Applications & Pathways
Solid Oxide Fuel Cell-Based Polygeneration Systems in Residential Applications: A Review of Technology, Energy Planning and Guidelines for Optimizing the Design
Oct 2022
Publication
Solid oxide fuel cells are an emerging energy conversion technology suitable for high-temperature power generation with proper auxiliary heat. Combining SOFCs and polygeneration has produced practical applications for modern energy system designs. Even though many researchers have reviewed these systems’ technologies opportunities and challenges reviews regarding the optimal strategy for designing and operating the systems are limited. Polygeneration is more complicated than any other energy generation type due to its ability to generate many types of energy from various prime movers. Moreover integration with other applications such as vehicle charging and fueling stations increases the complication in making the system optimally serve the loads. This study elaborates on the energy planning and guidelines for designing a polygeneration system especially for residential applications. The review of polygeneration technologies also aligns with the current research trend of developing green technology for modern and smart homes in residential areas. The proposed guideline is expected to solve the complication in other applications and technologies and design the polygeneration system optimally.
Hydrogen-rich Fuel Combustion Characteristics of a Counter Dual-swirl Combustor at Fixed Power
Nov 2021
Publication
In order to reduce the emission of carbon dioxide gas turbine power station will expect to use more clean fuels in the future especially those like hydrogen. Hydrogen-rich fuel(syngas) combustion characteristics of the novel counter dual-swirl gas turbine combustor under fixed calorific value input were studied by experiment and numerical simulation. PIV and temperature rake were used respectively to obtain the velocity and temperature distribution in the combustion chamber. The turbulence model of Reynolds stress and the kinetic model of detailed chemical syngas combustion were used simultaneously in the computational simulations. Based on the obtained results it was found that there is a reasonable agreement between the numerical results and the experimental data. The analysis shows that the flow field and temperature field of the combustor were almost unaffected by the change of hydrogen content and shows a nearly identical distribution structure under all conditions with hydrogen content below 90%; but when the H2 content reaches 90% the above characteristic plots were significantly changed. As the H2 content in the fuel increases on the center line of the combustor the jet velocity of the fuel decreased the temperature of the gas flow increased the recovery coefficient of total pressure decreased and the temperature distribution at the combustor outlet became more uniform. In addition it is also found that the syngas turbine with the same output power consumed less fuel than the gas turbine with hydrocarbon fuel. This paper provides reference for the study of hydrogen-rich syngas turbine and the application of hydrogen-rich fuel in combustor of energy system.
Charting a Course for Decarbonizing Maritime Transport
Apr 2021
Publication
As the backbone of global trade international maritime transport connects the world and facilitates economic growth and development especially in developing countries. However producing around three percent of global greenhouse gas (GHG) emissions and emitting around 15 percent of some of the world’s major air pollutants shipping is a major contributor to climate change and air pollution. To mitigate its negative environmental impact shipping needs to abandon fossil-based bunker fuels and turn to zero-carbon alternatives. This report the “Summary for Policymakers and Industry” summarizes recent World Bank research on decarbonizing the maritime sector. The analysis identifies green ammonia and hydrogen as the most promising zero-carbon bunker fuels within the maritime industry at present. These fuels strike the most advantageous balance of favorable features relating to their lifecycle GHG emissions broader environmental factors scalability economics and technical and safety implications. The analysis also identifies that LNG will likely only play a limited role in shipping’s energy transition due to concerns over methane slip and stranded assets. Crucially the research reveals that decarbonizing maritime transport offers unique business and development opportunities for developing countries. Developing countries with large renewable energy resources could take advantage of the new and emerging future zero-carbon bunker fuel market estimated at over $1 trillion to establish new export markets while also modernizing their own domestic energy and industrial infrastructure. However strategic policy interventions are needed to hasten the sector’s energy transition.
Low-Carbon Transition Pathway Planning of Regional Power Systems with Electricity-Hydrogen Synergy
Nov 2022
Publication
Hydrogen energy leads us in an important direction in the development of clean energy and the comprehensive utilization of hydrogen energy is crucial for the low-carbon transformation of the power sector. In this paper the demand for hydrogen energy in various fields is predicted based on the support vector regression algorithm which can be converted into an equivalent electrical load when it is all produced from water electrolysis. Then the investment costs of power generators and hydrogen energy equipment are forecast considering uncertainty. Furthermore a planning model is established with the forecast data initial installed capacity and targets for carbon emission reduction as inputs and the installed capacity as well as share of various power supply and annual carbon emissions as outputs. Taking Gansu Province of China as an example the changes of power supply structure and carbon emissions under different scenarios are analysed. It can be found that hydrogen production through water electrolysis powered by renewable energy can reduce carbon emissions but will increase the demand for renewable energy generators. Appropriate planning of hydrogen storage can reduce the overall investment cost and promote a low carbon transition of the power system
A Review on the Kinetics of Iron Ore Reduction by Hydrogen
Dec 2021
Publication
A clean energy revolution is occurring across the world. As iron and steelmaking have a tremendous impact on the amount of CO2 emissions there is an increasing attraction towards improving the green footprint of iron and steel production. Among reducing agents hydrogen has shown a great potential to be replaced with fossil fuels and to decarbonize the steelmaking processes. Although hydrogen is in great supply on earth extracting pure H2 from its compound is costly. Therefore it is crucial to calculate the partial pressure of H2 with the aid of reduction reaction kinetics to limit the costs. This review summarizes the studies of critical parameters to determine the kinetics of reduction. The variables considered were temperature iron ore type (magnetite hematite goethite) H2/CO ratio porosity flow rate the concentration of diluent (He Ar N2 ) gas utility annealing before reduction and pressure. In fact increasing temperature H2/CO ratio hydrogen flow rate and hematite percentage in feed leads to a higher reduction rate. In addition the controlling kinetics models and the impact of the mentioned parameters on them investigated and compared concluding chemical reaction at the interfaces and diffusion of hydrogen through the iron oxide particle are the most common kinetics controlling models.
A Review of Hydrogen Purification Technologies for Fuel Cell Vehicles
Mar 2021
Publication
Nowadays we face a series of global challenges including the growing depletion of fossil energy environmental pollution and global warming. The replacement of coal petroleum and natural gas by secondary energy resources is vital for sustainable development. Hydrogen (H2 ) energy is considered the ultimate energy in the 21st century because of its diverse sources cleanliness low carbon emission flexibility and high efficiency. H2 fuel cell vehicles are commonly the end-point application of H2 energy. Owing to their zero carbon emission they are gradually replacing traditional vehicles powered by fossil fuel. As the H2 fuel cell vehicle industry rapidly develops H2 fuel supply especially H2 quality attracts increasing attention. Compared with H2 for industrial use the H2 purity requirements for fuel cells are not high. Still the impurity content is strictly controlled since even a low amount of some impurities may irreversibly damage fuel cells’ performance and running life. This paper reviews different versions of current standards concerning H2 for fuel cell vehicles in China and abroad. Furthermore we analyze the causes and developing trends for the changes in these standards in detail. On the other hand according to characteristics of H2 for fuel cell vehicles standard H2 purification technologies such as pressure swing adsorption (PSA) membrane separation and metal hydride separation were analyzed and the latest research progress was reviewed.
The Effect of Hydrogen Addition on the Pollutant Emissions of a Marine Internal Combustion Engine Genset
Sep 2022
Publication
Hydrogen as a maritime fuel is one of the solutions that will assist the shipping sector in addressing the challenges regarding decarbonization taking into consideration the targets set for 2030 and 2050. The extensive utilization of hydrogen requires massive production of green hydrogen and the development of proper infrastructure to support a sustainable supply chain. An alternative solution is based on the on-board production of hydrogen where production units are installed on-board the vessel. Along these lines the HYMAR project aims to test the utilization of a hydrogen production unit for on-board use. The article deals with the use of hydrogen as a fuel for internal combustion engines taking into consideration reports from literature and the preliminary results of the HYMAR project focusing on the environmental impact and the reduction in emissions. Experimental investigation on a marine auxiliary engine for power generation under the HYMAR project leads to promising results regarding the environmental footprint of the internal combustion engine when hydrogen is added in the fuel mix with increasing percentages.
Decarbonization of the Steel Industry: A Techno-economic Analysis
Jan 2022
Publication
A substantial CO2-emmissions abatement from the steel sector seems to be a challenging task without support of so-called “breakthrough technologies” such as the hydrogen-based direct reduction process. The scope of this work is to evaluate both the potential for the implementation of green hydrogen generated via electrolysis in the direct reduction process as well as the constraints. The results for this process route are compared with both the well-established blast furnace route as well as the natural gas-based direct reduction which is considered as a bridge technology towards decarbonization as it already operates with H2 and CO as main reducing agents. The outcomes obtained from the operation of a 6-MW PEM electrolysis system installed as part of the H2FUTURE project provide a basis for this analysis. The CO2 reduction potential for the various routes together with an economic study are the main results of this analysis. Additionally the corresponding hydrogen- and electricity demands for large-scale adoption across Europe are presented in order to rate possible scenarios for the future of steelmaking towards a carbon-lean industry.
Decarbonising the Refinery Sector: A Socio-technical Analysis of Advanced Biofuels, Green Hydrogen and Carbon Capture and Storage Developments in Sweden
Nov 2021
Publication
The oil refinery industry is one of the major energy users and responsible for a large proportion of greenhouse gas (GHG) emissions. This sector is facing multiple sustainability-related transformation pressures forcing the industry to adapt to changing market conditions. The transition to a low-carbon economy will require oil refineries to adopt decarbonisation technologies like advanced biofuels green hydrogen and carbon capture and storage (CCS). However the development and implementation of these technologies is not a straightforward process and may be inhibited by lock-in and path dependency. This paper draws on expert interviews and combines the Technological Innovation Systems (TIS) and Multi-level Perspective (MLP) frameworks to examining the niche level development of three emerging technologies in the context of deep decarbonisation of refinery. This research finds that the development of the three decarbonisation technologies shares some of the challenges and opportunities and exhibits technology interdependency to some extent. Among the three TISs advanced biofuel is the most mature in terms of knowledge base actor-network legislation framework and market function. Green hydrogen and CCS encounter stronger momentum than before and can benefit from possible synergies across various sectors. However the analysis also reveals the lack of market formation mainly due to the lack of policy instruments for niche markets. Here policy recommendations for accelerating deep decarbonisation of the oil refinery industry are discussed. Finally we contribute to the sustainability transitions literature by exploring the dynamics of emerging TISs for industrial decarbonisation.
Research on the Hydrogen Consumption of Fuel Cell Electric Vehicles Based on the Flowmeter and Short-cut Method
Sep 2022
Publication
Energy consumption is essential for evaluating the competitiveness of fuel cell electric vehicles. A critical step in energy consumption measurement is measuring hydrogen consumption including the mass method the P/T method and the flowmeter method. The flowmeter method has always been a research focus because of its simple operation low cost and solid real-time performance. Current research has shown the accuracy of the flowmeter method under specific conditions. However many factors in the real scenario will influence the test result such as unintended vibration environment temperature and onboard hydrogen capacity calibration. On the other hand the short-cut method is also researched to replace the run-out method to improve test efficiency. To evaluate whether the flowmeter method basing on the short-cut method can genuinely reflect the hydrogen consumption of an actual vehicle we research and test for New European Driving Cycle (NEDC) and China Light-Duty Vehicle Test Cycle (CLTC) using the same vehicle. The results show that the short-cut method can save at least 50% of the test time compared with the run-out method. The error of the short-cut method based on the flowmeter for the NEDC working condition is less than 0.1% and for the CLTC working conditions is 8.12%. After adding a throttle valve and a 4L buffer tank the error is reduced to 4.76% from 8.12%. The test results show that hydrogen consumption measurement based on the flowmeter and short-cut method should adopt corresponding solutions according to the scenarios.
Environmental Life-Cycle Assessment of Eco-Friendly Alternative Ship Fuels (MGO, LNG, and Hydrogen) for 170 GT Nearshore Ferry
May 2022
Publication
With increasing concerns about environmental pollution the shipping industry has been considering various fuels as alternative power sources. This paper presents a study of the holistic environmental impacts of eco-friendly alternative ship fuels of marine gas oil (MGO) liquefied natural gas (LNG) and hydrogen across each of their life cycles from their production to the operation of the ship. The environmental impacts of the fuels were estimated by life-cycle assessment (LCA) analysis in the categories of well-to-tank tank-to-wake and well-to-wake phases. The LCA analysis was targeted for a 170 gross tonnage (GT) nearshore ferry operating in the ROK which was conceptually designed in the study to be equipped with the hydrogen fuel cell propulsion system. The environmental impact performance was presented with comparisons for the terms of global warming potential (GWP) acidification potential (AP) photochemical ozone creation potential (POCP) eutrophication potential (EP) and particulate matter (PM). The results showed that the hydrogen showed the highest GWP level during its life cycle due to the large amount of emissions in the hydrogen generation process through the steam methane reforming (SMR) method. The paper concludes with suggestions of an alternative fuel for the nearshore ferry and its production method based on the results of the study.
Techno-Economic Model for Scaling up of Hydrogen Refueling Stations
Oct 2022
Publication
In a recent publication the Hydrogen Council states that scaling up to greater production volumes leads to significant cost savings as a consequence of the industrialization of equipment manufacturing increased utilization standardization and improvements in system efficiency and flexibility. In this study a component-oriented techno-economic model is applied to five different European hydrogen refueling stations within the 3Emotion project which is planned to ensure capacities sufficient for increasing a fleet to 100 fuel cell buses. The investigation of the various cases shows that the levelized cost of hydrogen (LCOH) for large-scale applications will be in the range of about 4 €/kg to 7 €/kg within the boundaries analyzed. On-site production facilities were found to be the lower-cost design benefiting from the high volumes at stake and the economy of scale with respect to decentralized production due to the significant costs associated with retail hydrogen and transport. This study also illustrates the effects on the LCOH of varying the hydrogen delivery and production prices using a sensitivity analysis. The results show that by utilizing high-capacity trailers the costs associated with delivery could be reduced by 30%. Furthermore green hydrogen production could be a competitive solution if coupled with low electricity prices resulting in an LCOH between 4.21 €/kg and 6.80 €/kg.
Feasibility and Impact of a Swedish Fuel Cell-powered Rescue Boat
Jun 2021
Publication
With the increasing interest for zero-emission vehicles electric boats represent a growing area. Weight is a limiting factor for battery-powered boats therefore the use of fuel cell/battery systems is investigated. The present study examines the power requirements the energy-storage solutions and the sustainability assessment of a light and fast rescue boat operating in the Swedish lake Barken. A weight-optimized hybrid fuel cell/battery system is presented. The results show that if the hydrogen storage is wisely selected the weight of the hybrid system is significantly less than that of a battery system and can compete with an internal combustion engine system. The sustainability assessment highlights and compares the impact in terms of cost and emissions of the different energy storage solutions. The quantification of the emissions for the different energy systems under several scenarios shows a clear advantage for the electric solutions.
On the Way to Utilizing Green Hydrogen as an Energy Carrier—A Case of Northern Sweden
Mar 2024
Publication
Low or even zero carbon dioxide emissions will be an essential requirement for energy supplies in the near future. Besides transport and electricity generation industry is another large carbon emitter. Hydrogen produced by renewable energy provides a flexible way of utilizing that energy. Hydrogen as an energy carrier could be stored in a large capacity compared to electricity. In Sweden hydrogen will be used to replace coal for steel production. This paper discusses how the need for electricity to produce hydrogen will affect the electricity supply and power flow in the Swedish power grid and whether it will result in increased emissions in other regions. Data of the Swedish system will be used to study the feasibility of implementing the hydrogen system from the power system viewpoint and discuss the electricity price and emission issues caused by the hydrogen production in different scenarios. This paper concludes that the Swedish power grid is feasible for accommodating the additional electricity capacity requirement of producing green hydrogen for the steel industry. The obtained results could be references for decision makers investors and power system operators.
Assessment of Hydrogen Fuel for Rotorcraft Applications
Jun 2022
Publication
This paper presents the application of a multidisciplinary approach for the preliminary design and evaluation of the potential improvements in performance and environmental impact through the utilization of compressed (CGH2) and liquefied (LH2) hydrogen fuel for a civil tilt-rotor modelled after the NASA XV-15. The methodology deployed comprises models for rotorcraft flight dynamics engine performance flight path analysis hydrogen tank and thermal management system sizing. Trade-offs between gravimetric efficiency energy consumption fuel burn CO2 emissions and cost are quantified and compared to the kerosene-fuelled rotorcraft. The analysis carried out suggests that for these vehicle scales gravimetric efficiencies of the order of 13% and 30% can be attained for compressed and liquid hydrogen storage respectively leading to reduced range capability relative to the baseline tilt-rotor by at least 40%. At mission level it is shown that the hydrogen-fuelled configurations result in increased energy consumption by at least 12% (LH2) and 5% (CGH2) but at the same time significantly reduced life-cycle carbon emissions compared to the kerosene counterpart. Although LH2 storage at cryogenic conditions has a higher gravimetric efficiency than CGH2 (at 700 bar) it is shown that for this class of rotorcraft the latter is more energy efficient when the thermal management system for fuel pressurization and heating prior to combustion is accounted for.
Towards Deep Decarbonisation of Energy-Intensive Industries: A Review of Current Status, Technologies and Policies
Apr 2021
Publication
Industries account for about 30% of total final energy consumption worldwide and about 20% of global CO2 emissions. While transitions towards renewable energy have occurred in many parts of the world in the energy sectors the industrial sectors have been lagging behind. Decarbonising the energy-intensive industrial sectors is however important for mitigating emissions leading to climate change. This paper analyses various technological trajectories and key policies for decarbonising energy-intensive industries: steel mining and minerals cement pulp and paper and refinery. Electrification fuel switching to low carbon fuels together with technological breakthroughs such as fossil-free steel production and CCS are required to bring emissions from energy-intensive industry down to net-zero. A long-term credible carbon price support for technological development in various parts of the innovation chain policies for creating markets for low-carbon materials and the right condition for electrification and increased use of biofuels will be essential for a successful transition towards carbon neutrality. The study focuses on Sweden as a reference case as it is one of the most advanced countries in the decarbonisation of industries. The paper concludes that it may be technically feasible to deep decarbonise energy-intensive industries by 2045 given financial and political support.
Case Studies of Energy Storage with Fuel Cells and Batteries for Stationary and Mobile Applications
Mar 2017
Publication
In this paper hydrogen coupled with fuel cells and lithium-ion batteries are considered as alternative energy storage methods. Their application on a stationary system (i.e. energy storage for a family house) and a mobile system (i.e. an unmanned aerial vehicle) will be investigated. The stationary systems designed for off-grid applications were sized for photovoltaic energy production in the area of Turin Italy to provide daily energy of 10.25 kWh. The mobile systems to be used for high crane inspection were sized to have a flying range of 120 min one being equipped with a Li-ion battery and the other with a proton-exchange membrane fuel cell. The systems were compared from an economical point of view and a life cycle assessment was performed to identify the main contributors to the environmental impact. From a commercial point of view the fuel cell and the electrolyzer being niche products result in being more expensive with respect to the Li-ion batteries. On the other hand the life cycle assessment (LCA) results show the lower burdens of both technologies.
A Zero Carbon Route to the Supply of High-temperature Heat Through the Integration of Solid Oxide Electrolysis Cells and H2–O2 Combustion
Aug 2022
Publication
Previously suggested options to achieve carbon neutrality involve the use of fossil fuels with carbon capture or exploiting biomass as sources of energy. Industrial high-temperature heating could possibly exploit electrical heating or combustion using hydrogen. However it is difficult to replace all the current coal or natural gas furnaces with these options for chemical industry. In this work a method that integrates solid oxide electrolysis cells (SOEC) and H2–O2 combustion is proposed and the related parameters are modelled to analyze their impacts. There is no waste heat and waste emissions in the proposed option and all substances are recycled. Unlike previous research the heat required for SOEC operation is generated from H2 combustion. The best working condition is under thermoneutral voltage and the highest electricity-to-thermal efficiency that can be achieved is 86.88% under a current density of 12000 A/m2 and operating temperature of 750 ◦C. Ohmic overpotential has the greatest effect on electricity consumption and the anode activation overpotential is the second most important option. Increasing combustion product temperature cannot significantly improve thermal efficiency but can raise the available maximum thermal energy.
Multi-Time Scale Optimal Scheduling Model of Wind and Hydrogen Integrated Energy System Based on Carbon Trading
Jan 2023
Publication
In the context of carbon trading energy conservation and emissions reduction are the development directions of integrated energy systems. In order to meet the development requirements of energy conservation and emissions reduction in the power grid considering the different responses of the system in different time periods a wind-hydrogen integrated multi-time scale energy scheduling model was established to optimize the energy-consumption scheduling problem of the system. As the scheduling model is a multiobjective nonlinear problem the artificial fish swarm algorithm–shuffled frog leaping algorithm (AFS-SFLA) was used to solve the scheduling model to achieve system optimization. In the experimental test process the Griewank benchmark function and the Rosenbrock function were selected to test the performance of the proposed AFS-SFL algorithm. In the Griewank environment compared to the SFLA algorithm the AFS-SFL algorithm was able to find a feasible solution at an early stage and tended to converge after 110 iterations. The optimal solution was −4.83. In the test of total electric power deviation results at different time scales the maximum deviation of early dispatching was 14.58 MW and the minimum deviation was 0.56 MW. The overall deviation of real-time scheduling was the minimum and the minimum deviation was 0 and the maximum deviation was 1.89 WM. The integrated energy system adopted real-time scale dispatching with good system stability and low-energy consumption. Power system dispatching optimization belongs to the objective optimization problem. The artificial fish swarm algorithm and frog algorithm were innovatively combined to solve the dispatching model which improved the accuracy of power grid dispatching. The research content provides an effective reference for the efficient use of clean and renewable energy.
Performance Analysis of a Zero-Energy Building Using Photovoltaics and Hydrogen Storage
Mar 2023
Publication
The exploitation of renewable energy sources in the building sector is a challenging aspect of achieving sustainability. The incorporation of a proper storage unit is a vital issue for managing properly renewable electricity production and so to avoid the use of grid electricity. The present investigation examines a zero-energy residential building that uses photovoltaics for covering all its energy needs (heating cooling domestic hot water and appliances-lighting needs). The building uses a reversible heat pump and an electrical heater so there is not any need for fuel. The novel aspect of the present analysis lies in the utilization of hydrogen as the storage technology in a power-to-hydrogen-to-power design. The residual electricity production from the photovoltaics feeds an electrolyzer for hydrogen production which is stored in the proper tank under high pressure. When there is a need for electricity and the photovoltaics are not enough the hydrogen is used in a fuel cell for producing the needed electricity. The present work examines a building of 400 m2 floor area in Athens with total yearly electrical demand of 23656 kWh. It was found that the use of 203 m2 of photovoltaics with a hydrogen storage capacity of 34 m3 can make the building autonomous for the year period.
No more items...