United Kingdom
CFD Modeling OF LH2 Dispersion Using the ADREA-HF Code
Sep 2011
Publication
In the present work the computational fluid dynamics (CFD) code ADREA-HF has been applied to simulate the very recent liquefied hydrogen spill experiments performed by the Health Safety Laboratory (HSL). The experiment consists of four LH2 release trials over concrete at a fixed rate of 60 lt/min but with different release direction height and duration. In the modeling the hydrogen source was treated as a two phase jet enabling simultaneous modeling of pool formation spreading as well as hydrogen vapor dispersion. Turbulence was modeled with the standard k- model modified for buoyancy effects. The effect of solidification of the atmospheric humidity was taken into account. The predicted concentration at the experimental sensors? locations was compared with the observed one. The results from the comparison of the predicted concentration with and without solidification of the atmospheric humidity indicate that the released heat from the solidification affects significantly the buoyant behavior of the hydrogen vapor. Therefore the simulation with solidification of the atmospheric humidity is in better agreement with the experiment.
On Numerical Simulation of Liquefied and Gaseous Hydrogen Releases at Large Scales
Sep 2005
Publication
The large eddy simulation (LES) model developed at the University of Ulster has been applied to simulate releases of 5.11 m3 liquefied hydrogen (LH2) in open atmosphere and gaseous hydrogen (GH2) in 20-m3 closed vessel. The simulations of a spill of liquefied hydrogen confirmed the advantage of LES application to reproduce experimentally observed eddy structure of hydrogen-air cloud. The inclination angle of simulated cloud is close to experimentally reported 300. The processes of two phase hydrogen release and heat transfer were simplified by inflow of gaseous hydrogen with temperature 20 K equal to boiling point. It is shown that difference in inflow conditions geometry and grid resolution affects simulation results. It is suggested that phenomenon of air condensationevaporation in the cloud in temperature range 20-90 K should be accounted for in future. The simulations reproduced well experimental data on GH2 release and transport in 20-m3 vessel during 250 min including a phenomenon of hydrogen concentration growth at the bottom of the vessel. Higher experimental hydrogen concentration at the bottom is assumed to be due to non-uniformity of temperature of vessel walls generating additional convection. The comparison of convective and diffusion terms in Navie-Stokes equations has revealed that a value of convective term is more than order of magnitude prevail over a value of turbulent diffusion term. It is assumed that the hydrogen transport to the bottom of the vessel is driven by the remaining chaotic flow velocities superimposed on stratified hydrogen concentration field. Further experiments and simulations with higher accuracy have to be performed to confirm this phenomenon. It has been demonstrated that hydrogen-air mixture became stratified in about 1 min after release was completed. However one-dimensional models are seen not capable to reproduce slow transport of hydrogen during long period of time characteristic for scenarios such as leakage in a garage.
An Intercomparison Exercise on the Capabilities of CFD Models to Predict Deflagration of a Large-Scale H2-Air Mixture in Open Atmosphere
Sep 2005
Publication
This paper presents a compilation of the results supplied by HySafe partners participating in the Standard Benchmark Exercise Problem (SBEP) V2 which is based on an experiment on hydrogen combustion that is first described. A list of the results requested from participants is also included. The main characteristics of the models used for the calculations are compared in a very succinct way by using tables. The comparison between results together with the experimental data when available is made through a series of graphs. The results show quite good agreement with the experimental data. The calculations have demonstrated to be sensitive to computational domain size and far field boundary condition.
HyDeploy Gas Safe Webinar
Nov 2020
Publication
HyDeploy is a pioneering hydrogen energy project designed to help reduce UK CO2 emissions and reach the Government’s net zero target for 2050.
As the first ever live demonstration of hydrogen in homes HyDeploy aims to prove that blending up to 20% volume of hydrogen with natural gas is a safe and greener alternative to the gas we use now. It is providing evidence on how customers don’t have to change their cooking or heating appliances to take the blend which means less disruption and cost for them.
As the first ever live demonstration of hydrogen in homes HyDeploy aims to prove that blending up to 20% volume of hydrogen with natural gas is a safe and greener alternative to the gas we use now. It is providing evidence on how customers don’t have to change their cooking or heating appliances to take the blend which means less disruption and cost for them.
Can the Current EU Regulatory Framework Deliver Decarbonisation of Gas?
Jun 2020
Publication
This Energy Insight examines the current regulatory framework and challenges facing the natural gas industry (producers transporters suppliers and consumers) during the transition to a zero-carbon economy. The EU has declared its intention to be climate neutral by 2050 which means that the current level of natural gas usage will no longer be possible. However natural gas is a crucial component of energy supply representing 24 per cent of primary energy supply for the EU27+UK and 36 per cent of residential energy consumption. In some countries the use of natural gas is much higher – around 40 per cent of primary energy supply in Netherlands UK and Italy. The current framework impacting gas addresses two different market failures – natural monopolies for gas transportation and the externalities of Greenhouse Gas Emissions. The framework will not deliver decarbonisation of gas as it does not stimulate either supply or demand for alternatives such as hydrogen nor create the conditions to enable gas networks to transition to a decarbonised future. Policy makers need to prioritise their objectives to take account of the trade-offs involved in designing a new framework. Exclusion of certain low carbon technologies risks driving away investors and reduces the chances of targets being met whilst “picking winners” involves risks because of the many uncertainties involved such as future costs and time required to build new value chains.
Link to Document on Oxford Institute for Energy Studies website
Link to Document on Oxford Institute for Energy Studies website
Characterising Hydrogen Induced Cracking of Alloy 625+ Using Correlative SEM - EDX and NanoSIMS
Dec 2020
Publication
Hydrogen induced cracking behaviour of O&G nickel alloy 625+ (UNS N07716) was investigated. Deuterium was introduced electrochemically into samples by cathodic polarisation (3.5 wt.% NaCl.D2O) under different mechanical conditions. Subsequently deuterium distributions were mapped using NanoSIMS. Deuterium was used as an isotopic tracer instead of hydrogen to avoid the detection of hydrogen artefacts. Complimentary image analysis using scanning electron microscopy (SEM) and low voltage energy dispersive X-ray (EDX) allowed the identification of microstructural features corresponding to deuterium enrichments. The results provided experimental evidence of enrichments at dislocation slip bands (DSB) twin boundary and grain boundary features that include σ precipitates.
The Synergistic Effects of Alloying on the Performance and Stability of Co3Mo and Co7Mo6 for the Electrocatalytic Hydrogen Evolution Reaction
Oct 2020
Publication
Metal alloys have become a ubiquitous choice as catalysts for electrochemical hydrogen evolution in alkaline media. However scarce and expensive Pt remains the key electrocatalyst in acidic electrolytes making the search for earth-abundant and cheaper alternatives important. Herein we present a facile and efficient synthetic route towards polycrystalline Co3Mo and Co7Mo6 alloys. The single-phased nature of the alloys is confirmed by X-ray diffraction and electron microscopy. When electrochemically tested they achieve competitively low overpotentials of 115 mV (Co3Mo ) and 160 mV (Co7Mo6 ) at 10 mA cm−2 in 0.5 M H2SO4 and 120 mV (Co3Mo ) and 160 mV (Co7Mo6 ) at 10 mA cm−2 in 1 M KOH. Both alloys outperform Co and Mo metals which showed significantly higher overpotentials and lower current densities when tested under identical conditions confirming the synergistic effect of the alloying. However the low overpotential in Co3Mo comes at the price of stability. It rapidly becomes inactive when tested under applied potential bias. On the other hand Co7Mo6 retains the current density over time without evidence of current decay. The findings demonstrate that even in free-standing form and without nanostructuring polycrystalline bimetallic electrocatalysts could challenge the dominance of Pt in acidic media if ways for improving their stability were found.
Challenges to the Future of LNG: Decarbonisation, Affordability, and Profitability
Oct 2019
Publication
Decarbonisation should be very much on the radar of new LNG projects currently taking FID commissioning around 2024-25 and planning to operate up to 2050. The LNG community needs to replace an `advocacy’ message – based on the generality of emissions from combustion of natural gas being lower than from other fossil fuels – with certified data on carbon and methane emissions from specific elements of the value chain for individual projects. As carbon reduction targets tighten over the coming decade LNG cargoes which do not have value chain emissions certified by accredited authorities or which fail to meet defined emission levels run the risk of progressively being deemed to have a lower commercial value and eventually being excluded from jurisdictions with the strictest standards. There will be no place in this process for confidentiality; nothing less than complete transparency of data and methodologies will be acceptable.<br/>In relation to affordability prospects for new projects look much better than they did three years ago. Cost estimates for most new projects suggest that they will be able to deliver profitably to most established and anticipated import markets at or below the wholesale prices prevailing in those markets over the past decade although affordability in south Asian countries may be challenging. But new projects need to factor in costs related to future decarbonisation requirements in both exporting and importing countries. To the extent that LNG suppliers can meet standards through relatively low-cost offsets – forest projects low-cost biogas and biomethane – this may not greatly impact their commercial viability. However any requirement to transform methane into hydrogen with CCS in either the exporting or importing country would substantially impact project economics and the affordability of LNG relative to other energy choices.
Experimental Study of the Explosion Severity of Vented Methane/Hydrogen Deflagrations
Sep 2021
Publication
Adding hydrogen to mains natural gas has been identified as one of the main strategies to reduce CO2 emissions in the United Kingdom. This work aims to characterise the explosion severity of 80:20 v./v. methane/hydrogen blends (‘a blend’) and methane vented deflagrations. The explosion severity of homogenous mixtures was measured in a 15 m3 cubic steel chamber in which the relief area was provided by four windows and a door covered with polypropylene sheet. The pressure increase over time was characterised using piezo-resistive pressure transducers and the flame speed was estimated using ionisation probes installed in the walls of the enclosure. The explosion severity of both mixtures was determined for different equivalence ratios from lean to rich mixtures. The pressure over time presented very similar behaviour for both mixtures comprising multiple peaks divided into three main stages: a first stage related to a spherical confined explosion until the opening of the vent a second stage generated by increased combustion during venting and an oscillatory peak generated by acoustic disturbances with the enclosure. A slight increase in the first stage overpressure was observed for the blend in comparison with methane regardless of the equivalence ratio but no general trend in pressure was observed for other stages of the propagation. The effect of the blockage ratio on explosion severity was studied by adding metallic elements representing furniture in a room.
Intelligent Hydrogen Fuel Cell Range Extender for Battery Electric Vehicles
May 2019
Publication
Road transport is recognized as having a negative impact on the environment. Policy has focused on replacement of the internal combustion engine (ICE) with less polluting forms of technology including battery electric and fuel cell electric powertrains. However progress is slow and both battery and fuel cell based vehicles face considerable commercialization challenges. To understand these challenges a review of current electric battery and fuel cell electric technologies is presented. Based on this review this paper proposes a battery electric vehicle (BEV) where components are sized to take into account the majority of user requirements with the remainder catered for by a trailer-based demountable intelligent fuel cell range extender. The proposed design can extend the range by more than 50% for small BEVs and 25% for large BEVs (the extended range of vehicles over 250 miles) reducing cost and increasing efficiency for the BEV. It enables BEV manufacturers to design their vehicle battery for the most common journeys decreases charging time to provide convenience and flexibility to the drivers. Adopting a rent and drop business model reduces the demand on the raw materials bridging the gap in the amount of charging (refueling) stations and extending the lifespan for the battery pack.
Modifications in the Composition of CuO/ZnO/Al2O3 Catalyst for the Synthesis of Methanol by CO2 Hydrogenation
Jun 2021
Publication
Renewable methanol obtained from CO2 and hydrogen provided from renewable energy was proposed to close the CO2 loop. In industry methanol synthesis using the catalyst CuO/ZnO/Al2O3 occurs at a high pressure. We intend to make certain modification on the traditional catalyst to work at lower pressure maintaining high selectivity. Therefore three heterogeneous catalysts were synthesized by coprecipitation to improve the activity and the selectivity to methanol under mild conditions of temperature and pressure. Certain modifications on the traditional catalyst Cu/Zn/Al2O3 were employed such as the modification of the synthesis time and the addition of Pd as a dopant agent. The most efficient catalyst among those tested was a palladium-doped catalyst 5% Pd/Cu/Zn/Al2O3. This had a selectivity of 64% at 210 °C and 5 bar.
Sorption-enhanced Steam Methane Reforming for Combined CO2 Capture and Hydrogen Production: A State-of-the-Art Review
Oct 2021
Publication
The European Commission have just stated that hydrogen would play a major role in the economic recovery of post-COVID-19 EU countries. Hydrogen is recognised as one of the key players in a fossil fuel-free world in decades to come. However commercially practiced pathways to hydrogen production todays are associated with a considerable amount of carbon emissions. The Paris Climate Change Agreement has set out plans for an international commitment to reduce carbon emissions within the forthcoming decades. A sustainable hydrogen future would only be achievable if hydrogen production is “designed” to capture such emissions. Today nearly 98% of global hydrogen production relies on the utilisation of fossil fuels. Among these steam methane reforming (SMR) boasts the biggest share of nearly 3 50% of the global generation. SMR processes correspond to a significant amount of carbon emissions at various points throughout the process. Despite the dark side of the SMR processes they are projected to play a major role in hydrogen production by the first half of this century. This that a sustainable yet clean short/medium-term hydrogen production is only possible by devising a plan to efficiently capture this co-produced carbon as stated in the latest International Energy Agency (IEA) reports. Here we have carried out an in-depth technical review of the processes employed in sorption-enhanced steam methane reforming (SE-SMR) an emerging technology in low-carbon SMR for combined carbon capture and hydrogen production. This paper aims to provide an in-depth review on two key challenging elements of SE-SMR i.e. the advancements in catalysts/adsorbents preparation and current approaches in process synthesis and optimisation including the employment of artificial intelligence in SE-SMR processes. To the best of the authors‟ knowledge there is a clear gap in the literature where the above areas have been scrutinised in a systematic and coherent fashion. The gap is even more pronounced in the application of AI in SE-SMR technologies. As a result this work aims to fill this gap within the scientific literature.
Current Status of Automotive Fuel Cells for Sustainable Transport
May 2019
Publication
Automotive proton-exchange membrane fuel cells (PEMFCs) have finally reached a state of technological readiness where several major automotive companies are commercially leasing and selling fuel cell electric vehicles including Toyota Honda and Hyundai. These now claim vehicle speed and acceleration refueling time driving range and durability that rival conventional internal combustion engines and in most cases outperform battery electric vehicles. The residual challenges and areas of improvement which remain for PEMFCs are performance at high current density durability and cost. These are expected to be resolved over the coming decade while hydrogen infrastructure needs to become widely available. Here we briefly discuss the status of automotive PEMFCs misconceptions about the barriers that platinum usage creates and the remaining hurdles for the technology to become broadly accepted and implemented.
Which way to Net Zero? A Comparative Analysis of Seven UK 2050 Decarbonisation Pathways
Dec 2021
Publication
Since the UK’s Net Zero greenhouse gas emissions target was set in 2019 organisations across the energy systems community have released pathways on how we might get there – which end-use technologies are deployed across each sector of demand how our fossil fuel-based energy supply would be transferred to low carbon vectors and to what extent society must change the way it demands energy services. This paper presents a comparative analysis between seven published Net Zero pathways for the UK energy system collected from Energy Systems Catapult National Grid ESO Centre for Alternative Technology and the Climate Change Committee. The key findings reported are that (i) pathways that rely on less stringent behavioural changes require more ambitious technology development (and vice versa); (ii) electricity generation will increase by 51-160% to facilitate large-scale fuel-switching in heating and transport the vast majority of which is likely to be generated from variable renewable sources; (iii) hydrogen is an important energy vector in meeting Net Zero for all pathways providing 100-591 TWh annually by 2050 though the growth in demand is heavily dependent on the extent to which it is used in supplying heating and transport demand. This paper also presents a re-visited analysis of the potential renewable electricity generation resource in the UK. It was found that the resource for renewable electricity generation outstrips the UK’s projected 2050 electricity demand by a factor 12-20 depending on the pathway. As made clear in all seven pathways large-scale deployment of flexibility and storage is required to match this abundant resource to our energy demand.
A Review of the MSCA ITN ECOSTORE—Novel Complex Metal Hydrides for Efficient and Compact Storage of Renewable Energy as Hydrogen and Electricity
Mar 2020
Publication
Hydrogen as an energy carrier is very versatile in energy storage applications. Developments in novel sustainable technologies towards a CO2-free society are needed and the exploration of all-solid-state batteries (ASSBs) as well as solid-state hydrogen storage applications based on metal hydrides can provide solutions for such technologies. However there are still many technical challenges for both hydrogen storage material and ASSBs related to designing low-cost materials with low-environmental impact. The current materials considered for all-solid-state batteries should have high conductivities for Na+ Mg2+ and Ca2+ while Al3+-based compounds are often marginalised due to the lack of suitable electrode and electrolyte materials. In hydrogen storage materials the sluggish kinetic behaviour of solid-state hydride materials is one of the key constraints that limit their practical uses. Therefore it is necessary to overcome the kinetic issues of hydride materials before discussing and considering them on the system level. This review summarizes the achievements of the Marie Skłodowska-Curie Actions (MSCA) innovative training network (ITN) ECOSTORE the aim of which was the investigation of different aspects of (complex) metal hydride materials. Advances in battery and hydrogen storage materials for the efficient and compact storage of renewable energy production are discussed.
Delivering Clean Growth: CCUS Cost Challenge Taskforce Report
Jul 2018
Publication
An independent report by the CCUS Cost Challenge Taskforce setting out the industry’s view on how best to progress carbon capture usage and storage (CCUS) in the UK in order to enable the UK to have the option of deploying CCUS at scale during the 2030s subject to costs coming down sufficiently.
Investigating the Implications of a New-build Hybrid Power System for Roll-on/Roll-off Cargo Ships from a Sustainability Perspective – A Life Cycle Assessment Case Study
Aug 2016
Publication
Marine transport has been essential for international trade. Concern for its environmental impact was growing among regulators classification societies ship operators ship owners and other stakeholders. By applying life cycle assessment this article aimed to assess the impact of a new-build hybrid system (i.e. an electric power system which incorporated lithium ion batteries photovoltaic systems and cold-ironing) designed for Roll-on/Roll-off cargo ships. The study was carried out based on a bottom-up integrated system approach using the optimised operational profile and background information for manufacturing processes mass breakdown and end of life management plans. Resources such as metallic and non-metallic materials and energy required for manufacture operation maintenance dismantling and scrap handling were estimated. During operation 1.76 x 10^8 kg of marine diesel oil was burned releasing carbon monoxide carbon dioxide particulate matter hydrocarbons nitrogen oxides and sulphur dioxide which ranged 5–8 orders of magnitude. The operation of diesel gensets was the primary cause of impact categories that were relevant to particulate matter or respiratory inorganic health issues photochemical ozone creation eutrophication acidification global warming and human toxicity. Disposing metallic scrap was accountable for the most significant impact category ecotoxicity potential. The environmental benefits of the hybrid power system in most impact categories were verified in comparison with a conventional power system onboard cargo ships. The estimated results for individual impact categories were verified using scenario analysis. The study concluded that the life cycle of a new-build hybrid power system would result in significant impact on the environment human beings and natural reserves and therefore proper management of such a system was imperative.
Hydrogen Non-premixed Combustion in Enclosure with One Vent and Sustained Release: Numerical Experiments
Sep 2013
Publication
Numerical experiments are performed to understand different regimes of hydrogen non-premixed combustion in an enclosure with passive ventilation through one horizontal or vertical vent located at the top of a wall. The Reynolds averaged Navier–Stokes (RANS) computational fluid dynamics (CFD) model with a reduced chemical reaction mechanism is described in detail. The model is based on the renormalization group (RNG) k-ε turbulence model the eddy dissipation concept (EDC) model for simulation of combustion coupled with the 18-step reduced chemical mechanism (8 species) and the in-situ adaptive tabulation (ISAT) algorithm that accelerates the reacting flow calculations by two to three orders of magnitude. The analysis of temperature and species (hydroxyl hydrogen oxygen water) concentrations in time as well as the velocity through the vent shed a light on regimes and dynamics of indoor hydrogen fires. A well-ventilated fire is simulated in the enclosure at a lower release flow rate and complete combustion of hydrogen within the enclosure. Fire becomes under-ventilated at higher release flow rates with two different modes observed. The first mode is the external flame stabilised at the enclosure vent at moderate release rates and the second mode is the self-extinction of combustion inside and outside the enclosure at higher hydrogen release rates. The simulations demonstrated a complex reacting flow dynamics in the enclosure that leads to formation of the external flame or the self-extinction. The air intake into the enclosure at later stages of the process through the whole vent area is a characteristic feature of the self-extinction regime. This air intake is due to faster cooling of hot combustion products by sustained colder hydrogen leak compared to the generation of hot products by the ceasing chemical reactions inside the enclosure and hydrogen supply. In general an increase of hydrogen sustained release flow rate will change fire regime from the well-ventilated combustion within the enclosure through the external flame stabilised at the vent and finally to the self-extinction of combustion throughout the domain.
PEFC System Reactant Gas Supply Management and Anode Purging Strategy: An Experimental Approach
Jan 2022
Publication
In this report a 5 kW PEFC system running on dry hydrogen with an appropriately sized Balance of Plant (BoP) was used to conduct experimental studies and analyses of gas supply subsystems. The improper rating and use of BoP components has been found to increase parasitic loads which consequently has a direct effect on the polymer electrolyte fuel cell (PEFC) system efficiency. Therefore the minimisation of parasitic loads while maintaining desired performance is crucial. Nevertheless little has been found in the literature regarding experimental work on large stacks and BoP with the majority of papers concentrating on modelling. A particular interest of our study was the anode side of the fuel cell. Additionally the rationale behind the use of hydrogen anode recirculation was scrutinised and a novel anode purging strategy was developed and implemented. Through experimental modelling the use of cathode air blower was minimised since it was found to be the biggest contributor to the parasitic loads.
Heat and Buildings Strategy
Oct 2021
Publication
The heat and buildings strategy sets out the government’s plan to significantly cut carbon emissions from the UK’s 30 million homes and workplaces in a simple low-cost and green way whilst ensuring this remains affordable and fair for households across the country. Like the transition to electric vehicles this will be a gradual transition which will start by incentivizing consumers and driving down costs.<br/>There are about 30 million buildings in the UK. Heating these buildings contributes to almost a quarter of all UK emissions. Addressing the carbon emissions produced in heating and powering our homes workplaces and public buildings can not only save money on energy bills and improve lives but can support up to 240000 skilled green jobs by 2035 boosting the economic recovery levelling up across the country and ensuring we build back better.<br/>The heat and buildings strategy builds on the commitments made in Clean growth: transforming heating our Energy white paper and the Prime Minister’s 10 point plan. This strategy aims to provide a clear direction of travel for the 2020s set out the strategic decisions that need to be taken this decade and demonstrate how we plan to meet our carbon targets and remain on track for net zero by 2050.
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