms are delayed hydride cracking and stress corrosion cracking.
This article is a transcription of the recorded discussion of the session ‘Hydrogen in non-ferrous alloys’ at the Royal Society Discussion Meeting Challenges of Hydrogen in Metals 16–18 January 2017. The text is approved by the contributors. M.P. transcribed the session. M.A.S. assisted in the preparation of the manuscript.
Link to document download on Royal Society Website
This article is a transcription of the recorded discussion of the session ‘Hydrogen in non-ferrous alloys’ at the Royal Society Discussion Meeting Challenges of Hydrogen in Metals 16–18 January 2017. The text is approved by the contributors. M.P. transcribed the session. M.A.S. assisted in the preparation of the manuscript.
Link to document download on Royal Society Website
Bioanode as a Limiting Factor to Biocathode Performance in Microbial Electrolysis Cells
Mar 2017
Publication
The bioanode is important for a microbial electrolysis cell (MEC) and its robustness to maintain its catalytic activity affects the performance of the whole system. Bioanodes enriched at a potential of +0.2 V (vs. standard hydrogen electrode) were able to sustain their oxidation activity when the anode potential was varied from -0.3 up to +1.0 V. Chronoamperometric test revealed that the bioanode produced peak current density of 0.36 A/m2 and 0.37 A/m2 at applied potential 0 and +0.6 V respectively. Meanwhile hydrogen production at the biocathode was proportional to the applied potential in the range from -0.5 to -1.0 V. The highest production rate was 7.4 L H2/(m2 cathode area)/day at -1.0 V cathode potential. A limited current output at the bioanode could halt the biocathode capability to generate hydrogen. Therefore maximum applied potential that can be applied to the biocathode was calculated as -0.84 V without overloading the bioanode.
No more items...