Production & Supply Chain
Demonstration of Green Hydrogen Production Using Solar Energy at 28% Efficiency and Evaluation of its Economic Viability
Jan 2021
Publication
The solar to hydrogen (STH) efficiency of photovoltaic-electrolysis (PV-E) setups is a key parameter to lower the cost of green hydrogen produced. Commercial c-Si solar cells have neared saturation with respect to their efficiency which warrants the need to look at alternative technologies. In this work we report a concentrator photovoltaic-electrolysis (CPV-E) setup with a STH efficiency of 28% at 41 suns (without the use of Fresnel lenses) the highest reported efficiency using an alkaline system to date. Using this as a base case we carried out a detailed techno-economic (TEA) analysis which showed that despite the high cost associated with CPV cells the levelized cost of hydrogen (LCOH) is at $5.9 kg1 close to that from c-Si solar farms ($4.9 kg1 ) primarily due to the high STH efficiency. We also report sensitivity analysis of factors affecting both CPV and alkaline electrolyser systems such as the CPV module efficiency and installed capacity electrolyser stack lifetime operating current density and working hours. Our results indicate that in a scenario where the installed capacity of CPV technology matches that of silicon and with an electrolyser operating current density of 0.7 A cm2 the LCOH from CPV electrolysis systems can be.
High Proton-Conductive and Temperature-Tolerant PVC-P4VP Membranes towards Medium-Temperature Water Electrolysis
Mar 2022
Publication
Water electrolysis (WE) is a highly promising approach to producing clean hydrogen. Medium-temperature WE (100–350 ◦C) can improve the energy efficiency and utilize the low-grade water vapor. Therefore a high-temperature proton-conductive membrane is desirable to realize the medium-temperature WE. Here we present a polyvinyl chloride (PVC)-poly(4vinylpyridine) (P4VP) hybrid membrane by a simple cross-linking of PVC and P4VP. The pyridine groups of P4VP promote the loading rate of phosphoric acid which delivers the proton conductivity of the PVC-P4VP membrane. The optimized PVC-P4VP membrane with a 1:2 content ratio offers the maximum proton conductivity of 4.3 × 10−2 S cm−1 at 180 ◦C and a reliable conductivity stability in 200 h at 160 ◦C. The PVC-P4VP membrane electrode is covered by an IrO2 anode and a Pt/C cathode delivers not only the high water electrolytic reactivity at 100–180 ◦C but also the stable WE stability at 180 ◦C.
Far Off-shore Wind Energy-based Hydrogen Production: Technological Assessment and Market Valuation Designs
Jan 2020
Publication
This article provides a techno-economic study on coupled offshore wind farm and green hydrogen production via sea water electrolysis (OWF-H2). Offshore wind energy wind farms (OWF) and water electrolysis (WE) technologies are described. MHyWind (the tool used to perform simulations and optimisations of such plants) is presented as well as the models of the main components in the study. Three case studies focus on offshore wind farms either stand-alone or connected to the grid via export cables coupled with a battery and electrolysis systems either offshore or onshore. Exhaustive searches and optimisations performed allowed for rules of thumb to be derived on the sizing of coupled OWF-H2 plants that minimize costs of hydrogen production (LCoH2 in €/kgH2): Non-connected OWF-H2 coupled to a battery offers the lowest LCoH2 without the costs of H2 transportation when compared to cases where the WE is installed onshore and connected to the OWF. Using a simple power distribution heuristic increasing the number of installed WE allows the system to take advantage of more OWF energy but doesn’t improve plant efficiency whereas a battery always does. Finally within the scope of this study it is observed that power ratios of optimized plant architectures (leading to the lowest LCoH2) are between 0.8-0.9 for PWE/POWF and 0.3-0.35 for PBattery/POWF.
Techno-Economic Analysis of Low Carbon Hydrogen Production from Offshore Wind Using Battolyser Technology
Aug 2022
Publication
A battolyser is a combined battery electrolyser in one unit. It is based on flow battery technology and can be adapted to produce hydrogen at a lower efficiency than an electrolyser but without the need for rare and expensive materials. This paper presents a method of determining if a battolyser connected to a wind farm makes economic sense based on stochastic modelling. A range of cost data and operational scenarios are used to establish the impact on the NPV and LCOE of adding a battolyser to a wind farm. The results are compared to adding a battery or an electrolyser to a wind farm. Indications are that it makes economic sense to add a battolyser or battery to a wind farm to use any curtailed wind with calculated LCOE at £56/MWh to £58/MWh and positive NPV over a range of cost scenarios. However electrolysers are still too expensive to make economic sense.
HydroGenerally - Episode 1: The Colours of Hydrogen
Mar 2022
Publication
This first episode was inspired by an Innovate UK KTN perspective commenting on the UK government’s Hydrogen Strategy released by the Department of Business Energy and Industrial Strategy (BEIS) in August 2021. Following the publication of this perspective it was very evident to our Innovate UK KTN experts that the uses and challenges of ‘blue’ and ‘green’ hydrogens were generating a strong debate depending on their application areas.
Over a 20-minute discussion Simon Steffan and Sam try to answer the questions: how is hydrogen currently produced? How will it be produced in the future? And how will it fit in with the energy system?
The podcast can be found on their website
Over a 20-minute discussion Simon Steffan and Sam try to answer the questions: how is hydrogen currently produced? How will it be produced in the future? And how will it fit in with the energy system?
The podcast can be found on their website
Present and Projected Developments in Hydrogen Production: A Technological Review
Mar 2022
Publication
Energy supplies that are safe environmentally friendly dependable and cost-effective are important for society's long-term growth and improved living standards though political social and economic barriers may inhibit their availability. Constantly increasing energy demand is induced by substantial population growth and economic development putting an increasing strain on fossil fuel management and sustainability which account for a major portion of this rising energy demand and moreover creates difficulties because of greenhouse gas emissions growth and the depletion of resources. Such impediments necessitate a global shift away from traditional energy sources and toward renewables. Aside from its traditional role is viewed as a promising energy vector and is gaining international attention as a promising fuel path as it provides numerous benefits in use case scenarios and unlike other synthesized carbon-based fuels could be carbon-free or perhaps even negative on a life-cycle criterion. Hydrogen ( ) is one of the most significant chemical substances on earth and can be obtained as molecular dihydrogen through various techniques from both non-renewable and renewable sources. The drive of this paper is to deliver a technological overview of hydrogen production methods. The major challenges development and research priorities and potential prospects for production was discussed.
Advanced Catalysts for the Water Gas Shift Reaction
Apr 2022
Publication
The WGS reaction is an exothermic reaction between carbon monoxide and steam to form carbon dioxide and hydrogen. This reaction which has been used industrially for more than 100 years has recently received a great deal of attention from researchers as one of the ways to produce environmentally acceptable hydrogen from fossil fuels in large quantities. For the application of this reaction on an industrial scale the key is choosing the optimal catalysts that can ensure high CO conversion and have a long lifetime under industrial conditions. Therefore new types of catalysts are being developed that meet these requirements better than the Fe- and Cu-based catalysts commonly used in the past. The WGSR on a commercial nickel-based catalyst and a laboratory-prepared copper and cobalt-based catalyst was tested in a laboratory apparatus set up at the University of Chemistry and Technology Prague. The best performance of the laboratory-prepared catalyst was observed for the catalyst with a Cu content of 14.8 wt% and activated in a hydrogen atmosphere. The laboratory-prepared Co-based catalyst showed good WGSR activity in the temperature range of 200–450 ◦C although this was always inferior to that of the Cu-based catalyst. When subjected to the feed gas containing 0.4 mole% H2S the Co-based catalyst showed good resistance to sulphur poisoning. Therefore Co-based catalysts can be considered good sulphur-tolerant intermediate temperature WGSR catalysts.
Recent Development of Biomass Gasification for H2 Rich Gas Production
Mar 2022
Publication
Biomass gasification for hydrogen (H2) production provides outstanding advantages in terms of renewable energy resources carbon neutral high efficiency and environmental benefits. However the factors influencing H2 production from biomass gasification are complex which makes determining the optimal operating conditions challenging. Biomass gasification also poses challenges owing to the high associated tar content and low gas yield which need to be overcome. This review summarizes the influence of the gasification parameters on H2 production. Catalytic gasification technology and some of the latest catalysts such as composites and special structure catalysts are also summarized herein based on the requirements of high-purity H2 production. Moreover novel technologies such as staged gasification chemical looping gasification and adsorption-enhanced reforming for producing H2 rich gas are introduced. Finally the challenges and prospects associated with biomass gasification for H2 production are presented.
Electric-field-promoted Photo-electrochemical Production of Hydrogen from Water Splitting
Jul 2021
Publication
Given that conversion efficiencies of incident solar radiation to liquid fuels e.g. H2 are of the order of a few percent or less as quantified by ‘solar to hydrogen’ (STH) economically inexpensive and operationally straightforward ways to boost photo-electrochemcial (PEC) H2 production from solar-driven water splitting are important. In this work externally-applied static electric fields have led to enhanced H2 production in an energy-efficient manner with up to ~30–40% increase in H2 (bearing in mind fieldinput energy) in a prototype open-type solar cell featuring rutile/titania and hematite/iron-oxide (Fe2O3) respectively in contact with an alkaline aqueous medium (corresponding to respective relative increases of STH by ~12 and 16%). We have also performed non-equilibrium ab-initio molecular dynamics in both static electric and electromagnetic (e/m) fields for water in contact with a hematite/iron-oxide (0 0 1) surface observing enhanced break-up of water molecules by up to ~70% in the linear-response régime. We discuss the microscopic origin of such enhanced water-splitting based on experimental and simulation-based insights. In particular we external-field direction at the hematite surfaces and scrutinise properties of the adsorbed water molecules and OH– and H3O+ species e.g. hydrogen bonds between water-protons and the hematite surfaces’ bridging oxygen atoms as well as interactions between oxygen atoms in adsorbed water molecules and underlying iron atoms.
Energy Efficiency Based Control Strategy of a Three-Level Interleaved DC-DC Buck Converter Supplying a Proton Exchange Membrane Electrolyzer
Aug 2019
Publication
To face the intensive use of natural gas and other fossil fuels to generate hydrogen water electrolysis based on renewable energy sources (RES) seems to be a viable solution. Due to their fast response times and high efficiency proton exchange membrane electrolyzer (PEM EL) is the most suitable technology for long-term energy storage combined with RES. Like fuel cells the development of fit DC-DC converters is mandatory to interface the EL to the DC grid. Given that PEM EL operating voltages are quite low and to meet requirements in terms of output current ripples new emerging interleaved DC-DC converter topologies seem to be the best candidates. In this work a three-level interleaved DC-DC buck converter has been chosen to supply a PEM EL from a DC grid. Therefore the main objective of this paper is to develop a suitable control strategy of this interleaved topology connected to a PEM EL emulator. To design the control strategy investigations have been carried out on energy efficiency hydrogen flow rate and specific energy consumption. The obtained experimental results validate the performance of the converter in protecting the PEM EL during transient operations while guaranteeing correct specific energy consumption.
Parametric Study and Electrocatalyst of Polymer Electrolyte Membrane (PEM) Electrolysis Performance
Jan 2023
Publication
An investigation was conducted to determine the effects of operating parameters for various electrode types on hydrogen gas production through electrolysis as well as to evaluate the efficiency of the polymer electrolyte membrane (PEM) electrolyzer. Deionized (DI) water was fed to a single-cell PEM electrolyzer with an active area of 36 cm2 . Parameters such as power supply (50–500 mA/cm2 ) feed water flow rate (0.5–5 mL/min) water temperature (25−80 ◦C) and type of anode electrocatalyst (0.5 mg/cm2 PtC [60%] 1.5 mg/cm2 IrRuOx with 1.5 mg/cm2 PtB 3.0 mg/cm2 IrRuOx and 3.0 mg/cm2 PtB) were varied. The effects of these parameter changes were then analyzed in terms of the polarization curve hydrogen flowrate power consumption voltaic efficiency and energy efficiency. The best electrolysis performance was observed at a DI water feed flowrate of 2 mL/min and a cell temperature of 70 ◦C using a membrane electrode assembly that has a 3.0 mg/cm2 IrRuOx catalyst at the anode side. This improved performance of the PEM electrolyzer is due to the reduction in activation as well as ohmic losses. Furthermore the energy consumption was optimal when the current density was about 200 mA/cm2 with voltaic and energy efficiencies of 85% and 67.5% respectively. This result indicates low electrical energy consumption which can lower the operating cost and increase the performance of PEM electrolyzers. Therefore the optimal operating parameters are crucial to ensure the ideal performance and durability of the PEM electrolyzer as well as lower its operating costs.
Enabling Low-carbon Hydrogen Supply Chains Through Use of Biomass and Carbon Capture and Storage: A Swiss Case Study
Jul 2020
Publication
This study investigates the optimal design of low-carbon hydrogen supply chains on a national scale. We consider hydrogen production based on several feedstocks and energy sources namely water with electricity natural gas and biomass. When using natural gas we couple hydrogen production with carbon capture and storage. The design of the hydrogen biomass and carbon dioxide (CO2 ) infrastructure is performed by solving an optimization problem that determines the optimal selection size and location of the hydrogen production technologies and the optimal structure of the hydrogen biomass and CO2 O2 networks. First we investigate the rationale behind the optimal design of low-carbon hydrogen supply chains by referring to an idealized system configuration and by performing a parametric analysis of the most relevant design parameters of the supply chains such as biomass availability. This allows drawing general conclusions independent of any specific geographic features about the minimum-cost and minimum-emissions system designs and network structures. Moreover we analyze the Swiss case study to derive specific guidelines concerning the design of hydrogen supply chains deploying carbon capture and storage. We assess the impact of relevant design parameters such as location of CO2 storage facilities techno-economic features of CO2 capture technologies and network losses on the optimal supply chain design and on the competition between the hydrogen and CO2 networks. Findings highlight the fundamental role of biomass (when available) and of carbon capture and storage for decarbonizing hydrogen supply chains while transitioning to a wider deployment of renewable energy sources.
Editorial—Special Issue “Catalysis for Energy Production”
Jun 2021
Publication
The rapid increase in anthropogenic greenhouse gas concentrations in the last several decades means that the effects of climate change are fast becoming the familiar horsemen of a planetary apocalypse. Catalysis one of the pillars of the chemical and petrochemical industries will play a critical role in the effort to reduce the flow of greenhouse gases into the atmosphere. This Special Issue is timely as it provides a collection of high-quality manuscripts in a diverse range of topics which include the production of green hydrogen via water electrolysis the steam reforming of ethanol propane or glycerol the dry reforming of methane and the autothermal reforming of diesel surrogate fuel. The topic of the transformation of biomass waste to chemicals is also well represented as is the tackling of CO2 emissions via novel utilization technologies. The Editors are grateful to all authors for their valuable contributions and confident that this Special Issue will prove valuable to scholars university professors and students alike.
Overview of Biomass Conversion to Electricity and Hydrogen and Recent Developments in Low-Temperature Electrochemical Approaches
Nov 2020
Publication
Biomass is plant or animal material that stores both chemical and solar energies and that is widely used for heat production and various industrial processes. Biomass contains a large amount of the element hydrogen so it is an excellent source for hydrogen production. Therefore biomass is a sustainable source for electricity or hydrogen production. Although biomass power plants and reforming plants have been commercialized it remains a difficult challenge to develop more effective and economic technologies to further improve the conversion efficiency and reduce the environmental impacts in the conversion process. The use of biomass-based flow fuel cell technology to directly convert biomass to electricity and the use of electrolysis technology to convert biomass into hydrogen at a low temperature are two new research areas that have recently attracted interest. This paper first briefly introduces traditional technologies related to the conversion of biomass to electricity and hydrogen and then reviews the new developments in flow biomass fuel cells (FBFCs) and biomass electrolysis for hydrogen production (BEHP) in detail. Further challenges in these areas are discussed.
Catalyst Engineering for Electrochemical Energy Conversion from Water to Water: Water Electrolysis and the Hydrogen Fuel Cell
May 2020
Publication
In the context of the current serious problems related to energy demand and climate change substantial progress has been made in developing a sustainable energy system. Electrochemical hydrogen–water conversion is an ideal energy system that can produce fuels via sustainable fossil-free pathways. However the energy conversion efficiency of two functioning technologies in this energy system—namely water electrolysis and the fuel cell—still has great scope for improvement. This review analyzes the energy dissipation of water electrolysis and the fuel cell in the hydrogen–water energy system and discusses the key barriers in the hydrogen- and oxygen-involving reactions that occur on the catalyst surface. By means of the scaling relations between reactive intermediates and their apparent catalytic performance this article summarizes the frameworks of the catalytic activity trends providing insights into the design of highly active electrocatalysts for the involved reactions. A series of structural engineering methodologies (including nanoarchitecture facet engineering polymorph engineering amorphization defect engineering element doping interface engineering and alloying) and their applications based on catalytic performance are then introduced with an emphasis on the rational guidance from previous theoretical and experimental studies. The key scientific problems in the electrochemical hydrogen–water conversion system are outlined and future directions are proposed for developing advanced catalysts for technologies with high energy-conversion efficiency.
Self-Supported High-Entropy Alloy Electrocatalyst for Highly Efficient H2 Evolution in Acid Condition
Jul 2020
Publication
Developing non-precious catalysts as Pt substitutes for electrochemical hydrogen evolution reaction (HER) with superior stability in acidic electrolyte is of critical importance for large-scale low-cost hydrogen production from water. Herein we report a CoCrFeNiAl high-entropy alloy (HEA) electrocatalyst with self-supported structure synthesized by mechanical alloying and spark plasma sintering (SPS) consolidation. The HEA after HF treatment and in situ electrochemical activation for 4000 cycles of cyclic voltammetry (HF-HEAa2) presents favourable activity with overpotential of 73 mV to reach a current density of 10 mA cm−2 and a Tafel slope of 39.7 mV dec−1. The alloy effect of Al/Cr with Co/Fe/Ni at atomic level high-temperature crystallization as well as consolidation by SPS endow CoCrFeNiAl HEA with high stability in 0.5 M H2SO4 solution. The superior performance of HF-HEAa2 is related with the presence of metal hydroxides/oxides groups on HEA.
Dual Z-scheme Charge Transfer in TiO2–Ag–Cu2O Composite for Enhanced Photocatalytic Hydrogen Generation
Apr 2015
Publication
Photocatalytic hydrogen generation is one of the most promising solutions to convert solar power into green chemical energy. In this work a multi-component TiO2–Ag–Cu2O composite was obtained through simple impregnation-calcination of Cu2O and subsequent photodeposition of Ag onto electrospun TiO2 nanotubes. The resulting TiO2–Ag–Cu2O photocatalyst exhibits excellent photocatalytic H2 evolution activity due to the synergetic effect of Ag and Cu2O on electrospun TiO2nanotubes. A dual Z-scheme charge transfer pathway for photocatalytic reactions over TiO2–Ag–Cu2O composite was proposed and discussed. This work provides a prototype for designing Z-scheme photocatalyst with Ag as an electron mediator.
Modeling and Statistical Analysis of the Three-side Membrane Reactor for the Optimization of Hydrocarbon Production from CO2 Hydrogenation
Feb 2020
Publication
Direct CO2 hydrogenation to hydrocarbons is a promising method of reducing CO2 emissions along with producing value-added products. However reactor design and performance have remained a challenging issue because of low olefin efficiency and high water production as a by-product. Accordingly a one-dimensional non-isothermal mathematical model is proposed to predict the membrane reactor performance and statistical analysis is used to assess the effects of important variables such as temperatures of reactor (Tr:A) shell (Ts:B) and tube (Tt:C) as well as sweep ratio (θ:D) and pressure ratio (φ:E) and their interactions on the products yields. In addition the optimized operating conditions are also obtained to achieve maximum olefin yields. Results reveal that interacting effects comprising AB (TrTs) AC (TrTt) AE (Trφ) BC (TsTt) CE (Ttφ) CD (Ttθ) and DE (θφ) play important roles on the product yields. It is concluded that higher temperatures at low sweep and pressure ratios can maximize the yields of olefins while simultaneously the yields of paraffins are minimized. In this regard optimized values for Tr Ts Tt θ and φ are determined as 325 °C 306.96 °C 325 °C 1 and 1 respectively.
A Review on Recent Progress in the Integrated Green Hydrogen Production Processes
Feb 2022
Publication
The thermochemical water‐splitting method is a promising technology for efficiently con verting renewable thermal energy sources into green hydrogen. This technique is primarily based on recirculating an active material capable of experiencing multiple reduction‐oxidation (redox) steps through an integrated cycle to convert water into separate streams of hydrogen and oxygen. The thermochemical cycles are divided into two main categories according to their operating temperatures namely low‐temperature cycles (<1100 °C) and high‐temperature cycles (<1100 °C). The copper chlorine cycle offers relatively higher efficiency and lower costs for hydrogen production among the low‐temperature processes. In contrast the zinc oxide and ferrite cycles show great potential for developing large‐scale high‐temperature cycles. Although several challenges such as energy storage capacity durability cost‐effectiveness etc. should be addressed before scaling up these technologies into commercial plants for hydrogen production. This review critically examines various aspects of the most promising thermochemical water‐splitting cycles with a particular focus on their capabilities to produce green hydrogen with high performance redox pairs stability and the technology maturity and readiness for commercial use.
Modeling Photovoltaic-electrochemical Water Splitting Devices for the Production of Hydrogen Under Real Working Conditions
Jan 2022
Publication
Photoelectrochemical splitting of water is potentially a sustainable and affordable solution to produce hydrogen from sun light. Given the infancy stage of technology development it is important to compare the different experimental concepts and identify the most promising routes. The performance of photoelectrochemical devices is typically measured and reported under ideal irradiation conditions i.e. 1 sun. However real-life operating conditions are very different and are varying in time according to daily and seasonal cycles. In this work we present an equivalent circuit model for computing the steady state performance of photoelectrochemical cells. The model allows for a computationally efficient yet precise prediction of the system performance and a comparison of different devices working in real operating conditions. To this end five different photo-electrochemical devices are modeled using experimental results from literature. The calculated performance shows good agreement with experimental data of the different devices. Furthermore the model is extended to include the effect of illumination and tilt angle on the hydrogen production efficiency. The resulting model is used to compare the devices for different locations with high and low average illumination and different tilt angles. The results show that including real illumination data has a considerable impact on the efficiency of the PV-EC device. The yearly average solar-to-hydrogen efficiency is significantly lower than the ideal one. Moreover it is dependent on the tilt angle whose optimal value for European-like latitude is around 40. Notably we also show that the most performing device through the whole year might not necessarily be the one with highest sun-to-hydrogen efficiency for one-sun illumination.
Parametric Study of Pt/C-Catalysed Hydrothermal Decarboxylation of Butyric Acid as a Potential Route for Biopropane Production
Jun 2021
Publication
Sustainable fuel-range hydrocarbons can be produced via the catalytic decarboxylation of biomass-derived carboxylic acids without the need for hydrogen addition. In this present study 5 wt% platinum on carbon (Pt/C) has been found to be an effective catalyst for hydrothermally decarboxylating butyric acid in order to produce mainly propane and carbon dioxide. However optimisation of the reaction conditions is required to minimise secondary reactions and increase hydrocarbon selectivity towards propane. To do this reactions using the catalyst with varying parameters such as reaction temperatures residence times feedstock loading and bulk catalyst loading were carried out in a batch reactor. The highest yield of propane obtained was 47 wt% (close to the theoretical decarboxylation yield of 50 wt% on butyric acid basis) corresponding to a 96% hydrocarbon selectivity towards propane. The results showed that the optimum parameters to produce the highest yield of propane from the range investigated were 0.5 g butyric acid (0.57 M aqueous solution) 1.0 g Pt/C (50 mg Pt content) at 300 °C for 1 h. The reusability of the catalyst was also investigated which showed little or no loss of catalytic activity after four cycles. This work has shown that Pt/C is a suitable and potentially hydrothermally stable heterogeneous catalyst for making biopropane a major component of bioLPG from aqueous butyric acid solutions which can be sourced from bio-derived feedstocks via acetone-butanol-ethanol (ABE) fermentation.
Everything About Hydrogen Podcast: Is Small the Perfect Answer for SMRs?
Jun 2020
Publication
On this week’s episode the team discuss the appeal of modular reforming of biogas and natural gas with Mo Vargas from Bayotech. The company use a proprietary modular reformer technology to help provide low cost decentralise hydrogen production units for onsite demand at various scales using biogas waste gases and natural gas with carbon capture. With large scale steam methane reforming accounting for 95% of hydrogen production in major markets like the US and Europe today the team dive into the good the bad and the unusual considerations behind the growing international demand for modular methane reforming technologies and how Bayotech see the transition from a CO2 intensive process today to a net zero emission future. All this and more on the show!
The podcast can be found on their website
The podcast can be found on their website
Optimization of Geothermal- and Solar-driven Clean Electricity and Hydrogen Production Multi-generation Systems to Address the Energy Nexus
Jan 2022
Publication
Given the limited sources of fossil fuels mankind should find new ways to meet its energy demands. In this regard geothermal and solar energy are acknowledged as reliable safe promising and clean means for this purpose. In this research study a comparative analysis is applied on geothermal and solar-driven multi-generation systems for clean electricity and hydrogen production through energy and exergy assessments. The system consists of an organic Rankine cycle a proton electrolyte membrane electrolyzer and a thermoelectric generator subsystem. The Engineering Equation Solver software has been utilized in order to model the system and obtain the output contours sensitivity analysis and exergy destruction. The results were calculated considering the ambient temperature of Bandar Abbas city as a case study considering the geothermal system due to better performance in comparison to the solar system. According to the sensitivity analysis the turbine efficiency evaporator inlet temperature thermoelectric generator suitability criterion pump efficiency and evaporator inlet mass flow rate are the most influential parameters. Also the exergy analysis showed that the utmost system's exergy destruction is pertinent to the evaporator and the least is related to the pump. In addition the system produces 352816 kWh and 174.913 kg of electrical power and hydrogen during one year.
Everything About Hydrogen Podcast: Catching up on the State of Scale in PEM Electrolysis
Feb 2022
Publication
This episode of EAH is a chance for the team to catch up with one of our early guests on the show Graham Cooley - CEO of ITM Power. For the past twenty years ITM Power PLC has been designing and manufacturing electrolyser systems that generate hydrogen based on proton exchange membrane (PEM) technology. As the first hydrogen related company to be listed on the London Stock Exchange ITM are globally recognised experts in the field of electrolysis. In 2021 the company opened its first Gigafactory in Bessemer Park Sheffield: the world’s largest electrolyser production factory.
The podcast can be found on their website
The podcast can be found on their website
Everything About Hydrogen Podcast: Going "Green"
May 2021
Publication
Founded in 2007 and based in Denmark Green Hydrogen Systems designs and manufactures efficient standardized and modular electrolysers for the production of green hydrogen with renewable energy. Niels-Arne Baden has led the company to the upper echelons of the electrolysis sector and he now leads the company's strategy and and public-facing initiatives as the Vice President for Strategy and Public Affairs. On this episode of the Everything About Hydrogen podcast the EAH team sits down with Niels to talk about the journey of the clean hydrogen sector over the recent decades and its rise to prominence in the transition to a decarbonized energy future and how modular electrolysis fits into that picture.
The podcast can be found on their website
The podcast can be found on their website
Boosting the H2 Production Efficiency via Photocatalytic Organic Reforming: The Role of Additional Hole Scavenging System
Nov 2021
Publication
The simultaneous photocatalytic H2 evolution with environmental remediation over semiconducting metal oxides is a fascinating process for sustainable fuel production. However most of the previously reported photocatalytic reforming showed nonstoichiometric amounts of the evolved H2 when organic substrates were used. To explain the reasons for this phenomenon a careful analysis of the products and intermediates in gas and aqueous phases upon the photocatalytic hydrogen evolution from oxalic acid using Pt/TiO2 was performed. A quadrupole mass spectrometer (QMS) was used for the continuous flow monitoring of the evolved gases while high performance ion chromatography (HPIC) isotopic labeling and electron paramagnetic resonance (EPR) were employed to understand the reactions in the solution. The entire consumption of oxalic acid led to a ~30% lower H2 amount than theoretically expected. Due to the contribution of the photoKolbe reaction mechanism a tiny amount of formic acid was produced then disappeared shortly after the complete consumption of oxalic acid. Nevertheless a much lower concentration of formic acid was generated compared to the nonstoichiometric difference between the formed H2 and the consumed oxalic acid. Isotopic labeling measurements showed that the evolved H2 HD and/or D2 matched those of the solvent; however using D2O decreased the reaction rate. Interestingly the presence of KI as an additional hole scavenger with oxalic acid had a considerable impact on the reaction mechanism and thus the hydrogen yield as indicated by the QMS and the EPR measurements. The added KI promoted H2 evolution to reach the theoretically predictable amount and inhibited the formation of intermediates without affecting the oxalic acid degradation rate. The proposed mechanism by which KI boosts the photocatalytic performance is of great importance in enhancing the overall energy efficiency for hydrogen production via photocatalytic organic reforming.
Integration of a Dark Fermentation Effluent in a Microalgal-based Biorefinery for the Production of High-added Value Omega-3 Fatty Acids
Mar 2019
Publication
Dark fermentation is an anaerobic digestion process of biowaste used to produce hydrogen- for generation of energy- that however releases high amounts of polluting volatile fatty acids such as acetic acid in the environment. In order for this biohydrogen production process to become more competitive the volatile fatty acids stream can be utilized through conversion to high added-value metabolites such as omega-3 fatty acids. The docosahexaenoic acid is one of the two most known omega-3 fatty acids and has been found to be necessary for a healthy brain and proper cardiovascular function. The main source is currently fish which obtain the fatty acid from the primary producers microalgae through the food chain. Crypthecodinium cohnii a heterotrophic marine microalga is known for accumulating high amounts of docosahexaenoic acid while offering the advantage of assimilating various carbon sources such as glucose ethanol glycerol and acetic acid. The purpose of this work was to examine the ability of a C. cohnii strain to grow on different volatile fatty acids as well as on a pre-treated dark fermentation effluent and accumulate omega-3. The strain was found to grow well on relatively high concentrations of acetic butyric or propionic acid as main carbon source in a fed-batch pH-auxostat. Most importantly C. cohnii totally depleted the organic acid content of an ultra-filtrated dark fermentation effluent after 60 h of fed-batch cultivation therefore offering a bioprocess not only able to mitigate environmental pollutants but also to provide a solution for a sustainable energy production process. The accumulated docosahexaenoic acid content was as high as 29.8% (w/w) of total fatty acids.
Introducing Power-to-H3: Combining Renewable Electricity with Heat, Water and Hydrogen Production and Storage in a Neighbourhood
Oct 2019
Publication
In the transition from fossil to renewable energy the energy system should become clean while remaining reliable and affordable. Because of the intermittent nature of both renewable energy production and energy demand an integrated system approach is required that includes energy conversion and storage. We propose a concept for a neighbourhood where locally produced renewable energy is partly converted and stored in the form of heat and hydrogen accompanied by rainwater collection storage purification and use (Power-to-H3). A model is developed to create an energy balance and perform a techno-economic analysis including an analysis of the avoided costs within the concept. The results show that a solar park of 8.7 MWp combined with rainwater collection and solar panels on roofs can supply 900 houses over the year with heat (20 TJ) via an underground heat storage system as well as with almost half of their water demand (36000m3) and 540 hydrogen electric vehicles can be supplied with hydrogen (90 tonnes). The production costs for both hydrogen (8.7 €/kg) and heat (26 €/GJ) are below the current end user selling price in the Netherlands (10 €/kg and 34 €/GJ) making the system affordable. When taking avoided costs into account the prices could decrease with 20–26% while at the same time avoiding 3600 tonnes of CO2 a year. These results make clear that it is possible to provide a neighbourhood with all these different utilities completely based on solar power and rainwater in a reliable affordable and clean way.
Hydrogen Production by Water Electrolysis with Low Power and High Efficiency Based on Pre‐Magnetic Polarization
Mar 2022
Publication
In this paper a method of efficient hydrogen production using low‐power electrolysis based on pre‐magnetic polarization was proposed in order to improve the rate of hydrogen produc‐ tion by water electrolysis with reduced energy consumption molecular polarity and stress–strain characteristics of distilled water under the condition of a pre‐magnetic field. By constructing a mi‐ crophysical model of hydrogen proton energy‐level transition and a macroscopic mathematical model corresponding to magnetization vector‐polarization hydrogen proton concentration in the pre‐magnetic field the ionic conductivity electrolyte current density interelectrode voltage and hydrogen production efficiency under a varying magnetic field were qualitatively and quantita‐ tively analyzed. In addition an adjustable pre‐magnetic polarization hydrolyzing hydrogen pro‐ duction test platform was set up to verify the effectiveness of the proposed method. The repeated test results within a magnetic field strength range of 0–10000 GS showed that the conductivity of distilled water after pre‐magnetic polarization treatment increased by 2–3 times the electrolytic current density of the PEM (Proton Exchange Membrane) increased with increasing magnetic field strength the voltage between the poles continuously decreased and the hydrogen production rate was significantly improved. When the magnetic field strength reached 10000 GS the rate of hydro‐ gen production by the electrolysis of distilled water increased by 15%–20% within a certain period of time.
Finding Synergy Between Renewables and Coal: Flexible Power and Hydrogen Production from Advanced IGCC Plants with Integrated CO2 Capture
Feb 2021
Publication
Variable renewable energy (VRE) has seen rapid growth in recent years. However VRE deployment requires a fleet of dispatchable power plants to supply electricity during periods with limited wind and sunlight. These plants will operate at reduced utilization rates that pose serious economic challenges. To address this challenge this paper presents the techno-economic assessment of flexible power and hydrogen production from integrated gasification combined cycles (IGCC) employing the gas switching combustion (GSC) technology for CO2 capture and membrane assisted water gas shift (MAWGS) reactors for hydrogen production. Three GSC-MAWGS-IGCC plants are evaluated based on different gasification technologies: Shell High Temperature Winkler and GE. These advanced plants are compared to two benchmark IGCC plants one without and one with CO2 capture. All plants utilize state-of-the-art H-class gas turbines and hot gas clean-up for maximum efficiency. Under baseload operation the GSC plants returned CO2 avoidance costs in the range of 24.9–36.9 €/ton compared to 44.3 €/ton for the benchmark. However the major advantage of these plants is evident in the more realistic mid-load scenario. Due to the ability to keep operating and sell hydrogen to the market during times of abundant wind and sun the best GSC plants offer a 6–11%-point higher annual rate of return than the benchmark plant with CO2 capture. This large economic advantage shows that the flexible GSC plants are a promising option for balancing VRE provided a market for the generated clean hydrogen exists.
Comparative Analysis of Energy and Exergy Performance of Hydrogen Production Methods
Nov 2020
Publication
The study of the viability of hydrogen production as a sustainable energy source is a current challenge to satisfy the great world energy demand. There are several techniques to produce hydrogen either mature or under development. The election of the hydrogen production method will have a high impact on practical sustainability of the hydrogen economy. An important profile for the viability of a process is the calculation of energy and exergy efficiencies as well as their overall integration into the circular economy. To carry out theoretical energy and exergy analyses we have estimated proposed hydrogen production using different software (DWSIM and MATLAB) and reference conditions. The analysis consolidates methane reforming or auto-thermal reforming as the viable technologies at the present state of the art with reasonable energy and exergy efficiencies but pending on the impact of environmental constraints as CO2 emission countermeasures. However natural gas or electrolysis show very promising results and should be advanced in their technological and maturity scaling. Electrolysis shows a very good exergy efficiency due to the fact that electricity itself is a high exergy source. Pyrolysis exergy loses are mostly in the form of solid carbon material which has a very high integration potential into the hydrogen economy.
Global Status of CCS 2021: CCS Accelerating to Net Zero
Oct 2021
Publication
Carbon capture and storage (CCS) continues to make significant progress around the world against a backdrop of greater climate action from countries and private companies. The Global Status of CCS 2021 demonstrates the critical role of CCS as nations and industry accelerate to net-zero.<br/>The report provides detailed analyses of the global project pipeline international policy finance and emerging trends. In addition four regional overviews highlight the rapid development of CCS across North America Asia Pacific Europe and nearby regions and the Gulf Cooperation Council states.
Recent Application of Nanomaterials to Overcome Technological Challenges of Microbial Electrolysis Cells
Apr 2022
Publication
Microbial electrolysis cells (MECs) have attracted significant interest as sustainable green hydrogen production devices because they utilize the environmentally friendly biocatalytic oxidation of organic wastes and electrochemical proton reduction with the support of relatively lower external power compared to that used by water electrolysis. However the commercialization of MEC technology has stagnated owing to several critical technological challenges. Recently many attempts have been made to utilize nanomaterials in MECs owing to the unique physicochemical properties of nanomaterials originating from their extremely small size (at least <100 nm in one dimension). The extraordinary properties of nanomaterials have provided great clues to overcome the technological hurdles in MECs. Nanomaterials are believed to play a crucial role in the commercialization of MECs. Thus understanding the technological challenges of MECs the characteristics of nanomaterials and the employment of nanomaterials in MECs could be helpful in realizing commercial MEC technologies. Herein the critical challenges that need to be addressed for MECs are highlighted and then previous studies that used nanomaterials to overcome the technological difficulties of MECs are reviewed.
Economic Assessment of Clean Hydrogen Production from Fossil Fuels in the Intermountain-west Region, USA
Jan 2024
Publication
The transition from fossil fuels to carbon-neutral energy sources is necessary to reduce greenhouse gas (GHG) emissions and combat climate change. Hydrogen (H2) provides a promising path to harness fossil fuels to reduce emissions in sectors such as transportation. However regional economic analyses of various H2 production techniques are still lacking. We selected a well-known fossil fuel-exporting region the USA’s Intermountain-West (I-WEST) to analyze the carbon intensity of H2 production and demonstrate regional tradeoffs. Currently 78 % of global H2 production comes from natural gas and coal. Therefore we considered steam methane reforming (SMR) surface coal gasification (SCG) and underground coal gasification (UCG) as H2 production methods in this work. We developed the cost estimation frameworks of SMR SCG and UCG with and without carbon capture utilization and sequestration (CCUS). In addition we identified optimal sites for H2 hubs by considering the proximity to energy sources energy markets storage sites and CO2 sequestration sites. We included new production tax credits (PTCs) in the cost estimation to quantify the economic benefit of CCUS. Our results suggest that the UCG has the lowest levelized cost of H2 production due to the elimination of coal production cost. H2 production using the SMR process with 99 % carbon capture is profitable when the PTCs are considered. We also analyzed carbon utilization opportunities where CO2 conversion to formic acid is a promising profitable option. This work quantifies the potential of H2 production from fossil fuels in the I-WEST region a key parameter for designing energy transition pathways.
Critical Mineral Demands May Limit Scaling of Green Hydrogen Production
Jan 2024
Publication
Hydrogen (H2) is widely viewed as critical to the decarbonization of industry and transportation. Water electrolysis powered by renewable electricity commonly referred to as green H2 can be used to generate H2 with low carbon dioxide emissions. Herein we analyze the critical mineral and energy demands associated with green H2 production under three different hypothetical future demand scenarios ranging from 100–1000 Mtpa H2. For each scenario we calculate the critical mineral demands required to build water electrolyzers (i.e. electrodes and electrolyte) and to build dedicated or additional renewable electricity sources (i.e. wind and solar) to power the electrolyzers. Our analysis shows that scaling electrolyzer and renewable energy technologies that use platinum group metals and rare earth elements will likely face supply constraints. Specifically larger quantities of lanthanum yttrium or iridium will be needed to increase electrolyzer capacity and even more neodymium silicon zinc molybdenum aluminum and copper will be needed to build dedicated renewable electricity sources. We find that scaling green H2 production to meet projected netzero targets will require ~24000 TWh of dedicated renewable energy generation which is roughly the total amount of solar and wind projected to be on the grid in 2050 according to some energy transition models. In summary critical mineral constraints may hinder the scaling of green H2 to meet global net-zero emissions targets motivating the need for the research and development of alternative lowemission methods of generating H2
Large-Scale Hydrogen Production Systems Using Marine Renewable Energies: State-of-the-Art
Dec 2023
Publication
To achieve a more ecologically friendly energy transition by the year 2050 under the European “green” accord hydrogen has recently gained significant scientific interest due to its efficiency as an energy carrier. This paper focuses on large-scale hydrogen production systems based on marine renewable-energy-based wind turbines and tidal turbines. The paper reviews the different technologies of hydrogen production using water electrolyzers energy storage unit base hydrogen vectors and fuel cells (FC). The focus is on large-scale hydrogen production systems using marine renewable energies. This study compares electrolyzers energy storage units and FC technologies with the main factors considered being cost sustainability and efficiency. Furthermore a review of aging models of electrolyzers and FCs based on electrical circuit models is drawn from the literature and presented including characterization methods of the model components and the parameters extraction methods using a dynamic current profile. In addition industrial projects for producing hydrogen from renewable energies that have already been completed or are now in progress are examined. The paper is concluded through a summary of recent hydrogen production and energy storage advances as well as some applications. Perspectives on enhancing the sustainability and efficiency of hydrogen production systems are also proposed and discussed. This paper provides a review of behavioral aging models of electrolyzers and FCs when integrated into hydrogen production systems as this is crucial for their successful deployment in an ever-changing energy context. We also review the EU’s potential for renewable energy analysis. In summary this study provides valuable information for research and industry stakeholders aiming to promote a sustainable and environmentally friendly energy transition.
Offshore Green Hydrogen Production from Wind Energy: Critical Review and Perspective
Feb 2024
Publication
Hydrogen is envisaged to play a major role in decarbonizing our future energy systems. Hydrogen is ideal for storing renewable energy over longer durations strengthening energy security. It can be used to provide electricity renewable heat power long-haul transport shipping and aviation and in decarbonizing several industrial processes. The cost of green hydrogen produced from renewable via electrolysis is dominated by the cost of electricity used. Operating electrolyzers only during periods of low electricity prices will limit production capacity and underutilize high investment costs in electrolyzer plants. Hydrogen production from deep offshore wind energy is a promising solution to unlock affordable electrolytic hydrogen at scale. Deep offshore locations can result in an increased capacity factor of generated wind power to 60–70% 4–5 times that of onshore locations. Dedicated wind farms for electrolysis can use the majority >80% of the produced energy to generate economical hydrogen. In some scenarios hydrogen can be the optimal carrier to transport the generated energy onshore. This review discusses the opportunities and challenges in offshore hydrogen production using electrolysis from wind energy and seawater. This includes the impact of site selection size of the electrolyzer and direct use of seawater without deionization. The review compares overall electrolysis system efficiency cost and lifetime when operating with direct seawater feed and deionized water feed using reverse osmosis and flash evaporation systems. In the short to medium term it is advised to install a reverse osmosis plant with an ion exchanger to feed the electrolysis instead of using seawater directly.
An Estimation of Green Hydrogen Generation from Wind Energy: A Case Study from KSA
Sep 2023
Publication
Actually green hydrogen is viewed as a fundamental component in accelerating energy transition and empowering a sustainable future. The current study focuses on the estimation of green hydrogen generation by using wind energy via electrolysis in four sites located in Saudi Arabia. Results showed that the yearly amount of hydrogen that could be generated by using wind turbine ranges between 2542877 kg in Rafha and 3676925 kg in Dhahran. The hydrogen generated could be used to fuel vehicles and decrease the amount of GHG emission from vehicles in KSA. Also hydrogen may be used to store the excess of wind energy and to support the achievement of vision 2030 of the Kingdom. An economic assessment is carried out also in this paper. Results showed that the LCOH by using wind energy in KSA ranges from 2.82 $/kg to 3.81 $/kg.
Techno-economic Modelling of AEM Electrolysis Systems to Identify Ideal Current Density and Aspects Requiring Further Research
Aug 2023
Publication
Hydrogen produced by water electrolysis using renewable energy is a sustainable alternative to steam reformation. As a nascent commercial technology performance and economic comparisons of anion exchange membrane water electrolyzers (AEMWE) to other electrolyzer technology benchmarks are not available. We present a techno-economic model estimating AEMWE's baseline levelized cost of hydrogen (LCOH) at $5.79/kg considering trade-offs between current density efficiency stability capital and operating costs. The optimal current density is 1.38 A cm2 balancing stability and performance for the lowest LCOH. Using low-cost electricity and larger stack sizes AEMWE could achieve $2/kg low-carbon hydrogen. Technical improvements targeting system efficiency particularly reducing overpotentials in hydrogen and oxygen evolution reactions could further reduce LCOH to $1.29/kg approaching U.S. Department of Energy cost targets. There are hopes this model could raise the profile of AEMWE's economic potential to produce green hydrogen and highlight its suitability for decarbonizing the energy sector.
A Systematic Study on Techno-Economic Evaluation of Hydrogen Production
Sep 2023
Publication
This paper aims to perform a systematic review with a bibliometric approach of the technoeconomic evaluation studies of hydrogen production. To achieve this objective a comprehensive outline of hydrogen production processes from fossil and renewable sources is presented. The results reveal that electrolysis classified as water splitting is the most investigated process in the literature since it contributes to a reduction in greenhouse gas emissions and presents other advantages such as maturity and applicability energy efficiency flexibility and energy storage potential. In addition the processes of gasification classified as thermochemical and steam reforming classified as catalytic reforming are worth mentioning. Regarding the biological category there is a balance between research on photo fermentation and dark fermentation. The literature on the techno-economic evaluation of hydrogen production highlights significant gaps including a scarcity of comprehensive studies a lack of emphasis on commercial viability an absence of sensitivity analysis and the need for comparative analyses between production technologies.
Review on Bubble Dynamics in Proton Exchange Membrane Water Electrolysis: Towards Optimal Green Hydrogen Yield
Dec 2023
Publication
Water electrolysis using a proton exchange membrane (PEM) holds substantial promise to produce green hydrogen with zero carbon discharge. Although various techniques are available to produce hydrogen gas the water electrolysis process tends to be more cost-effective with greater advantages for energy storage devices. However one of the challenges associated with PEM water electrolysis is the accumulation of gas bubbles which can impair cell performance and result in lower hydrogen output. Achieving an in-depth knowledge of bubble dynamics during electrolysis is essential for optimal cell performance. This review paper discusses bubble behaviors measuring techniques and other aspects of bubble dynamics in PEM water electrolysis. It also examines bubble behavior under different operating conditions as well as the system geometry. The current review paper will further improve the understanding of bubble dynamics in PEM water electrolysis facilitating more competent inexpensive and feasible green hydrogen production.
A Review on the Environmental Performance of Various Hydrogen Production Technologies: An Approach Towards Hydrogen Economy
Nov 2023
Publication
Demand for hydrogen has grown and continues to rise as a versatile energy carrier. Hydrogen can be produced from renewable and non-renewable energy sources. A wide range of technologies to produce hydrogen in an environmentally friendly way have been developed. As the life cycle assessment (LCA) approach has become popular recently including in the hydrogen energy system this paper comprehensively reviews the LCA of hydrogen production technology. A subdivision based on the trends in the LCA studies hydrogen production technology goal and scope definition system boundary and environmental performance of hydrogen production is discussed in this review. Thermochemical hydrogen production is the most studied technology in LCA. However utilizing natural resources especially wind power in the electrolysis process stands out as an environmentally preferable solution when compared to alternative production processes. It is crucial to rethink reactors and other production-related equipment to improve environmental performance and increase hydrogen production efficiency. Since most of the previous LCA studies were conducted in developed countries and only a few were from developing countries a way forward for LCA application on hydrogen in developing countries was also highlighted and discussed. This review provides a comprehensive insight for further research on hydrogen production technology from an LCA perspective.
Carbon-negative Hydrogen Production (HyBECCS): An Exemplary Techno-economic and Environmental Assessment
Sep 2023
Publication
An exemplary techno-economic and environmental assessment of carbon-negative hydrogen (H2) production is carried out in this work. It is based on the so-called “dark photosynthesis” with carbon dioxide (CO2) capture and geological storage. As a special feature of the assessment the economic consequences due to the impact on the global climate are taken into account. The results indicate that the example project would be capable of generating negative GHG emissions under the assumptions made. The amount is estimated to be 17.72 kgCO2 to be removed from the atmosphere per kilogram of H2 produced. The levelized costs of carbon-negative hydrogen are obtained considering the economic impact of greenhouse gas emissions and removals. They are estimated to be 0.013 EUR/kWhH2. Compared to grey hydrogen from natural gas (0.12 EUR/kWhH2) and green hydrogen from electrolysis using renewable electricity (0.18 EUR/kWhH2) this shows a potential environmental-economic advantage of the considered example. Even without internalization of GHG impacts an economic advantage of the project (0.12 EUR/kWhH2) over green hydrogen (0.17 EUR/kWhH2) is indicated. Compared to other NETs the GHG removal efficiency is at the lower end of both BECCS and DACCS approaches.
Optimal Siting and Sizing of Hydrogen Production Modules in Distribution Networks with Photovoltaic Uncertainties
Nov 2023
Publication
Hydrogen production modules (HPMs) play a crucial role in harnessing abundant photovoltaic power by producing and supplying hydrogen to factories resulting in significant operational cost reductions and efficient utilization of the photovoltaic panel output. However the output of photovoltaic power is stochastic which will affect the revenue of investing in an HPM. This paper presents a comprehensive analysis of HPMs starting with the modeling of their operational process and investigating their influence on distribution system operations. Building upon these discussions a deterministic optimization model is established to address the corresponding challenges. Furthermore a two-stage stochastic planning model is proposed to determine optimal locations and sizes of HPMs in distribution systems accounting for uncertainties. The objective of the twostage stochastic planning model is to minimize the distribution system’s operational costs plus the investment costs of the HPM subject to power flow constraints. To tackle the stochastic nature of photovoltaic power a data-driven algorithm is introduced to cluster historical data into representative scenarios effectively reducing the planning model’s scale. To ensure an efficient solution a Benders’ decomposition-based algorithm is proposed which is an iterative method with a fast convergence speed. The proposed model and algorithms are validated using a widely utilized IEEE 33-bus system through numerical experiments demonstrating the optimality of the HPM plan generated by the algorithm. The proposed model and algorithms offer an effective approach for decision-makers in managing uncertainties and optimizing HPM deployment paving the way for sustainable and efficient energy solutions in distribution systems. Sensitivity analysis verifies the optimality of the HPM’s siting and sizing obtained by the proposed algorithm which also reveals immense economic and environmental benefits.
Energy Performance Assessment of a Solar-driven Thermochemical Cycle Device for Green Hydrogen Production
Sep 2023
Publication
This paper presents a novel dynamic simulation model for assessing the energy performance of solar-driven systems employed in green hydrogen production. The system consists of a parabolic dish collector that focuses solar radiation on two cerium-based thermochemical reactors. The model is based on a transient finitedifference method to simulate the thermal behaviour of the system and it integrates a theoretical analysis of materials and operating principles. Different empirical data were considered for experimentally validating it: a good agreement between experimental and simulated results was obtained for the temperatures calculated inside the thermochemical reactor (R2 = 0.99 MAPE = 6.3%) and the hourly flow rates of hydrogen oxygen and carbon monoxide (R2 = 0.96 MAPE = 10%) inside the thermochemical reactor. The model was implemented in a MatLab tool for the system dynamic analysis under different boundary conditions. Subsequently to explore the capability of this approach the developed tool was used for analysing the examined device operating in twelve different weather zones. The obtained results comprise heat maps of specific crucial instants and hourly dynamic trends showing redox reaction cycles occurring into the thermochemical reactors. The yearly hydrogen production ranges from 1.19 m3 /y to 1.64 m3 /y according to the hourly incident solar radiations outdoor air temperatures and wind speeds. New graphic tools for rapid feasibility studies are presented. The developed tools and the obtained results can be useful to the basic design of this technology and for the multi-objective optimization of its layout and main design/operating parameters.
Environmental and Material Criticality Assessment of Hydrogen Production via Anion Exchange Membrane Electrolysis
Oct 2023
Publication
The need to drastically reduce greenhouse gas emissions is driving the development of existing and new technologies to produce and use hydrogen. Anion exchange membrane electrolysis is one of these rapidly developing technologies and presents promising characteristics for efficient hydrogen production. However the environmental performance and the material criticality of anion exchange membrane electrolysis must be assessed. In this work prospective life cycle assessment and criticality assessment are applied first to identify environmental and material criticality hotspots within the production of anion exchange membrane electrolysis units and second to benchmark hydrogen production against proton exchange membrane electrolysis. From an environmental point of view the catalyst spraying process heavily dominates the ozone depletion impact category while the production of the membrane represents a hotspot in terms of the photochemical ozone formation potential. For the other categories the environmental impacts are distributed across different components. The comparison of hydrogen production via anion exchange membrane electrolysis and proton exchange membrane electrolysis shows that both technologies involve a similar life-cycle environmental profile due to similar efficiencies and the leading role of electricity generation for the operation of electrolysis. Despite the fact that for proton exchange membrane electrolysis much less material is required due to a higher lifetime anion exchange membrane electrolysis shows significantly lower raw material criticality since it does not rely on platinum-group metals. Overall a promising environmental and material criticality performance of anion exchange membrane electrolysis for hydrogen production is concluded subject to the expected technical progress for this technology.
Research on Hydrogen Production System Technology Based on Photovoltaic-Photothermal Coupling Electrolyzer
Dec 2023
Publication
Solar hydrogen production technology is a key technology for building a clean low-carbon safe and efficient energy system. At present the intermittency and volatility of renewable energy have caused a lot of “wind and light.” By combining renewable energy with electrolytic water technology to produce high-purity hydrogen and oxygen which can be converted into electricity the utilization rate of renewable energy can be effectively improved while helping to improve the solar hydrogen production system. This paper summarizes and analyzes the research status and development direction of solar hydrogen production technology from three aspects. Energy supply mode: the role of solar PV systems and PT systems in this technology is analyzed. System control: the key technology and system structure of different types of electrolytic cells are introduced in detail. System economy: the economy and improvement measures of electrolytic cells are analyzed from the perspectives of cost consumption efficiency and durability. Finally the development prospects of solar hydrogen production systems in China are summarized and anticipated. This article reviews the current research status of photovoltaic-photothermal coupled electrolysis cell systems fills the current research gap and provides theoretical reference for the further development of solar hydrogen production systems.
A Simulation Study on Evaluating the Influence of Impurities on Hydrogen Production in Geological Carbon Dioxide Storage
Sep 2023
Publication
In this study we examined the effect of CO2 injection into deep saline aquifers considering impurities present in blue hydrogen production. A fluid model was designed for reservoir conditions with impurity concentrations of 3.5 and 20%. The results showed that methane caused density decreases of 95.16 and 76.16% at 3.5 and 20% respectively whereas H2S caused decreases of 99.56 and 98.77% respectively. Viscosity decreased from 0.045 to 0.037 cp with increasing methane content up to 20%; however H2S did not affect the viscosity. Notably CO2 with H2S impacted these properties less than methane. Our simulation model was based on the Gorae-V properties and simulated injections for 10 years followed by 100 years of monitoring. Compared with the pure CO2 injection methane reached its maximum pressure after eight years and eleven months at 3.5% and eight years at 20% whereas H2S reached maximum pressure after nine years and two months and nine years and six months respectively. These timings affected the amount of CO2 injected. With methane as an impurity injection efficiency decreased up to 73.16% whereas with H2S it decreased up to 81.99% with increasing impurity concentration. The efficiency of CO2 storage in the dissolution and residual traps was analyzed to examine the impact of impurities. The residual trap efficiency consistently decreased with methane but increased with H2S. At 20% concentration the methane trap exhibited higher efficiency at the end of injection; however H2S had a higher efficiency at the monitoring endpoint. In carbon capture and storage projects methane impurities require removal whereas H2S may not necessitate desulfurization due to its minimal impact on CO2 storage efficiency. Thus the application of carbon capture and storage (CCS) to CO2 emissions containing H2S as an impurity may enable economically viable operations by reducing additional costs.
Review of Next Generation Hydrogen Production from Offshore Wind Using Water Electrolysis
Dec 2023
Publication
Hydrogen produced using renewable energy from offshore wind provides a versatile method of energy storage and power-to-gas concepts. However few dedicated floating offshore electrolyser facilities currently exist and therefore conditions of the offshore environment on hydrogen production cost and efficiency remain uncertain. Therefore this review focuses on the conversion of electrical energy to hydrogen using water electrolysis located in offshore areas. The challenges associated with the remote locations fluctuating power and harsh conditions are highlighted and recommendations for future electrolysis system designs are suggested. The latest research in polymer electrolyte membrane alkaline and membraneless electrolysis are evaluated in order to understand their capital costs efficiency and current research status for achieving scaled manufacturing to the GW scale required in the next three decades. Operating fundamentals that govern the performance of each device are investigated and future recommendations of research specifically for the integration of water electrolysers with offshore wind turbines is presented.
Renewable Energy Sources for Green Hydrogen Generation in Colombia and Applicable Case of Studies
Nov 2023
Publication
Electrification using renewable energy sources represents a clear path toward solving the current global energy crisis. In Colombia this challenge also involves the diversification of the electrical energy sources to overcome the historical dependence on hydropower. In this context green hydrogen represents a key energy carrier enabling the storage of renewable energy as well as directly powering industrial and transportation sectors. This work explores the realistic potential of the main renewable energy sources including solar photovoltaics (8172 GW) hydropower (56 GW) wind (68 GW) and biomass (14 GW). In addition a case study from abroad is presented demonstrating the feasibility of using each type of renewable energy to generate green hydrogen in the country. At the end an analysis of the most likely regions in the country and paths to deploy green hydrogen projects are presented favoring hydropower in the short term and solar in the long run. By 2050 this energy potential will enable reaching a levelized cost of hydrogen (LCOH) of 1.7 1.5 3.1 and 1.4 USD/kg-H2 for solar photovoltaic wind hydropower and biomass respectively.
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