United Kingdom
Effects of Oxidants on Hydrogen Spontaneous Ignition: Experiments and Modelling
Sep 2017
Publication
Experiments were performed on the influence of oxidants (air pure oxygen O2 and pure nitrous oxide N2O at atmospheric pressure) in the straight expansion tube after the burst disk on the hydrogen spontaneous ignition. The lowest pressure at which the spontaneous ignition is observed has been researched for a 4 mm diameter tube with a length of 10 cm for the two oxidant gases. The ignition phenomenon is observed with a high speed camera and the ex Read More
Framing Policy on Low Emissions Vehicles in Terms of Economic Gains: Might the Most Straightforward Gain be Delivered by Supply Chain Activity to Support Refuelling?
May 2018
Publication
A core theme of the UK Government's new Industrial Strategy is exploiting opportunities for domestic supply chain development. This extends to a special ‘Automotive Sector Deal’ that focuses on the shift to low emissions vehicles (LEVs). Here attention is on electric vehicle and battery production and innovation. In this paper we argue that a more straightforward gain in terms of framing policy around potential economic benefits may be made t Read More
Hydrogen Energy
Feb 2007
Publication
The problem of anthropogenically driven climate change and its inextricable link to our global society’s present and future energy needs are arguably the greatest challenge facing our planet. Hydrogen is now widely regarded as one key element of a potential energy solution for the twenty-first century capable of assisting in issues of environmental emissions sustainability and energy security. Hydrogen has the potential to provide for energy in transportat Read More
The Effect of Tube Internal Geometry on the Propensity to Spontaneous Ignition in Pressurized Hydrogen Release
Sep 2013
Publication
Spontaneous ignition of compressed hydrogen release through a length of tube with different internal geometries is numerically investigated using our previously developed model. Four types of internal geometries are considered: local contraction local enlargement abrupt contraction and abrupt enlargement. The presence of internal geometries was found to significantly increase the propensity to spontaneous ignition. Shock reflections fro Read More
Accelerating Innovation Towards Net Zero Emissions
Apr 2019
Publication
This report Accelerating innovation towards net zero commissioned by the Aldersgate Group and co-authored with Vivid Economics identifies out how the government can achieve a net zero target cost-effectively in a way that enables the UK to capture competitive advantages.The unique contribution of this report is to identify the lessons from successful and more rapid historical innovations and apply them to the challenge of meeting net zero emissio Read More
Ammonia-hydrogen Combustion in a Swirl Burner with Reduction of NOx Emissions
Sep 2019
Publication
Recently ammonia is being considered for fuelling gas turbines as a new sustainable source. It can undergo thermal cracking producing nitrogen hydrogen and unburned ammonia thus enabling the use of these chemicals most efficiently for combustion purposes. Ammonia being carbon-free may allow the transition towards a hydrogen economy. However one of the main constraints of this fuelling technique is that although the combustion of ammon Read More
Modelling a Kinetic Deviation of the Magnesium Hydrogenation Reaction at Conditions Close to Equilibrium
May 2019
Publication
A model has been derived for the magnesium hydrogenation reaction at conditions close to equilibrium. The reaction mechanism involves an adsorption element where the model is an extension of the Langmuir adsorption model. The concept of site availability (σs) is introduced whereby it has the capability to reduce the reaction rate. To improve representation of σs an adaptable semi-empirical equation has been developed. Supplement to the surface r Read More
A Comparison Study into Low Leak Rate Buoyant Gas Dispersion in a Small Fuel Cell Enclosure Using Plain and Louvre Vent Passive Ventilation Schemes
Sep 2017
Publication
The development of a ‘Hydrogen Economy’ will see hydrogen fuel cells used in transportation and the generation of power for buildings as part of a decentralised grid with low power units used in domestic and commercial environmental situations. Low power fuel cells will be housed in small protective enclosures which must be ventilated to prevent a build-up of hydrogen gas produced during normal fuel cell operation or a supply pipework leak. Read More
Synthesis of Activated Ferrosilicon-based Microcomposites by Ball Milling and their Hydrogen Generation Properties
Jan 2019
Publication
Ferrosilicon 75 a 50:50 mixture of silicon and iron disilicide has been activated toward hydrogen generation by processing using ball milling allowing a much lower concentration of sodium hydroxide (2 wt %) to be used to generate hydrogen from the silicon in ferrosilicon with a shorter induction time than has been reported previously. An activation energy of 62 kJ/mol was determined for the reaction of ball-milled ferrosilicon powder with sodium hydroxide sol Read More
HyDeploy Overview
May 2020
Publication
An overview of the HyDeploy project at Keele University where hydrogen is being blended with natural gas to demonstrate the feasibility of using hydrogen to heat our homes.
A Turbulent Combustion Model for Ignition of Rapidly Expanding Hydrogen Jets
Mar 2013
Publication
A turbulent combustion model based on the Linear Eddy Model for Large Eddy Simulation (LEM- LES) is currently proposed to study self-ignition events of rapidly expanding hydrogen jets. The model is a one-dimensional treatment of a diffusion-reaction system within each multi-dimensional LES cell. This reduces the expense of solving a complete multi-dimensional problem while preserving micro-scale hotspots and their effects on ignition. The curr Read More
Advanced Hydrogen and CO2 Capture Technology for Sour Syngas
Apr 2011
Publication
A key challenge for future clean power or hydrogen projects via gasification is the need to reduce the overall cost while achieving significant levels of CO2 capture. The current state of the art technology for capturing CO2 from sour syngas uses a physical solvent absorption process (acid gas removal–AGR) such as Selexol™ or Rectisol® to selectively separate H2S and CO2 from the H2. These two processes are expensive and require significant utility cons Read More
Bioanode and Biocathode Performance in a Microbial Electrolysis Cell
Jan 2017
Publication
The bioanode is important for a microbial electrolysis cell (MEC) and its robustness to maintain its catalytic activity affects the performance of the whole system. Bioanodes enriched at a potential of +0.2 V (vs. standard hydrogen electrode) were able to sustain their oxidation activity when the anode potential was varied from 0.3 up to +1.0 V. Chronoamperometric test revealed that the bioanode produced peak current density of 0.36 A/m2 and 0.37 A/ Read More
Accumulation of Hydrogen Released into a Vented Enclosure - Experimental Results
Sep 2013
Publication
This paper reports experimental results from a series of experiments in which gaseous hydrogen was released into a 31 m3 enclosure and the hydrogen concentrations at a number of points within the enclosure were monitored to assess whether hydrogen accumulation occurred and whether a homogeneous or stratified mixture was formed. The enclosure was located in the open air and therefore subject to realistic and therefore variable wind conditio Read More
Safety and Regulatory Challenges of Using Hydrogen/Natural Gas Blends in the UK
Sep 2019
Publication
The addition of hydrogen to natural gas for heating and cooking is being considered as a route to reducing carbon emissions in the United Kingdom (UK). The HyDeploy programme (hereafter referred to as HyDeploy) aims to demonstrate that hydrogen can be added to the natural gas supply without compromising public safety or appliance performance. This paper relates to the preparatory work for hydrogen injection on a live site at Keele University closed Read More
Hydrogen Wide Area Monitoring of LH2 Releases
Sep 2019
Publication
The characterization of liquid hydrogen (LH2) releases has been identified as an international research priority to expand the safe use of hydrogen as an energy carrier. The elucidation of LH2 release behavior will require the development of dispersion and other models guided and validated by empirical field measurements such as those afforded by Hydrogen Wide Area Monitoring (HyWAM). HyWAM can be defined as the quantitative spatial and tempo Read More
Political, Economic and Environmental Concerns: Discussion
Jun 2017
Publication
This session concerned the political economic and environmental impact on the hydrogen economy due to hydrogen embrittlement.This article is a transcription of the recorded discussion of ‘Political economic and environmental concerns’ at the Royal Society Scientific Discussion Meeting Challenges of Hydrogen and Metals 16–18 January 2017. The text is approved by the contributors. G.C.G.S. transcribed the session and F.F.D. assisted in the prep Read More
HyDeploy Webinar - Unlocking the Deployment of Hydrogen in the Grid
May 2020
Publication
A project overview of HyDeploy project led by Cadent Gas and supported by Northern Gas Networks Progressive Energy Ltd Keele University HSE – Science Division and ITM Power.First Phase:HyDeploy at Keele is the first stage of this three stage programme. In November 2019 the UK Health & Safety Executive gave permission to run a live test of blended hydrogen and natural gas on part of the private gas network at Keele University campus in Staffords Read More
Status of the Pre-normative Research Project PRESLHY for the Safe Use of LH2
Sep 2019
Publication
Liquid hydrogen (LH2) compared to compressed gaseous hydrogen offers advantages for large scale transport and storage of hydrogen with higher densities and potentially better safety performance. Although the gas industry has good experience with LH2 only little experience is available for the new applications of LH2 as an energy carrier. Therefore the European FCH JU funded project PRESLHY conducts pre-normative research for the safe use of cryoge Read More
Fire Tests Carried Out in FCH JU FIRECOMP Project, Recommendations and Application to Safety of Gas Storage Systems
Sep 2017
Publication
In the event of a fire composite pressure vessels behave very differently from metallic ones: the material is degraded potentially leading to a burst without significant pressure increase. Hence such objects are when necessary protected from fire by using thermally-activated devices (TPRD) and standards require testing cylinder and TPRD together. The pre-normative research project FireComp aimed at understanding better the conditions which may lead t Read More
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