Applications & Pathways

The Port of Rotterdam is an important industrial cluster comprising mainly oil refining chemical production and power generation. In 2016 the port’s industry accounted for 19% of the Netherlands’ total CO2 emissions. The Port of Rotterdam Authority is aware that the cluster is heavily exposed to future decarbonisation policies as most of its activities focus on trading handling converting and using fossil fuels. Based on a study for the Port Authority using a mixture of qualitative and quantitative methods our article explores three pathways whereby the port’s industry can maintain its strong position while significantly reducing its CO2 emissions and related risks by 2050. The pathways differ in terms of the EU’s assumed climate change mitigation ambitions and the key technological choices made by the cluster’s companies. The focus of the paper is on identifying key risks associated with each scenario and ways in which these could be mitigated.

In this paper we show for the first time the feasibility of ammonia exhaust gas reforming as a strategy for hydrogen production used in transportation. The application of the reforming process and the impact of the product on diesel combustion and emissions were evaluated. The research was started with an initial study of ammonia autothermal reforming (NH3 e ATR) that combined selective oxidation of ammonia (into nitrogen and water) and ammonia thermal decomposition over a ruthenium catalyst using air as the oxygen source. The air was later replaced by real diesel engine exhaust gas to provide the oxygen needed for the exothermic reactions to raise the temperature and promote the NH3 decomposition. The main parameters varied in the reforming experiments are O2/NH3 ratios NH3 concentration in feed gas and gas e hourly e space e velocity (GHSV). The O2/NH3 ratio and NH3 concentration were the key factors that dominated both the hydrogen production and the reforming process efficiencies: by applying an O2/NH3 ratio ranged from 0.04 to 0.175 2.5e3.2 l/min of gaseous H2 production was achieved using a fixed NH3 feed flow of 3 l/min. The reforming reactor products at different concentrations (H2 and unconverted NH3) were then added into a diesel engine intake. The addition of considerably small amount of carbon e free reformate i.e. represented by 5% of primary diesel replacement reduced quite effectively the engine carbon emissions including CO2 CO and total hydrocarbons.

Due to its high efficiency and reduced emissions new zero-emission hybrid electric vehicles have been selected as an attractive challenge for future transport applications. New zero -emission hybrid electric on the other hand has some major drawbacks from the complicated charging process. The hybrid electrical fuel cell system is introduced as the main source to intelligently control multi-source activities. An ultra-capacitor system is selected as the energy recovery assistance to monitor the fuel cell’s fast transient and peak power during critical periods. To regulate energy demand and supply an intelligent energy management system is proposed and tested through several constraints. The proposed approach system aims to act quickly against sudden circumstances related to hydrogen depletion in the prediction of the required fuel consumption basis. The proposed strategy tends to define the proper operating system according to energy demand and supply. The obtained results show that the designed system meets the targets set for the energy management unit by referring to an experimental velocity database.

In the present study Reynolds-Averaged Navier-Stokes simulations together with a novel flamelet generated manifold (FGM) hybrid combustion model incorporating preferential diffusion effects is utilised for the investigation of a hydrogen-blended diesel-hydrogen dual-fuel engine combustion process with high hydrogen energy share. The FGM hybrid combustion model was developed by coupling laminar flamelet databases obtained from diffusion flamelets and premixed flamelets. The model employed three control variables namely mixture fraction reaction progress variable and enthalpy. The preferential diffusion effects were included in the laminar flamelet calculations and in the diffusion terms in the transport equations of the control variables. The resulting model is then validated against an experimental diesel-hydrogen dual-fuel combustion engine. The results show that the FGM hybrid combustion model incorporating preferential diffusion effects in the flame chemistry and transport equations yields better predictions with good accuracy for the in-cylinder characteristics. The inclusion of preferential diffusion effects in the flame chemistry and transport equations was found to predict well several characteristics of the diesel-hydrogen dual-fuel combustion process: 1) ignition delay 2) start and end of combustion 3) faster flame propagation and quicker burning rate of hydrogen 4) high temperature combustion due to highly reactive nature of hydrogen radicals 5) peak values of the heat release rate due to high temperature combustion of the partially premixed pilot fuel spray with entrained hydrogen/air and then background hydrogen-air premixed mixture. The comparison between diesel-hydrogen dual-fuel combustion and diesel only combustion shows early start of combustion longer ignition delay time higher flame temperature and NOx emissions for dual-fuel combustion compared to diesel only combustion.

Ammonia (NH3) is among the largest-volume chemicals produced and distributed in the world and is mainly known for its use as a fertilizer in the agricultural sector. In recent years it has sparked interest in the possibility of working as a high-quality energy carrier and as a carbon-free fuel in internal combustion engines (ICEs). This review aimed to provide an overview of the research on the use of green ammonia as an alternative fuel for ICEs with a look to the future on possible applications and practical solutions to related problems. First of all the ammonia production process is discussed. Present ammonia production is not a “green” process; the synthesis occurs starting from gaseous hydrogen currently produced from hydrocarbons. Some ways to produce green ammonia are reviewed and discussed. Then the chemical and physical properties of ammonia as a fuel are described and explained in order to identify the main pros and cons of its use in combustion systems. Then the most viable solutions for fueling internal combustion engines with ammonia are discussed. When using pure ammonia high boost pressure and compression ratio are required to compensate for the low ammonia flame speed. In spark-ignition engines adding hydrogen to ammonia helps in speeding up the flame front propagation and stabilizing the combustion. In compression-ignition engines ammonia can be successfully used in dual-fuel mode with diesel. On the contrary an increase in NOx and the unburned NH3 at the exhaust require the installation of apposite aftertreatment systems. Therefore the use of ammonia seems to be more practicable for marine or stationary engine application where space constraints are not a problem. In conclusion this review points out that ammonia has excellent potential to play a significant role as a sustainable fuel for the future in both retrofitted and new engines. However significant further research and development activities are required before being able to consider large-scale industrial production of green ammonia. Moreover uncertainties remain about ammonia safe and effective use and some technical issues need to be addressed to overcome poor combustion properties for utilization as a direct substitute for standard fuels.

Alternative fuels are crucial to decarbonize the European maritime transport but their net climate benefits vary with the type of fuel and production country. In this study we assess the energy potential and climate change mitigation benefits of using agricultural and forest residues in different European countries for drop-in (Fast Pyrolysis Hydrothermal Liquefaction and Gasification to Fischer-Tropsch fuels or Bio-Synthetic Natural Gas) and hydrogen-based biofuels (hydrogen ammonia and methanol) with or without carbon capture and storage (CCS). Our results show the combinations of countries and biofuel options that successfully achieve the decarbonization targets set by the FuelEU Maritime initiative for the next years including a prospective analysis that include technological changes projected for the biofuel supply chains until 2050. With the current technologies the largest greenhouse gas (GHG) mitigation potential per year at a European scale is obtained with bio-synthetic natural gas and hydrothermal liquefaction. Among carbon-free biofuels ammonia currently has higher mitigation but hydrogen can achieve a lower GHG intensity per unit of energy with the projected decarbonization of the electricity mixes until 2050. The full deployment of CCS can further accelerate the decarbonization of the maritime sector. Choosing the most suitable renewable fuels requires a regional perspective and a transition roadmap where countries coordinate actions to meet ambitious climate targets.

To achieve future emission targets for internal combustion engines the use of hydrogen gas generated by renewable energy sources (known as “green” hydrogen) instead of fossil fuels plays a key role in the development of new combustion-based engine concepts. For new hydrogen engine generations there are different challenges concerning the injector layout and functionality. Especially when talking about direct hydrogen injection the key challenge is to ensure a proper mixing between hydrogen and the combustion air—the mixing of gas with a gas is not trivial as shown in this article. In terms of injector functionality it must be ensured that the requested amount of hydrogen gas needs to be provided in time and on the other hand accurately metered to provide an appropriate mixing formation quality inside the combustion chamber. This contribution discusses deep injector analysis techniques with pneumatic and optical approaches for an improved overall understanding of functionality and effects caused by operation with a gaseous fuel. A metering technique for gas flow characterization and for test simplification a comparison of hydrogen with helium and nitrogen as possible surrogate gases indicate that helium and nitrogen can act as a substitute for hydrogen in functional testing. Furthermore this contribution focuses on the usability of helium instead of hydrogen for the determination of spray properties. This is shown by the comparison of spray propagation images that were observed with the Schlieren technique in a pressure vessel proving comparable spray properties. In a next step the usage of spray-guiding devices to improve the global gas distribution during the injection period is discussed. Here it turns out that the volume increase does obviously not depend on the nozzle design. Thus the advantage of multi-hole guiding-devices is based on its flexible gas-jet orientation.

The concept of techno-economic pathways is used to investigate the potential implementation of CO2 abatement measures over time towards zero-emission steelmaking in Sweden. The following mitigation measures are investigated and combined in three pathways: top gas recycling blast furnace (TGRBF); carbon capture and storage (CCS); substitution of pulverized coal injection (PCI) with biomass; hydrogen direct reduction of iron ore (H-DR); and electric arc furnace (EAF) where fossil fuels are replaced with biomass. The results show that CCS in combination with biomass substitution in the blast furnace and a replacement primary steel production plant with EAF with biomass (Pathway 1) yield CO2 emission reductions of 83% in 2045 compared to CO2 emissions with current steel process configurations. Electrification of the primary steel production in terms of H-DR/EAF process (Pathway 2) could result in almost fossil-free steel production and Sweden could achieve a 10% reduction in total CO2 emissions. Finally (Pathway 3) we show that increased production of hot briquetted iron pellets (HBI) could lead to decarbonization of the steel industry outside Sweden assuming that the exported HBI will be converted via EAF and the receiving country has a decarbonized power sector.

Addressing the pressing challenge of global warming reducing greenhouse gas emissions in the transportation sector is a critical imperative. Battery and fuel cell electric vehicles have emerged as promising solutions for curbing emissions in this sector. In this study we conducted a comprehensive life cycle assessment (LCA) for typical passenger vehicles heavy-duty trucks and city buses using either proton-exchange membrane fuel cells or Li-ion batteries with different cell chemistries. To ensure accuracy we supplemented existing studies with data from the literature particularly for the recycling phase as database limitations were encountered. Our results highlight that fuel cell and battery systems exhibit large emissions in the production phase. Recycling can significantly offset some of these emissions but a comparison of the technologies examined revealed considerable differences. Overall battery electric vehicles consistently outperform fuel cell electric vehicles regarding absolute greenhouse gas emissions. Hence we recommend prioritizing battery electric over fuel cell vehicles. However deploying fuel cell electric vehicles could become attractive in a hydrogen economy scenario where other factors e. g. the conversion and storage of surplus renewable electricity via electrolysis become important.

Increasing sales of conventional fuel-based vehicles are leading to an increase in carbon emissions which are dangerous to the environment. To reduce these conventional fuel-based vehicles must be replaced with alternative fuel vehicles such as hydrogen-fueled. Hydrogen can fuel vehicles with near-zero greenhouse gas emissions. However to increase the penetration of such alternative fuel vehicles there needs to be adequate infrastructure specifically refueling infrastructure in place. This paper presents a comprehensive review of the different optimization strategies and methods used in the location of hydrogen refueling stations. The findings of the review in this paper show that there are various methods which can be used to optimally locate refueling stations the most popular being the p-median and flow-capture location models. It is also evident from the review that there are limited studies that consider location strategies of hydrogen refueling stations within a rural setting; most studies are focused on urban locations due to the high probability of penetration into these areas. Furthermore it is apparent that there is still a need to incorporate factors such as the safety elements of hydrogen refueling station construction and for risk assessments to provide more robust realistic solutions for the optimal location of hydrogen refueling stations. Hence the methods reviewed in this paper can be used and expanded upon to create useful and accurate models for a hydrogen refueling network. Furthermore this paper will assist future studies to achieve an understanding of the extant studies on hydrogen refueling station and their optimal location strategies.