Australia

Hydrogen embrittlement (HE) has been extensively studied in bulk materials. However little is known about the role of H on the plastic deformation and fracture mechanisms of nanoscale materials such as nanowires. In this study molecular dynamics simulations are employed to study the influence of H segregation on the behavior of intergranular cracks in bicrystalline α-Fe nanowires. The results demonstrate that segregated H atoms have weak embrittling effects on the predicted ductile cracks along the GBs but favor the cleavage process of intergranular cracks in the theoretically brittle directions. Furthermore it is revealed that cyclic loading can promote the H accumulation into the GB region ahead of the crack tip and overcome crack trapping thus inducing a ductile-to-brittle transformation. This information will deepen our understanding on the experimentally-observed H-assisted brittle cleavage failure and have implications for designing new nanocrystalline materials with high resistance to HE.

Electrocatalysts are capable of transforming water into hydrogen oxygen and therefore into energy in an environmentally friendly and sustainable manner. However the limitations in the research of high performance catalysts act as an obstructer in the development of using water as green energy. Here we report on a delicate method to prepare novel bimetallic metal organic framework derived electrocatalysts (C–NiCu–BDC–GO–CC) using graphene oxide (GO) modified carbon cloth as a 3D flexible and conductive substrate. The resultant electrocatalyst C–NiCu–BDC– GO–CC exhibited very low electron transfer resistance which benefited from its extremely thin 3D sponge-like morphology. Furthermore it showed excellent oxygen evolution reaction (OER) activity achieving 10 mA/cm2 at a low overpotential of 390 mV in 1 M KOH electrolyte with a remarkable durability of 10 h.

Where does hydrogen fit into a global sustainable energy strategy for the 21st century as we face the enormous challenges of irreversible climate change and uncertain oil supply? This fundamental question is addressed by sketching a sustainable energy strategy that is based predominantly on renewable energy inputs and energy efficiency with hydrogen playing a crucial and substantial role. But this role is not an ex -distributed hydrogen production storage and distribution centres relying on local renewable energy sources and feedstocks would be created to avoid the need for an expensive long-distance hydrogen pipeline system. There would thus be complementary use of electricity and hydrogen as energy vectors. Importantly bulk hydrogen storage would provide the strategic energy reserve to guarantee national and global energy security in a world relying increasingly on renewable energy; and longer-term seasonal storage on electricity grids relying mainly on renewables. In the transport sector a 'horses for courses' approach is proposed in which hydrogen fuel cell vehicles would be used in road and rail vehicles requiring a range comparable to today's petrol and diesel vehicles and in coastal and international shipping while liquid hydrogen would probably have to be used in air transport. Plug-in battery electric vehicles would be reserved for shorter-trips. Energy-economic-environmental modelling is recommended as the next step to quantify the net benefits of the overall strategy outlined.

Adoption of hydrogen energy as an alternative to fossil fuels could be a major step towards decarbonising and fulfilling the needs of the energy sector. Hydrogen can be an ideal alternative for many fields compared with other alternatives. However there are many potential environmental challenges that are not limited to production and distribution systems but they also focus on how hydrogen is used through fuel cells and combustion pathways. The use of hydrogen has received little attention in research and policy which may explain the widely claimed belief that nothing but water is released as a by-product when hydrogen energy is used. We adopt systems thinking and system dynamics approaches to construct a conceptual model for hydrogen energy with a special focus on the pathways of hydrogen use to assess the potential unintended consequences and possible interventions; to highlight the possible growth of hydrogen energy by 2050. The results indicate that the combustion pathway may increase the risk of the adoption of hydrogen as a combustion fuel as it produces NOx which is a key air pollutant that causes environmental deterioration which may limit the application of a combustion pathway if no intervention is made. The results indicate that the potential range of global hydrogen demand is rising ranging from 73 to 158 Mt in 2030 73 to 300 Mt in 2040 and 73 to 568 Mt in 2050 depending on the scenario presented.

Hydrogen has a very diverse chemistry and reacts with most other elements to form compounds which have fascinating structures compositions and properties. Complex metal hydrides are a rapidly expanding class of materials approaching multi-functionality in particular within the energy storage field. This review illustrates that complex metal hydrides may store hydrogen in the solid state act as novel battery materials both as electrolytes and electrode materials or store solar heat in a more efficient manner as compared to traditional heat storage materials. Furthermore it is highlighted how complex metal hydrides may act in an integrated setup with a fuel cell. This review focuses on the unique properties of light element complex metal hydrides mainly based on boron nitrogen and aluminum e.g. metal borohydrides and metal alanates. Our hope is that this review can provide new inspiration to solve the great challenge of our time: efficient conversion and large-scale storage of renewable energy.

This paper reports a new approach for exposing materials including solar cell structures to atomic hydrogen. This method is dubbed Shielded Hydrogen Passivation (SHP) and has a number of unique features offering high levels of atomic hydrogen at low temperature whilst inducing no damage. SHP uses a thin metallic layer in this work palladium between a hydrogen generating plasma and the sample which shields the silicon sample from damaging UV and energetic ions while releasing low energy neutral atomic hydrogen onto the sample. In this paper the importance of the preparation of the metallic shield either to remove a native oxide or to contaminate intentionally the surface are shown to be potential methods for increasing the amount of atomic hydrogen released. Excellent damage free surface passivation of thin oxides is observed by combining SHP and corona discharge obtaining minority carrier lifetimes of 2.2 ms and J0 values below 5.47 fA/cm2. This opens up a number of exciting opportunities for the passivation of advanced cell architectures such as passivated contacts and heterojunctions.

In this paper the hydrogen supply to an open-cathode PEM fuel cell (FC) by using metal hydride (MH) storage and thermal coupling between these two components are investigated theoretically. One of the challenges in using MH hydrogen storage canisters is their limited hydrogen supply rate as the hydrogen release from MH is an endothermic reaction. Therefore in order to meet the required hydrogen supply rate high amounts of MH should be employed that usually suggests storage of hydrogen to be higher than necessary for the application adding to the size weight and cost of the system. On the other hand the exhaust heat (i.e. that is usually wasted if not utilised for this purpose) from open-cathode FCs is a low-grade heat. However this heat can be transferred to MH canisters through convection to heat them up and increase their hydrogen release rate. A mathematical model is used to simulate the heat transfer between PEMFC exhaust heat and MH storage. This enables the prediction of the required MH for different FC power levels with and without heat supply to the MH storage. A 2.5-kW open-cathode FC is used to measure the exhaust air temperature at different output powers. It was found that in the absence of heat supply from the FC to the MH canisters significantly higher number of MH canisters are required to achieve the required rate of hydrogen supply to the FC for sustained operation (specially at high power outputs). However using the exhaust hot air from the FC to supply heat to the MH storage can reduce the number of the MH canisters required by around 40% to 70% for power output levels ranging from 500 W to 2000 W.

CCS is an emissions reduction technology critical to meeting global climate targets. The Global Status of CCS 2019 documents important milestones for CCS over the past 12 months its status across the world and the key opportunities and challenges it faces. We hope this report will be read and used by governments policy-makers academics media commentators and the millions of people who care about our climate.

Environmental issues related to global warming are constantly pushing the fossil fuel-based energy sector toward an efficient and economically viable utilization of renewable energy. However challenges related to renewable energy call for alternative routes of its conversion to fuels and chemicals by an emerging Power-to-X approach. Methane is one such high-valued fuel that can be produced through renewables-powered electrolytic routes. Such routes employ alkaline electrolyzers proton exchange membrane electrolyzers and solid oxide electrolyzers commonly known as solid oxide electrolysis cells (SOECs). SOECs have the potential to utilize the waste heat generated from exothermic methanation reactions to reduce the expensive electrical energy input required for electrolysis. A further advantage of an SOEC lies in its capacity to co-electrolyze both steam and carbon dioxide as opposed to only water and this inherent capability of an SOEC can be harnessed for in situ synthesis of methane within a single reactor. However the concept of in situ methanation in SOECs is still at a nascent stage and requires significant advancements in SOEC materials particularly in developing a cathode electrocatalyst that demonstrates activity toward both steam electrolysis and methanation reactions. Equally important is the appropriate reactor design along with optimization of cell operating conditions (temperature pressure and applied potential). This review elucidates those developments along with research and development opportunities in this space. Also presented here is an efficiency comparison of different routes of synthetic methane production using SOECs in various modes that is as a source of hydrogen syngas and hydrogen/carbon dioxide mixture and for in situ methane synthesis.

New vehicle technologies and fuels will drive the future of road transport in Australia. Increased availability of battery electric vehicles hydrogen fuel cell vehicles biofuels and associated recharging and refuelling infrastructure will:

• give consumers more choice
• provide productivity emissions reduction fuel security and air quality benefits

Our Future Fuels Strategy: Discussion Paper sets out the direction and practical actions to enable the private sector to commercially deploy low emissions road transport technologies at scale."

Hydrogen (H2) as a cleaner fuel has been suggested as a viable method of achieving the decarbonization objectives and meeting increasing global energy demand. However successful implementation of a full-scale hydrogen economy requires large-scale hydrogen storage (as hydrogen is highly compressible). A potential solution to this challenge is injecting hydrogen into geologic formations from where it can be withdrawn again at later stages for utilization purposes. The geostorage capacity of a porous formation is a function of its wetting characteristics which strongly influence residual saturations fluid flow rate of injection rate of withdrawal and containment security. However literature severely lacks information on hydrogen wettability in realistic geological and caprock formations which contain organic matter (due to the prevailing reducing atmosphere). We therefore measured advancing (θa) and receding (θr) contact angles of mica substrates at various representative thermo-physical conditions (pressures 0.1-25 MPa temperatures 308–343 K and stearic acid concentrations of 10−9 - 10−2 mol/L). The mica exhibited an increasing tendency to become weakly water-wet at higher temperatures lower pressures and very low stearic acid concentration. However it turned intermediate-wet at higher pressures lower temperatures and increasing stearic acid concentrations. The study suggests that the structural H2 trapping capacities in geological formations and sealing potentials of caprock highly depend on the specific thermo-physical condition. Thus this novel data provides a significant advancement in literature and will aid in the implementation of hydrogen geo-storage at an industrial scale.

The report documents current knowledge of the social issues surrounding hydrogen projects. It reviews leading practice stakeholder engagement and communication strategies and findings from focus groups and research activities across Australia.

The full report can be found at this link.

There is significant interest in Australia both federally and at the state level to develop a hydrogen production industry. Australia’s Chief Scientist Alan Finkel recently prepared a briefing paper for the COAG Energy Council outlining a road map for hydrogen. It identifies hydrogen has the potential to be a significant source of export revenue for Australia in future years assist with decarbonising Australia’s economy and could establish Australia as a leader in low emission fuel production.

As part of the ongoing investigations into the hydrogen production potential of Australia Geoscience Australia has been commissioned by the Department of Industry Innovation and Science to develop heat maps that show areas with high potential for future hydrogen production. The study is technology agnostic in that it considers hydrogen production via electrolysis using renewable energy sources and also fossil fuel hydrogen coupled with carbon capture and storage (CCS). The heat maps presented in this work are synthesized from the key individual national-scale datasets that are relevant for hydrogen production. In the case of hydrogen from electrolysis renewable energy potential and the availability of water are the most important factors with various infrastructural considerations playing a secondary role. In the case of fossil fuel hydrogen proximity to gas and coal resources water and availability of carbon storage sites are the important parameters that control the heat maps. In this report we present 5 different heat map scenarios reflecting different assumptions in the geospatial analysis and also reflecting to some degree the different projected timeframes for hydrogen production. The first three scenarios pertain to renewable energy and hydrogen There is significant interest in Australia both federally and at the state level to develop a hydrogen production industry. In August 2018 Australia’s Chief Scientist Dr Alan Finkel prepared a briefing paper for the COAG Energy Council outlining a road map for hydrogen. It identifies hydrogen has the potential to be a significant source of export revenue for Australia in future years assist with decarbonising Australia’s economy and could establish Australia as a leader in low emission fuel production.

As part of ongoing investigations into the hydrogen production potential of Australia Geoscience Australia has been engaged by the Department of Industry Innovation and Science to develop maps that show areas with high potential for future hydrogen production. The study is technology agnostic but considers only low carbon production processes. It includes hydrogen production via electrolysis using renewable energy sources (referred to as renewable hydrogen) as well as fossil fuel-derived hydrogen coupled with carbon capture and storage (CCS) (referred to as CCS hydrogen). The maps presented in this work are synthesized from the key individual national-scale datasets that are relevant for hydrogen production. In the case of hydrogen from electrolysis renewable energy potential (from wind solar and hydro resources) and the availability of water are the most important factors while various infrastructure considerations also play a role. In the case of CCS hydrogen proximity to gas and coal resources water and availability of carbon storage sites are the important parameters that control the spatial distribution of potential hydrogen production. In this report we present five different scenarios that reflect key differences in technologies for hydrogen production and the requirements of those technologies. Using geospatial analysis each scenario is translated into a heat map that shows regional trends in potential for hydrogen production based on access to underpinning resources and existing infrastructure.

Three scenarios explore the future potential for renewable hydrogen produced by electrolysis. These demonstrate a high potential for hydrogen production in the future near many Australian coastal areas which is even larger if infrastructure is available to transport renewable power generated from inland areas to the coast. Results also show significant future potential for hydrogen production in inland areas where water is available. The final two scenarios focus on the future potential for CCS hydrogen: a 2030 scenario and a 2050 scenario. A key factor in future CCS hydrogen potential is related to the timeframes for the availability of geological storage resources for CO_2.

Deloitte was commissioned by the National Hydrogen Taskforce established by the COAG Energy Council to undertake an Australian and Global Growth Scenario Analysis. Deloitte analysed the current global hydrogen industry its development and growth potential and how Australia can position itself to best capitalise on the newly forming industry.



To conceptualise the possibilities for Australia Deloitte created scenarios to model the realm of possibilities for Australia out to 2050 focusing on identifying the scope and distribution of economic and environmental costs and benefits from Australian hydrogen industry development. This work will aid in analysing the opportunities and challenges to hydrogen industry development in Australia and the actions needed to overcome barriers to industry growth manage risks and best drive industry development.



The full report is available on the Deloitte website at this link

Solar-driven electrolysis of water to generate hydrogen is emerging as a viable strategy to decarbonize the global energy economy. However this direction is more expensive than traditional fossil fuel generation of hydrogen and effective pathways to lower this cost need to be identified. Here we report a Monte Carlo approach to explore a wide range of input assumptions to identify key cost drivers targets and localized conditions necessary for competitive stand-alone dedicated PV powered hydrogen electrolysis. We determine the levelized cost of hydrogen (LCOH) considering historical weather data for specific locations to model our PV system and optimize its size compared to the electrolyzer. This analysis and its methods show the potential for green hydrogen production using off-grid PV shows the merits of remote systems in areas of high solar resource and provides cost and performance targets for electrolyzer technologies.

This paper presents a case study of using hydrogen for large-scale long-term storage application to support the current electricity generation mix of South Australia state in Australia which primarily includes gas wind and solar. For this purpose two cases of battery energy storage and hybrid battery-hydrogen storage systems to support solar and wind energy inputs were compared from a techno-economical point of view. Hybrid battery-hydrogen storage system was found to be more cost competitive with unit cost of electricity at $0.626/kWh (US dollar) compared to battery-only energy storage systems with a $2.68/kWh unit cost of electricity. This research also found that the excess stored hydrogen can be further utilised to generate extra electricity. Further utilisation of generated electricity can be incorporated to meet the load demand by either decreasing the base load supply from gas in the present scenario or exporting it to neighbouring states to enhance economic viability of the system. The use of excess stored hydrogen to generate extra electricity further reduced the cost to $0.494/kWh.

The storage of hydrogen is the key technology for a sustainable future. We developed an in silico procedure which is based on the combination of experimental and quantum-chemical methods. This method was used to evaluate energetic parameters for hydrogenation/dehydrogenation reactions of various pyrazine derivatives as a seminal liquid organic hydrogen carriers (LOHC) that are involved in the hydrogen storage technologies. With this in silico tool the tempo of the reliable search for suitable LOHC candidates will accelerate dramatically leading to the design and development of efficient materials for various niche applications.

Low-cost solar photovoltaics and wind offer a reliable and affordable pathway to deep decarbonization of energy which accounts for three quarters of global emissions. However large-scale deployment of solar photovoltaics and wind requires space and may be challenging for countries with dense population and high per capita energy consumption. This study investigates the future role of renewable energy in Japan as a case study. A 40-year hourly energy balance model is presented of a hypothetical 100% renewable Japanese electricity system using representative demand data and historical meteorological data. Pumped hydro energy storage high voltage interconnection and dispatchable capacity (existing hydro and biomass and hydrogen energy produced from curtailed electricity) are included to balance variable generation and demand. Differential evolution is used to find the least-cost solution under various constraints. This study shows that Japan has 14 times more solar and offshore wind resources than needed to supply 100% renewable electricity and vast capacity for off-river pumped hydro energy storage. Assuming significant cost reductions of solar photovoltaics and offshore wind towards global norms in the coming decades driven by large-scale deployment locally and global convergence of renewable generation costs the levelized cost of electricity is found to be US$86/Megawatt-hour for a solar-dominated system and US$110/Megawatt-hour for a wind-dominated system. These costs can be compared with 2020 average system prices on the spot market in Japan of US$102/Megawatt-hour. Cost of balancing 100% renewable electricity in Japan ranges between US$20–27/Megawatt-hour for a range of scenarios. In summary Japan can be self-sufficient for electricity supply at competitive costs provided that the barriers to the mass deployment of solar photovoltaics and offshore wind in Japan are overcome.

Owing to the high hydrogen content hydrocarbons are considered as an alternative source for hydrogen energy purposes. Complete decomposition of hydrocarbons results in the formation of gaseous hydrogen and solid carbonaceous by-product. The process is complicated by the methane formation reaction when the released hydrogen interacts with the formed carbon deposits. The present study is focused on the effects of the reaction mixture composition. Variations in the inlet hydrogen and methane concentrations were found to influence the carbon product’s morphology and the hydrogen production efficiency. The catalyst containing NiO (82 wt%) CuO (13 wt%) and Al2O3 (5 wt%) was prepared via a mechanochemical activating procedure. Kinetics of the catalytic process of hydrocarbons decomposition was studied using a reactor equipped with McBain balances. The effects of the process parameters were explored in a tubular quartz reactor with chromatographic analysis of the outlet gaseous products. In the latter case the catalyst was loaded piecemeal. The texture and morphology of the produced carbon deposits were investigated by nitrogen adsorption and electron microscopy techniques.

This paper proposes a novel hybrid marine renewable energy-harvesting system to increase energy production reduce levelized costs of energy and promote renewable marine energy. Firstly various marine renewable energy resources and state-of-art technologies for energy exploitation and storage were reviewed. The site selection criteria for each energy-harvesting approach were identified and a scoring matrix for site selection was proposed to screen suitable locations for the hybrid system. The Triton Knoll wind farm was used to demonstrate the effectiveness of the scoring matrix. An integrated energy system was designed and FE modeling was performed to assess the effects of additional energy devices on the structural stability of the main wind turbine structure. It has been proven that the additional energy structures have a negligible influence on foundation/structure deflection.

This discussion paper is for stakeholders who would like to shape the development of Victoria’s emerging green hydrogen sector identifying competitive advantages and priority focus areas for industry and the Victorian Government.<br/>The Victorian Government is using this paper to focus on the economic growth and sector development opportunities emerging for a Victorian hydrogen industry powered by renewable energy also known as ‘green’ hydrogen. In addition this paper seeks input from all stakeholders on how where and when the Victorian Government can act to establish a thriving green hydrogen economy.<br/>Although green hydrogen is the only type of hydrogen production within the scope of this discussion paper the development of the VHIP aligns with the policies projects and initiatives which support these other forms of hydrogen production. The VHIP is considering the broad policy landscape and actively coordinating with related hydrogen programs policies and strategies under development including the Council of Australian Governments (COAG) Energy Council’s National Hydrogen Strategy to ensure a complementary approach. In Victoria there are several programs and strategies in development and underway that have linkages with hydrogen and the VHIP.

Global energy sources are being transformed from hydrocarbon-based energy sources to renewable and carbon-free energy sources such as wind solar and hydrogen. The biggest challenge with hydrogen as a renewable energy carrier is the storage and delivery system’s complexity. Therefore other media such as ammonia for indirect storage are now being considered. Research has shown that at reasonable pressures ammonia is easily contained as a liquid. In this form energy density is approximately half of that of gasoline and ten times more than batteries. Ammonia can provide effective storage of renewable energy through its existing storage and distribution network. In this article we aimed to analyse the previous studies and the current research on the preparation of ammonia as a next-generation renewable energy carrier. The study focuses on technical advances emerging in ammonia synthesis technologies such as photocatalysis electrocatalysis and plasmacatalysis. Ammonia is now also strongly regarded as fuel in the transport industrial and power sectors and is relatively more versatile in reducing CO₂ emissions. Therefore the utilisation of ammonia as a renewable energy carrier plays a significant role in reducing GHG emissions. Finally the simplicity of ammonia processing transport and use makes it an appealing choice for the link between the development of renewable energy and demand.

The Hydrogen Strategy Group chaired by Australia’s Chief Scientist Dr Alan Finkel has today released a briefing paper on the potential domestic and export opportunities of a hydrogen industry in Australia.

Like natural gas hydrogen can be used to heat buildings and power vehicles. Unlike natural gas or petrol when hydrogen is burned there are no CO₂ emissions. The only by-products are water vapour and heat.

Hydrogen is the most abundant element in the universe not freely available as a gas on Earth but bound into many common substances including water and fossil fuels.

Hydrogen was first formally presented as a credible alternative energy source in the early 1970s but never proved competitive at scale as an energy source – until now. We find that the worldwide demand for hydrogen is set to increase substantially over coming decades driven by Japan’s decision to put imported hydrogen at the heart of its economy. Production costs are falling technologies are progressing and the push for non-nuclear low-emissions fuels is building momentum. We conclude that Australia is remarkably well-positioned to benefit from the growth of hydrogen industries and markets.

The use of hydrogen energy and the associated technologies is expected to increase in the coming years. The success of hydrogen energy technology (HET) is however dependent on public acceptance of the technology. Developing this new industry in a socially responsible way will require an understanding of the psychology factors that may facilitate or impede its public acceptance. This paper reviews 27 quantitative studies that have explored the relationship between psychological factors and HET acceptance. The findings from the review suggest that the perceived effects of the technology (i.e. the perceived benefits costs and risks) and the associated emotions are strong drivers of HET acceptance. This paper does though highlight some limitations with past research that make it difficult to make strong conclusions about the factors that influence HET acceptance. The review also reveals that few studies have investigated acceptance of different types of HET beyond a couple of applications. The paper ends with a discussion about directions for future research and highlights some practical implications for messaging and policy.

Replacement of precious catalyst with cost-effective alternatives would be significantly beneficial for hydrogen production via electrocatalytic hydrogen evolution reaction (HER). All candidates thus far are exclusively metallic catalysts which suffer inherent corrosion and oxidation susceptibility during acidic proton-exchange membrane electrolysis. Herein based on theoretical predictions we designed and synthesized nitrogen (N) and phosphorus (P) dual-doped graphene as a non-metallic electrocatalyst for sustainable and efficient hydrogen production. The N and Phetero-atoms could coactivate the adjacent C atom in the graphene matrix by affecting its valence orbital energy levels to induce a synergistically enhanced reactivity toward HER. As a result the dual-doped graphene showed higher electrocatalytic HER activity than single-doped ones and comparable performance to some of the traditional metallic catalysts.