Hydrogen Blending

The article reviews gas turbine combustion technologies focusing on their current ability to operate with hydrogen enriched natural gas up to 100% H2. The aim is to provide a picture of the most promising fuel-flexible and clean combustion technologies the object of current research and development. The use of hydrogen in the gas turbine power generation sector is initially motivated highlighting both its decarbonisation and electric grid stability objectives; moreover the state-of-the-art of hydrogen-blend gas turbines and their 2024 and 2030 targets are reported in terms of some key performance indicators. Then the changes in combustion characteristics due to the hydrogen enrichment of natural gas blends are briefly described from their enhanced reactivity to their pollutant emissions. Finally gas turbine combustion strategies both already commercially available (mostly based on aerodynamic flame stabilisation self-ignition and staging) or still under development (like the micro-mixing and the exhaust gas recirculation concepts) are described.

Britain’s Hydrogen Blending Delivery Plan which sets out how all five of Britain’s gas grid companies will meet the Government’s target for Britain’s network of gas pipes to be ready to deliver 20% hydrogen to homes and businesses from 2023 as a replacement for natural gas.

Operators of public electricity grids today are faced with the challenge of integrating increasing numbers of renewable and decentralized energy sources such as wind turbines and photovoltaic power plants into their grids. These sources produce electricity in a very inconstant manner due to the volatility of wind and solar power which further complicates power grid control and management. One key component that is required for modern energy infrastructures is the capacity to store large amounts of energy in an economically feasible way.<br/>One solution that is being discussed in this context is “power-to-gas” i.e. the use of surplus electricity to produce hydrogen (or even methane with an additional methanation process) which is then injected into the public natural gas grid. The huge storage capacity of the gas grid would serve as a buffer offering benefits with regards to sustainability and climate protection while also being cost-effective since the required infrastructure is already in place.<br/>One consequence would be however that the distributed natural gas could contain larger and fluctuating amounts of hydrogen. There is some uncertainty how different gas-fired applications and processes react to these changes. While there have already been several investigations for domestic appliances (generally finding that moderate amounts of H2 do not pose any safety risks which is the primary focus of domestic gas utilization) there are still open questions concerning large-scale industrial gas utilization. Here in addition to operational safety factors like efficiency pollutant emissions (NOX) process stability and of course product quality have to be taken into account.<br/>In a German research project Gas- und Wärme-Institut Essen e. V. (GWI) investigated the impact of higher and fluctuating hydrogen contents (up to 50 vol.-% much higher than what is currently envisioned) on a variety of industrial combustion systems using both numerical and experimental methods. The effects on operational aspects such as combustion behavior flame monitoring and pollutant emissions were analyzed.<br/>Some results of these investigations will be presented in this contribution.

The use of hydrogen as a non-emission energy carrier is important for the innovative development of the power-generation industry. Transmission pipelines are the most efficient and economic method of transporting large quantities of hydrogen in a number of variants. A comprehensive hydraulic analysis of hydrogen transmission at a mass flow rate of 0.3 to 3.0 kg/s (volume flow rates from 12000 Nm3/h to 120000 Nm3/h) was performed. The methodology was based on flow simulation in a pipeline for assumed boundary conditions as well as modeling of fluid thermodynamic parameters for pure hydrogen and its mixtures with methane. The assumed outlet pressure was 24 bar (g). The pipeline diameter and required inlet pressure were calculated for these parameters. The change in temperature was analyzed as a function of the pipeline length for a given real heat transfer model; the assumed temperatures were 5 and 25 ◦C. The impact of hydrogen on natural gas transmission is another important issue. The performed analysis revealed that the maximum participation of hydrogen in natural gas should not exceed 15%–20% or it has a negative impact on natural gas quality. In the case of a mixture of 85% methane and 15% hydrogen the required outlet pressure is 10% lower than for pure methane. The obtained results present various possibilities of pipeline transmission of hydrogen at large distances. Moreover the changes in basic thermodynamic parameters have been presented as a function of pipeline length for the adopted assumptions.

Hydrogen is of great significance for replacing fossil fuels and reducing carbon dioxide emissions. The application of hydrogen mixing with natural gas in gas network transportation not only improves the utilization rate of hydrogen energy but also reduces the cost of large-scale updating household or commercial appliance. This paper investigates the necessity of a gas mixing device for adding hydrogen to existing natural gas pipelines in the industrial gas network. A three-dimensional helical static mixer model is developed to simulate the mixing behavior of the gas mixture. In addition the model is validated with experimental results. Parametric studies are performed to investigate the effect of mixer on the mixing performance including the coefficient of variation (COV) and pressure loss. The research results show that based on the the optimum number of mixing units is three. The arrangement of the torsion angle of the mixing unit has a greater impact on the COV. When the torsion angle θ = 120◦ the COV has a minimum value of 0.66% and when the torsion angle θ = 60◦ the COV has a maximum value of 8.54%. The distance of the mixing unit has little effect on the pressure loss of the mixed gas but has a greater impact on the COV. Consecutive arrangement of the mixing units (Case A) is the best solution. Increasing the distance of the mixing unit is not effective for the gas mixing effect. Last but not least the gas mixer is optimized to improve the mixing performance.

In 2020 the European Commission launched a hydrogen strategy for a climate-neutral Europe setting out the conditions and actions for mainstreaming clean hydrogen along with targets for installing renewable hydrogen electrolysers by 2024 and 2030. Blending hydrogen alongside other gases into the existing gas grid is considered a possible interim first step towards decarbonising natural gas. In the present analysis we modelled electrolytic hydrogen generation as a process connecting two separate energy systems (power and gas). The analysis is based on a projection of the European power and gas systems to 2030 based on the EUCO3232.5 scenario. Multiple market configurations were introduced in order to assess the interplay between diverse power market arrangements and constraints imposed by the upper bound on hydrogen concentration. The study identifies the maximum electrolyser capacity that could be integrated in the power and gas systems the impact on greenhouse gas emissions and the level of price support that may be required for a broad range of electrolyser configurations. The study further attempts to shed some light on the potential side effects of having non-harmonised H2 blending thresholds between neighbouring Member States.

A thorough investigation of the thermodynamics and economic performance of a cogeneration system based on solid oxide fuel cells that provides heat and power to homes has been carried out in this study. Additionally different percentages of green hydrogen have been blended with natural gas to examine the techno-economic performance of the suggested cogeneration system. The energy and exergy efficiency of the system rises steadily as the hydrogen blending percentage rises from 0% to 20% then slightly drops at 50% H2 blending and then rises steadily again until 100% H2 supply. The system’s minimal levelised cost of energy was calculated to be 4.64 £/kWh for 100% H2. Artificial Neural Network (ANN) model was also used to further train a sizable quantity of data that was received from the simulation model. Heat power and levelised cost of energy estimates using the ANN model were found to be extremely accurate with coefficients of determination of 0.99918 0.99999 and 0.99888 respectively.

Blending hydrogen in existing natural gas pipelines compromises steel integrity because it increases fatigue crack growth promotes subcritical cracking and decreases fracture toughness. In this regard several laboratories reported that the fracture toughness measured in a hydrogen containing gaseous atmosphere KIH can be 50% or less than KIC the fracture toughness measured in air. From a pipeline integrity perspective fracture mechanics predicts that injecting hydrogen in a natural gas pipeline decreases the failure pressure and the size of the critical flaw at a given pressure level. For a pipeline with a given flaw size as shown in this work the effect of hydrogen embrittlement (HE) in the predicted failure pressure is largest when failure occurs by brittle fracture. The HE effect on failure pressure diminishes with a decreasing crack size or increasing fracture toughness. The safety margin after a successful hydrostatic test is reduced and therefore the time between hydrotests should be decreased. In this work all those effects were quantified using a crack assessment methodology (level 2 API 579-ASME FFS) considering literature values for KIH and KIC reported for an API 5L X52 pipeline steel. To characterize different scenarios various crack sizes were assumed including a small crack with a size close to the detection limit of current in-line inspection techniques and a larger crack that represents the largest crack size that could survive a hydrotest to 100% of the steel specified minimum yield stress. The implications of a smaller failure pressure and smaller critical crack size on pipeline integrity are discussed in this paper.

With the adjustment of energy structure the utilization of hydrogen energy has been widely attended. China’s carbon neutrality targets make it urgent to change traditional coal-fired power generation. The paper investigates the combustion of pulverized coal blended with hydrogen to reduce carbon emissions. In terms of calorific value the pulverized coal combustion with hydrogen at 1% 5% and 10% blending ratios is investigated. The results show that there is a significant reduction in CO2 concentration after hydrogen blending. The CO2 concentration (mole fraction) decreased from 15.6% to 13.6% for the 10% hydrogen blending condition compared to the non-hydrogen blending condition. The rapid combustion of hydrogen produces large amounts of heat in a short period which helps the ignition of pulverized coal. However as the proportion of hydrogen blending increases the production of large amounts of H2O gives an overall lower temperature. On the other hand the temperature distribution is more uniform. The concentrations of O2 and CO in the upper part of the furnace increased. The current air distribution pattern cannot satisfy the adequate combustion of the fuel after hydrogen blending.

Hydrogen energy represents a crucial pathway towards achieving carbon neutrality and is a pivotal facet of future strategic emerging industries. The safe and efficient transportation of hydrogen is a key link in the entire chain development of the hydrogen energy industry’s “production storage and transportation”. Mixing hydrogen into natural gas pipelines for transportation is the potential best way to achieve large-scale long-distance safe and efficient hydrogen transportation. Welds are identified as the vulnerable points in natural gas pipelines and compatibility between hydrogen-doped natural gas and existing pipeline welds is a critical technical challenge that affects the global-scale transportation of hydrogen energy. Therefore this article systematically discusses the construction and weld characteristics of hydrogen-doped natural gas pipelines the research status of hydrogen damage mechanism and mechanical property strengthening methods of hydrogen-doped natural gas pipeline welds and points out the future development direction of hydrogen damage mechanism research in hydrogen-doped natural gas pipeline welds. The research results show that: 1 Currently there is a need for comprehensive research on the degradation of mechanical properties in welds made from typical pipe materials on a global scale. It is imperative to systematically elucidate the mechanism of mechanical property degradation due to conventional and hydrogeninduced damage in welds of high-pressure hydrogen-doped natural gas pipelines worldwide. 2 The deterioration of mechanical properties in welds of hydrogen-doped natural gas pipelines is influenced by various components including hydrogen carbon dioxide and nitrogen. It is necessary to reveal the mechanism of mechanical property deterioration of pipeline welds under the joint participation of multiple damage mechanisms under multi-component gas conditions. 3 Establishing a fundamental database of mechanical properties for typical pipeline steel materials under hydrogen-doped natural gas conditions globally is imperative to form a method for strengthening the mechanical properties of typical high-pressure hydrogen-doped natural gas pipeline welds. 4 It is essential to promptly develop relevant standards for hydrogen blending transportation welding technology as well as weld evaluation testing and repair procedures for natural gas pipelines.