Australia
Zone Negligible Extent: Example of Specific Detailed Risk Assessment for Low Pressure Equipment in a Hydrogen Refuelling Station
Sep 2023
Publication
The MultHyFuel project aims to develop evidence-based guidelines for the safe implementation of Hydrogen Refueling Stations (HRS) in a multi-fuel context. As a part of the generation of good practice guidelines for HRS Hazardous Area Classification (HAC) methodologies were analyzed and applied to case studies representing example configurations of HRS. It has been anticipated that Negligible Extent (NE) classifications might be applicable for sections of the HRS for instance a hydrogen generator. A NE zone requires that an ignition of a flammable cloud would result in negligible consequences. In addition depending on the pressure of the system IEC 60079-10-1:2020 establishes specific requirements in order to classify the hazardous area as being of NE. One such requirement is that a zone of NE shall not be applied for releases from flammable gas systems at pressures above 2000 kPag (20 barg) unless a specific detailed risk assessment is documented. However there is no definition within the standard as to the requirements of the specific detailed risk assessment. In this work an example for a specific detailed risk assessment for the NE classification is presented:<br/>• Firstly the requirements of cloud volume dilution and background concentration for a zone of NE classification from IEC 60079-10-1:2020 are analyzed for hydrogen releases from equipment placed in a mechanically ventilated enclosure.<br/>• Secondly the consequences arising from the ignition of the localized cloud are estimated and compared to acceptable harm criteria in order to assess if negligible consequences are obtained from the scenario.<br/>• In addition a specific qualitative risk assessment for the ignition of the cloud in the enclosure was considered incorporating the estimated consequences and analyzing the available safeguards in the example system.<br/>Recommendations for the specific detailed risk assessment are proposed for this scenario with the intention to support improved definition of the requirement in future revisions of IEC 60079-10-1.
Towards Energy Freedom: Exploring Sustainable Solutions for Energy Independence and Self-sufficiency using Integrated Renewable Energy-driven Hydrogen System
Jan 2024
Publication
n the pursuit of sustainable energy solutions the integration of renewable energy sources and hydrogen technologies has emerged as a promising avenue. This paper introduces the Integrated Renewable Energy-Driven Hydrogen System as a holistic approach to achieve energy independence and self-sufficiency. Seamlessly integrating renewable energy sources hydrogen production storage and utilization this system enables diverse applications across various sectors. By harnessing solar and/or wind energy the Integrated Renewable EnergyDriven Hydrogen System optimizes energy generation distribution and storage. Employing a systematic methodology the paper thoroughly examines the advantages of this integrated system over other alternatives emphasizing its zero greenhouse gas emissions versatility energy resilience and potential for large-scale hydrogen production. Thus the proposed system sets our study apart offering a distinct and efficient alternative compared to conventional approaches. Recent advancements and challenges in hydrogen energy are also discussed highlighting increasing public awareness and technological progress. Findings reveal a payback period ranging from 2.8 to 6.7 years depending on the renewable energy configuration emphasizing the economic attractiveness and potential return on investment. This research significantly contributes to the ongoing discourse on renewable energy integration and underscores the viability of the Integrated Renewable EnergyDriven Hydrogen System as a transformative solution for achieving energy independence. The employed model is innovative and transferable to other contexts.
Artificial Intelligence/Machine Learning in Energy Management Systems, Control, and Optimization of Hydrogen Fuel Cell Vehicles
Mar 2023
Publication
Environmental emissions global warming and energy-related concerns have accelerated the advancements in conventional vehicles that primarily use internal combustion engines. Among the existing technologies hydrogen fuel cell electric vehicles and fuel cell hybrid electric vehicles may have minimal contributions to greenhouse gas emissions and thus are the prime choices for environmental concerns. However energy management in fuel cell electric vehicles and fuel cell hybrid electric vehicles is a major challenge. Appropriate control strategies should be used for effective energy management in these vehicles. On the other hand there has been significant progress in artificial intelligence machine learning and designing data-driven intelligent controllers. These techniques have found much attention within the community and state-of-the-art energy management technologies have been developed based on them. This manuscript reviews the application of machine learning and intelligent controllers for prediction control energy management and vehicle to everything (V2X) in hydrogen fuel cell vehicles. The effectiveness of data-driven control and optimization systems are investigated to evolve classify and compare and future trends and directions for sustainability are discussed.
Stable Electrolytic Hydrogen Production Using Renewable Energy
Oct 2024
Publication
The inherent intermittency of upstream solar and wind power can result in fluctuating electrolytic hydrogen production which is incompatible with the feedstock requirements of many downstream hydrogen storage and utilisation applications. Suitable backup power or storage (hydrogen or energy) strategies are thus needed in overall system design. This work conducts technoeconomic modelling to design electrolytic production systems featuring stable hydrogen output for various locations across Australia based on hourly weather data and determines the levelised cost of hydrogen (LCOH) emissions intensities and annual electrolyser usage factors. A stable truly green hydrogen supply is consistently achieved by imposing annual usage factor requirements on the system which forces the system modules (i.e. solar wind electrolyser and hydrogen storage) to be oversized in order to achieve the desired usage factor. Whilst the resultant system designs are however very location-specific a design that ensures a 100% usage factor costs approximately 22% more on average than a system design which is optimised for cost alone.
Green Energy Revolution and Substitution of Hydrocarbons with Hydrogen: Distribution Network Infrastructure Materials
Dec 2023
Publication
Global warming is an accepted fact of life on Earth posing grave consequences in the form of weather patterns with life-threatening outcomes for inhabitants and their cultures especially those of island countries. These wild and unpredictable weather patterns have persuaded authorities governments and industrial leaders to adapt a range of solutions to combat the temperature rise on Earth. One such solution is to abandon fossil fuels (hydrocarbons) for energy generation and employ renewable energy sources or at least use energy sources that do not generate greenhouse gases. One such energy carrier is hydrogen which is expected to slowly replace natural gas and will soon be pumped into the energy distribution pipeline network. Since the current energy distribution network was designed for hydrocarbons its use for hydrogen may pose some threat to the safety of urban society. This is the first time an overview article has examined the replacement of hydrocarbons by hydrogen from a totally different angle by incorporating material science viewpoints. This article discusses hydrogen properties and warns about the issue of hydrogen embrittlement in the current pipeline network if hydrogen is to be pumped through the current energy distribution network i.e. pipelines. It is recommended that sufficient study and research be planned and carried out to ensure the safety of using the current energy distribution network for hydrogen distribution and to set the necessary standards and procedures for future design and construction.
Hydrogen Liquefaction: A Review of the Fundamental Physics, Engineering Practice and Future Opportunities
Apr 2022
Publication
Hydrogen is emerging as one of the most promising energy carriers for a decarbonised global energy system. Transportation and storage of hydrogen are critical to its large-scale adoption and to these ends liquid hydrogen is being widely considered. The liquefaction and storage processes must however be both safe and efficient for liquid hydrogen to be viable as an energy carrier. Identifying the most promising liquefaction processes and associated transport and storage technologies is therefore crucial; these need to be considered in terms of a range of interconnected parameters ranging from energy consumption and appropriate materials usage to considerations of unique liquid-hydrogen physics (in the form of ortho–para hydrogen conversion) and boil-off gas handling. This study presents the current state of liquid hydrogen technology across the entire value chain whilst detailing both the relevant underpinning science (e.g. the quantum behaviour of hydrogen at cryogenic temperatures) and current liquefaction process routes including relevant unit operation design and efficiency. Cognisant of the challenges associated with a projected hydrogen liquefaction plant capacity scale-up from the current 32 tonnes per day to greater than 100 tonnes per day to meet projected hydrogen demand this study also reflects on the next-generation of liquid-hydrogen technologies and the scientific research and development priorities needed to enable them.
Hydrogen Storage Performance During Underground Hydrogen Storage in Depleted Gas Reservoirs: A Review
Mar 2024
Publication
Hydrogen has emerged as a promising alternative to meet the growing demand for sustainable and renewable energy sources. Underground hydrogen storage (UHS) in depleted gas reservoirs holds significant potential for large-scale energy storage and the seamless integration of intermittent renewable energy sources due to its capacity to address challenges associated with the intermittent nature of renewable energy sources ensuring a steady and reliable energy supply. Leveraging the existing infrastructure and well-characterized geological formations depleted gas reservoirs offer an attractive option for large-scale hydrogen storage implementation. However significant knowledge gaps regarding storage performance hinder the commercialization of UHS operation. Hydrogen deliverability hydrogen trapping and the equation of state are key areas with limited understanding. This literature review critically analyzes and synthesizes existing research on hydrogen storage performance during underground storage in depleted gas reservoirs; it then provides a high-level risk assessment and an overview of the techno-economics of UHS. The significance of this review lies in its consolidation of current knowledge highlighting unresolved issues and proposing areas for future research. Addressing these gaps will advance hydrogen-based energy systems and support the transition to a sustainable energy landscape. Facilitating efficient and safe deployment of UHS in depleted gas reservoirs will assist in unlocking hydrogen’s full potential as a clean and renewable energy carrier. In addition this review aids policymakers and the scientific community in making informed decisions regarding hydrogen storage technologies.
Shorter Message, Stronger Framing Increases Societal Acceptance for Hydrogen
Feb 2024
Publication
With the question of ‘can short messages be effective in increasing public support for a complex new technology (hydrogen)?‘ this study uses a representative national survey in Australia to analyze the differences and variations in subjective support for hydrogen in response to four differently framed short messages. The findings of this study show that short messages can increase social acceptance but the effects depend on how strongly the message is framed in terms of its alignment with either an economic or environmental values framework. Furthermore the effects depend on the social and cultural context of the receiver of the message.
A Review of Gas Phase Inhibition of Gaseous Hydrogen Embrittlement in Pipeline Steels
Feb 2024
Publication
The addition of small amounts of certain gases such as O2 CO and SO2 may mitigate hydrogen embrittlement in high-pressure gas transmission pipelines that transport hydrogen. To practically implement such inhibition in gas transmission pipelines a comprehensive understanding and quantification of this effect are essential. This review examines the impact of various added gases to hydrogen including typical odorants on gaseous hydrogen embrittlement of steels and evaluates their inhibition effectiveness. O2 CO and SO2 were found to be effective inhibitors of hydrogen embrittlement. Yet the results in the literature have not always been consistent partly because of the diverse range of mechanical tests and their parameters. The absence of systematic studies hinders the evaluation of the feasibility of using gas phase inhibitors for controlling gaseous hydrogen embrittlement. A method to quantify the effectiveness of gas phase inhibition is proposed using gas phase permeation studies.
Green Hydrogen Credit Subsidized Renewable Energy-hydrogen Business Models for Achieving the Carbon Netural Future
Feb 2024
Publication
The global resurgence of hydrogen as a clean energy source particularly green hydrogen derived from renewable energy is pivotal for achieving a carbon-neutral future. However scalability poses a significant challenge. This research proposes innovative business models leveraging the low-emission property of green hydrogen to reduce its financial costs thereby fostering its widespread adoption. Key components of the business workflow are elaborated mathematical formulations of market parameters are derived and case studies are presented to demonstrate the feasibility and efficiency of these models. Results demonstrate that the substantial costs associated with the current hydrogen industry can be effectively subsidized via the implementation of proposed business models. When the carbon emission price falls within the range of approximately 86–105 USD/ton free access to hydrogen becomes a viable option for end-users. This highlights the significance and promising potential of the proposed business models within the green hydrogen credit framework.
Storage Integrity During Underground Hydrogen Storage in Depleted Gas Reservoirs
Nov 2023
Publication
The transition from fossil fuels to renewable energy sources particularly hydrogen has emerged as a central strategy for decarbonization and the pursuit of net-zero carbon emissions. Meeting the demand for large-scale hydrogen storage a crucial component of the hydrogen supply chain has led to the exploration of underground hydrogen storage as an economically viable solution to global energy needs. In contrast to other subsurface storage options such as salt caverns and aquifers which are geographically limited depleted gas reservoirs have garnered increasing attention due to their broader distribution and higher storage capacity. However the safe storage and cycling of hydrogen in depleted gas reservoirs require the preservation of high stability and integrity in the caprock reservoir and wellbore. Nevertheless there exists a significant gap in the current research concerning storage integrity in underground hydrogen storage within depleted gas reservoirs and a systematic approach is lacking. This paper aims to address this gap by reviewing the primary challenges associated with storage integrity including geochemical reactions microbial activities faults and fractures and perspectives on hydrogen cycling. The study comprehensively reviews the processes and impacts such as abiotic and biotic mineral dissolution/precipitation reactivation and propagation of faults and fractures in caprock and host-rock wellbore instability due to cement degradation and casing corrosion and stress changes during hydrogen cycling. To provide a practical solution a technical screening tool has been developed considering controlling variables risks and consequences affecting storage integrity. Finally this paper highlights knowledge gaps and suggests feasible methods and pathways to mitigate these risks facilitating the development of large-scale underground hydrogen storage in depleted gas reservoirs.
Sustainability Certification for Renewable Hydrogen: An International Survey of Energy Professionals
Jun 2024
Publication
Hydrogen produced from renewable energy is being promoted to decarbonise global energy systems. To support this energy transition standards certification and labelling schemes (SCLs) aim to differentiate hydrogen products based on their system-wide carbon emissions and method of production characteristics. However being certified as low-carbon clean or green hydrogen does not guarantee broader sustainability across economic environmental social or governance dimensions. Through an international survey of energy-sector and sustainability professionals (n = 179) we investigated the desirable sustainability features for renewable hydrogen SCLs and the perceived advantages and disadvantages of sustainability certification. Our mixed-method study revealed general accordance on the feasible inclusion of diverse sustainability criteria in SCLs albeit with varying degrees of perceived essentiality. Within the confines of the data some differences in viewpoints emerged based on respondents’ geographical and supply chain locations which were associated with the sharing of costs and benefits. Qualitatively respondents found the idea of SCL harmonisation attractive but weighed this against the risks of duplication complicated administrative procedures and contradictory regulation. The implications of this research centre on the need for further studies to inform policy recommendations for an overarching SCL sustainability framework that embodies the principles of harmonisation in the context of multistakeholder governance.
Renewable Hydrogen Requirements and Impacts for Network Balancing: A Queensland Cae Study
Dec 2023
Publication
Hydrogen is the gas of the moment: an abundant element that can be created using renewable energy transported in gaseous or liquid form and offering the ability to provide energy with only water vapour as an emission. Hydrogen can also be used in a fuel blend in electricity generation gas turbines providing a low carbon option for providing the peak electricity to cover high demand and firming.<br/>While the electricity grid is itself transforming to decarbonising hard-to-abate industries such as cement and bauxite refineries are slower to reduce emissions constrained by their high temperature process requirements. Hydrogen offers a solution allowing onsite production process heat with waste heat recovery supporting blended gas turbine generation for onsite electricity supply.<br/>This article builds on decarbonisation pathway simulation results from an ANEM model of the electricity grid identifying the amount of peak demand energy required from gas turbines. The research then examines the quantity flow rate storage requirements and emissions reduction if this peak generation were supplied by open cycle hydrogen capable gas turbines.
Gas Storage in Geological Formations: A Comparative Review on Carbon Dioxide and Hydrogen Storage
Feb 2024
Publication
Carbon dioxide and hydrogen storage in geological formations at Gt scale are two promising strategies toward net-zero carbon emissions. To date investigations into underground hydrogen storage (UHS) remain relatively limited in comparison to the more established knowledge body of underground carbon dioxide storage (UCS). Despite their analogous physical processes can be used for accelerating the advancements in UHS technology the existing distinctions possibly may hinder direct applicability. This review therefore contributes to advancing our fundamental understanding on the key differences between UCS and UHS through multi-scale comparisons. These comparisons encompass key factors influencing underground gas storage including storage media trapping mechanisms and respective fluid properties geochemical and biochemical reactions and injection scenarios. They provide guidance for the conversion of our existing knowledge from UCS to UHS emphasizing the necessity of incorporating these factors relevant to their trapping and loss mechanisms. The article also outlines future directions to address the crucial knowledge gaps identified aiming to enhance the utilisation of geological formations for hydrogen and carbon dioxide storage.
Optimal Planning of Renewable Energy Park for Green Hydrogen Production Using Detailed Cost and Efficiency Curves of PEM Electrolyzer
Jul 2024
Publication
Installing multi-renewable energy (RE) power plants at designated locations known as RE parks is a promising solution to address their intermittent power. This research focuses on optimizing RE parks for three scenarios: photovoltaic (PV)-only wind-only and hybrid PV-wind with the aim of generating green hydrogen in locations with different RE potentials. To ensure rapid response to RE fluctuations a Proton Exchange Membrane (PEM) electrolyzer is employed. Furthermore this research proposes detailed models for manufacturer-provided wind power curves electrolyzer efficiency against its operating power and electrolyzer cost towards its capacity. Two optimization cases are conducted in MATLAB evaluating the optimum sizes of the plants in minimizing levelized cost of hydrogen (LCOH) using classical discrete combinatorial method and determining the ideal PV-to-wind capacity ratio for operating PEM electrolyzer within hybrid PV-wind parks using particle swarm optimization. Numerical simulations show that wind power-based hydrogen production is more cost-effective than PV-only RE parks. The lowest LCOH $4.26/kg H2 and the highest LCOH $14.378/kg H2 are obtained from wind-only and PV-only configurations respectively. Both occurred in Adum-Kirkeby Denmark as it has highest average wind speed and lowest irradiance level. Notably LCOH is reduced with the hybrid PV-wind configuration. The results suggest the optimum PV-to-wind capacity ratio is 65:35 on average and indicate that LCOH is more sensitive to electrolyzer’s cost than to electricity tariff variation. This study highlights two important factors i.e. selecting the suitable location based on the available RE resources and determining the optimum size ratio between the plants within the RE park.
Freshwater Supply for Hydrogen Production: An Underestimated Challenges
Jun 2024
Publication
This paper presents a thorough critical literature review aimed at understanding the challenges associated with freshwater supply associated with rapidly growing global hydrogen economies. The review has been prompted by the fact that the hydrogen production projected for 2030 will create at least an additional demand of 2.1 billion cubic meters for freshwater which needs to be addressed to support sustainable development of emerging hydrogen economies. The key solutions explored by this study include seawater and wastewater treatment methods for large-scale freshwater generation along with the newly introduced technique of direct seawater-fed electrolysis. Prior research indicates that desalination technologies including reverse osmosis and membrane distillation also offer promising avenues for large-scale freshwater production at costs comparable to other desalination techniques. Additionally low-temperature desalination methods such as membrane distillation could play a significant role in freshwater production for electrolysis underscoring the importance of exploring waste recovery opportunities within the system (e.g. fuel cell heat recovery). This review also identifies research gaps that need to be addressed to overcome freshwater supply challenges and enhance the sustainability and techno-economic viability of large-scale hydrogen energy systems.
Recent Progress and Techno-economic Analysis of Liquid Organic Hydrogen Carriers for Australian Renewable Energy Export - A Critical Review
Jan 2024
Publication
Hydrogen as a primary carbon-free energy carrier is confronted by challenges in storage and transportation. However liquid organic hydrogen carriers (LOHCs) present a promising solution for storing and transporting hydrogen at ambient temperature and atmospheric pressure. Unlike circular energy carriers such as methanol ammonia and synthetic natural gas LOHCs do not produce by-products during hydrogen recovery. LOHCs only act as hydrogen carriers and the carriers can also be recycled for reuse. Although there are considerable advantages to LOHCs there are also some drawbacks especially relative to the energy consumption during the dehydrogenation step of the LOHC recycling. This review summarizes the recent progresses in LOHC technologies focusing on catalyst developments process and reactor designs applications and techno-economic assessments (TEA). LOHC technologies can potentially offer significant benefits to Australia especially in terms of hydrogen as an export commodity. LOHCs can help avoid capital costs associated with infrastructure such as transportation vessels while reducing hydrogen loss during transportation such as in the case of liquid hydrogen (LH2). Additionally it minimises CO2 emissions as observed in methane and methanol reforming. Thus it is essential to dedicate more efforts to explore and develop LOHC technologies in the Australian context.
A 500 kW Hydrogen Fuel Cell-powered Vessel: From Concept to Sailing
Sep 2024
Publication
This paper presents the “Three Gorges Hydrogen Boat No. 1” a novel green hydrogen-powered vessel that has been successfully delivered and is currently sailing. This vessel integrated with a hydrogen production and bunkering station at its dedicated dock achieves zero-carbon emissions. It stores 240 kg of 35 MPa gaseous hydrogen and has a fuel cell system rated at 500 kW. We analysed the engineering details of the marine hydrogen system including hydrogen bunkering storage supply fuel cell and the hybrid power system with lithium-ion batteries. In the first bunkering trial the vessel was safely refuelled with 200 kg of gaseous hydrogen in 156 min via a bunkering station 13 m above the water surface. The maximum hydrogen pressure and temperature recorded during bunkering were 35.05 MPa and 39.04 ◦C respectively demonstrating safe and reliable shore-toship bunkering. For the sea trial the marine hydrogen system operated successfully during a 3-h voyage achieving a maximum speed of 28.15 km/h (15.2 knots) at rated propulsion power. The vessel exhibited minimal noise and vibration and its dynamic response met load change requirements. To prevent rapid load changes to the fuel cells 68 s were used to reach 483 kW from startup and 62 s from 480 kW to zero. The successful bunkering and operation of this hydrogen-powered vessel demonstrates the feasibility of zero-carbon emission maritime transport. However four lessons were identified concerning bunkering speed hydrogen cylinder leakage hydrogen pressure regulator malfunctions and fuel cell room space. The novelty of this work lies in the practical demonstration of a fully operational hydrogen-powered maritime vessel achieving zero emissions encompassing its design building operation and lessons learned. These parameters and findings can be used as a baseline for further engineering research.
Techno-economics of Renewable Hydrogen Export: A Case Study for Australia-Japan
Jul 2024
Publication
The shift from fossil fuels to clean energy carriers such as renewable H2 is imminent. Consequently a global H2 market is taking shape involving countries with limited or insufficient energy resources importing from renewable-rich countries. This study evaluates the techno-economics of renewable hydrogen (H2) export in a globally significant scenario in which Australia exports to Japan. To gain insight into the immediate realisable future the base year was selected as 2030 with a consequently small (in export terms) hydrogen production rate of 100 t/day landed capacity. Electricity was generated by photovoltaic arrays (PV) connected directly to proton exchange membrane (PEM) electrolyser plant allowing for flexible gaseous hydrogen (GH2) production. To enhance the fidelity of the technoeconomic model we incorporated rarely applied but impactful parameters including dynamic efficiency and the overload capacity of PEM electrolysers. The GH2 produced was assumed to be converted into condensed forms suitable for export by sea: liquid hydrogen (LH2) and the chemical carriers liquid ammonia (LNH3) methanol (MeOH) methylcyclohexane (MCH). These were assumed to be reconverted to GH2 at the destination. LNH3 and MCH emerged as promising carriers for export yielding the lowest landed levelised cost of hydrogen (LCOH). LH2 yielded the highest LCOH unless boiloff gas could be managed effectively and cheaply. A sensitivity analysis showed that a lower weighted average cost of capital (WACC) and scale-up can significantly reduce the landed LCOH. Increasing the production rate to 1000 t/day landed capacity very significantly lowered the landed LCOH providing a strong incentive to scale up and optimise the entire supply chain as fast as possible.
Empowering Fuel Cell Electric Vehicles Towards Sustainable Transportation: An Analytical Assessment, Emerging Energy Management, Key Issues, and Future Research Opportunities
Oct 2024
Publication
Fuel cell electric vehicles (FCEVs) have received significant attention in recent times due to various advantageous features such as high energy efficiency zero emissions and extended driving range. However FCEVs have some drawbacks including high production costs; limited hydrogen refueling infrastructure; and the complexity of converters controllers and method execution. To address these challenges smart energy management involving appropriate converters controllers intelligent algorithms and optimizations is essential for enhancing the effectiveness of FCEVs towards sustainable transportation. Therefore this paper presents emerging energy management strategies for FCEVs to improve energy efficiency system reliability and overall performance. In this context a comprehensive analytical assessment is conducted to examine several factors including research trends types of publications citation analysis keyword occurrences collaborations influential authors and the countries conducting research in this area. Moreover emerging energy management schemes are investigated with a focus on intelligent algorithms optimization techniques and control strategies highlighting contributions key findings issues and research gaps. Furthermore the state-of-the-art research domains of FCEVs are thoroughly discussed in order to explore various research domains relevant outcomes and existing challenges. Additionally this paper addresses open issues and challenges and offers valuable future research opportunities for advancing FCEVs emphasizing the importance of suitable algorithms controllers and optimization techniques to enhance their performance. The outcomes and key findings of this review will be helpful for researchers and automotive engineers in developing advanced methods control schemes and optimization strategies for FCEVs towards greener transportation.
Comprehensive Review of Development and Applications of Hydrogen Energy Technologies in China for Carbon Neutrality: Technology Advances and Challenges
Jul 2024
Publication
Concerning the transition from a carbon-based energy economy to a renewable energy economy hydrogen is considered an essential energy carrier for efficient and broad energy systems in China in the near future. China aims to gradually replace fossil fuel-based power generation with renewable energy technologies to achieve carbon neutrality by 2060. This ambitious undertaking will involve building an industrial production chain spanning the production storage transportation and utilisation of hydrogen energy by 2030 (when China’s carbon peak will be reached). This review analyses the current status of technological R&D in China’s hydrogen energy industry. Based on published data in the open literature we compared the costs and carbon emissions for grey blue and green hydrogen production. The primary challenges concerning hydrogen transportation and storage are highlighted in this study. Given that primary carbon emissions in China are a result of power generation using fossil fuels we provide an overview of the advances in hydrogen-to-power industry technology R&D including hydrogen-related power generation technology hydrogen fuel cells hydrogen internal combustion engines hydrogen gas turbines and catalytic hydrogen combustion using liquid hydrogen carriers (e.g. ammonia methanol and ethanol).
Economics of Renewable Hydrogen Production Using Wind and Solar Energy: A Case Study for Queensland, Australia
Dec 2023
Publication
This study presents a technoeconomic analysis of renewables-based hydrogen production in Queensland Australia under Optimistic Reference and Pessimistic scenarios to address uncertainty in cost predictions. The goal of the work was to ascertain if the target fam-gate cost of AUD 3/kg (approx. USD 2/kg) could be reached. Economies of scale and the learning rate concept were factored into the economic model to account for the effect of scale-up and cost reductions as electrolyser manufacturing capacity grows. The model assumes that small-scale to large-scale wind turbine (WT)-based and photovoltaic (PV)-based power generation plants are directly coupled with an electrolyser array and utilises hourly generation data for the Gladstone hydrogen-hub region. Employing first a commonly used simplified approach the electrolyser array was sized based on the maximum hourly power available for hydrogen production. The initial results indicated that scale-up is very beneficial: the levelised cost of green hydrogen (LCOH) could decrease by 49% from $6.1/kg to $3.1/kg when scaling PV-based plant from 10 MW to 1 GW and for WT-based plant by 36% from $5.8/kg to $3.7/kg. Then impacts on the LCOH of incorporating curtailment of ineffective peak power and electrolyser overload capacity were investigated and shown to be significant. Also significant was the beneficial effect of recognising that electrolyser efficiency depends on input power. The latter two factors have mostly been overlooked in the literature. Incorporating in the model the influence on the LCOH of real-world electrolyser operational characteristics overcomes a shortcoming of the simplified sizing method namely that a large portion of electrolyser capacity is under-utilised leading to unnecessarily high values of the LCOH. It was found that AUD 3/kg is achievable if the electrolyser array is properly sized which should help to incentivise large-scale renewable hydrogen projects in Australia and elsewhere.
Decarbonizing Combustion with Hydrogen Blended Fuels: An Exploratory Study of Impact of Hydrogen on Hydrocarbon Autoignition
Jan 2024
Publication
Blending hydrogen to existing fuel mix represents a major opportunity for decarbonisation. One important consideration for this application is the chemical interaction between hydrogen and hydrocarbon fuels arising from their different combustion chemistries and varying considerably with combustion processes. This paper conducted an exploratory study of hydrogen’s impact on autoignition in several combustion processes where hydrogen is used as a blending component or the main fuel. Case studies are presented for spark ignition engines (H2/natural gas) compression ignition engines (H2/diesel) moderate or intense low-oxygen dilution (MILD) combustors (H2/natural gas) and rotational detonation engines (H2/natural gas). Autoignition reactivity as a function of the hydrogen blending level is investigated numerically using the ignition delay iso-contours and state-of-the-art kinetic models at time scales representative of each application. The results revealed drastically different impact of hydrogen blending on autoignition due to different reaction temperature pressure and time scale involved in these applications leaving hydrocarbon interacting with hydrogen at different ignition branches where the negative pressure/temperature dependency of oxidation kinetics could take place. The resulted non-linear and at times non-monotonic behaviours indicate a rich topic for combustion chemistry and also demonstrates ignition delay iso-contour as a useful tool to scope autoignition reactivity for a wide range of applications.
Upcycling of Plastic Wastes for Hydrogen Production: Advances and Perspectives
Feb 2024
Publication
The abundant plastic wastes become an imperative global issue and how to handle these organic wastes gains growing scientific and industrial interest. Recently converting plastic wastes into hydrogen fuel has been investigated and the “waste-to-value” practice accelerates the circular economy. To accelerate the development of plastic-to-hydrogen conversion in this review recent advances in plastic-to-hydrogen conversion via thermochemical photocatalytic and electrocatalytic routes are analyzed. All of the thermo- photo- and electrochemical processes can transform different plastic wastes into hydrogen and the hydrogen production efficiency depends heavily on the selected techniques operating parameters and applied catalysts. The application of rational-designed catalysts can promote the selective production of hydrogen from plastic feedstocks. Further studies on process optimization cost-effective catalyst design and mechanism investigation are needed.
Advancing a Hydrogen Economy in Australia: Public Perceptions and Aspirations
Nov 2023
Publication
Supporters of hydrogen energy urge scaling up technology and reducing costs for competitiveness. This paper explores how hydrogen energy technologies (HET) are perceived by Australia’s general population and considers the way members of the public imagine their role in the implementation of hydrogen energy now and into the future. The study combines a nationally representative survey (n = 403) and semi-structured interviews (n = 30). Results show age and gender relationships with self-reported hydrogen knowledge. Half of the participants obtained hydrogen information from televised media. Strong support was observed for renewable hydrogen while coal (26%) and natural gas (41%) versions had less backing. Participants sought more safety-related information (41% expressed concern). Most felt uncertain about influencing hydrogen decisions and did not necessarily recognise they had agency beyond their front fence. Exploring the link between political identity and agency in energy decision-making is needed with energy democracy a potentially productive direction.
Opportunities and Challenges of Hydrogen Ports: An Empirical Study in Australia and Japan
Jul 2024
Publication
This paper investigated the opportunities and challenges of integrating ports into hydrogen (H2 ) supply chains in the context of Australia and Japan because they are leading countries in the field and are potential leaders in the upcoming large-scale H2 trade. Qualitative interviews were conducted in the two countries to identify opportunities for H2 ports necessary infrastructure and facilities key factors for operations and challenges associated with the ports’ development followed by an online survey investigating the readiness levels of H2 export and import ports. The findings reveal that there are significant opportunities for both countries’ H2 ports and their respective regions which encompass business transition processes and decarbonisation. However the ports face challenges in areas including infrastructure training standards and social licence and the sufficiency and readiness levels of port infrastructure and other critical factors are low. Recommendations were proposed to address the challenges and barriers encountered by H2 ports. To optimise logistics operations within H2 ports and facilitate effective integration of H2 applications this paper developed a user-oriented working process framework to provide guidance to ports seeking to engage in the H2 economy. Its findings and recommendations contribute to filling the existing knowledge gap pertaining to H2 ports.
Fuelling the Future: An In-depth Review of Recent Trends, Challenges and Opportunities of Hydrogen Fuel Cell for a Sustainable Hydrogen Economy
Sep 2023
Publication
Hydrogen has gained tremendous momentum worldwide as an energy carrier to transit to a net zero emission energy sector. It has been widely adopted as a promising large-scale renewable energy (RE) storage solution to overcome RE resources’ variability and intermittency nature. The fuel cell (FC) technology became in focus within the hydrogen energy landscape as a cost-effective pathway to utilize hydrogen for power generation. Therefore FC technologies’ research and development (R&D) expanded into many pathways such as cost reduction efficiency improvement fixed and mobile applications lifetime safety and regulations etc. Many publications and industrial reports about FC technologies and applications are available. This raised the necessity for a holistic review study to summarize the state-of-the-art range of FC stacks such as manufacturing the balance of plant types technologies applications and R&D opportunities. At the beginning the principal technologies to compare the well known types followed by the FC operating parameters are presented. Then the FC balance of the plant i.e. building components and materials with its functionality and purpose types and applications are critically reviewed with their limitations and improvement opportunities. Subsequently the electrical properties of FCs with their key features including advantages and disadvantages were investigated. Applications of FCs in different sectors are elaborated with their key characteristics current status and future R&D opportunities. Economic attributes of fuel cells with a pathway towards low cost are also presented. Finally this study identifies the research gaps and future avenues to guide researchers and the hydrogen industry.
Renewable Hydrogen for the Energy Transition in Australia - Current Trends, Challenges and Future Directions
Sep 2024
Publication
Hydrogen is viewed as a potential energy solution for the 21st century with capabilities to tackle issues relating to environmental emissions sustainability energy shortages and security. Even though there are potential benefits of renewable hydrogen towards transitioning to net-zero emissions there is a limited study on the current use ongoing development and future directions of renewable hydrogen in Australia. Thus this study conducts a systematic review of studies for exploring Australia’s renewable hydrogen energy transition current trends strategies developments and future directions. By using the Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) guidelines earlier studies from 2005 to 2024 from two major databases such as ProQuest and Web of Science are gathered and analyzed. The study highlights significant issues relating to hydrogen energy technologies and opportunities/challenges in production storage distribution utilization and environmental impacts. The study found that Australia’s ambition for a strong hydrogen economy is made apparent with its clear strategic actions to develop a clean technology-based hydrogen production storage and distribution system. This study provides several practical insights on Australia’s hydrogen energy transition hydrogen energy technologies investments and innovation as well as strategies/recommendations for achieving a more environment friendly secure affordable and sustainable energy future.
The Impact of Water Injection and Hydrogen Fuel on Performance and Emissions in a Hydrogen/Diesel Dual-Fuel Engine
Nov 2024
Publication
As the need for alternative energy sources and reduced emissions grows proven technologies are often sidelined in favour of emerging solutions that lack the infrastructure for mass adoption. This study explores a transitional approach by modifying existing compression ignition engines to run on a hydrogen/diesel mixture for performance improvement utilising water injection to mitigate the drawbacks associated with hydrogen combustion. This approach can yield favourable results with current technology. In this modelling study ten hydrogen energy ratios (0–90%) and nine water injection rates (0–700 mg/cycle) were tested in a turbocharged Cummins ISBe 220 31 six-cylinder diesel engine. An engine experiment was conducted to validate the model. Key performance indicators such as power mechanical efficiency thermal efficiency indicated mean effective pressure (IMEP) and brake-specific fuel consumption (BSFC) were measured. Both water injection and hydrogen injection led to slight improvements in all performance metrics except BSFC due to hydrogen’s lower energy density. In terms of emissions CO and CO2 levels significantly decreased as hydrogen content increased with reductions of 94% and 96% respectively at 90% hydrogen compared to the baseline diesel. Water injection at peak rates further reduced CO emissions by approximately 40% though it had minimal effect on CO2 . As expected NOx (which is a typical challenge with hydrogen combustion and also with diesel engines in general) increased with hydrogen fuelling resulting in an approximately 70% increase in total NOx emissions over the range of 0–90% hydrogen energy. Similar increases were observed in NO and NO2 e.g. 90% and 57% increases with 90% hydrogen respectively. However water injection reduced NO and NO2 levels by up to 16% and 83% respectively resulting in a net decrease in NOX emissions in many combined cases not only with hydrogen injection but also when compared to baseline diesel.
Optimizing an Integrated Hybrid Energy System with Hydrogen-based Storage to Develop an Off-grid Green Community for Sustainable Development in Bangladesh
Dec 2024
Publication
An integrated renewable system that utilizes solid waste-based biogas is important steps towards the sustainable energy solutions to rural off-grid communities in Bangladesh. In this study a hybrid energy system consisting of photovoltaic modules wind turbines biogas generators fuel cells and electrolyzer-hydrogen tank-based energy storage is optimized using non-dominated sorting genetic algorithm (NSGA-II). The hybrid system is optimized based on the cost of energy and human health damage as objective functions and a fuzzy decision-making technique is employed to determine the optimal solution to the multi-objective approach. Additionally several economic ecological and social indicators are also investigated while meeting a certain load reliability. An energy management strategy has been developed in the MATALB environment to satisfy the community load and the battery-driven electric vehicle load. Results from this comprehensive analysis suggest that the optimal configuration of PV/WT/FC/BG has an energy cost of 0.1634 $/kWh and an ecosystem damage of 0.00098 species.year. The human health damage and the human development index of the optimized system are 0.1732 DALYs and 0.696 DALYs respectively. Additionally the proposed system has a lifecycle emission of 123730 kg CO2-eq/year carbon emission penalties of $1856/year a job creation potential of 30 jobs/MW over the 25 years of project lifetime. The hybrid system oversees solid waste management solutions and provides the community with sustainable energy and vehicle recharge.
The Hydrogen-water Collision: Assessing Water and Cooling Demands for Large-scale Green Hydrogen Production in a Warming Climate
Dec 2024
Publication
Hydrogen is expected to play a critical role in future energy systems projected to have an annual demand of 401–660 Mt by 2050. With large-scale green hydrogen projects advancing in water-scarce regions like Australia Chile and the Middle East and North Africa understanding water requirements for large-scale green hydrogen production is crucial. Meeting this future hydrogen demand will necessitate 4010 to 6600 GL of demineralised water annually for electrolyser feedwater if dry cooling is employed or an additional 6015 to 19800 GL for cooling water per year if evaporative cooling is employed. Using International Panel of Climate Change 2050 climate projections this work evaluated the techno-economic implications of dry vs. evaporative cooling for large-scale electrolyser facilities under anticipated higher ambient temperatures. The study quantifies water demands costs and potential operational constraints showing that evaporative cooling is up to 8 times cheaper to implement than dry cooling meaning that evaporative cooling can be oversized to accommodate increased cooling demand of high temperature events at a lower cost. Furthermore of the nations analysed herein Chile emerged as having the lowest cost of hydrogen owing to the lower projected ambient temperatures and frequency of high temperature events.
A Study on Hydrogen Embrittlement of a High-strength Pipeline Steel Weldment after Microstructure Manipulation by Targeted Heat Treatments
Dec 2024
Publication
Hydrogen embrittlement (HE) is a major concern when steel pipelines are used for hydrogen transportation and storage. The weldments of steel pipelines are of particular concern because they are reported to have higher HE susceptibility compare to the base metal. In this work targeted heat treatments were used to manipulate the microstructure in a pipeline steel weldment to examine the effects of different microstructural features on HE susceptibility. Complementary analyses of the microstructure mechanical testing and fracture surface identified inclusions and ferrite morphology as the most dominant microstructural features that affect the susceptibility to HE. Specimens with different microstructures but sharing similar Ti-rich inclusions exhibited significant re ductions in elongation to failure after hydrogen charging and showed brittle fracture surfaces decorated with multiple ‘fish-eye’ features. In addition co-existence of bainitic microstructure with Ti-rich inclusions resulted in the highest susceptibility to HE.
A Risk-based Multi-criteria Decision-making Framework for Offshore Green Hydrogen System Developments: Pathways for Utilizing Existing and New Infrastructure
Mar 2024
Publication
Unlocking the potential of offshore renewables for green hydrogen (GH2) production can be a game-changer empowering economies with their visionary clean energy policies amplifying energy security and promoting economic growth. However their novelty entails uncertainty and risk necessitating a robust framework for facility deployment and infrastructure planning. To optimize offshore GH2 infrastructure placement this work proposes a novel and robust GIS-based multi-criteria decision-making (MCDM) framework. Encompassing thirtytwo techno-socio-economic-safety factors and ocean environmental impact analysis this methodology facilitates informed decision-making for sustainable and safe GH2 development. Utilizing the synergies between offshore wind and solar resources this study investigates the potential of hybrid ocean technologies to enhance space utilization and optimize efficiency. To illustrate the practical application of the proposed framework a case study examining a GH2 system in Australia's marine region and its potential nexus with nearby offshore industries has been conducted. The performed life cycle assessment (LCA) explored various configurations of GH2 production storage and transportation technologies. A Bayesian objective weight integrating technique has been introduced and contrasted statistically with the hybrid CRITIC Entropy MEREC and MARCOS-based MCDM approaches. Various locations are ranked based on the net present value of life cycle cost GH2 production capacity risk availability and environment sustainability factors illustrating their compatibility. A sensitivity analysis is conducted to confirm that a Bayesian approach improves the decision-making outcomes through identifying optimal criteria weights and alternative ranks more effectively. Empowering strategic GH2 decisions globally the proposed approach optimizes system performances cost sustainability and safety excelling in harsh environments.
Towards Safer Hydrogen Refuelling Stations: Insights from Computational Fluid Dynamics LH2 Leakage
May 2024
Publication
The transition to a sustainable future with hydrogen as a key energy carrier necessitates a comprehensive understanding of the safety aspects of hydrogen including liquid hydrogen (LH₂). Hence this study presents a detailed computational fluid mechanics analysis to explore accidental LH₂ leakage and dispersion in a hydrogen refuelling station under varied conditions which is essential to prevent fire and explosion. The correlated impact of influential parameters including wind direction wind velocity leak direction and leak rate were analysed. The study shows that hydrogen dispersion is significantly impacted by the combined effect of wind direction and surrounding structures. Additionally the leak rate and leak direction have a significant effect on the development of the flammable cloud volume (FCV) which is critical for estimating the explosion hazards. Increasing wind velocity from 2 to 4 m/s at a constant leak rate of 0.06 kg/s results in an 82% reduction in FCV. The minimum FCV occurs when leak and wind directions oppose at 4 m/s. The most critical situation concerning FCV arises when the leak and wind directions are perpendicular with a leak rate of 0.06 kg/s and a wind velocity of 2 m/s. These findings can aid in the development of optimised sensing and monitoring systems and operational strategies to reduce the risk of catastrophic fire and explosion consequences.
Challenges and Opportunities for Hydrogen Production from Microalgae
Nov 2015
Publication
The global population is predicted to increase from ~7.3 billion to over 9 billion people by 2050.Together with rising economic growth this is forecast to result in a 50% increase in fueldemand which will have to be met while reducing carbon dioxide (CO 2 ) emissions by 50–80%to maintain social political energy and climate security. This tension between rising fuel demandand the requirement for rapid global decarbonization highlights the need to fast-track thecoordinated development and deployment of efficient cost-effective renewable technologies forthe production of CO 2 neutral energy. Currently only 20% of global energy is provided aselectricity while 80% is provided as fuel. Hydrogen (H 2) is the most advanced CO 2 -free fuel andprovides a ‘common’ energy currency as it can be produced via a range of renewabletechnologies including photovoltaic (PV) wind wave and biological systems such as microalgaeto power the next generation of H 2 fuel cells. Microalgae production systems for carbon-basedfuel (oil and ethanol) are now at the demonstration scale. This review focuses on evaluating thepotential of microalgal technologies for the commercial production of solar-driven H2 fromwater. It summarizes key global technology drivers the potential and theoretical limits ofmicroalgal H2 production systems emerging strategies to engineer next-generation systems andhow these fit into an evolving H 2 economy.
A High-performance Capillary-fed Electrolysis Cell Promises More Cost-competitive Renewable Hydrogen
Mar 2022
Publication
Renewable or green hydrogen will play a critical role in the decarbonisation of hard-to-abate sectors and will therefore be important in limiting global warming. However renewable hydrogen is not cost-competitive with fossil fuels due to the moderate energy efficiency and high capital costs of traditional water electrolysers. Here a unique concept of water electrolysis is introduced wherein water is supplied to hydrogen- and oxygen-evolving electrodes via capillary-induced transport along a porous inter-electrode separator leading to inherently bubble-free operation at the electrodes. An alkaline capillary-fed electrolysis cell of this type demonstrates water electrolysis performance exceeding commercial electrolysis cells with a cell voltage at 0.5 A cm−2 and 85 °C of only 1.51 V equating to 98% energy efficiency with an energy consumption of 40.4 kWh/kg hydrogen (vs. ~47.5 kWh/kg in commercial electrolysis cells). High energy efficiency combined with the promise of a simplified balance-ofplant brings cost-competitive renewable hydrogen closer to reality.
Numerical Modelling of Hydrogen Release and Dispersion in Under-deck Compressed Hydrogen Storage of Marine Ships
Feb 2024
Publication
There is growing interest in using hydrogen (H2) as a marine fuel. Fire and explosion risks depend on hydrogen release and dispersion characteristics. Based on a validated Computational Fluid Dynamics (CFD) model this study performed hydrogen release and dispersion analysis on an under-deck compressed H2 storage system for a Live-Fish Carrier. A realistic under-deck H2 storage room was modelled based on the ship’s main dimensions and operational profile. Det Norske Veritas (DNV) Rules and Regulations for natural gas storage as a marine fuel were employed as base design guidelines. Case studies were developed to study the effect of two ceiling types (flat and slanted) in terms of flammable cloud formation and dissipation. During the leak’s duration it was found that the recommended ventilation rate was insufficient to dilute the average H2 concentration below 25% of the flammable range as required by DNV (1.2% required against 1.3% slanted and 1.4% flat). However after 35 s of gas extraction the H2 concentration was reduced to 0.5% and 0.6% in the slanted and flat cases respectively. The proposed methodology remains valid to improve the ventilation system and assess mitigation alternatives or other leakage scenarios in confined or semi-confined spaces containing compressed hydrogen gas.
Comparative Study of LNG, Liquid Hydrogen ,and Liquid Ammonia Post-release Evaporation and Dispersion During Bunkering
Apr 2024
Publication
The use of alternative fuels is a primary means for decarbonising the maritime industry. Liquefied natural gas (LNG) liquid hydrogen (LH2) and liquid ammonia (LNH3) are liquified gases among the alternative fuels. The safety risks associated with these fuels differ from traditional fuels. In addition to their low-temperature hazards the flammability of LNG and LH2 and the high toxicity of LNH3 present challenges in fuel handlings due to their high likelihood of fuel release during bunkering. This study aims at drawing extensive comparisons of the evaporation and vapour dispersion behaviours for the three fuels after release accidents during bunkering and discuss their safety issues. The study involved the release event of the three fuels on the main deck area of a reference bulk carrier with a deadweight of 208000 tonnes. Two release scenarios were considered: Scenario 1 involved a release of 0.3 m3 of fuel and Scenario 2 involved a release of 100 kg of fuel. An empirical equation was used to calculate the fuel evaporation process and the Computational Fluid Dynamic (CFD) code FDS was employed to simulate the dispersion of vapour clouds. The obtained results reveal that LH2 has the highest evaporation rate followed by LNG and LNH3. The vapour clouds of LNG and LNH3 spread along the main deck surface while the LH2 vapour cloud exhibits upward dispersion. The flammable vapour clouds of LNG and LH2 remain within the main deck area whereas the toxic gas cloud of LNH3 disperses towards the shore and spreads near the ground on the shore side. Based on the dispersion behaviours the hazards of LNG and LH2 are com parable while LNH3 poses significantly higher hazards. In terms of hazard mitigations effective water curtain systems can suppress the vapour dispersion.
Evaluation and Outlook for Australian Renewable Energy Export via Circular Liquid Hydrogen Carriers
Oct 2023
Publication
To combat global temperature rise we need affordable clean and renewable energy that does not add carbon to the atmosphere. Hydrogen is a promising option because it can be used as a carbon-free energy source. However storing and transporting pure hydrogen in liquid or gaseous forms is challenging. To overcome the limitations associated with conventional compressed and liquefied hydrogen or physio-chemical adsorbents for bulk storage and transport hydrogen can be attached to other molecules known as hydrogen carriers. Circular carriers which involve the production of CO2 or nitrogen during the hydrogen recovery process include substances such as methanol ammonia or synthetic natural gas. These carriers possess higher gravimetric and volumetric hydrogen densities (i.e. 12.5 wt% and 11.88 MJ/L for methanol) than cyclic carriers (i.e. 6.1 wt% and 5.66 MJ/L for methylcyclohexane (MCH)) which produce cyclic organic chemicals during dehydrogenation. This makes circular carriers particularly appealing for the Australian energy export market. Furthermore the production-decomposition cycle of circular carriers can be made carbon-neutral if they are derived from renewable H2 sources and combined with atmospheric or biomass-based CO2 or nitrogen. The key parameters are investigated in this study focusing on circular hydrogen carriers relevant to Australia. The parameters are ranked from 0 (worst) to 10 (best) depending on the bandwidth of the parameter in this review. Methanol shows great potential as a cost-effective solution for long-distance transport of renewable energy being a liquid at standard conditions with a boiling point of 64.7 °C. Methane is also an important hydrogen carrier due to the availability of natural gas infrastructure and its role as a significant export product for Australia.
Life Cycle Assessment of Renewable Hydrogen Transport by Ammonia
Nov 2024
Publication
Ammonia is a promising hydrogen carrier for enabling the efficient transport of hydrogen as observed by the many hydrogen transport projects using ammonia. For the clean energy future understanding environmental impacts of the transport system is important. This study conducts life cycle assessment (LCA) for the marine transport of renewable hydrogen using ammonia as the hydrogen carrier. The LCA considered renewable hydrogen produced from four systems; wind-powered electrolysis gasification of forest residue anaerobic digestion of food waste and landfill gas reforming; followed by Haber-Bosch ammonia synthesis using the renewable hydrogen and nitrogen produced from air separation. The ammonia was then transported 11000 km by sea to a destination facility where it was decomposed using either Ru or Ni catalysts to obtain hydrogen. Among the four hydrogen transport systems operated with renewable energy electrolysis-hydrogen system presented the highest global warming impact of 3.31 kg CO2 eq/kg H2 due to electricity use for the electrolysis whereas simpler processes based on a landfill gas system led to the lowest impact of 2.27 kg CO2 eq/kg H2. Process energy consumption was the major contributor to global warming impact with 27%–49.2% of contri bution. The consumption of metals and energy during wind turbine construction resulted in the most significant impact in six out of 12 midpoint impact categories for the electrolysis-hydrogen system which also led to the highest endpoint impacts. The endpoint impacts of the four systems were in the order of electrolysis > food waste > forest residue > landfill gas (from high to low) for both endpoint human health and ecosystems impacts. Ammonia decomposition using Ru catalysts exhibited slightly lower global warming impact than Ni catalysts while final purification of hydrogen by vanadium membrane presented 4.8% lower impacts than the purification by pressure swing adsorption. Large-scale hydrogen supply chains can be achieved by technological improve ment and support of policies and financial schemes.
Pieces of a Jigsaw: Opportunities and Challenges in the Nascent Australian Hydrogen Mobility Market
Mar 2023
Publication
Mobility has been a prominent target for proponents of the hydrogen economy. Given the complexities involved in the mobility value chain actors hoping to participate in this nascent market must overcome a range of challenges relating to the availability of vehicles the co-procurement of supporting infrastructure a favourable regulatory environment and a supportive community among others. In this paper we present a state-of-play account of the nascent hydrogen mobility market in Victoria Australia drawing on data from a workshop (N ¼ 15) and follow-up interviews (n ¼ 10). We interpret findings through a socio-technical framework to understand the ways in which fuel cell electric vehicles (FCEVs)dand hydrogen technologies more generallydare conceptualised by different stakeholder groups and how these conceptualisations mediate engagement in this unfolding market. Findings reveal prevailing efforts to make sense of the FCEV market during a period of considerable institutional ambiguity. Discourses embed particular worldviews of FCEV technologies themselves in addition to the envisioned roles the resultant products and services will play in broader environmental and energy transition narratives. Efforts to bring together stakeholders representing different areas of the FCEV market should be seen as important enablers of success for market participants.
Explosions of Hydrogen Storages and the Safety Considerations in Hydrogen-Powered Railway Applications—A Review
Nov 2024
Publication
As one of the most promising clean energy sources hydrogen power has gradually emerged as a viable alternative to traditional energy sources. However hydrogen safety remains a significant concern due to the potential for explosions and the associated risks. This review systematically examines hydrogen explosions with a focus on high-pressure and low-temperature storage transportation and usage processes mostly based on the published papers from 2020. The fundamental principles of hydrogen explosions classifications and analysis methods including experimental testing and numerical simulations are explored. Key factors influencing hydrogen explosions are also discussed. The safety issues of hydrogen power on railway applications are focused and finally recommendations are provided for the safe application of hydrogen power in railway transportation particularly for long-distance travel and heavy-duty freight trains with an emphasis on storage safety considerations.
A Review of Type V Composite Pressure Vessels and Automated Fibre Placement Based Manufacturing
Feb 2023
Publication
Hydrogen is emerging as a promising future energy medium in a wide range of industries. For mobile applica tions it is commonly stored in a gaseous state within high-pressure composite overwrapped pressure vessels (COPVs). The current state of the art pressure vessel technology known as Type V eliminates the internal polymer gas barrier used in Type IV vessels and instead relies on carbon fibre laminate to provide structural properties and prevent gas leakage. Achieving this functionality at high pressure poses several engineering challenges that have thus far prohibited commercial application. Additionally the traditional manufacturing process for COPVs filament winding has several constraints that limit the design space. Automated fibre placement (AFP) a highly flexible robotic composites manufacturing technique has the potential to replace filament winding for composite pressure vessel manufacturing and provide pathways for further vessel optimi sation. A combination of both AFP and Type V technology could provide an avenue for a new generation of highperformance composite pressure vessels. This critical review presents key work on industry-standard Type IV vessels alongside the current state of Type V CPV technology including manufacturing developments challenges cost relevance to commercial standards and future fabrication solutions using AFP. Additionally a novel Type V CPV design concept for a two-piece AFP produced vessel is presented.
Research and Development of Hydrogen Carrier Based Solutions for Hydrogen Compression and Storage
Aug 2022
Publication
Martin Dornheim,
Lars Baetcke,
Etsuo Akiba,
Jose-Ramón Ares,
Tom Autrey,
Jussara Barale,
Marcello Baricco,
Kriston Brooks,
Nikolaos Chalkiadakis,
Véronique Charbonnier,
Steven Christensen,
José Bellosta von Colbe,
Mattia Costamagna,
Erika Michela Dematteis,
Jose-Francisco Fernández,
Thomas Gennett,
David Grant,
Tae Wook Heo,
Michael Hirscher,
Katherine Hurst,
Mykhaylo V. Lototskyy,
Oliver Metz,
Paola Rizzi,
Kouji Sakaki,
Sabrina Sartori,
Emmanuel Stamatakis,
Alastair D. Stuart,
Athanasios Stubos,
Gavin Walker,
Colin Webb,
Brandon Wood,
Volodymyr A. Yartys and
Emmanuel Zoulias
Industrial and public interest in hydrogen technologies has risen strongly recently as hydrogen is the ideal means for medium to long term energy storage transport and usage in combination with renewable and green energy supply. In a future energy system the production storage and usage of green hydrogen is a key technology. Hydrogen is and will in future be even more used for industrial production processes as a reduction agent or for the production of synthetic hydrocarbons especially in the chemical industry and in refineries. Under certain conditions material based systems for hydrogen storage and compression offer advantages over the classical systems based on gaseous or liquid hydrogen. This includes in particular lower maintenance costs higher reliability and safety. Hydrogen storage is possible at pressures and temperatures much closer to ambient conditions. Hydrogen compression is possible without any moving parts and only by using waste heat. In this paper we summarize the newest developments of hydrogen carriers for storage and compression and in addition give an overview of the different research activities in this field.
Geomechanics of Hydrogen Storage in a Depleted Gas Field
Feb 2024
Publication
We perform a simulation study of hydrogen injection in a depleted gas reservoir to assess the geomechanical impact of hydrogen storage relative to other commonly injected gases (methane CO2). A key finding is that the differences in hydrogen density compressibility viscosity and thermal properties compared to the other gases result in significantly less thermal perturbation at reservoir level. The risks of fault reactivation and wellbore fractures due to thermally-induced stress changes are significantly lower when storing hydrogen compared to results observed in CO2 scenarios. This implies that hydrogen injection and production has a much smaller geomechanical footprint with benefits for operational safety. We also find that use of nitrogen cushion gas ensures efficient deliverability and phase separation in the reservoir. However in this study a large fraction of cushion gas was back-produced in each cycle demonstrating the need for further studies of the surface processing requirements and economic implications.
Artificial Intelligence for Hydrogen-Enabled Integrated Energy Systems: A Systematic Review
Aug 2024
Publication
Hydrogen-enabled Integrated Energy Systems (H-IES) stand out as a promising solution with the potential to replace current non-renewable energy systems. However their development faces challenges and has yet to achieve widespread adoption. These main challenges include the complexity of demand and supply balancing dynamic consumer demand and challenges in integrating and utilising hydrogen. Typical energy management strategies within the energy domain rely heavily on accurate models from domain experts or conventional approaches such as simulation and optimisation approaches which cannot be satisfied in the real-world operation of H-IES. Artificial Intelligence (AI) or Advanced Data Analytics (ADA) especially Machine Learning (ML) has the ability to overcome these challenges. ADA is extensively used across several industries however further investigation into the incorporation of ADA and hydrogen for the purpose of enabling H-IES needs to be investigated. This paper presents a systematic literature review to study the research gaps research directions and benefits of ADA as well as the role of hydrogen in H-IES.
Uncovering an Emerging Policy Direction for Australian Energy and Future Fuels Using a "Participatory Decision-Making" Framework
Aug 2024
Publication
Introduction: An online deliberative engagement process was undertaken with members of the general public to understand what they value or would like to change about the energy system within the broader context of decarbonizing Australia's energy networks identifying a role for future fuels (hydrogen and biogas). Citizens developed a set of principles that could guide Australia's path toward a low-carbon energy future reflecting on expectations they place upon energy transition. Next citizens' principles were shared with policy-makers in government and policy-influencers from the energy industry using an online interactive workshop.<br/>Methods: This study analyses policy-makers and -influencers response to citizens' guiding principles using the 'diamond of participatory decision-making' framework for analysis. Convergence and divergence in diverse complex and rich views across cohorts and implications thereupon energy policy were identified.<br/>Results: Although considerable alignment between multi-stakeholders' views was noted key areas of divergence or what is called the “groan zone” were easily identified in relation to social and environmental justice issues. This groan zone highlights the struggles that energy policy-makers face -the need to listen and respond to citizens' voices vs. the need for practical and workable policies that also support overarching government or industry objectives.<br/>Discussion: Policy making when the views of different stakeholders align is relatively straightforward. However this is not the case where the expectations diverge. More creative measures will be needed to address divergent views and expectations whilst maintaining procedural fairness in this case using democratic deliberative engagement processes. While the use of deliberative processes is gaining momentum worldwide particularly concerning climate change and energy transition policies this paper also highlights the benefits of conducting a robust post facto analysis of the content of the processes. Areas of alignment where policy can be made and implemented relatively easily without contention are identified. Other areas (such as making electrification mandatory) might be more complex or have unwanted negative social and environmental justice effects. Overall this paper bridges an analytical gap between “expectation studies” and participatory research. By borrowing terminology from a participatory research framework we sharpen the concepts in “expectation studies” from a consensus inclusion and diversity standpoint.
Fuelling a Clean Future: A Systematic Review of Techno-Economic and Life Cycle Assessments in E-Fuel Development
Aug 2024
Publication
The transition to sustainable energy has ushered in the era of electrofuels (e-fuels) which are synthesised using electricity from renewable sources water and CO2 as a sustainable alternative to fossil fuels. This paper presents a systematic review of the techno-economic (TEA) and life cycle assessments (LCAs) of e-fuel production. We critically evaluate advancements in production technologies economic feasibility environmental implications and potential societal impacts. Our findings indicate that while e-fuels offer a promising solution to reduce carbon emissions their economic viability depends on optimising production processes and reducing input material costs. The LCA highlights the necessity of using renewable energy for hydrogen production to ensure the genuine sustainability of e-fuels. This review also identifies knowledge gaps suggesting areas for future research and policy intervention. As the world moves toward a greener future understanding the holistic implications of e-fuels becomes paramount. This review aims to provide a comprehensive overview to guide stakeholders in their decision-making processes.
Modelling and Simulation of an Integrated Coupled Reactor for Hydrogen Production and Carbon Dioxide Utilisation in an Integrated Fuel Cell Power System
Dec 2024
Publication
In today’s world the need for sustainable energy solutions is paramount to address the ongoing crisis of increasing greenhouse gas emissions and global warming. Industries heavily reliant on fossil fuels must explore alternative energy sources. Hydrogen with its high heating value and zero direct emissions has emerged as a promising fuel for the future. Electrolytic hydrogen production has gained significance as it enables demand-side response grid stabilization using excess energy and the mitigation of curtailment from intermittent renewable energy sources (RES) such as solar and wind. Advanced combined heat and power (CHP) systems comprise of Solid oxide fuel cell (SOFC) module and a coupled reforming reactor to capture energy contained in the SOFC exhaust gases from SOFC. In present work 3D CFD model of an experimental coupled reactor used for onsite hydrogen production is developed and implemented into ANSYS Fluent® software. The study is aimed at opti mizing the reactor performance by identifying appropriate kinetic models for reforming and combustion re actions. SOFC anode off-gas (AOG) comprising mainly of unconverted hydrogen is combined with methane combustion to enhance thermal efficiency of the reactor and hence the CHP system. Kinetic models for catalytic reforming and combustion are implemented into ANSYS Fluent® through custom-built user defined functions (UDFs) written in C programming language. Simulation results are validated with experimental data and found in good agreement. AOG assisted combustion of methane shows a substantial improvement in thermal efficiency of the system. Improvement in thermal efficiency and reduction in carbon-based fuel demand AOG utilization contributes to sustainable hydrogen production and curtailment of greenhouse gas emissions.
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