Applications & Pathways

Hydrogen energy is an important technical route to achieve carbon peak and carbon neutrality. Direct injection hydrogen engine is one of the ways of hydrogen energy application. It has the advantages of high thermal efficiency and limit/reduce abnormal combustion phenomena. In order to explore the cycle characteristics of direct injection hydrogen engine based on a 2.0L direct injection hydrogen engine an experimental study on the cycle characteristics of direct injection hydrogen engine was carried out. The experimental results show that cycle variation increases from 0.67% to 1.02% with the increasing of engine speed. The cycle variation decreases from 1.52% to 0.64% with the increasing of engine load. As the equivalence ratio increases the cycle variation first decreases significantly from 2.52% to 0.35% and then stabilizes. The ignition advance angle has a better angle to minimize the cycle variation. An experimental study on the influence of the start of injection on the cycle variation was carried out. As the engine speed/engine load is 2000rpm/4bar the cycle variation increases from 0.72% to 2.42% with the start of injection changing from -280°CA to -180°CA; then rapidly decreases to 0.99% and then increases to 2.26% with the start of injection changing from -180°CA to -100°CA. The experimental results show that SOI could cause significant influence on cycle variation because of intake valve closing and shortening mixing time and both the process of intake valve closing and lagging the SOI could cause the cycle variation to increase. The SOI remarkably affects the cycle variation at low engine load/equivalence ratio and high engine speed. This study lays the foundation for the follow-up research of hydrogen engine performance matching of the cycle variation.

Nowadays the combustion of fossil fuels for transportation has a major negative impact on the environment. All nations are concerned with environmental safety and the regulation of pollution motivating researchers across the world to find an alternate transportation fuel. The transition of the transportation sector towards sustainability for environmental safety can be achieved by the manifestation and commercialization of clean hydrogen fuel. Hydrogen fuel for sustainable mobility has its own effectiveness in terms of its generation and refueling processes. As the fuel requirement of vehicles cannot be anticipated because it depends on its utilization choosing hydrogen refueling and onboard generation can be a point of major concern. This review article describes the present status of hydrogen fuel utilization with a particular focus on the transportation industry. The advantages of onboard hydrogen generation and refueling hydrogen for internal combustion are discussed. In terms of performance affordability and lifetime onboard hydrogen-generating subsystems must compete with what automobile manufacturers and consumers have seen in modern vehicles to date. In internal combustion engines hydrogen has various benefits in terms of combustive properties but it needs a careful engine design to avoid anomalous combustion which is a major difficulty with hydrogen engines. Automobile makers and buyers will not invest in fuel cell technology until the technologies that make up the various components of a fuel cell automobile have advanced to acceptable levels of cost performance reliability durability and safety. Above all a substantial advancement in the fuel cell stack is required.

Owing to the complexity of the sector industrial activities are often represented with limited technological resolution in integrated energy system models. In this study we enriched the technological description of industrial activities in the integrated energy system analysis optimisation (IESA-Opt) model a peer-reviewed energy system optimisation model that can simultaneously provide optimal capacity planning for the hourly operation of all integrated sectors. We used this enriched model to analyse the industrial decarbonisation of the Netherlands for four key activities: high-value chemicals hydrocarbons ammonia and steel production. The analyses performed comprised 1) exploring optimality in a reference scenario; 2) exploring the feasibility and implications of four extreme industrial cases with different technological archetypes namely a bio-based industry a hydrogen-based industry a fully electrified industry and retrofitting of current assets into carbon capture utilisation and storage; and 3) performing sensitivity analyses on key topics such as imported biomass hydrogen and natural gas prices carbon storage potentials technological learning and the demand for olefins. The results of this study show that it is feasible for the energy system to have a fully bio-based hydrogen-based fully electrified and retrofitted industry to achieve full decarbonisation while allowing for an optimal technological mix to yield at least a 10% cheaper transition. We also show that owing to the high predominance of the fuel component in the levelled cost of industrial products substantial reductions in overnight investment costs of green technologies have a limited effect on their adoption. Finally we reveal that based on the current (2022) energy prices the energy transition is cost-effective and fossil fuels can be fully displaced from industry and the national mix by 2050

The overall ambition of the study has been to assess the commercial and operational viability of alternative marine fuels based on review existing academic and industry literature. The approach assesses how well six alternative fuels perform compared to LNG fuel on a set of 11 key parameters. Conventional fuels are not covered in this study however 2020 compliant fuels (HFO+scrubber and low sulphur fuels are included in the conclusion for comparative purposes.

The current research on green hydrogen can focus from the perspective of production but understanding the demand side is equally important to the initial creation of a hydrogen ecosystem in countries with low industrial activities that can utilise large amounts of hydrogen in the short term. Early movers in these countries must create a demand market in parallel with the green hydrogen plant commissioning. This paper presents research that explores the heavy-duty transport sector as a market-of-interest for early deployment of green hydrogen in Ireland. Conducting a survey-based market research amongst this sector indicate significant interest in hydrogen on the island of Ireland and the barriers the participants presented have been overcome in other jurisdictions. The study develops a model to estimate 1.) the annual hydrogen demand and 2.) the corresponding delivery cost to potential hydrogen consumers either directly or to central hydrogen fuelling hubs.

The increasing energy demand and the subsequent climate change consequences are supporting the search for sustainable alternatives to fossil fuels. In this scenario the link between hydrogen and renewable energy is playing a key role and unitized hydrogen-chlorine (H2-Cl2) regenerative cells (RFCs) have become promising candidates for renewable energy storage. Described herein are the recent advances in cell configurations and catalysts for the different reactions that may take place in these systems that work in both modes: electrolysis and fuel cell. It has been found that platinum (Pt)-based catalysts are the best choice for the electrode where hydrogen is involved whereas for the case of chlorine ruthenium (Ru)-based catalysts are the best candidates. Only a few studies were found where the catalysts had been tested in both modes and recent advances are focused on decreasing the amount of precious metals contained in the catalysts. Moreover the durability of the catalysts tested under realistic conditions has not been thoroughly assessed becoming a key and mandatory step to evaluate the commercial viability of the H2-Cl2 RFC technology.

Decarbonization of the steel industry is one of the pathways towards a fossil-fuel-free environment. The steel industry is one of the top contributors to greenhouse gas emissions. Most of these emissions are directly linked to the use of a fossil-fuelbased reductant. Replacing the fossil-based reductant with green H2 enables the transition towards a fossil-free steel industry. The carbon-free iron produced will cause the refining and steelmaking operations to have a starting point far from today’s operations. In addition to carbon being an alloying element in steel production carbon addition controls the melting characteristics of the reduced iron. In the present study the effect of carbon content and form (cementite/graphite) in hydrogen-reduced iron ore pellets on their melting characteristics was examined by means of a differential thermal analyser and optical dilatometer. Carburized samples with a carbon content < 2 wt % did not show any initial melting at the eutectic temperature. At and above 2 wt % the carburized samples showed an initial melting at the eutectic temperature irrespective of the carbon content. However the absorbed heat varies with varied carbon content. The carbon form does not affect the initial melting temperature but it affects the melting progression. Carburized samples melt homogenously while melting of iron-graphite mixtures occurs locally at the interface between iron and carbon particles and when the time is not long enough melting might not occur to any significant extent. Therefore at any given carbon content > 2 wt % the molten fraction is higher in the case of carburized samples which is indicated by the amount of absorbed melting heat.

The production of fat steel products is commonly linked to highly integrated sites which include hot metal generation via the blast furnace basic oxygen furnace (BOF) continuous casting and subsequent hot-rolling. In order to reach carbon neutrality a shift away from traditional carbon-based metallurgy is required within the next decades. Direct reduction (DR) plants are capable to support this transition and allow even a stepwise reduction in CO2 emissions. Nevertheless the implementation of these DR plants into integrated metallurgical plants includes various challenges. Besides metallurgy product quality and logistics special attention is given on future energy demand. On the basis of carbon footprint methodology (ISO 14067:2019) diferent scenarios of a stepwise transition are evaluated and values of possible CO2equivalent (CO2eq) reduction are coupled with the demand of hydrogen electricity natural gas and coal. While the traditional blast furnace—BOF route delivers a surplus of electricity in the range of 0.7 MJ/kg hot-rolled coil; this surplus turns into a defcit of about 17 MJ/ kg hot-rolled coil for a hydrogen-based direct reduction with an integrated electric melting unit. On the other hand while the product carbon footprint of the blast furnace-related production route is 2.1 kg CO2eq/kg hot-rolled coil; this footprint can be reduced to 0.76 kg CO2eq/kg hot-rolled coil for the hydrogen-related route provided that the electricity input is from renewable energies. Thereby the direct impact of the processes of the integrated site can even be reduced to 0.15 kg CO2eq/ kg hot-rolled coil. Yet if the electricity input has a carbon footprint of the current German or European electricity grid mix the respective carbon footprint of hot-rolled coil even increases up to 3.0 kg CO2eq/kg hot-rolled coil. This underlines the importance of the availability of renewable energies.

The present study enters in the context of reducing harmful emissions of the marine fleet by using three of the most promising alternative fuels namely methanol ammonia and hydrogen. These fuels are to be examined from the perspective of both the first and second laws of thermodynamics when employed in turbocharged and intercooled Homogeneous Charge Compression Ignition Engines (HCCI) under various values of ambient temperature and equivalence ratio. Results showed that the highest engine performance values favour using ammonia as fuel followed in order by hydrogen and methanol. Furthermore most of the exergy destruction rates (65.26% ammonia to 84.02% for hydrogen) of the exergy destruction rate occurring in the engine take place in the HCCI engine.

This paper discusses fuel cell electric vehicles and more specifically the challenges and development of hydrogen-fueled buses for people accessing this transportation in cities and urban environments. The study reveals the main innovations and challenges in the field of hydrogen bus deployment and identifies the most common approaches and errors in this area by extracting and critically appraising data from sources important to the energy perspective. Three aspects of the development and horizons of fuel cell electric buses are reviewed namely energy consumption energy efficiency and energy production. The first is associated with the need to ensure a useful and sustainable climate-neutral public transport. Herewith the properties of the hydrogen supply of electric buses and their benefits over gasoline gas and battery vehicles are discussed. The efficiency issue is related to the ratio of consumed and produced fuel in view of energy losses. Four types of engines–gasoline diesel gas and electrical–are evaluated in terms of well-to-wheel tank-to-wheel delivery and storage losses. The third problem arises from the production operating and disposal constraints of the society at the present juncture. Several future-oriented initiatives of the European Commission separate countries and companies are described. The study shows that the effectiveness of the FCEBs depends strongly on the energy generation used to produce hydrogen. In the countries where the renewables are the main energy sources the FCEBs are effective. In other regions they are not effective enough yet although the future horizons are quite broad.