Germany

The paper presents the first outcomes of the experimental numerical and theoretical studies performed in the funded by Fuel Cell and Hydrogen Joint Undertaking (FCH2 JU) project HyTunnel-CS. The project aims to conduct pre-normative research (PNR) to close relevant knowledge gaps and technological bottlenecks in the provision of safety of hydrogen vehicles in underground transportation systems. Pre normative research performed in the project will ultimately result in three main outputs: harmonised recommendations on response to hydrogen accidents recommendations for inherently safer use of hydrogen vehicles in underground traffic systems and recommendations for RCS. The overall concept behind this project is to use inter-disciplinary and inter-sectoral prenormative research by bringing together theoretical modelling and experimental studies to maximise the impact. The originality of the overall project concept is the consideration of hydrogen vehicle and underground traffic structure as a single system with integrated safety approach. The project strives to develop and offer safety strategies reducing or completely excluding hydrogen-specific risks to drivers passengers public and first responders in case of hydrogen vehicle accidents within the currently available infrastructure.

Hydrogen storage in depleted gas fields is a promising option for the large-scale storage of excess renewable energy. In the framework of the hydrogen storage assessment for the “Underground Sun Storage” project we conduct a multi-step geochemical modelling approach to study fluid–rock interactions by means of equilibrium and kinetic batch simulations. With the equilibrium approach we estimate the long-term consequences of hydrogen storage whereas kinetic models are used to investigate the interactions between hydrogen and the formation on the time scales of typical storage cycles. The kinetic approach suggests that reactions of hydrogen with minerals become only relevant over timescales much longer than the considered storage cycles. The final kinetic model considers both mineral reactions and hydrogen dissolution to be kinetically controlled. Interactions among hydrogen and aqueous-phase components seem to be dominant within the storage-relevant time span. Additionally sensitivity analyses of hydrogen dissolution kinetics which we consider to be the controlling parameter of the overall reaction system were performed. Reliable data on the kinetic rates of mineral dissolution and precipitation reactions specifically in the presence of hydrogen are scarce and often not representative of the studied conditions. These uncertainties in the kinetic rates for minerals such as pyrite and pyrrhotite were investigated and are discussed in the present work. The proposed geochemical workflow provides valuable insight into controlling mechanisms and risk evaluation of hydrogen storage projects and may serve as a guideline for future investigations.

Operators of public electricity grids today are faced with the challenge of integrating increasing numbers of renewable and decentralized energy sources such as wind turbines and photovoltaic power plants into their grids. These sources produce electricity in a very inconstant manner due to the volatility of wind and solar power which further complicates power grid control and management. One key component that is required for modern energy infrastructures is the capacity to store large amounts of energy in an economically feasible way.<br/>One solution that is being discussed in this context is “power-to-gas” i.e. the use of surplus electricity to produce hydrogen (or even methane with an additional methanation process) which is then injected into the public natural gas grid. The huge storage capacity of the gas grid would serve as a buffer offering benefits with regards to sustainability and climate protection while also being cost-effective since the required infrastructure is already in place.<br/>One consequence would be however that the distributed natural gas could contain larger and fluctuating amounts of hydrogen. There is some uncertainty how different gas-fired applications and processes react to these changes. While there have already been several investigations for domestic appliances (generally finding that moderate amounts of H2 do not pose any safety risks which is the primary focus of domestic gas utilization) there are still open questions concerning large-scale industrial gas utilization. Here in addition to operational safety factors like efficiency pollutant emissions (NOX) process stability and of course product quality have to be taken into account.<br/>In a German research project Gas- und Wärme-Institut Essen e. V. (GWI) investigated the impact of higher and fluctuating hydrogen contents (up to 50 vol.-% much higher than what is currently envisioned) on a variety of industrial combustion systems using both numerical and experimental methods. The effects on operational aspects such as combustion behavior flame monitoring and pollutant emissions were analyzed.<br/>Some results of these investigations will be presented in this contribution.

Hydrogen storage is expected to play a crucial role in the comprehensive defossilization of energy systems. In this context the focus is typically on underground hydrogen storage (e.g. in salt caverns). However aboveground storage which is independent of geological conditions and might offer other technical advantages could provide systemic benefits and thereby gain shares in the hydrogen storage market. Against this background this paper examines the market relevance of aboveground compared to underground hydrogen storage. Using the opensource energy system model and optimization framework of Europe PyPSA-Eur the influence of geological independence storage cost relations and technical storage characteristics (i.e. efficiencies) on mentioned market relevance of aboveground hydrogen storage are investigated. Further the expectable market relevance based on current cost projections for the future is assessed. The studies show that in terms of hydrogen capacities aboveground hydrogen storage plays a considerably smaller role compared to underground hydrogen storage. Even when assuming comparatively low aboveground storage cost it will not exceed 1.7% (1.9 TWhH2LHV) of total hydrogen storage capacities in a cost-optimal European energy system. Regarding the amounts of annually stored hydrogen aboveground storage could play a larger role reaching a maximum share of 32.5% (168 TWhH2 LHV a-1) of total stored hydrogen throughout Europe. However these shares are only achievable for low cost storage in particularly suited energy system supply configurations. For higher aboveground storage costs or lower efficiencies shares drop below 10% sharply. The analysis identifies some especially influential factors for achieving higher market relevance. Besides storage costs the demand-orientation of a particular aboveground storage system (e.g. hydrogen storage at demand pressure levels) plays an essential role in market relevance. Further overall efficiency can be a beneficial factor. Still current projections of future techno-economic characteristics show that aboveground hydrogen storage is too expensive or too inefficient compared to underground storage. Therefore to achieve notable market relevance rather drastic cost reductions beyond current expectations would be needed for all assessed aboveground hydrogen storage technologies.

Replacing fossil fuels with energy sources and carriers that are sustainable environmentally benign and affordable is amongst the most pressing challenges for future socio-economic development. To that goal hydrogen is presumed to be the most promising energy carrier. Electrocatalytic water splitting if driven by green electricity would provide hydrogen with minimal CO2 footprint. The viability of water electrolysis still hinges on the availability of durable earth-abundant electrocatalyst materials and the overall process efficiency. This review spans from the fundamentals of electrocatalytically initiated water splitting to the very latest scientific findings from university and institutional research also covering specifications and special features of the current industrial processes and those processes currently being tested in large-scale applications. Recently developed strategies are described for the optimisation and discovery of active and durable materials for electrodes that ever-increasingly harness first principles calculations and machine learning. In addition a technoeconomic analysis of water electrolysis is included that allows an assessment of the extent to which a large-scale implementation of water splitting can help to combat climate change. This review article is intended to cross-pollinate and strengthen efforts from fundamental understanding to technical implementation and to improve the ‘junctions’ between the field’s physical chemists materials scientists and engineers as well as stimulate much-needed exchange among these groups on challenges encountered in the different domains.

The Carbon2Chem project aims to convert exhaust gases from the steel industry into chemicals such as methanol to reduce CO2 emissions. Here H2 is required for the conversion of CO2 into methanol. Although much effort is put to produce H2 from renewables the use of fossil fuels especially natural gas seems to be fundamental in the short term. For this reason the development of clean technologies for the processing of natural gas with a low environmental impact has become a topic of utmost importance. In this context methane pyrolysis has received special attention to produce CO2-free H2.

Hydrogen fuel cell vehicles can complement other electric vehicle technologies as a zeroemission technology and contribute to global efforts to achieve the emission reduction targets. This article spotlights the current deployment status of fuel cells in road transport. For this purpose data collection was performed by the Advanced Fuel Cells Technology Collaboration Programme. Moreover the available incentives for purchasing a fuel cell vehicle in different countries were reviewed and future perspectives summarized. Based on the collected information the development trends in the last five years were analyzed and possible further trends that could see the realization of the defined goals derived. The number of registered vehicles was estimated to be 51437 units with South Korea leading the market with 90% of the vehicles being concentrated in four countries. A total of 729 hydrogen refueling stations were in operation with Japan having the highest number of these. The analysis results clearly indicate a very positive development trend for fuel cell vehicles and hydrogen refueling stations in 2021 with the highest number of new vehicles and stations in a single year paralleling the year’s overall economic recovery. Yet a more ambitious ramp-up in the coming years is required to achieve the set targets.

The production of fat steel products is commonly linked to highly integrated sites which include hot metal generation via the blast furnace basic oxygen furnace (BOF) continuous casting and subsequent hot-rolling. In order to reach carbon neutrality a shift away from traditional carbon-based metallurgy is required within the next decades. Direct reduction (DR) plants are capable to support this transition and allow even a stepwise reduction in CO2 emissions. Nevertheless the implementation of these DR plants into integrated metallurgical plants includes various challenges. Besides metallurgy product quality and logistics special attention is given on future energy demand. On the basis of carbon footprint methodology (ISO 14067:2019) diferent scenarios of a stepwise transition are evaluated and values of possible CO2equivalent (CO2eq) reduction are coupled with the demand of hydrogen electricity natural gas and coal. While the traditional blast furnace—BOF route delivers a surplus of electricity in the range of 0.7 MJ/kg hot-rolled coil; this surplus turns into a defcit of about 17 MJ/ kg hot-rolled coil for a hydrogen-based direct reduction with an integrated electric melting unit. On the other hand while the product carbon footprint of the blast furnace-related production route is 2.1 kg CO2eq/kg hot-rolled coil; this footprint can be reduced to 0.76 kg CO2eq/kg hot-rolled coil for the hydrogen-related route provided that the electricity input is from renewable energies. Thereby the direct impact of the processes of the integrated site can even be reduced to 0.15 kg CO2eq/ kg hot-rolled coil. Yet if the electricity input has a carbon footprint of the current German or European electricity grid mix the respective carbon footprint of hot-rolled coil even increases up to 3.0 kg CO2eq/kg hot-rolled coil. This underlines the importance of the availability of renewable energies.

In contrast to sustainable aviation fuels for use in conventional combustion engines hydrogen-electric powertrains constitute a fundamentally novel approach that requires extensive effort from various engineering disciplines. A transient system analysis has been applied to a 500 kW shaft-power-class powertrain. The model was fed with high-level system requirements to gain a fundamental understanding of the interaction between sub-systems and components. Transient effects such as delays in pressure build up heat transfer and valve operation substantially impact the safe and continuous operation of the propulsion system throughout a typical mission profile which is based on the Daher TBM850. The lumped-parameters network solver provides results quickly which are used to derive requirements for subsystems and components which support their in-depth future development. E.g. heat exchanger transfer rates and pressure drop of the motor's novel hydrogen cooling system are established. Furthermore improvements to the system architecture such as a compartmentalization of the tank are identified.

Hydrogen is one of the most promising power sources for meeting the aviation sector’s long-term decarbonization goals. Although on-board hydrogen systems namely fuel cells are extensively researched the maintenance repair and overhaul (MRO) perspective remains mostly unaddressed. This paper analyzes fuel cells from an MRO standpoint based on a literature review and comparison with the automotive sector. It also examines how well the business models and key resources of MRO providers are currently suited to provide future MRO services. It is shown that fuel cells require extensive MRO activities and that these are needed to meet the aviation sector’s requirements for price safety and especially durability. To some extent experience from the automotive sector can be built upon particularly with respect to facility requirements and qualification of personnel. Yet MRO providers’ existing resources only partially allow them to provide these services. MRO providers’ underlying business models must adapt to the implementation of fuel cells in the aviation sector. MRO providers and services should therefore be considered and act as enablers for the introduction of fuel cells in the aviation industry.